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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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CDs "inserted" abundant FeB based electrode via "local photothermal effect" strategy toward efficient overall seawater splitting

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00415A, Research Article
Shiheng Liang, Liugang Wu, Yiming Wang, Yuqi Shao, Hongyuan Song, Ziliang Chen, Weiju Hao
Construction of high-efficiency, long-stable catalytic electrodes for hydrogen by seawater splitting is a huge challenge in the field of green hydrogen. Herein, a matrix-type titanium dioxide nanorod (Ti/TiO2) is constructed...
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Crude oil futures rebound after Tuesday’s fall

By www.thehindubusinessline.com
Published On :: Wed, 09 Oct 2024 11:59:50 +0530

Uncertainties over the developments in West Asia helped boost the price of the commodity


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Crude oil futures recover after Tuesday’s fall

By www.thehindubusinessline.com
Published On :: Wed, 16 Oct 2024 10:29:58 +0530

October crude oil futures were trading at ₹5953, up by 0.30 per cent, and November futures were trading at ₹5931, up by 0.58 per cent, during the initial hours


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Stronger monsoon winds bringing more rainfall to arid regions of north-west India: Southampton varsity study

By www.thehindubusinessline.com
Published On :: Mon, 21 Oct 2024 17:54:05 +0530

The study reports 40% increase in south-west monsoon rainfall over north-west India in recent years  


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Not much relevance of windfall tax on crude now: Advisor to PM

By www.thehindubusinessline.com
Published On :: Wed, 23 Oct 2024 15:15:22 +0530

Windfall Tax is to counterbalance the unusually high profits earned by oil and gas companies from high global crude oil prices


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Board to convene consumers meeting next week over falling natural rubber prices

By www.thehindubusinessline.com
Published On :: Thu, 24 Oct 2024 14:08:38 +0530

Rubber Board officials said prices exceeded Rs₹200 on June 11 but plummeted 24 per cent to ₹187 per kg by October 21. The Board may ask consumers to proactively purchase in the domestic market


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Oil prices likely to fall after Israel shows restraint in strikes on Iran

By www.thehindubusinessline.com
Published On :: Sun, 27 Oct 2024 09:53:24 +0530

Scores of Israeli jets completed three waves of strikes before dawn on Saturday against missile factories and other sites near Tehran and in western Iran, in the latest exchange in the escalating conflict between the Middle East rivals


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Crude oil futures fall as industry data shows inventory gain in US 

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 11:00:11 +0530

Market eyes results of the US presidential election


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Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

By www.thehindubusinessline.com
Published On :: Sun, 29 Oct 2023 17:45:00 +0530

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 


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Crystal-ball gazing: Diagnostics, faster & more precise

By www.thehindubusinessline.com
Published On :: Sun, 07 Jan 2024 17:59:23 +0530

Comprehensive remote monitoring has the potential to revolutionise healthcare


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More than just a number: A call to improve adverse event reporting

By www.thehindubusinessline.com
Published On :: Sun, 26 May 2024 19:06:43 +0530

Heal the hurt: Redressal and support are critical to keep the faith in the system from breaking down


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Global rice prices drop over 10% after India lifts all curbs on exports

By www.thehindubusinessline.com
Published On :: Wed, 30 Oct 2024 18:46:37 +0530

Arrival of new crop in Pakistan, Myanmar add to the pressure on the market


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Blue Pearl, a new fish farmer producer company launched in Kodungallur

By www.thehindubusinessline.com
Published On :: Fri, 01 Nov 2024 19:42:36 +0530

Highlighting the rapid growth of the fisheries sector, the Minister said the Centre has outlined several schemes dedicated to strengthening the fisheries sector


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India’s night temperature rise in October breaks all time record, November may be ‘above normal’

By www.thehindubusinessline.com
Published On :: Fri, 01 Nov 2024 20:15:13 +0530

October was the warmest pan-India basis since 1901, with the mean temperature recording 1.23 degree Celsius above normal


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South Peninsula records 7% above normal rainfall so far, poised to get even more from later this week

By www.thehindubusinessline.com
Published On :: Mon, 04 Nov 2024 11:43:45 +0530

Easterly to north-easterly flows starting to rebuild after being scattered by severe cyclone Dana over the Bay


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Fertilizer sales hold steady as imports fall, production up 2% in H1

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 20:10:09 +0530

Government controls fertilizer sales, imports drop significantly, concerns raised over availability and pricing impacting farmers and production targets


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‘Lifting of MEP on non-Basmati rice helps India compete globally’

By www.thehindubusinessline.com
Published On :: Thu, 07 Nov 2024 14:59:41 +0530

The Food Ministry has announced another tender for 50,000 tonnes set to open on November 18


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Call for joint efforts to reduce greenhouse gas emissions at 31st Swadeshi Science Congress

By www.thehindubusinessline.com
Published On :: Thu, 07 Nov 2024 16:05:38 +0530

31st Swadeshi Science Congress inaugurated at Kochi’s ICAR-CIFT 


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Indian Tea Association calls for creating rating system based on quality of retail packets

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 21:24:18 +0530

Consumers should know the quality of blends used in the packets, says itsIndian Tea Association chief Hemant Bangur


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Key challenges faced by farmer producer companies in the agricultural ecosystem

By www.thehindubusinessline.com
Published On :: Sat, 09 Nov 2024 09:30:00 +0530

Building genuine connections and understanding the intrinsic motivations of farmers can create a vibrant ecosystem


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AP proposes ₹43,402 crore budget for agri allied sectors

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 14:35:44 +0530

Kinjarapu Acchannayudu, Andhra Pradesh Minister for Agriculture, said “the Government proposes a multi-pronged approach to make agriculture a profitable venture”


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Ginners call off stir as CCI asks farmers to bring raw cotton kapas to the nearest market yards

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 20:40:39 +0530

Cotton Corp assures to procure all fair-grade cotton from growers


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Promises fall flat for Maharashtra’s farmers amid unending agrarian crisis

By www.thehindubusinessline.com
Published On :: Tue, 12 Nov 2024 08:50:21 +0530

In the last 9 months alone, 1,933 Maharashtra farmers took their lives, a stark testament to the ongoing agrarian crisis that remains untouched by political promises 


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Cabinet greenlights ₹6,800 crore railway projects in key allies-run States of Andhra Pradesh, Bihar

By www.thehindubusinessline.com
Published On :: Thu, 24 Oct 2024 20:18:35 +0530

Emphasises development over politics, with religious and trade significance


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Proper road infrastructure, skilled workforce among key challenges for logistics industry: experts

By www.thehindubusinessline.com
Published On :: Sat, 26 Oct 2024 13:51:52 +0530

These challenges are pushing logistics firms to balance cost management, workforce, and technology investment to maintain competitiveness


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New terminal operating system and bunching of ships disrupt truck movements at Kattupalli and Ennore container terminals

By www.thehindubusinessline.com
Published On :: Tue, 29 Oct 2024 19:09:35 +0530

While the issue with the of TOS has been addressedsorted out, the trailers are still facing delays in the scanning centre


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India looks to alleviate container shortage amid Chinese front-loading and rising freight costs

By www.thehindubusinessline.com
Published On :: Sun, 03 Nov 2024 19:18:00 +0530

Govt working on policy interventions and increased capacities to address global demand


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KCCI unveils gallery showcasing Mangaluru’s rich maritime trade history 

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 15:42:35 +0530

The Jewesh trader of the 12th Century Abraham Bin Yiju called Mangaluru his home for 17 years, trading with various communities in the port


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Adani Kattupalli port continues to face operational challenges

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 15:49:23 +0530

Only one container ship to be berthed between November 11 and 14


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Air India-Vistara merger to save over ₹500 crore annually

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 20:28:09 +0530

Unified entity aims to achieve larger global and domestic footprint; the transformation strategy aims for ₹1,800 crore savings by FY27


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Airtel rolls out Covid support initiative for medium, small size companies

By www.thehindubusinessline.com
Published On :: Sat, 15 May 2021 13:34:27 +0530

Businesses will be able to set up a cloud communication platform with a Covid SOS feature


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On August 15, Carnegie Hall echoed with Eastern and Western musical notes

By www.thehindu.com
Published On :: Thu, 18 Aug 2022 18:06:17 +0530

Festival of India@75 brought together stalwart musicians to celebrate the freedom of musical expression


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85% industry leaders call for major investments in quantum computing: Report

By www.newkerala.com
Published On :: Tue, 12 Nov 2024 15:56:01 +0530


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Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, 15,18161-18169
DOI: 10.1039/D4SC04318A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan Li
A sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.
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A facile self-saturation process enabling the stable cycling of a small molecule menaquinone cathode in aqueous zinc batteries

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, 15,17971-17978
DOI: 10.1039/D4SC04685D, Edge Article
Open Access
Shuo Li, Guoli Zhang, Qianrui Li, Tianshun He, Xiaoqi Sun
A facile self-saturation strategy, realized by the introduction of a hydrophobic methyl group on naphthoquinone, is demonstrated to suppress the dissolution of small molecule cathode materials and achieve stable cycling in aqueous zinc cells.
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Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, 15,18111-18126
DOI: 10.1039/D4SC04852K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. Ofial
Combined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.
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Dilute nanocomposites for capacitive energy storage: progress, challenges and prospects

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05437G, Perspective
Open Access
Li Li, Wenhan Xu, Guanchun Rui, Shixian Zhang, Qiming Zhang, Qing Wang
Electrostatic capacitors (ECs) are critical components in advanced electronics and electric power systems due to their rapid charge-discharge rate and high power density. While polymers are ideal for ECs due...
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Pd(II)-Catalyzed Enantioselective C-H Olefination and Photoregulation of Sterically-Hindered Diarylethenes

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05375C, Edge Article
Open Access
Guanlun Zhang, Xu Wu, Shiyu Mao, Mengqi Li, Honglong Hu, Bing-Feng Shi, Weihong Zhu
Sterically-hindered diarylethenes with intrinsic chirality have shown great potential in chiral signal regulation, light-controlled liquid crystals (LCs), etc. Their unique enantiospecific phototransformation between axial chirality of ring-open isomer and central...
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Phenacylselenoesters allow facile selenium transfer and hydrogen selenide generation

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05788K, Edge Article
Open Access
Utsav Dey Sarkar, Mahima Rana, Harinath Chakrapani
A new series of phenacylselenoesters that generate hydrogen selenide in the presence of esterase and a biological thiol under ambient conditions is reported.
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Pd/NHC sequentially catalyzed atroposelective synthesis of planar-chiral macrocycles

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05482B, Edge Article
Open Access
Gongming Yang, Shangde Liu, Shujie Ji, Xingsen Wu, Jian Wang
The unprecedented non-enzymatically atroposelective synthesis of planar-chiral macrocycles via a Pd/NHC sequential catalytic intermolecular macrocyclization is reported.
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Merging nucleophilic phosphine catalysis and photocatalysis for the rapid assembly of 2-oxabicyclo-[2.1.1]hexane scaffolds from feedstock allyl alcohols

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06684G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David M. Whalley, Luca Carlino, Okky Dwichandra Putra, Niall A. Anderson, Susannah C. Coote, Olivier Lorthioir
A synthesis of 2-oxabicyclo-[2.1.1]hexanes from readily available allyl alcohols and electron-poor arylalkynes. The transformation utilises phosphine catalysis and energy transfer catalysis for rapid assembly of these diverse scaffolds.
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From small changes to big gains: pyridinium-based tetralactam macrocycle for enhanced sugar recognition in water

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06190J, Edge Article
Open Access
Canjia Zhai, Ethan Cross Zulueta, Alexander Mariscal, Chengkai Xu, Yunpeng Cui, Xudong Wang, Huang Wu, Carson Doan, Lukasz Wojtas, Haixin Zhang, Jianfeng Cai, Libin Ye, Kun Wang, Wenqi Liu
Incorporating pyridinium into an anthracene-based macrocycle significantly enhances its sugar binding affinity by increasing hydrogen bonding and expanding the contact surface area.
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Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article
Open Access
Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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Allosteric release of cucurbit[6]uril from a rotaxane using a molecular signal

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC03970J, Edge Article
Open Access
Aneta Závodná, Petr Janovský, Václav Kolařík, Jas S. Ward, Zdeňka Prucková, Michal Rouchal, Kari Rissanen, Robert Vícha
Repulsions between portals of cucurbit[n]urils are sufficiently strong to unlock the rotaxane structure.
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Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06083K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa Jung
The modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.
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Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05396F, Edge Article
Open Access
Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff Zaleski
Using a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...
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All that jazz

By www.thehindu.com
Published On :: Sat, 05 Nov 2016 00:00:00 +0530

After being part of the Mumbai Film Festival, The Vitaliy Tkachuk Quartet would like to come back to Mumbai soon, finds Satya Kandala


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Writer calling writer

By www.thehindu.com
Published On :: Mon, 07 Nov 2016 00:00:00 +0530

Hatufim creator Gideon Raff speaks to Aniruddha Guha about the cultural variances of different versions of the same story


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