Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication

Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Catal. Sci. Technol., 2024, 14,6180-6185
DOI: 10.1039/D4CY01117A, Communication

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Ren-Rui Xu, Chang-Sheng Kuai, Xiao-Feng Wu
An efficient strategy for the synthesis of acrylamides via palladium-catalyzed carbonylation, using 1,2-dichloroethane and amines as starting materials has been developed.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00979G, Paper

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Peixue Wang, Shimin Liu, Xinjiang Cui, Feng Shi
Effectively synthesis of methyl ethyl carbamate from dimethyl carbonate and ethanol using 14 wt% KATriz/Al₂O₃ in fixed bed mode.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper

Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper

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Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper

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Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni₉₉Pt₁/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01035C, Paper

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Matthew E. Potter, Lucas Spiske, Philipp N. Plessow, Evangeline B. McShane, Marina Carravetta, Alice E. Oakley, Takudzwa Bere, James H. Carter, Bart D. Vandegehuchte, Kamila M. Kaźmierczak, Felix Studt, Robert Raja
Using a model microporous catalyst, the influence of acid site density and partial pressure is explored in alkane isomerisation. Combining with DFT calculations shows the role of olefins in this industrially important catalytic process.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01140F, Paper

Meiyan Guo, Wanxiang Yang, Yi Li, Yongfan Zhang, Wei Lin
Cadmium sulfide (CdS) exhibits remarkable light absorption capabilities and is widely employed in photocatalytic reduction of CO2. Nevertheless, the role of crystal facet effects on the micro-scale mechanisms governing CO2...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper

Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp²)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01006J, Paper

Kai Cui, Jiaming Yang, Yuli Jing, Junwen Chen, Chen Zhao, Peng Wu, Xiaohong Li
A Cu–0.03Mo/SiO₂ catalyst realized the one-pot deep hydrogenation of maleic anhydride to 1,4-butanediol at 200 °C, under 5 MPa of hydrogen pressure with 100% conversion and 88.3% selectivity, one of the highest values for this target reaction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01115E, Paper

Xinyu Zhang, Chunlei Zhang, Siyu Gao, Xinyu Chen, Siyuan Chen, Shengran Zhou, Di Yu, Lanyi Wang, Xiaoqiang Fan, Xuehua Yu, Zhen Zhao
A series of Co₃O₄ catalysts with different morphologies were prepared by a hydrothermal method. Among them, the sea urchin shaped Co₃O₄ catalyst exhibits the best catalytic performance for soot combustion.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01070A, Review Article

Deyu Chu, Jinjing Ma, Qishun Liu, Jie Fu, Heng Yin
Optimizing the production process of high value-added chemicals derived from renewable biomass holds immense promise for clean energy utilization and environmental sustainability.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00745J, Paper

Lijin Gan, Zekun Liu, Lei Feng, Yi Duan, Guangyuan Xu, Si Chen, Huan Yan
Adipic aldehyde, as a precursor for polymers, has significant industrial applications, where the hydroformylation of 1,3-butadiene is a promising routine to fabricate adipic aldehyde. However, the heterogeneous hydroformylation of 1,3-butadiene...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01018C, Paper

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Martin Gerbaulet, Anja Hemschemeier, Thomas Happe
CbA5H from Clostridium beijerinckii is an oxygen-stable [FeFe]-hydrogenase. Here we report that CbA5H is stable in high concentrations of acetone and acetonitrile and also withstands intermediate concentrations of DMSO, ethanol and methanol.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper

Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
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Catal. Sci. Technol., 2024, 14,6503-6512
DOI: 10.1039/D4CY00760C, Paper

Bruce A. Lobo Sacchelli, Suellen M. P. Onguene, Ruben S. M. Almeida, Alexandra M. M. Antunes, Dmytro S. Nesterov, Leandro H. Andrade, Elisabete C. B. A. Alegria, Martin H. G. Prechtl
Tuning selectivities with oxidants: O₂ oxidises methanol to the carboxylate level and N₂O oxidises it to the formaldehyde level.
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Catal. Sci. Technol., 2024, 14,6573-6583
DOI: 10.1039/D4CY00969J, Paper

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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.
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Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper

Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper

Open Access

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Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Catal. Sci. Technol., 2024, 14,6609-6620
DOI: 10.1039/D4CY00968A, Paper

Nien-Chi Chang Liao, R. Sidick Basha, Bo-Hao Shih, Chia-Chun Liu, Miao-Han Wang, Po-Heng Lin, Chin-Fa Lee
Three distinct copper cluster complexes (A–C) were synthesized and their bonding was investigated by XRD studies. These complexes effectively catalyze the C–S coupling reaction of less reactive aliphatic thiols to synthesize thioether derivatives.
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Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper

Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt₁/Nb₂O₅, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb₂O₅ selectively promotes the hydrogenolysis of the –CH₂OH group rather than the hydrogenation of the –CHO group.
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Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper

Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO₄ solution by electrochemical technology to catalyze the reduction of N₂ to NH₃. It was found that the applied magnetic field can significantly increase the current density.
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Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper

Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H₂O₂ dissociation on heteroatom-doped carbon nanomaterials.
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Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper

Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO₂ nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO₂ and methanol, attributed to their superior surface acidity, basicity, Ce³⁺ concentration, and oxygen vacancies.
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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper

Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper

Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO₂. The CO₂ conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper

Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper

Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO₂ with epoxides.
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Catal. Sci. Technol., 2024, 14,6710-6719
DOI: 10.1039/D4CY00739E, Paper

Charlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann Pellegrin
A perylene-doped mesoporous silica material is used as a photocatalyst to produce H₂O₂ from aerated polluted water samples under light soaking.
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Catal. Sci. Technol., 2024, 14,6701-6709
DOI: 10.1039/D4CY01101E, Paper

Jingjing Jiang, Yuyao Chen, Shijian Zhou, Haoran Xie, Changlai Li, Zheng Wei, Yan Kong
Defect engineering (such as doping of non-metallic elements or vacancies) is a universally effective modification to improve the electronic structure and physical properties of g-C₃N₄, which has been widely applied in various photocatalytic systems.
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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper

Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C₃N₄ as a CO₂ photo-thermal-reduction catalyst can effectively convert CO₂ to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Catal. Sci. Technol., 2024, 14,6496-6502
DOI: 10.1039/D4CY00869C, Communication

Elena Gkantzou, Theofilia Koulopoulou, Hannah Brass, David Schönauer, Anton Glieder, Selin Kara
In the context of empowering biocatalysis, an easy-to-develop, reproducible, and easy-to-scale biocatalytic system is demonstrated as a microfluidic screening platform.
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Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper

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Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article

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Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Catal. Sci. Technol., 2024, 14,6720-6720
DOI: 10.1039/D4CY90084G, Correction

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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper

Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00860J, Paper

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Bing Wang, Nicola Da Roit, Michael Zimmermann, Markus Boese, Thomas Zevaco, Silke Behrens
Pd/Zn-nanoparticles were used as precursors to study the influence of the molar Zn/Pd ratio and hierarchical HZSM-5 zeolites in the syngas-to-dimethyl ether process.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper

Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO₂ mitigation through conversion into useful chemicals.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper

Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication

Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
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Nanoscale, 2024, 16,20027-20036
DOI: 10.1039/D4NR03321C, Minireview

Shunsuke Yamada, Takashi Honda
This review highlights recent progress in increasing the operating voltage of biodegradable primary batteries by suppressing or substituting the hydrogen evolution reaction at the cathode with alternative redox reaction.
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Nanoscale, 2024, 16,20048-20059
DOI: 10.1039/D4NR03565H, Minireview

Joydip Sengupta, Chaudhery Mustansar Hussain
Silicene-based technologies can be applied in photonic hyperthermia and drug delivery for oncology treatment.
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Nanoscale, 2024, 16,20235-20251
DOI: 10.1039/D4NR02602K, Paper

Rishit S. Shukla, Vidit B. Zala, Sanjeev K. Gupta, P. N. Gajjar
BP/GaN and BP/GaP core/shell nanowires (CSNWs) show good sensitivity for some small oxide gases. Also, BP/GaP CSNWs show >33% photovoltaic conversion efficiency.
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Nanoscale, 2024, 16,20037-20047
DOI: 10.1039/D4NR02906B, Minireview

Yusuf Olatunji Waidi, Nipun Jain
This article presents MXenes' potential in 3D bioprinting, discussing their benefits for bio-printed scaffolds, 3D bioprinting techniques, bio-ink criteria, applications of MXene-incorporated constructs, current challenges, and future directions.
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Nanoscale, 2024, 16,20155-20167
DOI: 10.1039/D4NR03113J, Paper

Rajeev Gupta, Monika Singhal
A novel eco-friendly composite electrode/current collector made from polycaprolactone and graphite filler offers bulk conductivity, is freestanding, cost-effective, and shows supercapacitive energy storage potential with electrodeposited polyaniline.
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Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper

Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Nanoscale, 2024, 16,20252-20259
DOI: 10.1039/D4NR02622E, Paper

Hyo-Bin Ahn, Hyunjong Lim, Jaegu Song, Jisung Lee, Seung-Young Park, Minwoong Joe, Chang-Jong Kang, Kyoung-Whan Kim, Tae-Eon Park, Tuson Park, Changgu Lee
The phase diagram and M–H curves of the metamagnetic regime of (Fe_1−xCo_x)₃GaTe₂ with x = 0.19–0.26 at various temperatures were studied.
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Nanoscale, 2024, 16,20194-20201
DOI: 10.1039/D4NR03435J, Paper

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Lukas Schubert, Chiara Nenninger, Maximilian Nöth, Thomke Belthle, Robert Dirk de Lange, Andrij Pich, Ulrich Schwaneberg, Dominik Wöll
The distribution and local catalytic activity of Cytochrome P450 enzymes immobilized in microgels by electrostatic interaction has been determined with a combination of in situ super-resolution fluorescence microscopy experiments.
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Nanoscale, 2024, 16,20288-20303
DOI: 10.1039/D4NR02541E, Paper

Zhenghui Xie, Feiran Meng, Junlong Yang, Yuhong Wang, Chul B. Park, Pengjian Gong, Guangxian Li
Hybrid 1D nanofiber/2D nanoplatelet nanocomposite foam sensor and Monte-Carlo modelling of complex 1D/2D sensing nanostructure.
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Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper

H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
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