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Small Industries Development Bank of India

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Small Industries Development Bank of India


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Container Corporation of India

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Container Corporation of India


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Reserve Bank of India

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Reserve Bank of India


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Ministry of New and Renewable Energy

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Ministry of New and Renewable Energy


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Facile fabrication of a hybrid polymer electrolyte via initiator-free thiol–ene photopolymerization for high-performance all-solid-state lithium metal batteries

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Polym. Chem., 2020, 11,2732-2739
DOI: 10.1039/D0PY00203H, Paper
Cai Zuo, Binghua Zhou, Ye Hyang Jo, Sibo Li, Gong Chen, Shaoqiao Li, Wen Luo, Dan He, Xingping Zhou, Zhigang Xue
The article reports the facile fabrication of a solid polymer electrolyte via initiator-free thiol–ene photopolymerization for all-solid-state lithium metal batteries.
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Tin(II) 2-ethylhexanoate catalysed methanolysis of end-of-life poly(lactide)

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Polym. Chem., 2020, 11,2625-2629
DOI: 10.1039/D0PY00292E, Communication
Melanie Hofmann, Christoph Alberti, Felix Scheliga, Roderich R. R. Meißner, Stephan Enthaler
The depolymerisation of end-of-life poly(lactide) (PLA) goods was studied as part of the chemical recycling of PLA.
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Correction: Block copolymer hierarchical structures from the interplay of multiple assembly pathways

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Polym. Chem., 2020, 11,2762-2762
DOI: 10.1039/D0PY90057E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessandro Ianiro, Meng Chi, Marco M. R. M. Hendrix, Ali Vala Koç, E. Deniz Eren, Michael Sztucki, Andrei V. Petukhov, Gijsbertus de With, A. Catarina C. Esteves, Remco Tuinier
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A covalently crosslinked silk fibroin hydrogel using enzymatic oxidation and chemoenzymatically synthesized copolypeptide crosslinkers consisting of a GPG tripeptide motif and tyrosine: control of gelation and resilience

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00187B, Paper
Hiromitsu Sogawa, Takuya Katashima, Keiji Numata
A covalently crosslinked silk fibroin hydrogel was successfully formed via an enzymatic crosslinking reaction using copolypeptides, which consist of a glycine–proline–glycine tripeptide motif and tyrosine, as linker molecules.
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Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00369G, Paper
Xun Zhang, Siping Hu, Qiang Ma, Saihu Liao
A visible light-regulated ring-opening polymerization of lactones has been developed based on the excited state acidity of ESPT molecules.
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Synthesis and enantioseparation of proline-derived helical polyacetylenes as chiral stationary phases for HPLC

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00205D, Paper
Ge Shi, Xiao Dai, Yue Zhou, Jie Zhang, Jun Shen, Xinhua Wan
Proline-derived aliphatically substituted polyacetylenes with stable helical conformations exhibit an excellent enantioseparation ability as chiral stationary phases of HPLC.
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Synthesis of star-shaped polyzwitterions with adjustable UCST and fast responsiveness by a facile RAFT polymerization

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00318B, Paper
Zhi Li, Hao Li, Zhonghe Sun, Botao Hao, Tung-Chun Lee, Anchao Feng, Liqun Zhang, San H. Thang
We describe crosslinking of polyzwitterions for the formation of novel star-shaped polymers with low polydispersities and dual-responsiveness using RAFT polymerization.
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Poly(hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00088D, Review Article
Elena Gabirondo, Ainara Sangroniz, Agustin Etxeberria, Sergio Torres-Giner, Haritz Sardon
Poly(hydroxy acids) derived from the self-condensation of hydroxy acid are biodegradable and can be fully recycled in a Circular Economy approach.
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Cross-linker control of vitrimer flow

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00233J, Paper
Bassil M. El-Zaatari, Jacob S. A. Ishibashi, Julia A. Kalow
The rate of stress relaxation in a vitrimer can be modulated by changing solely the structure of the cross-linker electrophile.
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Surfactant-free synthesis of layered double hydroxide-armored latex particles

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00140F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
X. G. Qiao, P.-Y. Dugas, V. Prevot, E. Bourgeat-Lami
MgAl-layered double hydroxide (LDH)-armored latexes were produced by Pickering emulsion polymerization of styrene using 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) as auxiliary comonomers.
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Miniemulsion polymerization of styrene using carboxylated graphene quantum dots as surfactant

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00404A, Paper
Le N. M. Dinh, Lakshmi N. Ramana, Vipul Agarwal, Per B. Zetterlund
Carboxylated graphene quantum dots (cGQDs) were synthesized from dextrose and sulfuric acid via a hydrothermal process, and subsequently used as sole surfactant in miniemulsion polymerization of styrene.
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Using the dynamic behavior of macrocyclic monomers with a bis(hindered amino)disulfide linker for the preparation of end-functionalized polymers

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00366B, Paper
Hirogi Yokochi, Rikito Takashima, Daisuke Aoki, Hideyuki Otsuka
End-functionalized polymers were synthesized by simply heating a mixture of a macrocyclic compound with one bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) moiety and bifunctional acyclic BiTEMPS compounds as sources of repeat units and terminal groups, respectively.
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Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00249F, Communication
Zhonghua Cheng, Lei Wang, Yan He, Xingjia Chen, Xiaojun Wu, Hangxun Xu, Yaozu Liao, Meifang Zhu
A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts.
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Synthesis of acrylamide-based block-copolymer brushes under flow: monitoring real-time growth and surface restructuring upon drying

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00219D, Paper
Open Access
Joydeb Mandal, Andrea Arcifa, Nicholas D. Spencer
Block-copolymer brushes of water-soluble acrylamides have been synthesised by SI-ATRP under continuous flow and their growth monitored in situ by means of a quartz-crystal microbalance with dissipation (QCM-D).
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Preparation of aryl polysulfonates via a highly efficient SuFEx click reaction, their controllable degradation and functionalized behavior

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00435A, Communication
Zhenlei Cao, Feng Zhou, Pei-Yang Gu, Dongyun Chen, Jinghui He, John R. Cappiello, Peng Wu, Qingfeng Xu, Jianmei Lu
Polysulfonates obtained from SuFEx click reaction can be degraded using DBU. The degradation process was further utilized to prepare functional polymers.
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Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00174K, Paper
Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai, Bao-Tsan Ko
Catalyst 1 was reported for the first time to be effective for nickel-catalyzed CO2/CHO copolymerization at 1 atm CO2 pressure.
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Enhanced thermomechanical property of a self-healing polymer via self-assembly of a reversibly cross-linkable block copolymer

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00310G, Paper
Hyang Moo Lee, Suguna Perumal, Gi Young Kim, Jin Chul Kim, Young-Ryul Kim, Minsoo P. Kim, Hyunhyup Ko, Yecheol Rho, In Woo Cheong
Introduction of a self-healable block copolymer increases the mechanical property whilst maintaining self-healing efficiency.
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Hydrogen-bonded supramolecular micelle-mediated drug delivery enhances the efficacy and safety of cancer chemotherapy

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Polym. Chem., 2020, 11,2791-2798
DOI: 10.1039/D0PY00082E, Paper
Chih-Chia Cheng, Ya-Ting Sun, Ai-Wei Lee, Shan-You Huang, Wen-Lu Fan, Yu-Hsuan Chiao, Chih-Wei Chiu, Juin-Yih Lai
Multiple hydrogen-bonded supramolecular polymers tend to form stable spherical micelles with oppositely charged anticancer drugs in biological environments, which improves cellular drug uptake and more effectively induces apoptosis in cancer cells.
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Temporal control of RAFT polymerization via magnetic catalysis

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Polym. Chem., 2020, 11,2838-2846
DOI: 10.1039/D0PY00220H, Paper
Amin Reyhani, Omid Mazaheri, Masood S. Alivand, Kathryn A. Mumford, Greg Qiao
Magnetic core–shell structured Fe3O4@Fe(II)–MOF nanoparticles have enabled the temporal control of RAFT polymerization via an “on–off” process.
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Polymerization of dopamine accompanying its coupling to induce self-assembly of block copolymer and application in drug delivery

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Polym. Chem., 2020, 11,2811-2821
DOI: 10.1039/D0PY00085J, Paper
Yudian Qiu, Zongyuan Zhu, Yalei Miao, Panke Zhang, Xu Jia, Zhongyi Liu, Xubo Zhao
The polymerization of dopamine and its coupling occur in succession, which synergistically induces the self-assembly of block copolymer to yield ordered structures, including micelles and vesicles.
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Simple improvements to Gilch synthesis and molecular weight modulation of MEH-PPV

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Polym. Chem., 2020, 11,2831-2837
DOI: 10.1039/D0PY00072H, Paper
Riley O'shea, Wallace W. H. Wong
The solvent and temperature used in the Gilch synthesis of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) were varied to achieve an improved set of reaction conditions.
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Vesicular assemblies of thermoresponsive amphiphilic polypeptide copolymers for guest encapsulation and release

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Polym. Chem., 2020, 11,2889-2903
DOI: 10.1039/D0PY00135J, Paper
Mahammad Anas, Somdeb Jana, Tarun K. Mandal
Thermoresponsive amphiphilic polypeptide copolymers are synthesized via different polymerization techniques for their self-assembly into vesicular aggregates for guest encapsulation and release.
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Self-supported rhodium catalysts based on a microporous metal–organic framework for polymerization of phenylacetylene and its derivatives

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Polym. Chem., 2020, 11,2904-2913
DOI: 10.1039/D0PY00170H, Paper
Li Zhang, Qingbin Cao, Fei Gao, Yuping Dong, Xiaofang Li
Highly efficient, cis-selective, stable, recyclable and reusable heterogeneous single-site MOF-supported rhodium catalysts polymerize PA and its derivatives, producing cis-transoidal PPAs and their functional derivatives having a helical configuration or AIE properties.
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Synthesis of a side-chain hole transporting polymer through Mitsunobu post-functionalization for efficient inverted perovskite solar cells

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Polym. Chem., 2020, 11,2883-2888
DOI: 10.1039/D0PY00134A, Paper
Liuyuan Lan, Xiang Deng, Jie Zhang, Jingdong Luo, Alex K.-Y. Jen
Mitsunobu post-functionalization was utilized to construct a new efficient dopant-free side-chain hole transporting polymer for inverted perovskite solar cells, exhibiting a power conversion efficiency of 17.75% and a high fill factor over 81%.
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Synthesis of biscarboxylic acid functionalised EDTA mimicking polymers and their ability to form Zr(IV) chelation mediated nanostructures

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Polym. Chem., 2020, 11,2799-2810
DOI: 10.1039/D0PY00304B, Paper
Meike N. Leiske, Julia A. Walker, Aadarash Zia, Nicholas L. Fletcher, Kristofer J. Thurecht, Thomas P. Davis, Kristian Kempe
We present a new biscarboxylic acid acrylate, which is used for the synthesis of double hydrophilic EDTA-mimicking block copolymers capable of self-assembly upon zirconium complexation.
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Well-controlled polymerization of tri-vinyl dynamic covalent boroxine monomer: one dynamic covalent boroxine moiety toward a tunable penta-responsive polymer

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Polym. Chem., 2020, 11,2914-2922
DOI: 10.1039/D0PY00401D, Paper
Shun-Shun Li, Xin-Hu Lv, Xiao-Li Sun, Wen-Ming Wan, Hongli Bao
Attributed to dynamic characteristics of dynamic covalent boroxine, well-controlled polymerization of tri-vinyl monomer and molecular design of penta-responsive polymer with only one functional moiety are achieved.
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Tuning polymer properties of non-covalent crosslinked PDMS by varying supramolecular interaction strength

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Polym. Chem., 2020, 11,2847-2854
DOI: 10.1039/D0PY00139B, Paper
Open Access
Brigitte A. G. Lamers, Marcin L. Ślęczkowski, Fabian Wouters, Tom A. P. Engels, E. W. Meijer, Anja R. A. Palmans
Linear polydimethylsiloxane (PDMS) is crosslinked by supramolecular grafts to obtain materials with strikingly different mechanical properties by tuning the strength of the non-covalent interactions.
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Mechanical activation of polymers containing two adjacent mechanophores

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Polym. Chem., 2020, 11,2864-2868
DOI: 10.1039/D0PY00279H, Paper
Richard Stevenson, Min Zhang, Guillaume De Bo
Polymers containing two adjacent mechanophores cleave at the same as a single-mechanophore chains.
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Influence of surface charge on the formulation of elongated PEG-b-PDLLA nanoparticles

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Polym. Chem., 2020, 11,2775-2780
DOI: 10.1039/D0PY00280A, Communication
Open Access
Roxane Ridolfo, David S. Williams, Jan C. M. van Hest
Amphiphilic PEG-PDLLA copolymers undergo assembly into polymersomes and can be transformed into tubular shapes using dialysis. By fine-tuning the shape change conditions also amine- and carboxylic acid modified polymersomes can now be effectively turned into tubes.
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Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00322K, Paper
Haoyu Yu, Jianwei Shao, Dong Chen, Li Wang, Wantai Yang
TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.
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Amide transformation as an efficient postpolymerization modification approach for the synthesis of functional polyacetylenes

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00398K, Paper
Juntao Ren, Heng Liu, Xuequan Zhang, Yanming Hu, Guangyuan Zhou, Toshio Masuda
Modification of a precursor polyacetylene with various amines and alcohols through amide transformation gives access to a series of functional polymers showing nonlinear optical, luminescence, enhanced surface energy, and redox active properties.
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Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00453G, Paper
Yongjun Shin, Matthew L. Becker
A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)2(THF)2 catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.
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Hierarchical self-assembled nanostructures of lactone-derived thiobarbiturate homopolymers for stimuli-responsive delivery applications

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00367K, Paper
Piyali Mandal, Diptendu Patra, Raja Shunmugam
Hierarchical self-assembled nanostructures of lactone-derived thiobarbiturate homopolymers for stimuli-responsive delivery applications are shown.
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Tacticity dependence of single chain polymer folding

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00133C, Paper
Open Access
Denis Danilov, Elaheh Sedghamiz, Heike Fliegl, Hendrik Frisch, Christopher Barner-Kowollik, Wolfgang Wenzel
Precision polymerization techniques offer the exciting opportunity to manufacture single-chain nanoparticles (SCNPs) with intramolecular crosslinks placed in specific positions along the polymer chain.
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Self-assembly of strawberry-like organic–inorganic hybrid particle clusters with directionally distributed bimetal and facile transformation of the core and corona

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00237B, Paper
Shuxing Mei, Mingwang Pan, Juan Wang, Xiaopeng Zhang, Shaofeng Song, Chao Li, Gang Liu
Controllable structure of organic–inorganic hybrid particle clusters were successfully fabricated by self-assembly which derived from the strong interaction between carboxyl groups of the organic particles and amino groups of the inorganic particles.
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Polymersome formation induced by encapsulation of water-insoluble molecules within ABC triblock terpolymers

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00426J, Paper
Rintaro Takahashi, Shotaro Miwa, Carsten Rössel, Shota Fujii, Ji Ha Lee, Felix H. Schacher, Kazuo Sakurai
We found a morphological transition from spherical micelles to polymersomes induced by encapsulation of hydrophobic guest molecules.
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Multi-photon polymerization of bio-inspired, thymol-functionalized hybrid materials with biocompatible and antimicrobial activity

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00281J, Communication
Open Access
Kostas Parkatzidis, Maria Chatzinikolaidou, Eleftherios Koufakis, Maria Kaliva, Maria Farsari, Maria Vamvakaki
Thymyl-methacrylate functionalized, hybrid 3D scaffolds, fabricated by multi-photon lithography, exhibit excellent biocompatibility and antimicrobial action for bone and dental tissue engineering.
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Rapid production of block copolymer nano-objects via continuous-flow ultrafast RAFT dispersion polymerisation

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00276C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sam Parkinson, Stephen T. Knox, Richard A. Bourne, Nicholas J. Warren
Continuous-flow reactors are exploited for conducting ultrafast RAFT dispersion polymerisation for the preparation of diblock copolymer nanoparticles.
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Comprehensive theoretical and experimental study of near infrared absorbing copolymers based on dithienosilole

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00330A, Paper
Katarzyna Brymora, Wissem Khelifi, Sylvie Blanc, Lionel Hirsch, Antoine Bousquet, Christine Lartigau-Dagron, Frederic Castet
In recent contributions [Eur. Polym. J. 2013, 49, 4176; Macromolecules 2019, 52, 13, 4820], we reported a series of low band gap copolymers with the objective of shifting the absorption...
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Fluorescent chemosensors based on conjugated polymers with N-heterocyclic moieties: two decades of progress

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Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00336K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Taisheng Wang, Na Zhang, Wei Bai, Yinyin Bao
A brief summary of representative fluorescent chemosensors based on conjugated polymers with N-heterocyclic moieties, followed by a discussion on the limitations and challenges of current systems, as well as possible future research directions.
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Room Temperature Synthesis of Block Copolymer Nano-Objects with Different Morphologies via Ultrasound Initiated RAFT Polymerization-Induced Self-Assembly (Sono-RAFT-PISA)

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00461H, Paper
Jing Wan, Bo Fan, Yiyi Liu, Tina Hsia, Kaiyuan Qin, Tanja Junkers, Boon M. Teo, San Thang
Polymerization-induced self-assembly (PISA), which allows scalable synthesis of nano-objects, has drawn significant research attention in the past decade. However, the initiation methods in most of the current reported PISA are...
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Dibenzothiophene-S,S-Dioxide-Bispyridinium-Fluorene-Based Polyelectrolytes for Cathode Buffer Layers of Polymer Solar Cells

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00416B, Paper
Guiting Chen, Dan Cheng, Wenyan Zou, Ziyan Cai, Yufeng Xie, Yaqi Chen, Baitian He, Hong-Qing Hao, Wei Yang, Yong Cao
Herein, a novel electron-deficient conjugated water/alcohol-soluble polyelectrolyte (WSPE) named as PFSOPyCl-E, consisting of dibenzothiophene-S,S-dioxide, bispyridinium salts and fluorene with ethylene oxide side chains, was presented. Previously we have synthesized another...
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Optimizing the Thermoelectric Performance of Conjugated Polymer Backbones via Incorporating Tailored Platinum (II) Acetylides

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Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00464B, Paper
Chunfa Liu, Xiaojun Yin, Jianwen Liu, Chunmei Gao, Lei Wang
Efforts to improve the electrical conductivity (σ) of the organic semiconductors propose the critical challenge for high performance organic thermoelectric (TE) devices. Herein, five new conjugated polymers incorporated with different...
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Photo-induced copper mediated copolymerization of activated-ester methacrylate polymers and their use as reactive precursors to prepare multi-dentate ligands for the water transfer of inorganic nanoparticles

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Polym. Chem., 2020, 11,2969-2985
DOI: 10.1039/D0PY00212G, Paper
Binh T. Mai, Markus J. Barthel, Aidin Lak, Tommaso Avellini, Ana Maria Panaite, Emille M. Rodrigues, Luca Goldoni, Teresa Pellegrino
Polymers bearing activated ester groups are synthesized using photo-ATRP and used as precursors for direct synthesis of multi-phosphonic acid functionalized ligands which are able to transfer different nanoparticles with distinct cores into water.
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Effects of tacticity and chiral center-to-dipole distance on mesogen-free liquid crystalline self-assembly of sulfonyl-containing comb-like polymers

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Polym. Chem., 2020, 11,3018-3031
DOI: 10.1039/D0PY00199F, Paper
Caleb A. Bohannon, Man-Hin Kwok, Ruipeng Li, Lei Zhu, Bin Zhao
Mesogen-free comb-like polyethers bearing strongly interacting mono- and di-sulfonylated side chains exhibit well-defined liquid crystalline self-assembly.
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Development and disassembly of single and multiple acid-cleavable block copolymer nanoassemblies for drug delivery

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Polym. Chem., 2020, 11,2934-2954
DOI: 10.1039/D0PY00234H, Review Article
Arman Moini Jazani, Jung Kwon Oh
Acid-degradable block copolymer-based nanoassemblies are promising intracellular candidates for tumor-targeting drug delivery as they exhibit the enhanced release of encapsulated drugs through their dissociation.
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