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Essentials of microeconomics / Bonnie Nguyen and Andrew Wait

Nguyen, Bonnie, author




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Monitoring the world economy, 1820-1992 / by Angus Maddison

Maddison, Angus




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The gifthorse : a critical look at equal employment opportunity in Australia / Gretchen Poiner and Sue Wills

Poiner, Gretchen




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You can't kill the spirit : women in a Welsh mining village / Jill Miller

Miller, Jill




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Invisible labor : hidden work in the contemporary world / edited by Marion G. Crain, Winifred R. Poster, Miriam A. Cherry




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Extraction empire : undermining the systems, states, & scales of Canada's global resource empire / edited by Pierre Bélanger




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A Companion to U.S. Foreign Relations: Colonial Era to the Present


 

Covers the entire range of the history of U.S. foreign relations from the colonial period to the beginning of the 21st century.

A Companion to U.S. Foreign Relations is an authoritative guide to past and present scholarship on the history of American diplomacy and foreign relations from its seventeenth century origins to the modern day. This two-volume reference work presents a collection of historiographical essays by prominent scholars. The essays



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Cascade polymerizations: recent developments in the formation of polymer repeat units by cascade reactions

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01475C, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gregory I. Peterson, Tae-Lim Choi
Cascade polymerizations provide new routes to unique polymer structures. In this perspective, we summarize their performance, monomer scope, and mechanisms.
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Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00554A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chi Y. Cheng, Josh E. Campbell, Graeme M. Day
Evolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.
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Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00480D, Edge Article
Open Access
Yi-Tsao Chen, Haw Yang, Jhih-Wei Chu
The mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.
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Aerosol-assisted route to low-E transparent conductive gallium-doped zinc oxide coatings from pre-organized and halogen-free precursor

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00502A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Clara Sanchez-Perez, Sebastian C. Dixon, Jawwad A. Darr, Ivan P. Parkin, Claire J. Carmalt
A pre-organised and halogen-free ZnO precursor is used to deposit GZO coatings via aerosol-assisted CVD with properties that exceed industrial standards for low-E coatings and photovoltaics.
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When Hollow Multi-Shelled Structures (HoMSs) Meet Metal-Organic Frameworks (MOFs)

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01284J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zumin Wang, Nailiang Yang, Dan Wang
Hollow multishelled structures (HoMSs) have distinguished advantages, such as large effective surface area, short mass transport route, and high loading capacity, but the fabrication of HoMS was a big challenge....
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Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01911A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech Pisula
The solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.
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Covalent Organic Frameworks as Microreactors: Confinement-enhanced Electrochemiluminescence

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01817A, Edge Article
Open Access
Wei-Jia Zeng, Kun Wang, Wenbin Liang, Yaqin Chai, Ruo Yuan, Ying Zhuo
Herein, the electrochemiluminescence (ECL) microreactors with enhanced intensity and extreme stability were firstly established by the assembly of tris(2,2’-bipyridyl) ruthenium (II) (Ru(bpy)32+) onto the covalent organic frameworks (COFs) where a...
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Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00676A, Edge Article
Open Access
Bryan Owens-Baird, Juliana P. S. Sousa, Yasmine Ziouani, Dmitri Y. Petrovykh, Nikolai A. Zarkevich, Duane D. Johnson, Yury V. Kolen'ko, Kirill Kovnir
The effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide (m-NiP2).
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Thermal effects – an alternative mechanism for plasmon-assisted photocatalysis

Chem. Sci., 2020, Advance Article
DOI: 10.1039/C9SC06480J, Edge Article
Open Access
Yonatan Dubi, Ieng Wai Un, Yonatan Sivan
A simple Arrhenius-based theory of heating, rather than “hot electrons”, can reproduce some high-profile photocatalysis experimental results to remarkable accuracy. Flaws in temperature measurement may have led to wrong conclusions.
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Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01572E, Edge Article
Open Access
Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj Kumar
Base-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.
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A straightforward approach to antibodies recognising cancer specific glycopeptidic neoepitopes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00317D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajime Wakui, Yoshikazu Tanaka, Toyoyuki Ose, Isamu Matsumoto, Koji Kato, Yao Min, Taro Tachibana, Masaharu Sato, Kentaro Naruchi, Fayna Garcia Martin, Hiroshi Hinou, Shin-Ichiro Nishimura
We developed new class of designated antibodies targeting of “dynamic neoepitopes” elaborated by disease-specific O-glycosylation at the immunodominant mucin domains.
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Molecular recognition of pyrazine N,N'-dioxide using aryl extended calix[4]pyrroles

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01496F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chenxing Guo, Hu Wang, Vincent M. Lynch, Xiaofan Ji, Zachariah A. Page, Jonathan L. Sessler
The molecular recognition of pyrazine N,N'-dioxide by aryl extended 'two-walled' calix[4]pyrrole-based receptors is seen to stabilise two different binding modes in the solid state.
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Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00997K, Edge Article
Open Access
Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don Tilley
A cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.
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Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00463D, Edge Article
Open Access
Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. Williams
A new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.
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Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01833C, Edge Article
Open Access
Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D Bloch
We describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...
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Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01445A, Edge Article
Open Access
Lei Zhang, Xile Hu
A direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.
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Pore engineering of ultrathin covalent organic framework membranes for organic solvent nanofiltration and molecular sieving

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01679A, Edge Article
Open Access
Digambar B. Shinde, Li Cao, A. D. Dinga Wonanke, Xiang Li, Sushil Kumar, Xiaowei Liu, Mohamed N. Hedhili, Abdul-Hamid Emwas, Matthew Addicoat, Kuo-Wei Huang, Zhiping Lai
Pore surface engineering of ultrathin COF membranes by introducing different lengths of alkyl chains into the skeleton, which allows us to precisely control the pore size of COF membranes for OSN applications and molecular sieving.
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Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01112F, Edge Article
Open Access
Matthias Müller, Antti J Karttunen, Magnus Richard Buchner
The hexa-μ2-amido-tetraammine-tetraberyllium compounds [Be4(NH2)6(NH3)4]X2 (X = Cl, Br, I, CN, SCN, N3) have been prepared from beryllium metal and NH4X or [Be(NH3)4]X2 in liquid ammonia at ambient temperature. The obtained...
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Evolution of pure hydrocarbon hosts: simpler structure, higher performance and universal application in RGB phosphorescent organic light-emitting diodes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01238F, Edge Article
Open Access
Qiang Wang, Fabien Lucas, Cassandre Quinton, Yang-Kun Qu, Joëlle Rault-Berthelot, Olivier Jeannin, Sheng-Yi Yang, Fan-Cheng Kong, Sarvendra Kumar, Liang-Sheng Liao, Cyril Poriel, Zuo-Quan Jiang
In this work, we propose pure hydrocarbon materials as universal hosts for high-efficiency red, green and blue phosphorescent organic light-emitting diodes.
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Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes

Chem. Sci., 2020, 11,4287-4296
DOI: 10.1039/C9SC06006E, Minireview
Open Access
Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. Engle
Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.
The content of this RSS Feed (c) The Royal Society of Chemistry




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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

Chem. Sci., 2020, 11,4297-4304
DOI: 10.1039/D0SC00735H, Minireview
Open Access
Eike Brunner, Marcus Rauche
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization.
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What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts

Chem. Sci., 2020, 11,4381-4390
DOI: 10.1039/D0SC01026J, Edge Article
Open Access
Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen Niemeyer
Supramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.
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Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation

Chem. Sci., 2020, 11,4439-4443
DOI: 10.1039/D0SC01289K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Arunachalam Sagadevan, Anastasios Charitou, Fen Wang, Maria Ivanova, Martin Vuagnat, Michael F. Greaney
A ruthenium-catalyzed ortho C–H arylation process is described using visible light.
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Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents

Chem. Sci., 2020, 11,4374-4380
DOI: 10.1039/D0SC00206B, Edge Article
Open Access
Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. Cozzolino
A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.
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J-dimer emission in interwoven metal–organic frameworks

Chem. Sci., 2020, 11,4391-4396
DOI: 10.1039/D0SC00876A, Edge Article
Open Access
Wesley J. Newsome, Arnab Chakraborty, Richard T. Ly, Gavin S. Pour, David C. Fairchild, Amanda J. Morris, Fernando J. Uribe-Romo
J-dimer emission is an emergent property that occurs when pairs of ground-state fluorophores associate within multivariate MOFs producing tunable red shifted emission.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Machine-enabled inverse design of inorganic solid materials: promises and challenges

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00594K, Minireview
Open Access
Juhwan Noh, Geun Ho Gu, Sungwon Kim, Yousung Jung
The grand challenge of materials science, discovery of novel materials with target properties, can be greatly accelerated by machine-learned inverse design strategies.
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Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
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Designing naphthopyran mechanophores with tunable mechanochromic behavior

Chem. Sci., 2020, 11,4525-4530
DOI: 10.1039/D0SC01359E, Edge Article
Open Access
Brooke A. Versaw, Molly E. McFadden, Corey C. Husic, Maxwell J. Robb
Structure–activity relationships for strategic substitution of the naphthopyran mechanophore scaffold enable polymeric materials with tunable mechanochromic behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00002G, Edge Article
Open Access
Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano
Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.
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Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01544J, Perspective
Open Access
Rebecca A. Olson, Angie B. Korpusik, Brent S. Sumerlin
Light-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.
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Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01025A, Edge Article
Open Access
Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor Alabugin
How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...
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Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
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Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
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Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
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The Role of Porphyrin Peripheral Substituents in Determining the Reactivities of Ferrous Nitrosyl Species

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01625J, Edge Article
Open Access
Sk Amanullah, Abhishek Dey
Ferrous nitrosyl {FeNO}7 species are intermediates common to the catalytic cycles of Cd1NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity vary dramatically in these enzymes. The former...
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Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01796E, Edge Article
Open Access
David Zhi Hong Zee, T. David Harris
Catalytic heme active sites of enzymes are sequestered by the protein superstructure and are regulated by precisely defined outer coordination spheres. Here, we emulate both of these protective functions in...
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09/22:00 CST Marine Wind Warning Summary for South Australia




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Weather Warnings for Queensland - land areas. Issued by the Australian Bureau of Meteorology




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Many electronics shops defy DM’s order in Patna

A day after the state home department issued an order allowing certain categories of shops to reopen, some electronics, electrical and vehicle spare parts shops reopened in the city on Thursday.




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Monitor kitchens at quarantine centres: Bihar CM

CM Nitish Kumar on Friday asked chief secretary Deepak Kumar to increase the number of kitchens proportionate to people staying at each quarantine centre so that they could get quality meals on time.




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Preschool in three cultures revisited : China, Japan, and the United States / Joseph Tobin, Yeh Hsueh, and Mayumi Karasawa

Tobin, Joseph Jay




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Applied learning design in an online teacher-education course / Jillian J. Downing

Downing, Jillian J., author