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The rent of form: architecture and labor in the digital age / Pedro Fiori Arantes ; translated by Adriana Kauffmann ; foreword by Reinhold Martin

Rotch Library - NA2543.T43 A7313 2018




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Surfacedesign: material landscapes / James A Lord, Roderick Wyllie, Geoff di Girolomo ; foreword by Alan Maskin ; conversation with Anita Berrizbeitia

Rotch Library - SB470.S845 L67 2019




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The decorated tenement: how immigrant builders and architects transformed the slum in the Gilded Age / Zachary J. Violette

Rotch Library - NA7880.V56 2019




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[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




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[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




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[ASAP] Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00021




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[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




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Free Content Forever?

In this week’s episode, we turn our gaze to the topic of ad-blockers and paid content. We discuss Vitaly from Smashing Magazine’s recent post looking at how they are funding their content strategy and discuss our own views on paying for digital content.

As always we book end the show with some “bants” including heartfelt thanks to some of our favourite supporters and a nod to a Cornish brewing companies new site.




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Gujarat clears ordinance for labour reforms

In the wake of exodus of thousands of migrant workers who are leaving the state, the Gujarat cabinet has approved a new ordinance where existing stringent labour laws will be liberalised to ensure smooth functioning of industries in the post lockdown period.




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IIEBM - Learning experience for gen-next leaders

If you are an aspiring management student, you might have been storming your head after reading about all the academic rigour and jam-packed schedules that o...




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Gujarat HC allows an accused bail for Ramzan

The Gujarat high court has granted temporary bail to a murder accused to observe fasts during the holy month of Ramzan. He will have to surrender to jail on May 25, after Eid-ul-Fitr.​




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Eight held for hunting nilgai in Chhota Udepur

Eight persons from Bhumaswada village in Chhota Udepur district were arrested on Friday for poaching a nilgai on April 21. The kingpin father-son duo was already nabbed on May 6.




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Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
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Humin based resin for wood modification and property improvement

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03620B, Paper
Open Access
Anna Sangregorio, Anitha Muralidhara, Nathanael Guigo, Lisbeth G. Thygesen, Guy Marlair, Carlo Angelici, Ed de Jong, Nicolas Sbirrazzuoli
Focus on humins, a co-product from sugar conversion, to highlight their capacity to impregnate wood cell walls for making durable wood products.
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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
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Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
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Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
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Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
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Eco-friendly and sustainable synthesis of biocompatible nanomaterials for diagnostic imaging: current challenges and future perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00734J, Critical Review
Ghazaleh Jamalipour Soufi, Siavash Iravani
Current advancements, important challenges and future perspectives of biocompatible nanomaterials for diagnostic imaging are discussed as well as their greener synthesis.
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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
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A Strategy for The Assembly of Glypromate® and Structure-Related Analogues by Tandem Sequential Peptide Coupling

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00143K, Paper
Ivo E Sampaio-Dias, Luís Pinto da Silva, Sandra G Silva, Xerardo Garcia-Mera, José Enrique Rodriguez-Borges
This work describes an improved and greener methodology in solution-phase synthesis for the preparation of Glypromate® (glycyl-L-prolyl-L-glutamic acid, GPE), a potent neuropeptide with applications in neurodegenerative conditions such as Huntington's,...
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Insights into pressure tunable reaction rates for electrochemical reduction of CO2 in organic electrolytes

Green Chem., 2020, 22,2434-2442
DOI: 10.1039/D0GC00013B, Paper
Charles I. Shaughnessy, David J. Sconyers, Hyun-Jin Lee, Bala Subramaniam, James D. Blakemore, Kevin C. Leonard
Modeling and simulation reveal the mechanistic basis for the pressure-tunable rates of CO2 reduction at elevated pressures of CO2.
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Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
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A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks

Green Chem., 2020, 22,2498-2504
DOI: 10.1039/C9GC04033A, Paper
Lei Zhang, Rongran Liang, Cheng Hang, Haiying Wang, Lin Sun, Lei Xu, Dairong Liu, Zhenyi Zhang, Xingmin Zhang, Feifan Chang, Shengyu Zhao, Wei Huang
A general solution-phase synthetic strategy is developed to construct both porous organic cages (POCs) and covalent organic frameworks (COFs) by simply stirring and heating organic solvent/water solutions of aldehydes and amines in the presence of MOH (M = Na, K, and Cs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
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Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

Green Chem., 2020, 22,2605-2612
DOI: 10.1039/D0GC00223B, Paper
Jikuan Qiu, Huiyong Wang, Yuling Zhao, Pengxin Guan, Zhiyong Li, Hucheng Zhang, Hongshuai Gao, Suojiang Zhang, Jianji Wang
A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.
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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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Using dialkyl amide via forming hydrophobic deep eutectic solvents to separate citric acid from fermentation broth

Green Chem., 2020, 22,2526-2533
DOI: 10.1039/C9GC04401A, Paper
Lijuan Liu, Qifeng Wei, Yong Zhou, Xiulian Ren
The separation of citric acids was realized by utilizing hydrophobic deep eutectic solvents (DESs), which were formed by using N,N-dibutylacetamide as a hydrogen acceptor and citric acid as the hydrogen bond.
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Mechanochemical synthesis of mixed metal, mixed linker, glass-forming metal–organic frameworks

Green Chem., 2020, 22,2505-2512
DOI: 10.1039/D0GC00546K, Paper
Michael F. Thorne, María Laura Ríos Gómez, Alice M. Bumstead, Shichun Li, Thomas D. Bennett
Methods to produce glass forming metal–organic frameworks (MOFs) rely on solvothermal syntheses which have high energy requirements, low yields and large teratogenic solvent usage. We present mechanochemical methods to overcome these issues.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Evaluating lignin valorization via pyrolysis and vapor-phase hydrodeoxygenation for production of aromatics and alkenes

Green Chem., 2020, 22,2513-2525
DOI: 10.1039/C9GC04245H, Paper
Open Access
Alireza Saraeian, Alvina Aui, Yu Gao, Mark M. Wright, Marcus Foston, Brent H. Shanks
Lignin valorization to chemicals is an important component of creating economically viable biofuels production from lignocellulosic biomass.
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A review of sustainable and intensified techniques for extraction of food and natural products

Green Chem., 2020, 22,2325-2353
DOI: 10.1039/C9GC03878G, Tutorial Review
Open Access
Farid Chemat, Maryline Abert Vian, Anne-Sylvie Fabiano-Tixier, Marinela Nutrizio, Anet Režek Jambrak, Paulo E. S. Munekata, Jose M. Lorenzo, Francisco J. Barba, Arianna Binello, Giancarlo Cravotto
This review presents innovative extraction techniques and their role in promoting sustainable ingredients for the food, cosmetic and pharmaceutical industries.
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Introducing deep eutectic solvents as flux boosting and surface cleaning agents for thin film composite polyamide membranes

Green Chem., 2020, 22,2381-2387
DOI: 10.1039/D0GC00762E, Communication
Nidhi Maalige R., Sweedal A. Dsouza, Matheus M. Pereira, Veerababu Polisetti, Dibyendu Mondal, Sanna Kotrappanavar Nataraj
This study introduced DESs as versatile and multi-tasking agents to modify the surface roughness and wettability of a TFC-PA membrane to boost the permeate flux rate and they also proved to be cleaning agents for organically fouled TFC-PA membranes.
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Visible-light-promoted oxidative desulphurisation: a strategy for the preparation of unsymmetrical ureas from isothiocyanates and amines using molecular oxygen

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00070A, Paper
Ziyu Gan, Guoqing Li, Qiuli Yan, Weiseng Deng, Yuan-Ye Jiang, Daoshan Yang
A green and efficient visible-light promoted oxidative desulphurisation protocol has been proposed for the construction of unsymmetrical ureas under mild conditions with broad substrate scope and good functional group tolerance.
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Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00820F, Paper
Open Access
K. U. Künnemann, L. Schurm, D. Lange, T. Seidensticker, S. Tilloy, E. Monflier, D. Vogt, J. M. Dreimann
Long-term applications of cyclodextrins in the aqueous biphasic hydroformylation of higher olefins with high selectivities and simultaneous catalyst recycling.
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Boron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00730G, Communication
Qiang Wan, Jianling Zhang, Bingxing Zhang, Dongxing Tan, Lei Yao, Lirong Zheng, Fanyu Zhang, Lifei Liu, Xiuyan Cheng, Buxing Han
Herein, we synthesize B-doped CuO nanobundles for electrocatalytic CO2 reduction. Ethylene is the only multi-carbon product and a maximum ethylene faradaic efficiency (FE) of 58.4% can be achieved at −1.1 V (versus the reversible hydrogen electrode).
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Chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols and alcohols catalyzed by nickel(II) and copper(II)-catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00520G, Paper
Rahul B. Sonawane, Swapnali R. Sonawane, Nishant K. Rasal, Sangeeta V. Jagtap
A crucial chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols, and alcohols in the presence of amines catalyzed by Ni(II) and Cu(II) complexes with 8-hydroxyquinoline in a homogeneous medium is achieved.
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Outstanding Reviewers for Green Chemistry in 2019

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC90042G, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Green Chemistry in 2019, as selected by the editorial team for their significant contribution to the journal.
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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Development and validation of an ecofriendly HPLC-DAD method for the determination of oleuropein and its applicability to several matrices: olive oil, olive leaf extracts and nanostructured lipid carriers.

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00965B, Paper
Amaia Huguet-Casquero, Tania Belen Lopez-Mendez, Eusebio Gainza, Jose Luis Pedraz
Oleuropein is a natural ingredient largely used in nutritional supplements. This study reports on the development, validation and application of an HPLC method based on UV-vis detection for determining oleuropein...
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Sulfonic acid modified hollow polymer nanospheres with tunable wall-thickness for improving biodiesel synthesis efficiency

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00905A, Paper
Wenliang Song, Yu Zhang, Anuraj Varyambath, Ji Su Kim, Il Kim
Precisely designing the morphology and size of nanostructures is vital in green chemistry as various advanced applications depend upon the shapes and dimensions of the functionalised materials. Herein, we report...
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Functionalized magnetic nanosized materials for efficient biodiesel synthesis via acid–base/enzyme catalysis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00924E, Critical Review
Anping Wang, Putla Sudarsanam, Yufei Xu, Heng Zhang, Hu Li, Song Yang
This critical review introduces the preparation methods, structural and performance control, protection, and functionalization of magnetic nanoparticles as easily recyclable and efficient heterogeneous catalysts for biodiesel synthesis.
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A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01142H, Communication
Noémie Emmanuel, Pauline Bianchi, Julien Legros, Jean-Christophe M. Monbaliu
Intensified chemical neutralization of a chemical warfare agent simulant CEES with air and light under continuous flow conditions.
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Photoreforming of food waste into value-added products over visible-light-absorbing catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01240H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Taylor Uekert, Florian Dorchies, Christian M. Pichler, Erwin Reisner
Food and mixed wastes are converted into H2 and organics over CdS and carbon nitride photocatalysts.
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Photochemical strategies for C–N bond formation via metal catalyst-free (hetero) aryl C(sp2)–H functionalization

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01088J, Tutorial Review
Qing-Qing Kang, Wenfeng Wu, Qiang Li, Wen-Ting Wei
The development of efficient and mild methods to assemble C–N bonds represents an important and appealing goal in modern synthetic chemistry.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Humidity-responsive Molecular Gate-opening mechanism for Gas Separation in Ultraselective Nanocellulose/IL Hybrid Membranes

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00544D, Paper
Saravanan. Janakiram, Luca Ansaloni, Soo Ah Jin, Xinyi Yu, Zhongde Dai, Richard J Spontak, Liyuan Deng
Nanofibrillated cellulose (NFC) represents an important class of bio-based nanomaterials that possess favorable properties including hydrophilicity, 1D structure, biodegradability, and surface tunability. Although widely known for its effective gas-barrier attributes...
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For Good Mothering Advice, Skip the Mommy Blogs and Look to Christ

Parenting children requires a rich understanding of God’s nature.

Mothers today face an onslaught of mixed messages about how best to parent in the 21st century. Podcasts, blogs, and books on mommy-ing abound, but many of them indulge regularly in shallow parenting advice and fallacies about excessive self-care or “me-time.”

In the midst of the coronavirus quarantine, moms on social media often advise diametrically opposed strategies: Take regular mental health breaks while your children gorge on Netflix, or schedule out every minute of children’s at-home education so they don’t fall behind in productivity. The message seems to be either “love yourself first” or “pour all your energy into your children’s future.”

Neither side answers the more important question: How do we mother like Jesus Christ during this particular cultural moment? In the words of an overused adage, “What would Jesus do?”

In Motherhood: A Confession, Natalie Carnes, associate professor of theology at Baylor University, attempts to answer this question by sharing her personal experience of raising three daughters. She follows the structure and style of Augustine’s autobiography, Confessions, and elevates the conversation about motherhood from the self-centered to the spiritual without ever losing touch with the beauty of the ordinary. Part memoir and part theological study, Motherhood: A Confession explores “how motherhood, infancy, and children disclose what it means to be human in relation to the divine.”

Carnes’s core argument is that mothering imitates God. We birth forth disciples, hand down tradition, and grow our children into the church. By knowing the maternal attributes of God, we better mother our own children, and we also ...

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Interview: Singing in the Storm With Rain for Roots

The group’s latest album offers a timely message for this global moment.

Is a pandemic the best time or the worst time to release an album of children’s music based on the Psalms? Musicians Flo Paris Oakes, Sandra McCracken, and Katy Bowser Hutson hope that All Creatures, the fourth album from their musical collective Rain for Roots, reaches the world at just the right time and offers hope in the midst of a storm. The album explores the emotional range of Israel’s original songbook and points listeners to God’s glory made manifest in creation.

The three Nashville musicians talked with Megan Fowler about their project, which just released.

The three previous Rain for Roots albums have focused on Bible stories, parables, and Advent. What was the inspiration for All Creatures?

McCracken: We started out talking about Psalms, and then all these images of creation were so present in the themes that were coming up. So we started paying attention to that. A secondary theme that emerged was songs, loosely based on Psalms, but then creation and the creatures that we saw calling us into worship. It’s not strictly a praise album, but a praise album by way of the Psalms, by way of the owls and birds.

Hutson: When you say it that way, Sandra, the two themes that kind of run through are, one, there’s so much of seeing how God reveals who he is in the natural world; and two, yes, there’s so much beautiful praise, but there’s also lament and fear. I like that the Psalms are such a great way to display, to young ones in particular, that all of the range of emotions are okay to bring before the face of God.

Oakes: And that God is with us, not just in this spiritual realm, but in our humanity. God is with us in every bit of the physical world.

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