ac Wage theft? : what wage theft?! : exploitation of general and specialist cleaners working in retail chains for contracting or subcontracting cleaning companies / The Senate, Education and Employment References Committee By prospero.murdoch.edu.au Published On :: Australia. Parliament. Senate. Education and Employment References Committee, author, issuing body Full Article
ac General Manager's report into developments in making enterprise agreements under the Fair Work Act 2009 (Cth) 2015-2018 / Bernadette O'Neill, General Manager By prospero.murdoch.edu.au Published On :: O'Neill, Bernadette, author Full Article
ac General Manager's report into individual flexibility arrangements under s.653 of the Fair Work Act 2009 (Cth) 2015-2018 / Bernadette O'Neill, General Manager By prospero.murdoch.edu.au Published On :: O'Neill, Bernadette, author Full Article
ac General Manager's report into the operation of the provisions of the National Employment Standards relating to requests for flexible working arrangements and extensions of unpaid parental leave under s.653 of the Fair Work Act 2009 (Cth) 2015-2018 / By prospero.murdoch.edu.au Published On :: O'Neill, Bernadette Full Article
ac Jobactive : failing those it is intended to serve / The Senate, Education and Employment References Committee By prospero.murdoch.edu.au Published On :: Australia. Parliament. Senate. Education and Employment References Committee, author, issuing body Full Article
ac First report : Inquiry into Australia's aid program in the Indo-Pacific / Joint Standing Committee on Foreign Affairs, Defence and Trade By prospero.murdoch.edu.au Published On :: Australia. Parliament. Joint Standing Committee on Foreign Affairs, Defence and Trade, author, issuing body Full Article
ac Report 477 : Commonwealth financial statements - second report, and foreign investment in real estate : inquiries based on Auditor-General's Reports 24 and 48 (2017-18) / Joint Committee of Public Accounts and Audit By prospero.murdoch.edu.au Published On :: Australia. Parliament. Joint Committee of Public Accounts and Audit, author, issuing body Full Article
ac The global challenge of encouraging sustainable living : opportunities, barriers, policy and practice / edited by Shane Fudge, Michael A. Peters, Steven M. Hoffman, Walter Wehrmeyer By prospero.murdoch.edu.au Published On :: Full Article
ac Report 478 : issuing of a certificate under section 37 of the Auditor-General's Act 1997 : inquiry based on Auditor-General's Report No. 6 (2018–19) / Joint Committee of Public Accounts and Audit By prospero.murdoch.edu.au Published On :: Australia. Parliament. Joint Committee of Public Accounts and Audit, author, issuing body Full Article
ac Extraction empire : undermining the systems, states, & scales of Canada's global resource empire / edited by Pierre Bélanger By prospero.murdoch.edu.au Published On :: Full Article
ac The Case for Economic Democracy By www.wiley.com Published On :: 2020-04-13T04:00:00Z The idea that the people have a right to shape political decisions through democratic means is widely accepted. The same cannot be said of the decisions that impact on our everyday economic life in the workplace and beyond. Andrew Cumbers shows why this is wrong, and why, in the context of the rising tide of populism and the perceived crisis of liberal democracy, economic democracy's time has come. Four decades of market deregulation, financialisation Read More... Full Article
ac The Case for Economic Democracy By www.wiley.com Published On :: 2020-04-13T04:00:00Z The idea that the people have a right to shape political decisions through democratic means is widely accepted. The same cannot be said of the decisions that impact on our everyday economic life in the workplace and beyond. Andrew Cumbers shows why this is wrong, and why, in the context of the rising tide of populism and the perceived crisis of liberal democracy, economic democracy's time has come. Four decades of market deregulation, financialisation Read More... Full Article
ac Transferring Axial Molecular Chirality Through a Sequence of On-Surface Reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01653E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Néstor Merino-Díez, Mohammed S. G. Mohammed, Jesus Castro, Luciano Colazzo, Alejandro Berdonces-Layunta, James Lawrence, Jose Ignacio Pascual, Dimas G. de Oteyza, Diego PeñaFine management of chiral processes on solid surfaces has progressed over the years, yet still faces the need for the controlled and selective production of advanced chiral materials. Here, we...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Cascade polymerizations: recent developments in the formation of polymer repeat units by cascade reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01475C, Perspective Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gregory I. Peterson, Tae-Lim ChoiCascade polymerizations provide new routes to unique polymer structures. In this perspective, we summarize their performance, monomer scope, and mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Retrosynthetic strategies and their impact on synthesis of arcutane natural products By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01441A, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shelby V. McCowen, Nicolle A. Doering, Richmond SarpongDecisions, decisions, decisions: the interplay between different retrosynthetic strategies in the synthesis of the highly bridged, polycyclic arcutane natural products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00554A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chi Y. Cheng, Josh E. Campbell, Graeme M. DayEvolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00480D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi-Tsao Chen, Haw Yang, Jhih-Wei ChuThe mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Covalent Organic Frameworks as Microreactors: Confinement-enhanced Electrochemiluminescence By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01817A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wei-Jia Zeng, Kun Wang, Wenbin Liang, Yaqin Chai, Ruo Yuan, Ying ZhuoHerein, the electrochemiluminescence (ECL) microreactors with enhanced intensity and extreme stability were firstly established by the assembly of tris(2,2’-bipyridyl) ruthenium (II) (Ru(bpy)32+) onto the covalent organic frameworks (COFs) where a...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00676A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bryan Owens-Baird, Juliana P. S. Sousa, Yasmine Ziouani, Dmitri Y. Petrovykh, Nikolai A. Zarkevich, Duane D. Johnson, Yury V. Kolen'ko, Kirill KovnirThe effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide (m-NiP2).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01572E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj KumarBase-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01890B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Santosh K. Pagire, Naoya Kumagai, Masakatsu ShibasakiAn efficient cooperative chiral Lewis acid and photoredox catalytic system towards the highly enantioselective radical conjugate addition of α-amino radicals to α,β-unsaturated amides is developed with the implementation of unique auxiliaries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac A straightforward approach to antibodies recognising cancer specific glycopeptidic neoepitopes By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00317D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hajime Wakui, Yoshikazu Tanaka, Toyoyuki Ose, Isamu Matsumoto, Koji Kato, Yao Min, Taro Tachibana, Masaharu Sato, Kentaro Naruchi, Fayna Garcia Martin, Hiroshi Hinou, Shin-Ichiro NishimuraWe developed new class of designated antibodies targeting of “dynamic neoepitopes” elaborated by disease-specific O-glycosylation at the immunodominant mucin domains.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Dynamic reaction-induced phase separation in tunable, adaptive covalent networks By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00605J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Katie M. Herbert, Patrick T. Getty, Neil D. Dolinski, Jerald E. Hertzog, Derek de Jong, James H. Lettow, Joy Romulus, Jonathan W. Onorato, Elizabeth M. Foster, Stuart J. RowanDynamic covalent networks comprised of tunable thia-Michael bonds result in phase separated networks with tailorable mechanical and adaptive properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Metal-metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00646G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shubham Deolka, Orestes Rivada, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin, Julia R KhusnutdinovaWe report selective formation of heterobimetallic PtII/CuI complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Ring-Fused Cyclobutanes via Cycloisomerization of Alkylidenecyclopropane Acylsilanes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC02224A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Erick M Carreira, Sarah S Eichenberger, Moritz Hönig, Matthieu JR Richter, Renana Gershoni-PoranneA novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed. The readily available starting materials participate in tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes, which...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01534B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie ZhuQuantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01112F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matthias Müller, Antti J Karttunen, Magnus Richard BuchnerThe hexa-μ2-amido-tetraammine-tetraberyllium compounds [Be4(NH2)6(NH3)4]X2 (X = Cl, Br, I, CN, SCN, N3) have been prepared from beryllium metal and NH4X or [Be(NH3)4]X2 in liquid ammonia at ambient temperature. The obtained...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Biofunctional Janus Particles Promote Phagocytosis of Tumor Cells by Macrophages By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01146K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ya-Ru Zhang, Jia-Qi Luo, Jia-Xian Li, Qiu-Yue Huang, Xiao-Xiao Shi, Yong-Cong Huang, Kam W Leong, Weiling He, Jinzhi DuHerein, a versatile strategy for the construction of biofunctional Janus particles (JPs) through the combination of Pickering emulsion and copper-free click chemistry is developed for the study of particle-mediated cell-cell interactions. A...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4305-4311DOI: 10.1039/D0SC01159B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi OoiRadical–ion pair generation from common Lewis pairs and its application to catalytic carbon–carbon bond formation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Peculiar bond characters of fivefold coordinated octet compound crystals By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4340-4350DOI: 10.1039/D0SC00292E, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.An-An Sun, Shang-Peng Gao, Gong GuA refreshed view of chemical bonds in solids unveils unusual bonding in fivefold coordinated bulk crystals of octet compounds: out-of-plane cation–anion chain bonding via overlapping pz orbitals replaces in-plane π bonding of the isolated monolayer.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac An RGB-emitting molecular cocktail for the detection of bacterial fingerprints By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4403-4409DOI: 10.1039/D0SC01704C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sheng Hong, Di-Wei Zheng, Qiu-Ling Zhang, Wei-Wei Deng, Wen-Fang Song, Si-Xue Cheng, Zhi-Jun Sun, Xian-Zheng ZhangA technique named the Microcolor system was developed to detect microbes and diagnose diseases based on changes in microbiota signatures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Redox-inactive ions control the redox-activity of molecular vanadium oxides By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4450-4455DOI: 10.1039/D0SC01401J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Simon Greiner, Benjamin Schwarz, Mark Ringenberg, Maximilian Dürr, Ivana Ivanovic-Burmazovic, Maximilian Fichtner, Montaha Anjass, Carsten StrebThe enhanced redox-activity of a molecular vanadium oxide cluster upon functionalization with redox-inert Ca2+ ions is reported together with initial insights into its performance as a lithium ion battery cathode.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4397-4402DOI: 10.1039/D0SC00844C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong LiA novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4381-4390DOI: 10.1039/D0SC01026J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen NiemeyerSupramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4439-4443DOI: 10.1039/D0SC01289K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arunachalam Sagadevan, Anastasios Charitou, Fen Wang, Maria Ivanova, Martin Vuagnat, Michael F. GreaneyA ruthenium-catalyzed ortho C–H arylation process is described using visible light.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4488-4498DOI: 10.1039/D0SC00544D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-TejadaA fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4499-4507DOI: 10.1039/D0SC00135J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming HuMetal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Machine-enabled inverse design of inorganic solid materials: promises and challenges By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00594K, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juhwan Noh, Geun Ho Gu, Sungwon Kim, Yousung JungThe grand challenge of materials science, discovery of novel materials with target properties, can be greatly accelerated by machine-learned inverse design strategies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4475-4481DOI: 10.1039/D0SC01194K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-EwingShort-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4360-4373DOI: 10.1039/C9SC06272F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. GaffneyPhotoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Redox deracemization of β,γ-alkynyl α-amino esters By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4444-4449DOI: 10.1039/D0SC00944J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lu Zhang, Rongxiu Zhu, Aili Feng, Changyin Zhao, Lei Chen, Guidong Feng, Lei LiuA one-pot deracemization of β,γ-alkynyl α-amino esters consisting of an aerobic oxidation and chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation has been described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Functional group interaction profiles: a general treatment of solvent effects on non-covalent interactions By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4456-4466DOI: 10.1039/D0SC01288B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mark D. Driver, Mark J. Williamson, Joanne L. Cook, Christopher A. HunterFunctional group interaction profiles are a quantitative tool for predicting the effect of solvent on the free energy changes associated with non-covalent interactions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00002G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi NakanoStructural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01544J, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rebecca A. Olson, Angie B. Korpusik, Brent S. SumerlinLight-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC02020F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey StephensonHydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01025A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor AlabuginHow far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01290D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P CramerA diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00021C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Koichiro Masuda, Shū KobayashiA direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac Near-infrared light-activated membrane fusion for cancer cell therapeutic applications By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00863J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar WillnerThe spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ac The Role of Porphyrin Peripheral Substituents in Determining the Reactivities of Ferrous Nitrosyl Species By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01625J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sk Amanullah, Abhishek DeyFerrous nitrosyl {FeNO}7 species are intermediates common to the catalytic cycles of Cd1NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity vary dramatically in these enzymes. The former...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
