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Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02603A, Paper
Takeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa Mehrkhodavandi
Alkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.
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Oxaphosphiranes: isolable phosphorus-containing epoxide rings

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02915A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer Streubel
A new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.
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Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT01765J, Paper
Romain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim Storr
The synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...
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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
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Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02901A, Paper
Maxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia Spitsyna
The hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...
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A ratiometric luminescence thermometer based on lanthanide encapsulated complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02639J, Paper
Aribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju Laishram
This paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.
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Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02563F, Paper
Changfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu Han
A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication
Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
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A grain-like cerium oxide nanostructure: synthesis and uric acid sensing application

Dalton Trans., 2024, 53,17794-17802
DOI: 10.1039/D4DT02056A, Paper
Rafiq Ahmad, Sakeena Masrat, Md. Tabish Rehman, Mohamed F. AlAjmi, Shamshad Alam, Prabhash Mishra, Byeong-Il Lee
Hydrothermally prepared grain-like CeO2 nanostructures were useful for creating a high-performance and non-enzymatic sensor for uric acid detection.
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Fluorescent molecular systems based on carborane-perylenediimide conjugates

Dalton Trans., 2024, 53,17841-17851
DOI: 10.1039/D4DT02477J, Paper
Open Access
Ruben Rodriguez-Madrid, Sohini Sinha, Laura Parejo, Jordi Hernando, Rosario Núñez
o-Carborane–perylenediimide conjugates exhibit exceptional fluorescence properties in solution, while red-light excimer emission is observed in their aggregated forms and in dispersible nanoparticles.
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Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites

Dalton Trans., 2024, 53,18021-18026
DOI: 10.1039/D4DT02421D, Paper
Afif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki Motohashi
The oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).
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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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The dark side of digital dependence

The dreaded blue screen can throw life out gear in the most unlikeliest of places




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Karnataka makes online applications mandatory for private aided school teacher recruitment

DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently




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Sahitya Sammelana: ₹50 lakh set aside for drinking water supply




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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]




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Schema-focused working methods for arts and body-based therapies [electronic resource] : a practical guide / edited by Suzanne Haeyen.

New York, NY : Routledge , 2024.




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Over nine crore voters to decide Maha's fate on Nov 20




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Maha CM asks officials to provide compensation for farm losses due to unseasonal rains




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People have seen our work... Devendra Fadnavis exudes confidence in Mahayuti alliance retaining power in Maharashtra




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Maha: Malad residents saving money on medicines, courtesy Jan Aushadhi Kendras




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Prioritise celebrating Diwali with lights to avoid noise and air pollution: BMC issues new guidelines for firecracker use during festivities




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Maharashtra: Malad residents saving money on medicines, courtesy Jan Aushadhi Kendras




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Maha: Under PMBJP, Nalasopara residents buying cheaper medicines; thank PM Modi




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With nothing to lose, India will be a dangerous side now, says Ajay Jadeja

Ajay Jadeja, emphasising India’s edge, said: “We may not reach the World Test Championship final, but I believe we can secure the series win.




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Morning Digest: Unidentified terrorist killed in encounter in J&K’s Sopore; Biden, Trump to meet in the White House on November 13, and more

Here is a select list of stories to start the day




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Chennai Grandmasters | Chithambaram downs Arjun, throws the title race wide open

With this win, Chithambaram (3.5) has joined Iranian Tabatabaei (3.5) to trail leaders Arjun (4) and Aronian (4) by just half a point




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McSweeney to open, Inglis also handed maiden Test call up for BGT opener

Nathan McSweeney had emerged as a strong contender for the opener's spot, earning backing from the likes of David Warner and Ricky Ponting




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A novel graphene oxide–microalgae hybrid material for the removal of pentavalent arsenic from natural water and industrial wastewater

Environ. Sci.: Water Res. Technol., 2024, 10,2796-2808
DOI: 10.1039/D4EW00308J, Paper
Eliana S. Lemos, Evelyn M. Valdés Rodríguez, Adrián Bonilla Petriciolet, Andrea M. Ray, Leticia B. Escudero
The adsorption process using bionanomaterials based on graphene oxide and green microalgae for the removal of arsenic from complex samples of natural water and industrial wastewater.
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Production of birnessite-type manganese oxides by biofilms from oxygen-supplemented biological activated carbon (BAC) filters

Environ. Sci.: Water Res. Technol., 2024, 10,2844-2857
DOI: 10.1039/D4EW00208C, Paper
Amanda Larasati, Olga Bernadet, Gert Jan W. Euverink, H. Pieter J. van Veelen, Maria Cristina Gagliano
The application of a novel enrichment approach revealed the potential of manganese-oxidizing bacteria (MnOB) from full-scale biofilters treating wastewater to produce manganese oxides as crystalline, efficient birnessite catalysts.
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Effects of chloride transport on the bioelectrochemical remediation of nitrate-contaminated groundwater

Environ. Sci.: Water Res. Technol., 2024, 10,2776-2786
DOI: 10.1039/D4EW00335G, Paper
Hanyu Tang, McKenzie Burns, Mohan Qin
The impact of ion competition on nitrate removal from contaminated groundwater using membrane-based bioelectrochemical systems is investigated.
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AIBEA warns of nationwide strike, but says date not decided yet

The bank employees union demands filling ‘more than a lakh vacancies’ at banks across India; says customer service has been badly hit 




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LTTS to acquire California firm Intelliswift for an aggregate consideration of $110 million

As per the filing, Intelliswift services four of the top five hyperscalers and caters to over 25 Fortune 500 companies including five of the top 10 ER&D spenders in Software and Technology




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Munnar panchayat continues eviction of illegal roadside shops

In four days the authorities have removed nearly 100 roadside shops




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Meet Aswanth A, the visual designer behind the IFFK 2024 logo and brand identity concept

The IFFK film festival will take place in Thiruvananthapuram from December 13 onwards




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Sharon Raj murder case: key digital evidence links Greeshma to the poisoning




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Technopark-based HEX20 set to fly its maiden satellite with SpaceX




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Six injured as two cars collide head-on near Kazhakuttam




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World T20 to use Spidercam




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Mithali Raj confident

‘Women’s cricket will stand alone as a brand in itself’




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Quietly confident of our chances: Duminy

The left-hander feels the Indian pitches would give him ample opportunities to shine




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Premier Futsal is a good development: FAI President




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Sharad Pawar resigns as MCA president

Pawar was in his second innings as president of the MCA after being elected last year for a two-year term.




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Support India on terror, ours not a friendship to hide: Rivlin

Jerusalem is proud to stand with New Delhi “in its defence of the values of democracy,” he asserts.




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Frank-Walter Steinmeier to be Germany’s next President




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Six killed in suicide attack near Iraq's Kerbala




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Obama confident of policy continuity

On his final foreign tour, U.S. President says Trump is committed to NATO and other key alliances




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15 missing in Indonesia boat accident

After a speedboat collided with a Vietnamese cargo vessel