y Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02703E, PaperVilakkathala U. Krishnapriya, Cherumuttathu H. SureshDinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02838D, PaperYiwen Guan, Xian Xu, Xin XuAn FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02508C, PaperJustin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van StipdonkA series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02627F, PaperWenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie DingCage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02781G, PaperRuopei Sun, Erwan Dupuis, Jean Aupiais, Pascal ReillerThe formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Price pooling mantra: Wake up to expensive electricity By www.thehindubusinessline.com Published On :: Tue, 02 Apr 2013 13:15:05 +0530 Full Article Siddhartha P Saikia
y Media & Freebies: a murky connection By www.thehindubusinessline.com Published On :: Fri, 31 May 2013 16:21:44 +0530 Full Article Siddhartha P Saikia
y Sword swinging in the civic body By www.thehindubusinessline.com Published On :: Thu, 30 May 2013 15:24:50 +0530 Full Article S Madhavan
y Virtual reality By www.thehindubusinessline.com Published On :: Wed, 05 Jun 2013 12:22:22 +0530 Full Article S Madhavan
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y Unfurling a mythological gem By www.thehindubusinessline.com Published On :: Sun, 30 Jun 2013 01:46:01 +0530 Full Article S Madhavan
y Why do we succumb to pressure? By www.thehindubusinessline.com Published On :: Tue, 23 Jul 2013 12:34:12 +0530 Full Article S Madhavan
y In a state of urgency By www.thehindubusinessline.com Published On :: Thu, 08 Aug 2013 16:28:45 +0530 Full Article S Madhavan
y Many facets of intolerance By www.thehindubusinessline.com Published On :: Fri, 23 Aug 2013 16:42:24 +0530 Full Article S Madhavan
y The show off syndrome By www.thehindubusinessline.com Published On :: Mon, 23 Sep 2013 12:04:00 +0530 Full Article S Madhavan
y A way with birds By www.thehindu.com Published On :: Sun, 11 Aug 2024 02:47:00 +0530 As the world became deafeningly silent during the lockdown, birdsong was the only solace Full Article Open Page
y Ball badminton days By www.thehindu.com Published On :: Sun, 18 Aug 2024 02:00:00 +0530 In the early 1980s, local clubs in Mysuru used to conduct round-robin tournaments of the game Full Article Open Page
y Lessons from a rain lily By www.thehindu.com Published On :: Sun, 18 Aug 2024 02:45:00 +0530 Stay in tune with nature’s cycles and seasons as they teach us the lesson of patient waiting Full Article Open Page
y Achieving gender parity is still a dream By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:03:00 +0530 Antiquated stereotypes about the roles and responsibilities of women are a pain Full Article Open Page
y Thriving technology, waning memory By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:33:00 +0530 Too many digital nannies are robbing us of the power of memory Full Article Open Page
y A traveller’s diary By www.thehindu.com Published On :: Sun, 01 Sep 2024 03:55:00 +0530 An edge-of-the-seat drive through treacherous mountain roads Full Article Open Page
y Dog days By www.thehindu.com Published On :: Sun, 01 Sep 2024 05:55:00 +0530 When man’s best friend attacks children and infirm people Full Article Open Page
y Shedding light on local history By www.thehindu.com Published On :: Sun, 15 Sep 2024 00:40:34 +0530 It’s the lifeblood of community identities and is vital for preserving cultural heritage Full Article Open Page
y A shrinking Himalayan passage By www.thehindu.com Published On :: Sun, 15 Sep 2024 01:05:00 +0530 A visit to Nagmithong Nala near Kargil, where the threat of a glacial lake outburst flood looms large and Botkol Pass is set to become inaccessible Full Article Open Page
y A dictionary at hand By www.thehindu.com Published On :: Sun, 29 Sep 2024 01:07:43 +0530 Consult it regularly to develop your own vocabulary Full Article Open Page
y Live life to the fullest at any age By www.thehindu.com Published On :: Sun, 29 Sep 2024 02:32:00 +0530 Birthdays are not just a celebration of the years gone by, but a reminder to live fully, no matter what age one is Full Article Open Page
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y A women-only conversation, but for all By www.thehindu.com Published On :: Sun, 13 Oct 2024 04:13:00 +0530 Why do we descend to the misogynistic use of ‘girlish’ and ‘womanly’ as labels to demean some of the complex disciplines? Full Article Open Page
y Permeating partiarchy By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:05:00 +0530 It’s no longer about confining women to the kitchen; it subtly disguises itself as praise for how well women juggle careers and family Full Article Open Page
y Evolving value systems By www.thehindu.com Published On :: Sun, 27 Oct 2024 01:22:00 +0530 While there should not be judgments on what is good or bad, time, space and context determine what is acceptable or not Full Article Open Page
y Learning it the hard way By www.thehindu.com Published On :: Sun, 27 Oct 2024 01:48:00 +0530 How a simple fix was given the go-by and how it led to worries Full Article Open Page
y Book of the Year 2017 By physicsworld.com Published On :: 2017-12-13T14:42:08Z Physics World book experts Matin Durrani and Tushna Commissariat discuss the themes and trends that surround some of the best popular-physics books of 2017, before announcing the winner of our annual book award Full Article
y NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy By physicsworld.com Published On :: 2018-01-19T14:46:48Z Register now: 8 March 2018 A webinar sponsored by HORIBA Scientific Full Article
y Physics in 2018 By physicsworld.com Published On :: 2018-01-23T15:51:48Z Physics World journalists discuss what excites them about the year ahead Full Article
y Enhancing radiotherapy with MRI By physicsworld.com Published On :: 2018-01-25T14:58:04Z Bas Raaymakers describes how MRI can help target tumours with improved accuracy Full Article
y Tracking proton therapy with acoustic waves By physicsworld.com Published On :: 2018-02-01T10:39:31Z Katia Parodi describes an innovative technique for improving ion-beam therapy Full Article
