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Probing the potential of Al2CO/SiC heterostructures for visible light driven photocatalytic water splitting using first-principles strategies

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00885E, Paper
Amina Shehbaz, Abdul Majid, Hira Batool, Mohammad Alkhedher, Sajjad Haider, Kamran Alam
Photocatalytic water splitting is a sustainable and eco-friendly method for renewable energy production. The fabrication of an efficient photocatalyst based on two-dimensional (2D) interfaces with suitable band offsets is at...
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A new versatile crystalline sponge for organic structural analysis without the need of activation

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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07946E, Paper
Jin chang Liu, Weiping Huang, Yuxin Tian, Wei Xu, Wen-Cai Ye, Ren-Wang Jiang
Crystalline sponges made “crystallography without crystals” and received current attentions, but were difficult to apply directly because of the tedious activation procedures. It was important to prepare crystalline sponges that...
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Origin of sputter damage during transparent conductive oxide deposition for semitransparent perovskite solar cells

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06654A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qing Yang, Weiyuan Duan, Alexander Eberst, Benjamin Klingebiel, Yueming Wang, Ashish Kulkarni, Andreas Lambertz, Karsten Bittkau, Yongqiang Zhang, Svetlana Vitusevich, Uwe Rau, Thomas Kirchartz, Kaining Ding
The origin of sputter damage during transparent conductive oxide deposition is ion bombardment rather than plasma radiation. Ion bombardment increased recombination, whereas plasma radiation reduced recombination.
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Scalable preparation of flexible heterogeneous graphene oxide structures for high performance wet power generation

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01819B, Paper
Yu Gao, Xiaoming Cai, Yuzhou Zhao, Wentian Huang, Jian Lv, Jie Wang, Zhenliang Hao, Huiming Liang, Honglin Tan, Jinming Cai
Moisture-driven energy generation (MEG) has attracted great attention in recent years, and the interaction of functionalized nanomaterials with water offers the possibility of MEG. However, current MEG devices require specific...
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The balancing act between high electronic and low ionic transport influenced by perovskite grain boundaries

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA04458K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nadja Glück, Nathan S. Hill, Marcin Giza, Eline Hutter, Irene Grill, Johannes Schlipf, Udo Bach, Peter Müller-Buschbaum, Achim Hartschuh, Thomas Bein, Tom Savenije, Pablo Docampo
Grain size and orientation's impact on charge carriers is explored via a new solvent engineering method for MAPbI3 solar cells. Drift-diffusion simulations connect s-shaped JV curves to slower ions.
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Metal–support interaction triggered d–p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper
Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe2O3 catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica with promoted CO insertion and C–C coupling for higher alcohol synthesis from syngas

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01179A, Paper
Zhuoshi Li, Siqi Fan, Zhuang Zeng, Shaoxia Guo, Xiaofeng Pei, Shouying Huang, Yong Wang, Yue Wang, Xinbin Ma
Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica showed superior performance for HAS than catalysts with uncoated and amorphous supports.
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Reduction on Specific Lattice Planes for Metal-organic Frameworks/Poly-pyrrole Composites with Dilated Porosity

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00766B, Paper
Wenxiu He, Xu Zhai, Zhipeng Qiao, Huan Chen, Weiliang Tian, Yu Fu, Junyi Chen
Owing to the microporosity, metal-organic frameworks (MOFs) have attracted great attention in various applications, whereas their potential in mass transfer and diffusion of larger molecules have been limited. To break...
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Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg1/2Ti1/2)O3–PbTiO3 ferroelectric re-entrant relaxor

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00240G, Paper
Laijun Liu, Kaiyuan Chen, Dawei Wang, Manuel Hinterstein, Anna-Lena Hansen, Michael Knapp, Biaolin Peng, Xianran Xing, Yuanpeng Zhang, Jing Kong, Abhijit Pramanick, Mads Ry Vogel Jørgensen, Frederick Marlton
Local structure information of relaxor ferroelectrics is key to a clear understanding of their structure–property relationships. The size of polar nanoregions is determined based on the local atomic displacement and dielectric response.
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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Renewable Aromatic Hydrocarbons from Waste Cooking Oil over Hierarchical Imidazole Supported Zeolite

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00416G, Paper
Bipul Sarkar, Bhanu Joshi, Omvir Singh, Ankit Agrawal, Neha Dhiman, Bhanu Prasad Vempatapu, Navin Gopinathan , Anjan Ray
Unlike coal, oil, or natural gas, waste cooking oil (WCO) acts as a renewable source of carbon. It can be converted into energy, fuels, and fine chemicals, instead of being...
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Regulating the local microenvironment on porous Cu nanosheets for enhancing electrocatalytic CO2 reduction selectivity to ethylene

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01198H, Paper
Dan Wang, Qingqing Song, Kaibin Li, Yuwei Zhou, Junjun Mao, Chenchen Zhang, Yang Lou, Chengsi Pan, Jiawei Zhang, Yongfa Zhu, Ying Zhang
Local microenvironments of the ECO2RR play an important role in tuning the adsorption energy of crucial intermediates, which helps enhance ECO2RR selectivity.
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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
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Bio-inspired design of a self-supported bismuth microforest for high performance sodium storage

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00950A, Paper
Jia Bai, Yan Liu, Ben Pu, Qi Tang, Yongbin Wang, Ruihan Yuan, Jin Cui, Yi Yang, Xiaojia Zheng, Bin Zhou, Weiqing Yang
A self-supported bismuth microforest anode material, prepared by a simple, efficient and scalable in situ galvanic replacement approach, exhibits high performance for sodium-ion batteries.
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Closed pore structure engineering from ultra-micropores with the assistance of polypropylene for boosted sodium ion storage

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01375A, Paper
Xue Li, Ning Sun, Shaohong Zhang, Razium Ali Soomro, Bin Xu
Closed pore architectures with exceptional Na-storage performance have been successfully fabricated from ultra-micropores with the assistance of polypropylene.
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Highly stable photovoltaic effects in A2+–Zr4+ (A = Ca, Sr, Ba) co-doped BiFeO3 films with self-polarization

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00649F, Paper
Lei Shi, Wenyue Zhao, Zhao Wang, Wenjing Hua, Xiaoxia Yang, Weidong Fei, Yu Zhao
The photovoltaic responses and temperature stabilities of A2+–Zr4+ (A = Ca, Sr, Ba) composite doped BiFeO3 films with self-polarization were enhanced in the R to MA phase transition.
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Cubic-to-hexagonal Structural Phase Transition in Metal Halide Compounds: A DFT Study

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06604E, Paper
Iván Ornelas-Cruz, Ramiro M. dos Santos, José E. González, Matheus Paes Lima, Juarez L. F. Da Silva
Phase transitions into photo-inactive structural phases have impacted the use of metal halide perovskites as photovoltaic materials. However, the chemical composition has been found to mitigate this issue. This study...
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Molecular-polaron-coupling-enhanced photocatalytic CO2 reduction on copper phthalocyanine/NiMgFe layered double hydroxide nanocomposites

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07538A, Paper
Yuexian Li, Wenli Su, Xiaoyan Wang, Jun Lu, Wenkai Zhang, Shuo Wei
We built CuPcS/NiMgFe-LDHs composites and probed the unique photogenerated-carrier transfer mechanism. A series of long-range Forster energy transfers prolonged the lifetime of photogenerated carriers to match the timescale of surface reaction.
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Harvesting solar energy with a Ni-MOF-based evaporator for efficient solar thermal storage and steam generation

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00203B, Paper
You Xu, Zhengyun Wang, Xianbao Wang, Zhenzhen Guo, Muhammad Sultan Irshad, Naila Arshad, Jiang Gong, Hongfang Liu, Guangfang Li
A hybrid solar evaporator comprising a Ni-based metal–organic framework material and a phase change material composite was fabricated for high performance solar-thermal energy storage and continuous solar vapor generation.
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S-doped TiN supported N, P, S-tridoped TiO2 with hetero-phase junctions for fuel cell startup/shutdown durability

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01475H, Paper
Mitsuharu Chisaka, Jubair A. Shamim, Wei-Lun Hsu, Hirofumi Daiguji
A platinum group metal-free S-doped TiN-supported N, P, S-tridoped TiO2 catalyst with anatase/rutile TiO2 hetero-phase junctions is revealed to display a high durability against fuel cell startup/shutdown cycles not to lose its anion dopants.
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Machine Learning Enabled Exploration of Multicomponent Metal Oxides for Catalyzing Oxygen Reduction in Alkaline Media

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01884B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xue Jia, Hao Li
Low-cost metal oxides have emerged as promising candidates used as electrocatalysts for oxygen reduction reaction (ORR) due to their remarkable stability under oxidizing conditions, particularly in alkaline media. Recent studies...
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The Role of Mn in Boosting Wide Potential Window on Solid Solution Derived Electrodes for Aqueous Supercapacitors

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00979G, Paper
Ziying Shi, Enzuo Liu, Biao Chen, Junwei Sha, Lihua Qian, Zhijia Zhang, Xiaopeng Han, Wenbin Hu, Chunnian He, Naiqin Zhao, Jianli Kang
The interaction mechanism of the multi-element oxide electrodes remains a challenge, despite the fact that their synergy can not only improve the electronic structure, but also broaden the working potential...
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Highly selective and high-performance sulfonated poly(ether ether ketone)-based hybrid membrane enabled by complexed UiO-66-NH2 and sulfonated graphitic carbon nitride for vanadium flow battery

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00988F, Paper
Caiyuan Zhao, Haixia Wang, Lang Li, Liping Liu, Xinrui Cui, Haifeng Shi
A series of sulfonated poly(ether ether ketone) (SPEEK) hybrid membranes (SPEEK/NF) with a constant 1 wt% complexed nanofillers (NF) comprising of UiO-66-NH2 and sulfonated graphitic carbon nitride (s-g-C3N4) are prepared...
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Toward record high Zn2+ storage in carbon electrodes via pore confinement engineering

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01191K, Paper
Xiubo Zhang, Chang Yu, Yuanyang Xie, Jinhe Yu, Yingbin Liu, Yi Yang, Jianjian Wang, Shuqin Lan, Siyi Hou, Kunlun Liu, Jieshan Qiu
The effective specific surface area is proposed and well correlated with Zn2+ storage, guiding maximum Zn2+ storage within carbon. Multiple in situ spectroscopy techniques clarify the co-adsorption mechanism of hydrated Zn2+, SO42−, and H+.
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Tua Tagovailoa on his post-interception tackle: "I wouldn't do anything differently"

By sports.yahoo.com
Published On :: Thu, 14 Nov 2024 00:49:52 GMT

Dolphins QB has no regrets about risking another concussion.


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The fluorescence distinction of chiral enantiomers: a Zn coordination polymer sensor for the detection of cinchonine and cinchonidine

By pubs.rsc.org
Published On ::

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03506B, Paper
Wenping Hu, Nan Wu, Dechao Li, Yefang Yang, Shaowen Qie, Shuai Su, Ruijie Xu, Wenting Li, Ming Hu
A Zn coordination polymer was constructed to identify chiral cinchonine and cinchonidine with high sensitivity, selectivity, and reproducibility.
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Breaking the Trade-off Between ∆EST and Oscillator Strength in Hybrid LR/SR-CT Compounds for Enhanced TADF Performance

By pubs.rsc.org
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J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04549A, Paper
Nikhitha R., Anirban Mondal
Achieving an ideal thermally activated delayed fluorescence (TADF) emitter requires balancing a minimal singlet-triplet energy gap (∆EST) with a considerable oscillator strength (f), which are typically mutually exclusive. By strategically...
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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

By pubs.rsc.org
Published On ::

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
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Bank Nifty Prediction today – November 13, 2024: Short when the support is breached

By www.thehindubusinessline.com
Published On :: Wed, 13 Nov 2024 11:11:35 +0530

Bank Nifty futures is now testing the support at 51,000


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Coimbatore District Police arrest two men for robbing Kerala jeweller of ₹54 lakh

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 19:29:30 +0530


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Legal battle over permanent English teacher appointments in high school continues

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 20:27:56 +0530

Govt cites financial problems; PSC rank-holders say posts are being created for other language subjects


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Food prices rising due to failed policies of Modi govt., says Congress

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 21:03:46 +0530

Tomatoes, onions, and potatoes disappearing from common man’s plate, says Jairam Ramesh


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BJP’s win in recent polls is expression of people’s faith in govt. policies: Haryana Governor

By www.thehindu.com
Published On :: Thu, 14 Nov 2024 07:50:35 +0530


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Govt. charges BRS with hatching conspiracies to stall development projects for political gains

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 19:17:30 +0530

Dy CM says involvement of BRS leader in Lagacharla incident exposes the party’s intentions


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Hyderabad GPO extends operating hours for mail bookings

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 20:49:21 +0530


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Global fossil emissions to reach record high in 2024; India's share to rise by 4.6%: Report

By www.thehindubusinessline.com
Published On :: Wed, 13 Nov 2024 10:10:34 +0530

According to a UN report released last month, India's greenhouse gas emissions surged by 6.1 per cent in 2023, contributing to 8 per cent of the global total


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Google.org awards USD 1 mn grant to Karya to boost ai-based economic opportunities for low-income communities

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:40:02 +0530


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India among top 10 countries in patents, trademarks, and industrial designs: WIPO 2024 report

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:58:02 +0530


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Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:02:02 +0530


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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:04:01 +0530


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'PM Modi's govt gives highest priority to over 35 mn Indian diaspora', says EAM Jaishankar on website launch for Pravasi Bharatiya Divas

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 16:04:01 +0530


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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 18:34:02 +0530


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BRO rescues 20 vehicles stuck in snow in J-K's Bandipora

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:12:01 +0530


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Union Education Minister Dharmendra Pradhan urges states to support exam reforms for zero-error entrance test

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:22:01 +0530


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Union Jal Shakti Minister CR Paatil chairs 13th high-powered review meeting of Brahmaputra Board

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:34:02 +0530


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HC quashes magistrate court’s directive to register FIR against police officers

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 19:36:51 +0530

Magistrate court’s order to file FIR against police officers, including IPS officer and former Malappuram Superintendent of Police Sujith Das, in connection with an alleged sexual assault case quashed


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Afghanistan attends U.N. climate talks for first time since Taliban return to power

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 11:33:16 +0530

Afghanistan’s first delegation at United Nations climate talks since the Taliban’s return to power in 2021 has arrived in Baku, Azerbaijan


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In vitro identification of oridonin hybrids as potential anti-TNBC agents inducing cell cycle arrest and apoptosis by regulation of p21, γH2AX and cleaved PARP

By pubs.rsc.org
Published On ::

RSC Med. Chem., 2024, 15,3674-3694
DOI: 10.1039/D4MD00580E, Research Article
Jinhua Ning, Nini Zhan, Zhanpan Wu, Yuzhe Li, Die Zhang, Yadian Shi, Yingxun Zhou, Chuan-Huizi Chen, Wenbin Jin
Oridonin analogue 11a showed significant antitumor efficacy in vitro via cell cycle arrest and apoptosis by regulation of p21, γH2AX and cleaved PARP accumulation, meanwhile, displayed much more stable than oridonin in human plasma.
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Stachydrine, a pyrrole alkaloid with promising therapeutic potential against metabolic syndrome and associated organ dysfunction

By pubs.rsc.org
Published On ::

RSC Med. Chem., 2024, 15,3652-3673
DOI: 10.1039/D4MD00425F, Review Article
Semim Akhtar Ahmed, Prasenjit Manna, Jagat Chandra Borah
Metabolic syndrome is a multifaceted condition marked by interconnected risk factors, significantly increasing the risk of serious diseases like cardiovascular disease, type 2 diabetes, and stroke.
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