b Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18013-18020DOI: 10.1039/D4DT02533D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. NolanDespite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17976-17988DOI: 10.1039/D4DT02355B, PaperThe Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang TranVarious 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17789-17793DOI: 10.1039/D4DT02791D, CommunicationGargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. SenThe reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17777-17782DOI: 10.1039/D4DT02766C, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. MeadeA Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02703E, PaperVilakkathala U. Krishnapriya, Cherumuttathu H. SureshDinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02838D, PaperYiwen Guan, Xian Xu, Xin XuAn FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02508C, PaperJustin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van StipdonkA series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
b Single-ion magnetism in novel Btp-based cobalt complexes of different charge By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02338B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez LópezBy deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
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