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Towards high performance and durable soft tactile actuators

Chem. Soc. Rev., 2024, 53,3485-3535
DOI: 10.1039/D3CS01017A, Review Article
Open Access
Matthew Wei Ming Tan, Hui Wang, Dace Gao, Peiwen Huang, Pooi See Lee
This review assesses diverse strategies to enhance the actuation performance and durability of soft tactile actuators, enabling optimal functionality in real-world conditions.
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Double-cavity cucurbiturils: synthesis, structures, properties, and applications

Chem. Soc. Rev., 2024, 53,3536-3560
DOI: 10.1039/D3CS00961K, Review Article
Qing Li, Zhengwei Yu, Carl Redshaw, Xin Xiao, Zhu Tao
This review article presents the structures, properties, and the emerging applications of a subset of cucurbit[n]uril-type receptors that have two cavities.
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Correlating concerted cations with oxygen redox in rechargeable batteries

Chem. Soc. Rev., 2024, 53,3561-3578
DOI: 10.1039/D3CS00550J, Review Article
Shiqi Wang, Lifan Wang, David Sandoval, Tongchao Liu, Chun Zhan, Khalil Amine
This review underscores the critical importance of oxygen redox and elucidates the precise commonalities of cations in regulating oxygen redox.
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Zn-based batteries for sustainable energy storage: strategies and mechanisms

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00295K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lei Tang, Haojia Peng, Jiarui Kang, Han Chen, Mingyue Zhang, Yan Liu, Dong Ha Kim, Yijiang Liu, Zhiqun Lin
This review systematically summarizes various redox mechanisms in Zn-based batteries and design strategies to improve their electrochemical performance, which provides a reference for future development of high-performance Zn-based batteries.
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Visible photons as ideal reagents for the activation of coloured organic compounds

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01129A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lorenzo Di Terlizzi, Luca Nicchio, Stefano Protti, Maurizio Fagnoni
In search for the perfect wave(length). This review is dedicated to recent efforts in the development of visible light driven photochemical strategies occurring in coloured organic compounds.
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Gel polymer electrolytes for rechargeable batteries toward wide-temperature applications

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00551H, Review Article
Open Access
Xiaoyan Zhou, Yifang Zhou, Le Yu, Luhe Qi, Kyeong-Seok Oh, Pei Hu, Sang-Young Lee, Chaoji Chen
Design principles, engineering strategies, challenges, and opportunities of gel polymer electrolytes for rechargeable batteries toward wide-temperature applications are thoroughly reviewed.
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Selective C(aryl)–O bond cleavage in biorenewable phenolics

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00570D, Review Article
Gilles De Smet, Xingfeng Bai, Bert U. W. Maes
Selective removal of the hydroxy, methoxy or both groups in biorenewable oxygenated arenes (derived from lignin depolymerization) provides, respectively, anisoles, phenols and benzenes.
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Flexible molecular crystals for optoelectronic applications

Chem. Soc. Rev., 2024, 53,3687-3713
DOI: 10.1039/D3CS00116D, Review Article
Chuanxin Wei, Liang Li, Yingying Zheng, Lizhi Wang, Jingyao Ma, Man Xu, Jinyi Lin, Linghai Xie, Panče Naumov, Xuehua Ding, Quanyou Feng, Wei Huang
This review provides a comprehensive and concise overview of the current flexible molecular crystals, specifically concerning their mechanical properties and optoelectronic performance, intending to advance their flexible optoelectronic applications.
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Electrochemical coupling in subnanometer pores/channels for rechargeable batteries

Chem. Soc. Rev., 2024, 53,3829-3895
DOI: 10.1039/D3CS01043K, Review Article
Yao-Jie Lei, Lingfei Zhao, Wei-Hong Lai, Zefu Huang, Bing Sun, Pauline Jaumaux, Kening Sun, Yun-Xiao Wang, Guoxiu Wang
This review categorizes subnanometer pores/channels (SNPCs) from structural perspective and demonstrates electrochemical couplings in SNPCs for batteries while proposing corresponding challenges and future research directions.
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Recent advances in the chemistry of isolable carbene analogues with group 13–15 elements

Chem. Soc. Rev., 2024, 53,3896-3951
DOI: 10.1039/D3CS00784G, Review Article
Mian He, Chaopeng Hu, Rui Wei, Xin-Feng Wang, Liu Leo Liu
This review provides an overview of main group carbene analogues, covering recent advancements, synthesis strategies, and the diverse reactivity of elements in groups 13–15 based on their structural characteristics.
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Peptide-based self-assembled monolayers (SAMs): what peptides can do for SAMs and vice versa

Chem. Soc. Rev., 2024, 53,3714-3773
DOI: 10.1039/D3CS00921A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Carlos Redondo-Gómez, Paula Parreira, M. Cristina L. Martins, Helena S. Azevedo
Self-assembled monolayers (SAMs) based on peptides represent a reproducible platform for screening and studying peptide functions and facilitating their translation into multidisciplinary applications.
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Degradable biomedical elastomers: paving the future of tissue repair and regenerative medicine

Chem. Soc. Rev., 2024, 53,4086-4153
DOI: 10.1039/D3CS00923H, Review Article
Ben Jia, Heyuan Huang, Zhicheng Dong, Xiaoyang Ren, Yanyan Lu, Wenzhi Wang, Shaowen Zhou, Xin Zhao, Baolin Guo
This review critically analyzes degradable biomedical elastomers, focusing on their degradation, synthesis, microstructure, and role in tissue repair. It guides experts in balancing degradation with tissue repair for improved applications.
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Recycling of spent lithium-ion batteries for a sustainable future: recent advancements

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00898C, Review Article
Open Access
Basanta Kumar Biswal, Bei Zhang, Phuong Thi Minh Tran, Jingjing Zhang, Rajasekhar Balasubramanian
A critical review of the recent developments in the recycling of spent Li-ion batteries using five major technologies (direct recycling, pyrometallurgy, hydrometallurgy, bioleaching and electrometallurgy) and evaluation of their sustainability.
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Sarthak, Rakshitha, Basim, and Kaushik complete the double




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Why the 2024 F1 season has the makings of a blockbuster

The sport’s fans have longed for a situation in which multiple constructors are in contention for victories, and out of nowhere in 2024, this compelling scenario has manifested. Moreover, the four teams that have tasted victory this year have top driver lineups, which allows for great racing




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Red Bull braces for its most formidable challenge yet

Led by the irresistible Verstappen, the outfit, over the last three years, has ended Mercedes’ dominance. But amidst an upheaval among its personnel, exits of key strategists, an underperforming driver and increasing competition, Red Bull has its back to the wall. As the F1 circus regroups at Zandvoort on Sunday, can the reigning champion handle the tricky transition phase that has tripped many a successful sporting franchise?




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Hockey India names 27 core probables for pre-Olympic camp; striker Dilpreet misses out

The Indian team is returning to the national camp after a successful outing in the FIH Hockey Pro League, where it currently occupies the fourth spot after earning 24 points from 16 matches




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Paris Olympics: Harmanpreet’s brace enables India to overcome Ireland challenge

With two wins and a draw, India has gathered seven points from three matches and has almost made it to the quarterfinals.




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Students block road, demand classrooms in Dharmapuri




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Board exam countdown: how to keep the blues away

Study tips, lifestyle tips, checklist and more to handle the challenge.




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Isabel and the invisible world / Alan Lightman ; illustrated by Ramona Kaulitzki

Lightman, Alan P., 1948- author




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Tumble / Adriana Hernandez Bergstrom

Hernandez Bergstrom, Adriana, author, illustrator




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Poetry 101 : from Shakespeare and Rupi Kaur to iambic pentameter and blank verse, everything you need to know about poetry / Susan Dalzell

Dalzell, Susan, author




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Tablet fragments / Tamar Rubin ; Clarise Foster, editor

Rubin, Tamar, 1986- author




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Extreme weather for kids : lessons and activities all about hurricanes, tornadoes, blizzards, and more! / Matthew Cappucci ; illustrated by Stephanie Hathaway

Cappucci, Matthew, author




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Pineshish the blue jay : an Algonquin story / written by Michel Noël ; illustrated by Camille Lavoie ; translated by Louis Anctil

Noël, Michel, 1944-2021, author




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Abracadabra, it's spring! / by Anne Sibley O'Brien ; illustrated by Susan Gal

O'Brien, Anne Sibley, author




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Negative cat / Sophie Blackall

Blackall, Sophie, author, illustrator




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‘Start-up valuations are more palatable in India’

Why Rocketship.vc prefers to back ideas rather than valuations




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‘We hope to see the first public offering in agritech next year’

Why VC firm Omnivore is betting on agritech, rural fintech




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Investors scramble for a slice of AI pie

AI start-up valuations skyrocket as venture capitalists vie to spot an OpenAI-like home-grown winner 




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What prevents a business from scaling sustainably?

Why a headcount spike cannot be confused with organisational growth




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The values that Silicon Valley brings to the table

What would it take for the Indian start-up ecosystem to match the calibre of Silicon Valley




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Drawing water from air on a sustainable, industrial scale

Uravu Labs devises an affordable means of mimicking nature’s water cycle




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When talent becomes unaffordable for startups

Why good leadership is increasingly beyond the means of startups looking to build great products




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CO insertion enabled γ-C(sp3)–H heteroarylative carbonylation of tertiary alcohols via heteroaryl migration

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05361C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xin Qi, Yuanrui Wang, Xiao-Feng Wu
A carbonylative γ-C(sp3)–H functionalization of alcohols via migration of heteroaryl groups to produce 1,4-diketones has been developed.
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Loss of fluorine during crosslinking by the biarylitide P450Blt proceeds due to restricted peptide orientation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication
Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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Yolk-shelled MoS2/C@Void@C@MoS2 nanospheres as a stable and high-rate anode in sodium/potassium ion batteries

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05088F, Communication
Mang Niu, Zongfan Zhu, Zhenkai Mou, Wenpei Kang
Yolk-shelled MoS2/C@Void@C@MoS2 exhibits superior high-rate sodium/potassium sodium storage capability, owing to the large inner void and ingenious shell.
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Composition tunable and stable spontaneous emission and lasing in Cd-alloyed perovskite microdisks

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04488F, Communication
Dmitry A. Tatarinov, Elizaveta V. Sapozhnikova, Daria Khmelevskaia, Yangyang Ju, Dmitriy M. Dolgintsev, Elena V. Bodyago, Alexandr A. Marunchenko, Alexey E. Zhukov, Haizheng Zhong, Ivan G. Scheblykin, Anatoly P. Pushkarev
All-inorganic Cd-alloyed perovskite microdisks were synthesized by pressure-assisted high temperature recrystallization. The microdisks showed composition tunable and temporally stable photoluminescence.
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Helical aromatic foldamers with tubular cavities capable of accommodating multiple halide ions

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05474A, Communication
Seungwon Lee, Byeung Ju Lee, Geunmoo Song, Kyu-Sung Jeong
A series of pyridinium–indolocarbazole oligomers has been synthesized, which fold into helical structures with tubular cavities capable of accommodating up to four iodide ions in a linear arrangement.
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Visible light-activated polyphenol–Al3+ coordination for ambient and quantitative xylose-to-furfural conversion

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication
Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al3+ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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Endosomolytic Peptides Enable the Cellular Delivery of Peptide Nucleic Acids

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05214E, Communication
Open Access
JoLynn B. Giancola, Ronald T. Raines
Precision genetic medicine enlists antisense oligonucleotides (ASOs) to bind to nucleic acid targets important for human disease. Peptide nucleic acids (PNAs) have many desirable attributes as ASOs but lack cellular...
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Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Lipidic biomass as a renewable chemical building block for polymeric materials

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04993D, Feature Article
Rafael Turra Alarcon, Gabriel Iago Iago, Caroline Gaglieri, Aniele De Moura, Éder Tadeu Gomes Cavalheiro, Gilbert Bannach
Polymers are intrinsically connected to our modern society and are found and used in different technologies. Although polymers are worthwhile, concerns about synthetic polymers from non-renewable sources have arisen. Therefore,...
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Tunable synthesis of magnetoelectric CoFe2O4–BaTiO3 core–shell nanowires

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03701D, Communication
Noah D. Ferson, John R. Ganiban, David P. Arnold, Jennifer S. Andrew
CoFe2O4–BaTiO3 core–shell nanowires with tunable magnetic anisotropy and magnetoelectric coupling are generated using a template-assisted synthetic procedure providing composition control.
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Polymeric antibubbles with strong ultrasound imaging capabilities

Chem. Commun., 2024, 60,13340-13343
DOI: 10.1039/D4CC03572K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roman A. Barmin, Jens Köhler, Michael Pohl, Bea Becker, Fabian Kiessling, Twan Lammers, Albert T. Poortinga, Roger M. Pallares
Antibubbles are liquid droplets encapsulated by a gas film and are proposed for ultrasound-triggered drug release. Here, we develop polymeric microbubbles with greater ultrasound imaging response than conventional Pickering-stabilized antibubbles.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent

Chem. Commun., 2024, 60,13372-13375
DOI: 10.1039/D4CC04319G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz J. Ernst, Merlin Kleoff, Patrick Voßnacker, Günther Thiele, Christian Müller, Sebastian Riedel
The reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6], which shows similar reactivity as PCl5 and can be used as a potential PCl3-storage material.
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Efficient electrocoupling of CO2 and N2 to urea by a gas-penetrable Bi nanosheet-wrapped Cu hollow fiber

Chem. Commun., 2024, 60,13420-13423
DOI: 10.1039/D4CC04595E, Communication
Jinning Wang, Yuyu Wang, Fang Wang, Jinfu Ma, Zhengguo Zhang, Shixiong Min
A gas-penetrable electrode of Bi nanosheet-wrapped Cu hollow fiber (Bi NSAs@Cu HF) exhibits high activity and stability for urea production from the electrocoupling of CO2 and N2.
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