ca You can't kill the spirit : women in a Welsh mining village / Jill Miller By prospero.murdoch.edu.au Published On :: Miller, Jill Full Article
ca Global political economy : evolution & dynamics / Robert O'Brien & Marc Williams By prospero.murdoch.edu.au Published On :: O'Brien, Robert, 1963- author Full Article
ca Extraction empire : undermining the systems, states, & scales of Canada's global resource empire / edited by Pierre Bélanger By prospero.murdoch.edu.au Published On :: Full Article
ca The Case for Medicare for All By www.wiley.com Published On :: 2020-03-17T04:00:00Z Largely privately funded with relatively little public regulation, the United States healthcare system is both expensive and inefficient, providing poor care to large parts of the population. For decades, Americans have wrestled with how to fix their broken healthcare system. In this razor-sharp contribution to the healthcare debate, leading economist and former adviser to Bernie Sanders Gerald Friedman recommends that we build on what works: a Medicare Read More... Full Article
ca Political Economies of the Middle East and North Africa By www.wiley.com Published On :: 2020-03-30T04:00:00Z Despite its oil wealth, the Middle East and North Africa is economically stagnating. Growth rates are comparatively unfavorable and insufficient to substantially improve citizens’ lives. Whether this economic inertia can be overcome or will continue into the indefinite future is a vital question that confronts both the region and the world. In this book leading Middle East scholar Robert Springborg discusses the economic future of this region by Read More... Full Article
ca The Case for Economic Democracy By www.wiley.com Published On :: 2020-04-13T04:00:00Z The idea that the people have a right to shape political decisions through democratic means is widely accepted. The same cannot be said of the decisions that impact on our everyday economic life in the workplace and beyond. Andrew Cumbers shows why this is wrong, and why, in the context of the rising tide of populism and the perceived crisis of liberal democracy, economic democracy's time has come. Four decades of market deregulation, financialisation Read More... Full Article
ca The Case for Economic Democracy By www.wiley.com Published On :: 2020-04-13T04:00:00Z The idea that the people have a right to shape political decisions through democratic means is widely accepted. The same cannot be said of the decisions that impact on our everyday economic life in the workplace and beyond. Andrew Cumbers shows why this is wrong, and why, in the context of the rising tide of populism and the perceived crisis of liberal democracy, economic democracy's time has come. Four decades of market deregulation, financialisation Read More... Full Article
ca Political Economies of the Middle East and North Africa By www.wiley.com Published On :: 2020-04-14T04:00:00Z Despite its oil wealth, the Middle East and North Africa is economically stagnating. Growth rates are comparatively unfavorable and insufficient to substantially improve citizens’ lives. Whether this economic inertia can be overcome or will continue into the indefinite future is a vital question that confronts both the region and the world. In this book leading Middle East scholar Robert Springborg discusses the economic future of this region by Read More... Full Article
ca Informality Revisited: Latin American Perspectives on Housing, the State and the Market By www.wiley.com Published On :: 2020-04-20T04:00:00Z Informality Revisited offers an overview of recent debates about Latin American government programmes for the formalisation of informal settlements and housing provision in a neo-liberal context. Contributions from Latin American researchers analyse the contradictions in government actions and evaluate the consequences for urban poverty. Read More... Full Article
ca Political Geography: A Critical Introduction By www.wiley.com Published On :: 2020-04-27T04:00:00Z Brings political geography to life—explores key concepts, critical debates, and contemporary research in the field. Political geography is the study of how power struggles both shape and are shaped by the places in which they occur—the spatial nature of political power. PoliticalGeography: A Critical Introduction helps students understand how power is related to space, place, and territory, illustrating how everyday life and the world of global conflict Read More... Full Article
ca Cascade polymerizations: recent developments in the formation of polymer repeat units by cascade reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01475C, Perspective Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gregory I. Peterson, Tae-Lim ChoiCascade polymerizations provide new routes to unique polymer structures. In this perspective, we summarize their performance, monomer scope, and mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC02213F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu Mao, Wenxuan Zhao, Shuo Lu, Lei Yu, Yi Wang, Yong Liang, Shengyang Ni, Yi PanRedox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for Cu-catalysed C–C bond formation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00554A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chi Y. Cheng, Josh E. Campbell, Graeme M. DayEvolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00480D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi-Tsao Chen, Haw Yang, Jhih-Wei ChuThe mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Palladium-catalysed 5-endo-trig allylic (hetero)arylation By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01932A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bara Singh, Siddheshwar K. Bankar, Ketan Kumar, S. S. V. RamasastryA palladium-catalysed intramolecular allylic (hetero)arylation strategy for the synthesis of fused cyclopentenes incorporated with all-carbon quaternary and spiro centres is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Allylic C(sp3)–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00819B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiaqi Jia, Rajesh Kancherla, Magnus Rueping, Long HuangA new catalytic method for the direct alkylation of allylic C(sp3)–H bonds from unactivated alkenes via synergistic organo- and photoredox catalysis is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01911A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech PisulaThe solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00676A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bryan Owens-Baird, Juliana P. S. Sousa, Yasmine Ziouani, Dmitri Y. Petrovykh, Nikolai A. Zarkevich, Duane D. Johnson, Yury V. Kolen'ko, Kirill KovnirThe effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide (m-NiP2).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Thermal effects – an alternative mechanism for plasmon-assisted photocatalysis By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/C9SC06480J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yonatan Dubi, Ieng Wai Un, Yonatan SivanA simple Arrhenius-based theory of heating, rather than “hot electrons”, can reproduce some high-profile photocatalysis experimental results to remarkable accuracy. Flaws in temperature measurement may have led to wrong conclusions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01890B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Santosh K. Pagire, Naoya Kumagai, Masakatsu ShibasakiAn efficient cooperative chiral Lewis acid and photoredox catalytic system towards the highly enantioselective radical conjugate addition of α-amino radicals to α,β-unsaturated amides is developed with the implementation of unique auxiliaries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca A straightforward approach to antibodies recognising cancer specific glycopeptidic neoepitopes By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00317D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hajime Wakui, Yoshikazu Tanaka, Toyoyuki Ose, Isamu Matsumoto, Koji Kato, Yao Min, Taro Tachibana, Masaharu Sato, Kentaro Naruchi, Fayna Garcia Martin, Hiroshi Hinou, Shin-Ichiro NishimuraWe developed new class of designated antibodies targeting of “dynamic neoepitopes” elaborated by disease-specific O-glycosylation at the immunodominant mucin domains.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Molecular recognition of pyrazine N,N'-dioxide using aryl extended calix[4]pyrroles By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01496F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chenxing Guo, Hu Wang, Vincent M. Lynch, Xiaofan Ji, Zachariah A. Page, Jonathan L. SesslerThe molecular recognition of pyrazine N,N'-dioxide by aryl extended 'two-walled' calix[4]pyrrole-based receptors is seen to stabilise two different binding modes in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00997K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don TilleyA cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01534B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie ZhuQuantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01833C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D BlochWe describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01445A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lei Zhang, Xile HuA direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Highly efficient non-doped blue fluorescent OLEDs with low efficiency roll-off based on hybridized local and charge transfer excited state emitters By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01341B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xianhao Lv, Mizhen Sun, Lei Xu, Runzhe Wang, Huayi Zhou, Yuyu Pan, Shitong Zhang, Qikun Sun, Shanfeng Xue, Wenjun YangA new pure fluorescent blue HLCT-emitter was designed and synthesized. Highly efficient non-doped blue OLEDs with low efficiency roll-off were achieved.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC02253E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juan Mangas-Sanchez, Mahima Sharma, Sebastian C. Cosgrove, Jeremy I. Ramsden, James R. Marshall, Thomas W. Thorpe, Ryan B. Palmer, Gideon Grogan, Nicholas J. TurnerFungal reductive aminases as effective biocatalysts for the preparation of chiral primary amines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Regioselective B(3,4)–H Arylation of o-Carboranes by Weak Amide Coordination at Room Temperature By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01515F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu-Feng Liang, Long Yang, Becky Bongsuiru Jei, Rositha Kuniyil, Lutz AckermannPalladium-catalyzed regioselective di- or mono-arylation of o-carboranes was achieved by weakly coordinating amides at room temperature. Thereby, a series of B(3,4)-diarylated and B(3)-monoarylated o-carboranes anchored with valuable functional groups were...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I) By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01512A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana SanchezThe first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Evolution of pure hydrocarbon hosts: simpler structure, higher performance and universal application in RGB phosphorescent organic light-emitting diodes By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01238F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiang Wang, Fabien Lucas, Cassandre Quinton, Yang-Kun Qu, Joëlle Rault-Berthelot, Olivier Jeannin, Sheng-Yi Yang, Fan-Cheng Kong, Sarvendra Kumar, Liang-Sheng Liao, Cyril Poriel, Zuo-Quan JiangIn this work, we propose pure hydrocarbon materials as universal hosts for high-efficiency red, green and blue phosphorescent organic light-emitting diodes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4287-4296DOI: 10.1039/C9SC06006E, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. EngleNickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4305-4311DOI: 10.1039/D0SC01159B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi OoiRadical–ion pair generation from common Lewis pairs and its application to catalytic carbon–carbon bond formation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca General and selective synthesis of primary amines using Ni-based homogeneous catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4332-4339DOI: 10.1039/D0SC01084G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. JagadeeshA Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4397-4402DOI: 10.1039/D0SC00844C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong LiA novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4381-4390DOI: 10.1039/D0SC01026J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen NiemeyerSupramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4488-4498DOI: 10.1039/D0SC00544D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-TejadaA fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4516-4524DOI: 10.1039/D0SC01319F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar WillnerBiocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4499-4507DOI: 10.1039/D0SC00135J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming HuMetal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4475-4481DOI: 10.1039/D0SC01194K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-EwingShort-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4360-4373DOI: 10.1039/C9SC06272F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. GaffneyPhotoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Small-molecule fluorescent probes for imaging gaseous signaling molecules: current progress and future implications By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01482F, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mingwang Yang, Jiangli Fan, Jianjun Du, Xiaojun PengThis perspective article aims to introduce the design principles and recognition strategies of small-molecule fluorescent probes which are applied for the detection of gas signaling molecules including NO, CO and H2S in biological systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Selective electrochemical reduction of carbon dioxide to ethanol via a relay catalytic platform By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01133A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juan Du, Shaopeng Li, Shulin Liu, Yu Xin, Bingfeng Chen, Huizhen Liu, Buxing HanThe relay catalytic platform is very efficient and selective for CO2 electroreduction to ethanol.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Geometric landscapes for material discovery within energy–structure–function maps By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00049C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seyed Mohamad Moosavi, Henglu Xu, Linjiang Chen, Andrew I. Cooper, Berend SmitWe introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Ultraviolet photochemistry of ethane: implications for the atmospheric chemistry of the gas giants By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01746A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yao Chang, Jiayue Yang, Zhichao Chen, Zhiguo Zhang, Yong Yu, Qingming Li, Zhigang He, Weiqing Zhang, Guorong Wu, Rebecca A. Ingle, Matthew Bain, Michael N. R. Ashfold, Kaijun Yuan, Xueming Yang, Christopher S. HansenThe vacuum ultraviolet photodissociation dynamics of ethane provide clues for modelling the atmospheric chemistry of the gas giants.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC02020F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey StephensonHydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC90081H, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Leslie A. Nickerson, Benjamin D. Bergstrom, Mingchun Gao, Yuan-Shin Shiue, Croix J. Laconsay, Matthew R. Culberson, Walker A. Knauss, James C. Fettinger, Dean J. Tantillo, Jared T. ShawTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01025A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor AlabuginHow far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01763A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal KhanThe first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01290D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P CramerA diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
