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Disentangling Site Occupancy, Cation Regulation, and Oxidation State Regulation of the Broadband Near Infrared Emission in Chromium Doped SrGa4O7 Phosphor

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00332H, Research Article
Jun'an Lai, Jianbei Qiu, Qi Wang, Dacheng Zhou, Zhangwen Long, yong yang, SongHan Hu, Xizheng Li, Jiacheng Pi, Jing Wang
Cr3+-doped phosphors are attracting attention for broadband near-infrared (NIR) applications. However, some mechanisms are still unclear due to the entangled crystallographic site occupancy and changeable valence of chromium in the...
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Controllable synthesis of a mesoporous NiO/Ni nanorod as an excellent catalyst for urea electro-oxidation

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00316F, Research Article
Qing Li, Nan Li, Jing An, Huan Pang
Mesoporous rod-like structured composites of NiO/Ni have been successfully prepared via a low temperature heat treatment of the precursor NiC2O4·2H2O in N2.
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SrTaO2N co-doped with La/Zr as promising photocatalysts for water reduction under visible light illumination

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article
Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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Ag nanoparticle embedded Cu nanoporous hybrid arrays for the selective electrocatalytic reduction of CO2 towards ethylene

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article
Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO2 to C2H4, and exhibit a maximum Faraday Efficiency 41.3%.
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Ni-Doped magnesium manganese oxide as a cathode and its application in aqueous magnesium-ion batteries with high rate performance

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article
Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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Systematic Study of the Optical Properties of Mononuclear Hybrid Organo-Inorganic Lanthanoid Complexes.

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00232A, Research Article
Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, Guillermo Minguez Espallargas, Lauro J. Q. Maia, Gisane Gasparotto, Ricardo Costa de Santana, Walter Cañón-Mancisidor
A series of hybrid organo-inorganic mononuclear lanthanoid complexes, [n-NBu4]3[LnH(PW11O39)(phen)2]·H2O, denoted as LM4-1-Ln (Ln = DyIII, TbIII, EuIII, NdIII, ErIII, HoIII and GdIII), were synthesized via hydrothermal synthesis and were structurally...
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Highly efficient water splitting over a RuO2/F-doped graphene electrocatalyst with ultra-low ruthenium content

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article
Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO2/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm−2 for electrocatalytic water splitting.
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Synthesis of dual emitting iodocuprates: can solvents switch the reaction outcome?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article
Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

Inorg. Chem. Front., 2020, 7,1845-1850
DOI: 10.1039/C9QI01431D, Research Article
Jonghoon Choi, Yunho Lee
Catalytic hydrogenation of CO2 occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.
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A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system

Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article
Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)4]2− complexes within π-acidic cavities.
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Temperature-regulated construction of hierarchical titanosilicate zeolites

Inorg. Chem. Front., 2020, 7,1872-1879
DOI: 10.1039/D0QI00120A, Research Article
Yue Song, Risheng Bai, Yongcun Zou, Zhaochi Feng, Jihong Yu
A temperature-regulated method was developed to construct anatase-free hierarchical TS-1 zeolite catalysts by utilizing a two-step hydrothermal crystallization strategy with tetrabutylammonium hydroxide as the sole organic template.
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Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Electrochemical behavior of NiCl2/Ni in acidic AlCl3-based ionic liquid electrolyte

Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article
Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl2 cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl2 during discharging in acidic AlCl3-based electrolyte.
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Restricted active space simulations of the metal L-edge X-ray absorption spectra and resonant inelastic X-ray scattering: revisiting [CoII/III(bpy)3]2+/3+ complexes

Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article
Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Luminescent metal–organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants

Inorg. Chem. Front., 2020, 7,1801-1821
DOI: 10.1039/D0QI00167H, Review Article
Partha Samanta, Sumanta Let, Writakshi Mandal, Subhajit Dutta, Sujit K. Ghosh
This review aims to provide an overview regarding the development of luminescent metal–organic frameworks (LMOFs) based sensory materials for the detection of cationic inorganic and organic water pollutants.
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Highly efficient CO2 capture and conversion of a microporous acylamide functionalized rht-type metal–organic framework

Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article
Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO2-philic acylamide groups exhibits high performance for CO2 capture, separation and chemical conversion.
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A new honeycomb metal–carboxylate-tetrazolate framework with multiple functions for CO2 conversion and selective capture of C2H2, CO2 and benzene

Inorg. Chem. Front., 2020, 7,1957-1964
DOI: 10.1039/D0QI00181C, Research Article
Gang-Ding Wang, Yong-Zhi Li, Wen-Juan Shi, Lei Hou, Zhonghua Zhu, Yao-Yu Wang
A stable Cd-MOF was built by a carboxylate-tetrazolate ligand, which contains hexagonal channels and reveals multiple functions including separation of CO2/CH4, C2H2/CO2, C2H2/CH4 and benzene/cyclohexane, and catalytic conversion of CO2 with epoxides.
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π-Type halogen bonding enhanced the long-lasting room temperature phosphorescence of Zn(II) coordination polymers for photoelectron response applications

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article
Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Interconnected porous nanoflakes of CoMo2S4 as an efficient bifunctional electrocatalyst for overall water electrolysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article
Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo2S4 are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Mechanism of oxygen vacancy assisted water-splitting of LaMnO3: Inorganic perovskite prediction for fast solar thermochemical H2 production

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article
Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Aerobic Oxidation Catalyzed by Polyoxometalates Associated to an Artificial Reductase at Room Temperature and in Water

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article
Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

1 videodisc (101 min.) : sound, color ; 4 3/4 in




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It's no more just about Real or Barca breaking records: La Liga India head

Jose Antonio Cachaza, MD, LaLiga India, dwells on his team's digital strategy to reach fans in remote villages that even courier companies don't reach




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Broadcasters have an opportunity to do a TikTok on TV: BARC CEO Sunil Lulla

The average daily reach of TV rose from 560 million Indians pre-COVID-19 (January 11-31) to 592 million post-COVID-19 (March 14-20)




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We cannot run away to moon, need to develop herd immunity: Epidemiologist

Muliyil tells Somesh Jha that the days of eradicating the disease is over and the country should move towards developing 'herd immunity'




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Article :: My Workflow: here's my typical start-to-finish project

In this sample chapter from The Adobe Photoshop Lightroom Classic CC Book for Digital Photographers, learn how Scott Kelby uses the same workflow in Lightroom for every type of project.




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Article :: Creating the Back of a Business Card

In this sample chapter from Learn Adobe Illustrator CC for Graphic Design and Illustration: Adobe Certified Associate Exam Preparation, 2nd Edition, explore the Appearance panel in Adobe Illustrator CC and work through a project scenario to learn techniques for drawing and manipulating paths.




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Article :: Isometric Drawing with AutoCAD 2020

A hands-on, activity-based approach to learning Isometric Drawing with AutoCAD, including drawing exercises that both assess and reinforce your understanding of the material.




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Article :: AutoCAD 2020: Quick Start Tutorial

Learn the basics necessary to start a new drawing, create and modify some objects, add annotation features, and print out your work with AutoCAD 2020.




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Lifestyle changes may help prevent half of Alzheimer’s cases





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Scar Project: When men get breast cancer




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A smartphone case to monitor heart rate, blood pressure






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Low vitamin D levels in body linked to cancer, heart disease





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British experiment shows food companies can help to reduce hypertension




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To lose those calories, eat some negative ones




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Colon cancer screening saves lives




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Study discounts Testosterone therapy for prostate cancer




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Vasectomy may up prostate cancer risk




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Short Course: Caffeine may worsen menopausal hot flashes, night sweats




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Healthy diet can delay and reverse autoimmune diseases