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The healing touch in troubled times

How a hospital in rural Kashmir coped during the lockdown




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When parched fields bloomed with flow of water

An initiative to build groundwater reserves has turned farmers’ fortunes in Raigad district




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Reaping a knowledge-enabled harvest

A joint project educating Uttar Pradesh farmers on sustainable agriculture practices has helped improve output




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With no stable income, their earnings have bolted

Covid-19 has meant no tourists or joy rides at the Ridge in Shimla, leaving horse owners in penury




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Reaping profits from perishables

Through innovation, two start-ups help tribal and marginal farmers in Chhattisgarh and Bihar preserve and market their produce




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The blackboard must beckon

Covid impact: Mental health issues and children dropping out of school must be tackled urgently




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Life blooms for Odisha farmers with waterbody rejuvenation




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ARIA-AT Public Data Management Page

Over the last few months, we’ve been making substantial improvements to the ARIA-AT app, from backend database work to performance improvements, to making the app generally nicer to use. One of these improvements is the ability to view the Data Management Page without being logged in. The Data Management page allows visitors to view the […]




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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Synthesis of furan-based conjugated polymers with tunable bandgaps via direct C–H arylation of oligofurans

Polym. Chem., 2024, 15,4339-4348
DOI: 10.1039/D4PY00834K, Paper
Hui Guo, Dayong Jiang, Yufan Gu, Ruixin Wang, Luoyi Wang, Xu-Hui Jin
Using long oligofurans as synthetic building blocks has been found to enable the efficient synthesis of conjugated furan-based polymers through direct C–H arylation, which exhibit excellent antimicrobial activity.
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Comment on “Limonene as a renewable unsaturated hydrocarbon solvent for living anionic polymerization of β-myrcene” by A. Dev, A. Rösler and H. Schlaad, Polym. Chem., 2021, 12, 3084

Polym. Chem., 2024, 15,4364-4365
DOI: 10.1039/D4PY00913D, Comment
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akhil Dev, Alexander Rösler, Helmut Schlaad
Polymyrcenyllithium chains in DL-limonene solution are present as dimeric associates and not as single chains.
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Scalable design of uniform oligourethanes for impact study of chain length, sequence and end groups on thermal properties

Polym. Chem., 2024, 15,4319-4326
DOI: 10.1039/D4PY01001A, Paper
Open Access
Jens Van Hoorde, Nezha Badi, Filip E. Du Prez
A bidirectional growth-based protocol is used for the synthesis of a series of sequence-defined oligourethanes in large scale (50 g). The effect of chain length, sequence and end group functionalities on the thermal properties is evaluated.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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Long afterglow epoxidized soybean oil polymer composites with reversible dynamic cross-linking for intelligent coating

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00857J, Paper
Jiaman Hu, Zihao Wang, Minglin Yang, Chuansong Yu, Siyu Li, Yinggang Miao, Xiangqian Quan, Jize Liu, Shiyang Shao
High-performance coatings with advanced functions such as long afterglow luminescence and self-healing have attracted great interest around the world, however, the integration of these desired multifunctions in a single composite...
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Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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Expanding the poly(2-oxazoline) block copolymer possibilities through nitroxide mediated polymerisation

Polym. Chem., 2024, 15,4416-4424
DOI: 10.1039/D4PY00887A, Paper
Open Access
James Lefley, C. Remzi Becer
In recent years, poly(2-oxazoline)s (POx) have become a sought-after biomaterial to replace PEG. Endcapping POx with BlocBuilder MA enables copolymerization with a variety of vinylic monomers, producing unique POx-vinyl block copolymer combinations.
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A novel amine-first strategy suitable for preparing both functional and engineering bio-polyamides: furfurylamine as the sole furan source for bisfuranic diamine/diacid monomers

Polym. Chem., 2024, 15,4433-4446
DOI: 10.1039/D4PY00567H, Paper
Hong-Hui Shu, Yun Liu, Sheng-Li Han, Xiu-Qin Fang, Chang Wang, Cheng-Mei Liu
Biomass-based polyamides (bioPAs) are renewable materials that are viable alternatives to petroleum-based polyamides in the engineering field.
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Polyols from cashew nut shell liquid (CNSL): corner-stone building blocks for cutting-edge bio-based additives and polymers

Polym. Chem., 2024, 15,4375-4415
DOI: 10.1039/D4PY00851K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Emilie Rojtman, Maxinne Denis, Camille Sirvent, Vincent Lapinte, Sylvain Caillol, Benoit Briou
From CNSL to polyols.
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Bio-photo-Fenton-like RAFT polymerization under blue light

Polym. Chem., 2024, 15,4447-4453
DOI: 10.1039/D4PY00593G, Paper
James L. Grace, Greg G. Qiao
An oxygen-tolerant bio-photo-Fenton RAFT polymerization method that possesses good livingness and temporal control.
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Acid-labile and non-degradable cross-linked star polymer model networks by aqueous polymerization for in situ encapsulation and release

Polym. Chem., 2024, 15,4454-4464
DOI: 10.1039/D3PY00677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gavin Irvine, Stuart Herron, Daniel W. Lester, Efrosyni Themistou
Aqueous RAFT polymerization for the preparation of degradable and non-degradable cross-linked star polymer model networks, in situ dye encapsulation and release.
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Increase of spatiotemporal resolution and reproducible layer thicknesses in cationic vat photopolymerization

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01046A, Paper
Emile Goldbach, Xavier Allonas, Christian Ley, Lucile Halbardier, Céline Croutxé-Barghorn
Pyridines allow a good control of the cationic photopolymerization of epoxies.
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Solvent quality shape control in continuous flow block copolymer self-assembly

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01174K, Communication
Axel-Laurenz Buckinx, Lakshani J. Weerarathna, Anna Sokolova, Tanja Junkers
The influence of solvent quality on block copolymer self assembly is studied in detail using SANS online monitoring.
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Constructing self-healing flexible supercapacitors via graphene oxide synergistic multi-network polymer-supramolecular hydrogel electrolyte

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00809J, Paper
Xiaoyan Li, Xiuting Shi, Anbai Li, Mengmeng Xun, Shuzhen Cui, Kanjun Sun, Hui Peng, Guofu Ma, Yuxi Xu
Hydrogels are increasing interest and have great potential as electrolytes for flexible supercapacitors (FSCs) in wearable and portable electronic devices. However, the hydrogel electrolytes for practical applications are hampered by...
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Star Copolymers with Tunable Clusteroluminescence

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01198H, Communication
Zixuan Zhou, Xiang Chen, Yang Wang, Ting Li, Xuhui Zhang, Bihua Xia, Shibo Wang, Weifu Dong, Jinliang Qiao
Clusteroluminescence (CL) has recently drawn more attention due to its unique photophysical behaviors that differ from traditional conjugated luminogens. However, the design of red emission from such systems is still...
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Reversible aminolysis: a new concept for postpolymerization modification

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00827H, Communication
Koki Kasai, Hideki Amii, Ryohei Kakuchi
Efficient yet reversible aminolysis postpolymerization modification reactions.
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Reducing Agent Triggered Templated Synthesis of Dynamic Covalent Poly(disulfide)s Nanonetwork: Remarkable Tuning in Noncovalent Encapsulation Stabilities and Cargo Release

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01109K, Paper
Arun Mondal, S. K. Sujauddin, Dhiman Mondal, Soumya Kolay, Shuvajyoti Sarkar, Mijanur Rahaman Molla
Here, we demonstrated a new methodology for the templated synthesis of cross-linked poly(disulfide)s based dynamic covalent nanonetwork as highly stable potential delivery vehicle in the field of chemotherapeutic applications. The...
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Strategies to prepare polymers with cleavable linkages releasing active agents in acidic media

Polym. Chem., 2024, 15,4491-4518
DOI: 10.1039/D4PY00854E, Review Article
Nachnicha Kongkatigumjorn, Daniel Crespy
Hydrolysis stability of labile linkages in polymers can be tuned through careful selection of substituent groups near these linkages to selectively release active substances.
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Acrylate–methacrylate radical copolymerization kinetics of sparingly water-soluble monomers in polar and nonpolar solvents

Polym. Chem., 2024, 15,4542-4553
DOI: 10.1039/D4PY01015A, Paper
Noushin Rajabalinia, Fatemeh Salarhosseini, Robin A. Hutchinson
The influence of solvent on radical copolymerization kinetics is studied to provide insight to emulsion polymerization systems.
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Synthesis of degradable polyester with high molecular weight and excellent mechanical properties through copolymerization modification of poly(butylene succinate)

Polym. Chem., 2024, 15,4570-4579
DOI: 10.1039/D4PY01050G, Paper
Hongji Wang, Xiaojun Ma, Hanyu Yao, Haohao Chang, Yin Lv, Zhong Wei
The degradable copolymer of polybutylene succinate (PBS) modified with tricyclodecane dimethanol (TCD) presented significantly enhanced tensile strength and elongation at break.
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Interpretable machining learning assisted insights into bifunctional squaramide catalyzed ring-opening polymerization of lactide

Polym. Chem., 2024, 15,4562-4569
DOI: 10.1039/D4PY00866A, Paper
Shaoju Cao, Mengting Hong, Junyuan Hu, Zhenjiang Li, Jin Huang, Kai Guo
A bifunctional squaramide catalyst with tunable activity enables the controlled ring-opening polymerization of lactide. Combining bench experiments and interpretable machine learning offer insights into catalyst structures, promoting catalyst design.
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Structure, humidity adaptivity, and elasticity of hydrogen-bonded complexes formed by self-assembly of a triblock copolymer and a homopolymer

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00959B, Paper
Weijie Wang, Hanxin Jian, Hao Huang, Fengfeng Feng, Qingye Meng, Yuli Li, Gang Chen, Shuguang Yang
The tri-block copolymer polystyrene-b-poly(ethylene oxide)-b-polystyrene (SES) and the homopolymer poly(acrylic acid) (PAA) were applied to fabricate elastomers with multi-hierarchical architectures.
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Biodegradable pressure sensors with high sensitivity and wide detection range via a piezoresistive/capacitive dual response

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00675E, Paper
Xiaowan Luan, Yanlong Zhu, Yankun Chen, Xiaoxia Gu, Qian Xu, Guoming Liu, Xiu-Qin Zhang, Minxuan Kuang
Eco-friendly strategies are strongly needed to address the issue of e-waste pollution. Green electronics constructed from degradable polymers have attracted widespread attention. In this paper, a piezoresistive/capacitive dual-response pressure sensor...
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Phase-separated structures of tunable thermoresponsive and matrix polymers for large-scale temperature monitoring coatings

J. Mater. Chem. B, 2024, 12,10886-10892
DOI: 10.1039/D4TB01743A, Paper
Risako Shibata, Satoru Matsuda, Hirofumi Kawakubo, Hiroaki Imai, Yuya Oaki
Layered polydiacetylene (PDA) exhibits a thermoresponsive color change. The thermoresponsivity and large-scale coatability are controlled for medical applications by the intercalated guests and matrix polymer, respectively.
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Engineering disease analyte response in peptide self-assembly

J. Mater. Chem. B, 2024, 12,10757-10769
DOI: 10.1039/D4TB01860E, Review Article
Open Access
Sihan Yu, Matthew J. Webber
The need to enhance the precision and specificity of therapeutic nanocarriers has led to the development of nanoscale peptide assemblies capable of sensing and responding to disease-related analytes.
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Sulfur–tetrazine as highly efficient visible-light activatable photo-trigger for designing photoactivatable fluorescence biomolecules

J. Mater. Chem. B, 2024, 12,10839-10849
DOI: 10.1039/D4TB01817F, Communication
Shudan Yang, Mengxi Zhang, Axel Loredo, David Soares, Yulun Wu, Han Xiao
Light-activated fluorescence represents a potent tool for investigating subcellular structures and dynamics, offering enhanced control over the temporal and spatial aspects of the fluorescence signal.
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Retraction: Biologically responsive, sustainable release from metallo-drug coordinated 1D nanostructures

J. Mater. Chem. B, 2024, 12,11042-11042
DOI: 10.1039/D4TB90170C, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Naohiro Kameta, Soo Jin Lee, Mitsutoshi Masuda, Toshimi Shimizu
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Surface Modified Laser-Induced Graphene based Flexible Biosensor for Multiplexed Sweat Analysis

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01936A, Paper
Sudipta Choudhury, Saad Zafar, Deepak Deepak, Abhishek Panghal, Bimlesh Lochab, Susanta Sinha Roy
The growing popularity of electrochemical sensors featuring non-invasive biosensing technologies has generated significant enthusiasm for continuous monitoring of bodily fluid biomarkers, potentially aiding in the early detection of health issues...
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Photoresponsive prodrug-based liposomes for controllable release of the anticancer drug chlorambucil

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01620C, Paper
Xiaoting Wang, Guangtian Suo, Shinan Ma, Chunxi Yang, Chunyan Bao
A photoresponsive lipid prodrug was designed to form nanomedicines for accurate and controllable drug release in response to light irradiation.
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Scalable fabrication of porous membrane incorporating human extracellular matrix-like collagen for guided bone regeneration

J. Mater. Chem. B, 2024, 12,11142-11155
DOI: 10.1039/D4TB00962B, Paper
Qingyi Wang, Feng Zhou, Tiecheng Qiu, Yiling Liu, Wenxin Luo, Zhanqi Wang, Haiyun Li, E. Xiao, Qiang Wei, Yingying Wu
We fabricated a PCL/hCol membrane with an asymmetric porous structure for guided bone regeneration via nonsolvent-induced phase separation method. It shows superior mechanical and degradation properties, biocompatibility and osteoinductive effect.
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Enzymatic self-assembly of short peptides for cell spheroid formation

J. Mater. Chem. B, 2024, 12,11210-11217
DOI: 10.1039/D4TB01154F, Paper
Open Access
Jiaqi Guo, Weiyi Tan, Bing Xu
Biphenyl-capped phosphopeptides instruct cell aggregation into spheroids, with minimal effective concentrations below 10 μM. Key factors driving morphogenesis include the self-assembly ability and dynamic shapeshifting of the peptide assemblies.
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A near-infrared superoxide generator based on a biocompatible indene-bearing heptamethine cyanine dye

J. Mater. Chem. B, 2024, 12,11202-11209
DOI: 10.1039/D4TB01663G, Paper
Nikita Bel’ko, Anna Mal’tanova, Anastasiya Bahdanava, Anatol Lugovski, Sviatlana Fatykhava, Polina Shabunya, Adam Smaliakou, Sergey Poznyak, Tatsiana Kulahava, Michael Samtsov
A heptamethine cyanine dye with an indene moiety and 4-meso-chloride generates superoxide inside cells upon near-infrared photoactivation, inducing cell death.
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A simple hydrogen peroxide-activatable Bodipy for tumor imaging and type I/II photodynamic therapy

J. Mater. Chem. B, 2024, 12,11165-11171
DOI: 10.1039/D4TB01650E, Paper
Fangqing Ge, Yujie Sun, Yu Wang, Dan Yu, Zhijia Wang, Fabiao Yu, Bingran Yu, Hongbing Fu
A H2O2-activatable Bodipy with simultaneous type I and type II photosensitization was designed for tumor imaging and therapy.
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Drug-delivery and biological activity in colorectal cancer of a supramolecular porous material assembled from heptameric chromium-copper-adenine entities

J. Mater. Chem. B, 2024, 12,11156-11164
DOI: 10.1039/D4TB01521E, Paper
Sandra Mena-Gutiérrez, Ekain Maiza-Razkin, Jon Pascual-Colino, Marcos J. Araúzo-Bravo, Garikoitz Beobide, Oscar Castillo, Ainara Castellanos-Rubio, Daniela Gerovska, Antonio Luque, Sonia Pérez-Yáñez
Supramolecular metal-organic porous materials as drug delivery systems, modulation of the release kinetics using cholesterol as pore blocking agent and its impact on colorectal cancer cell cultures: cytotoxicity and RNA-seq transcriptomics studies.
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Chitosan-functionalized nanobubbles for precision oncology: advances in targeted cancer therapeutics

J. Mater. Chem. B, 2024, 12,11076-11088
DOI: 10.1039/D4TB01930J, Review Article
Vivek Pandey, Tejasvi Pandey
The convergence of nanotechnology and cancer therapeutics has opened new frontiers in the development of advanced drug delivery systems.
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Nanobiopolymers in cancer therapeutics: advancing targeted drug delivery through sustainable and controlled release mechanisms

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB00599F, Review Article
Shikha Gulati, Nabeela Ansari, Yamini Moriya, Kumud Joshi, Disha Prasad, Gargi Sajwan, Shefali Shukla, Sanjay Kumar, Rajender S. Varma
Nanobiopolymers in cancer therapeutics offer sustainable and targeted drug delivery with controlled release, enhancing treatment efficacy while ensuring sustainability and biodegradability for improved patient care.
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Correction: Blood-clotting model and simulation analysis of polyvinyl alcohol–chitosan composite hemostatic materials

J. Mater. Chem. B, 2024, 12,11265-11266
DOI: 10.1039/D4TB90174F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yifan Zhao, Junhong Hao, Zexin Chen, Mengmeng Li, Jianxun Ren, Xiaobing Fu
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A water playground for peptide re-assembly from fibrils to plates

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01727G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simone Adorinni, Marina Kurbasic, Ana M. Garcia, Slavko Kralj, Ottavia Bellotto, Erica Scarel, Paolo Pengo, Rita De Zorzi, Michele Melchionna, Attilivio V. Vargiu, Silvia Marchesan
Water plays a key role in the irreversible transition from peptide fibrils to plates.
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Illuminating cisplatin-induced ferroptosis in non-small-cell lung cancer with biothiol-activatable fluorescent/photoacoustic bimodal probes

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01656D, Paper
Li Xu, Hongwen Liu, Yi Kong, Lingyun Li, Jia Li, Kang Li, Shuzhi Liang, Bolin Chen
Using activatable NIR fluorescent/PA bimodal probes, we successfully monitored real-time biothiol changes during ferroptosis in NSCLC cells and tumors, revealing enhanced ferroptosis with the combined use of erastin and cisplatin.
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Bioinspired programmable coacervate droplets and self-assembled fibers through pH regulation of monomers

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01550A, Paper
Satyajit Patra, Sushmitha Chandrabhas, Subi J. George
Phase separation or phase transitions pervade the biological domain, where proteins and RNA engage in liquid-liquid phase separation (LLPS), forming liquid-like membraneless organelles. The misregulation or dysfunction of these proteins...
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