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Effect of temperature and large guest molecules on the C–H symmetric stretching vibrational frequencies of methane in structure H and I clathrate hydrates

RSC Adv., 2020, 10,17473-17478
DOI: 10.1039/D0RA02748K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Go Fuseya, Satoshi Takeya, Akihiro Hachikubo
Temperature effect on C–H symmetric stretching frequencies of CH4 in water cages of sI and sH clathrate hydrates were clarified.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Position-locking of volatile reaction products by atmosphere and capping layers slows down photodecomposition of methylammonium lead triiodide perovskite

RSC Adv., 2020, 10,17534-17542
DOI: 10.1039/D0RA03572F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fengshuo Zu, Thorsten Schultz, Christian M. Wolff, Dongguen Shin, Lennart Frohloff, Dieter Neher, Patrick Amsalem, Norbert Koch
Gas pressure and capping layers under ultrahigh vacuum prevent methylammonium lead triiodide photo-degradation due to efficient back-reaction of volatile compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The synergistic influence of polyethyleneimine-grafted graphene oxide and iodide for the protection of steel in acidizing conditions

RSC Adv., 2020, 10,17739-17751
DOI: 10.1039/D0RA00864H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
K. R. Ansari, Dheeraj Singh Chauhan, M. A. Quraishi, A. Y. Adesina, Tawfik A. Saleh
Herein, graphene oxide (GO) was chemically functionalized with polyethyleneimine (PEI) in a single step to obtain PEI-GO, which was characterized via FTIR spectroscopy, SEM, and TEM.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Boosting performances of triboelectric nanogenerators by optimizing dielectric properties and thickness of electrification layer

RSC Adv., 2020, 10,17752-17759
DOI: 10.1039/D0RA02181D, Paper
Open Access
Xiaofang Kang, Chongxiang Pan, Yanghui Chen, Xiong Pu
Enhanced output performances of a triboelectric nanogenerator (TENG) are achieved by optimizing the high-dielectric-constant filler content in the electrification layer and decreasing its thickness.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Work function modification of PEDOT:PSS by mixing with barium acetylacetonate

RSC Adv., 2020, 10,17673-17680
DOI: 10.1039/D0RA02575E, Paper
Open Access
K. L. Woon, W. S. Wong, N. Chanlek, H. Nakajima, S. Tunmee, V. S. Lee, A. Ariffin, P. Songsiriritthigul
Modification of poly(3,4-ethylenedioxythiophene)polystyrene sulfonate as electron injection layer.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanochemical approach to synthesize citric acid-soluble fertilizer of dittmarite (NH4MgPO4·H2O) from talc/NH4H2PO4 mixture

RSC Adv., 2020, 10,17686-17693
DOI: 10.1039/D0RA00387E, Paper
Open Access
Yonghao Tan, Lin Sha, Nengkui Yu, Zhengshuo Yang, Jun Qu, Zhigao Xu
Dittmarite synthesis by a mechanochemical route for application as a citric acid-soluble fertilizer.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhancing the performance of LARP-synthesized CsPbBr3 nanocrystal LEDs by employing a dual hole injection layer

RSC Adv., 2020, 10,17653-17659
DOI: 10.1039/D0RA02622K, Paper
Open Access
Dingyan Xu, Qun Wan, Siyao Wu, Yu Zhao, Xinglei Xu, Liang Li, Gufeng He
The current and power efficiencies of CsPbBr3 NC LEDs are improved 1.5 and 1.8 times by employing a dual HAT-CN/MoO3 hole injection layer.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Elongated conductive structures in detonation soot of high explosives

RSC Adv., 2020, 10,17620-17626
DOI: 10.1039/D0RA01393E, Paper
Open Access
Nataliya P. Satonkina, Alexander P. Ershov, Alexey O. Kashkarov, Ivan A. Rubtsov
Micrographs of transmission electron microscopy of saved detonation products of benzotrifuroxane at different scales.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A novel series of phenolic temozolomide (TMZ) esters with 4 to 5-fold increased potency, compared to TMZ, against glioma cells irrespective of MGMT expression

RSC Adv., 2020, 10,17561-17570
DOI: 10.1039/D0RA02686G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Leroy Shervington, Oliver Ingham, Amal Shervington
The standard of care treatment for patients diagnosed with glioblastoma multiforme (GBM) is temozolomide (TMZ).
The content of this RSS Feed (c) The Royal Society of Chemistry




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A highly sensitive, selective and renewable carbon paste electrode based on a unique acyclic diamide ionophore for the potentiometric determination of lead ions in polluted water samples

RSC Adv., 2020, 10,17552-17560
DOI: 10.1039/D0RA01435D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. A. Zayed, Walaa H. Mahmoud, Ashraf A. Abbas, Aya E. Ali, Gehad G. Mohamed
Due to the toxicity of lead(II) to all living organisms destroying the central nervous system and leading to circulatory system and brain disorders, the development of effective and selective lead(II) ionophores for its detection is very important.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective cytotoxic effect against the MDA-MB-468 breast cancer cell line of the antibacterial palindromic peptide derived from bovine lactoferricin

RSC Adv., 2020, 10,17593-17601
DOI: 10.1039/D0RA02688C, Paper
Open Access
Andrea Barragán-Cárdenas, Maribel Urrea-Pelayo, Víctor Alfonso Niño-Ramírez, Adriana Umaña-Pérez, Jean Paul Vernot, Claudia Marcela Parra-Giraldo, Ricardo Fierro-Medina, Zuly Rivera-Monroy, Javier García-Castañeda
The cytotoxic effect against the breast cancer cell line MDA-MB-468 of the palindromic peptide LfcinB (21–25)Pal: 1RWQWRWQWR9 and its analogous peptides, obtained via alanine scanning, was evaluated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical reduction of CO2 to ethylene on Cu/CuxO-GO composites in aqueous solution

RSC Adv., 2020, 10,17572-17581
DOI: 10.1039/D0RA02754E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nusrat Rashid, Mohsin Ahmad Bhat, U. K. Goutam, Pravin Popinand Ingole
Herein, we present fabrication of graphene oxide supported Cu/CuxO nano-electrodeposits which efficiently and selectively can electroreduce CO2 into ethylene with a faradaic efficiency of 34% and conversion rate of 194 mmol g−1 h−1 at −0.985 V vs. RHE.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correction: Influence of co-cultures of Streptococcus thermophilus and probiotic lactobacilli on quality and antioxidant capacity parameters of lactose-free fermented dairy beverages containing Syzygium cumini (L.) Skeels pulp

RSC Adv., 2020, 10,16905-16905
DOI: 10.1039/D0RA90046J, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sabrina Laís Alves Garcia, Gabriel Monteiro da Silva, Juliana Maria Svendsen Medeiros, Anna Paula Rocha de Queiroga, Blenda Brito de Queiroz, Daniely Rayane Bezerra de Farias, Joyceana Oliveira Correia, Eliane Rolim Florentino, Flávia Carolina Alonso Buriti
The content of this RSS Feed (c) The Royal Society of Chemistry




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Computational study on the polymerization reaction of D-aminopeptidase for the synthesis of D-peptides

RSC Adv., 2020, 10,17582-17592
DOI: 10.1039/D0RA01138J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joan Gimenez-Dejoz, Kousuke Tsuchiya, Ayaka Tateishi, Yoko Motoda, Takanori Kigawa, Yasuhisa Asano, Keiji Numata
We studied the molecular mechanism of D-aminopeptidase for the synthesis of polypeptides incorporating D-amino acids.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Preparation of phosphorus-doped porous carbon for high performance supercapacitors by one-step carbonization

RSC Adv., 2020, 10,17768-17776
DOI: 10.1039/D0RA02398A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Guanfeng Lin, Qiong Wang, Xuan Yang, Zhenghan Cai, Yongzhi Xiong, Biao Huang
P-doped porous carbon can be prepared by one-step carbonization using biomass sawdust impregnated with a small amount of phosphoric acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A chitosan-based edible film with clove essential oil and nisin for improving the quality and shelf life of pork patties in cold storage

RSC Adv., 2020, 10,17777-17786
DOI: 10.1039/D0RA02986F, Paper
Open Access
Karthikeyan Venkatachalam, Somwang Lekjing
This study assessed chitosan (CS)-based edible films with clove essential oil (CO) and nisin (NI) singly or in combination, for improving quality and shelf life of pork patties stored in cold conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dependence on co-adsorbed water in the reforming reaction of ethanol on a Rh(111) surface

RSC Adv., 2020, 10,17787-17794
DOI: 10.1039/D0RA02015J, Paper
Open Access
Yu-Yao Hsia, Po-Cheng Chien, Lu-Hsin Lee, Yu-Ling Lai, Li-Chung Yu, Yao-Jane Hsu, Jeng-Han Wang, Meng-Fan Luo
Adsorbed ethanol molecules penetrated readily through pre-adsorbed water to react at the Rh surface; they decomposed at a promoted probability.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ni stabilized rock-salt structured CoO; Co1−xNixO: tuning of eg electrons to develop a novel OER catalyst

RSC Adv., 2020, 10,17845-17853
DOI: 10.1039/D0RA03050C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rakesh Mondal, Himanshu Ratnawat, Sarvesh Kumar, Anil Kumar, Preetam Singh
Incorporation of Ni into CoO lattices helps to stabilize the rock salt structure and modulate the eg electrons to develop superior OER and ORR electrocatalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effect of Zn doping on phase transition and electronic structures of Heusler-type Pd2Cr-based alloys: from normal to all-d-metal Heusler

RSC Adv., 2020, 10,17829-17835
DOI: 10.1039/D0RA02951C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaotian Wang, Mengxin Wu, Tie Yang, Rabah Khenata
By first-principles calculations, for Heusler alloys Pd2CrZ (Z = Al, Ga, In, Tl, Si, Sn, P, As, Sb, Bi, Se, Te, Zn), the effect of Zn doping on their phase transition and electronic structure has been studied in this work.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Microwave roasting of blast furnace slag for carbon dioxide mineralization and energy analysis

RSC Adv., 2020, 10,17836-17844
DOI: 10.1039/D0RA02846K, Paper
Open Access
Zike Han, Jianqiu Gao, Xizhi Yuan, Yanjun Zhong, Xiaodong Ma, Zhiyuan Chen, Dongmei Luo, Ye Wang
This paper highlights the potential of microwave roasting in solid-waste treatment and carbon dioxide storage.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced methane gas storage in the form of hydrates: role of the confined water molecules in silica powders

RSC Adv., 2020, 10,17795-17804
DOI: 10.1039/D0RA01754J, Paper
Open Access
Pinnelli S. R. Prasad, Burla Sai Kiran, Kandadai Sowjanya
Rapid and efficient methane hydrate conversions by utilising the water molecules confined in intra- and inter-granular space of silica powders.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis, characterization and corrosion inhibition behavior of 2-aminofluorene bis-Schiff bases in circulating cooling water

RSC Adv., 2020, 10,17816-17828
DOI: 10.1039/D0RA01903H, Paper
Open Access
Wenchang Wei, Zheng Liu, Chuxin Liang, Guo-Cheng Han, Jiaxing Han, Shufen Zhang
Two new bis-Schiff bases, namely 2-bromoisophthalaldehyde-2-aminofluorene (M1) and glutaraldehyde 2-aminofluorene (M2) were synthesized and were characterized, the potentiodynamic polarization curve confirmed that they were anode type inhibitors.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile synthesis of a direct Z-scheme BiOCl–phosphotungstic acid heterojunction for the improved photodegradation of tetracycline

RSC Adv., 2020, 10,17369-17376
DOI: 10.1039/D0RA02396E, Paper
Open Access
Haijuan Tong, Bingfang Shi, Shulin Zhao
A one-step hydrothermal approach for synthesizing BiOCl–phosphotungstic acid (BiOCl–HPW) heterojunctions is proposed. The prepared BiOCl–HPW heterojunction exhibited good stability and photocatalytic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correction: Narrowing band gap and enhanced visible-light absorption of metal-doped non-toxic CsSnCl3 metal halides for potential optoelectronic applications

RSC Adv., 2020, 10,17869-17869
DOI: 10.1039/D0RA90054K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakiul Islam, A. K. M. Akther Hossain
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effect of new carbonyl cyanide aromatic hydrazones on biofilm inhibition against methicillin resistant Staphylococcus aureus

RSC Adv., 2020, 10,17854-17861
DOI: 10.1039/D0RA03124K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xueer Lu, Ziwen Zhang, Yingying Xu, Jun Lu, Wenjian Tang, Jing Zhang
2e and 2j with strong p-NO2 and p-CF3 at phenyl ring had the lowest MICs against S. aureus and MRSA. 2e displayed unaided or synergistic efficacy against MRSA, especially combined with ofloxacin. EM revealed that 2e destroys biofilms and cell membranes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Research on the controllable degradation of N-methylamido and dialkylamino substituted at the 5th position of the benzene ring in chlorsulfuron in acidic soil

RSC Adv., 2020, 10,17870-17880
DOI: 10.1039/D0RA00811G, Paper
Open Access
Fan-Fei Meng, Lei Wu, Yu-Cheng Gu, Sha Zhou, Yong-Hong Li, Ming-Gui Chen, Shaa Zhou, Yang-Yang Zhao, Yi Ma, Zheng-Ming Li
These results will provide valuable information to discover tailored SU with controllable degradation properties to meet the needs of individual crops.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of heteroatom-containing pyrrolidine derivatives based on Ti(O-iPr)4 and EtMgBr-catalyzed carbocyclization of allylpropargyl amines with Et2Zn

RSC Adv., 2020, 10,17881-17891
DOI: 10.1039/D0RA02677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rita N. Kadikova, Ilfir R. Ramazanov, Azat M. Gabdullin, Oleg S. Mozgovoj, Usein M. Dzhemilev
The Ti(O-iPr)4 and EtMgBr-catalyzed regio and stereoselective carbocyclization of N-allyl-substituted 2-alkynylamines with Et2Zn, followed by deuterolysis or hydrolysis, affords the corresponding methylenepyrrolidine derivatives in high yields.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Anatomy of an HTML5 WordPress theme

This site has been written in HTML5 and used to use WordPress to manage the content. I’ll explain why I used HTML5, describe the structure of the theme templates, and show some of the ways I tried to tame WordPress’s tendency to add mess to the source code.

As this is my personal site I wanted to experiment with using HTML5, CSS3, and WAI-ARIA. All these documents are currently working drafts and subject to change. However, the web documents and applications of the future are going to be written in HTML5 and I wanted to see the benefits of using it to markup static documents. Using CSS 2.1, let alone the CSS3 selectors and properties that some browser vendors have implemented, has many advantages for controlling the presentation of semantically coded documents. For this reason I am not going to avoid using basic CSS 2.1 selectors just to faithfully reproducing this site’s design in IE6. However, I have tried to accommodate IE 7 and IE 8 users by using an HTML5 enabling script so that the new HTML5 elements can be styled in those browsers if users have Javascript enabled.

HTML5 templates

I started with a static prototype of this site developed on my local server. WordPress makes it very easy to create your own templates and, therefore, it is no problem to use HTML5. This theme only has 3 main templates: index, single, and archive. There are of course templates for 404s, attachments, comments, etc., but I won’t discuss them as they are all based on the 3 main templates. All the templates include ARIA roles as an accessibility aide.

The single.php template has this rough structure:

<!DOCTYPE html>
<html lang="en">
<head>
  <meta charset="utf-8">
  <title></title>
  <link rel="stylesheet" href="default.css">
</head>

<body>
  <header role="banner"></header>
  <nav role="navigation"></nav>
  <article role="main">
    <header>
      <time datetime="YYYY-MM-DD"></time>
      <h1></h1>
    </header>
    <footer></footer>
  </article>
  <nav></nav>
  <aside role="complementary"></aside>
  <footer role="contentinfo">
    <small></small>
  </footer>
</body>
</html>

The first line of the document is the HTML5 DOCTYPE. The new <article> element contains the content of each post. The same structure is used for the index.php template except that there are several articles displayed on each page and the ARIA role value of main is not used. In contrast, the archive.php template houses all the article excerpts in a <section> element with the ARIA role of main because the list of archived posts is itself the main content of the document.

A clean theme

WordPress tends to add classes, elements, and other bits of code in certain places. I haven’t used any of the WordPress functions that add class names to the body and to elements wrapping a post and also wanted to avoid cluttering the source code with any other unnecessary markup. This required a bit of fiddling around with the theme’s functions.php file. I’m not a PHP developer so this might not be pretty!

Removing actions from wp_head()

WordPress has a hook called wp_head that sits in the header.php of most themes. To avoid it inserting unwanted code into the <head> of the document I used the remove_action function to disable the functions that were responsible. The following code was added to the functions.php file of my theme:

// Remove links to the extra feeds (e.g. category feeds)
remove_action( 'wp_head', 'feed_links_extra', 3 );
// Remove links to the general feeds (e.g. posts and comments)
remove_action( 'wp_head', 'feed_links', 2 );
// Remove link to the RSD service endpoint, EditURI link
remove_action( 'wp_head', 'rsd_link' );
// Remove link to the Windows Live Writer manifest file
remove_action( 'wp_head', 'wlwmanifest_link' );
// Remove index link
remove_action( 'wp_head', 'index_rel_link' );
// Remove prev link
remove_action( 'wp_head', 'parent_post_rel_link', 10, 0 );
// Remove start link
remove_action( 'wp_head', 'start_post_rel_link', 10, 0 );
// Display relational links for adjacent posts
remove_action( 'wp_head', 'adjacent_posts_rel_link', 10, 0 );
// Remove XHTML generator showing WP version
remove_action( 'wp_head', 'wp_generator' );

Source: WPEngineer.com: Cleanup WordPress Header

Removing an empty <span>

If you want to create excerpts you can either write them into the excerpt box or use the <--more--> quicktag in the WordPress editor. I just wanted the first paragraph of my posts to be used as the excerpt and so using the in-editor tag was the most practical approach I was aware of. However, when you do this WordPress will insert an empty <span> in the post’s content. This element has an id so that the area following the excerpt can be targeted by “more” or “continue reading” links. I removed both the empty <span> and the jump link by adding the following code to the functions.php file of the theme:

// removes empty span
function remove_empty_read_more_span($content) {
  return eregi_replace("(<p><span id="more-[0-9]{1,}"></span></p>)", "", $content);
}
add_filter('the_content', 'remove_empty_read_more_span');

Source: Ganda Manurung: Remove Empty Span Tag On WordPress

// removes url hash to avoid the jump link
function remove_more_jump_link($link) {
  $offset = strpos($link, '#more-');
  if ($offset) {
    $end = strpos($link, '"',$offset);
  }
  if ($end) {
    $link = substr_replace($link, '', $offset, $end-$offset);
  }
  return $link;
}
add_filter('the_content_more_link', 'remove_more_jump_link');

Source: WordPress Codex: Customizing the Read More

Displaying images in the excerpt

For posts that display nothing but a photograph (yes, they will be shit but I’m hoping it gets me using my camera a bit more often) I wanted the image to show up in the archives. Equally, if the first paragraph of a post contained a link I wanted that to be preserved. The default the_excerpt() template tag doesn’t allow for this so it needed some modifying. I added a new function, which is just a modified version of the core excerpt function, to the functions.php file and then made sure that the template tag executed this function rather than the one contained in the core WordPress files.

function improved_trim_excerpt($text) {
   if ( '' == $text ) {
      $text = get_the_content('');
      $text = strip_shortcodes( $text );
      $text = apply_filters('the_content', $text);
      $text = str_replace(']]>', ']]&amp;gt;', $text);
      $text = strip_tags($text, '<p><img><a>');
      $excerpt_length = apply_filters('excerpt_length', 55);
      $words = explode(' ', $text, $excerpt_length + 1);
      if (count($words) > $excerpt_length) {
         array_pop($words);
         array_push($words, '[...]');
         $text = implode(' ', $words);
         $text = force_balance_tags($text);
      }
   }
   return $text;
}
remove_filter('get_the_excerpt', 'wp_trim_excerpt');
add_filter('get_the_excerpt', 'improved_trim_excerpt');

Source: Aaron Russell: Improving WordPress’ the_excerpt() template tag

I prefer not to have empty elements in the markup and so I needed a way to conditionally insert the “Older entries”, “Newer Entries”, etc., links into templates. The solution I’m using here, which isn’t perfect, is to add this to functions.php:

function show_posts_nav() {
  global $wp_query;
  return ($wp_query->max_num_pages > 1);
}

Source: Eric Martin: Conditional navigation links in WordPress

And then to wrap the navigation markup in the templates with the following:

<?php if (show_posts_nav()) : ?>
<nav>
   <ul>
      <li><?php next_posts_link('&#171; Older Entries') ?></li>
      <li><?php previous_posts_link('Newer Entries &#187;') ?></li>
   </ul>
</nav>
<?php endif; ?>

Summary

It’s fairly easy to create a simple site with HTML5 and to use WordPress to deliver it. At the moment there are issues with Internet Explorer because you cannot style HTML5 elements unless you use Javascript. However, HTML5 redefines the meaning of certain elements (such as <dl>, which has become a more versatile “description list”) and allows block elements to be wrapped in a link. Therefore, there is still benefit in using the HTML5 DOCTYPE even if you do not make use of the new elements.

Further reading

  1. HTML5 working draft
  2. HTML5 differences from HTML4
  3. Accessible Rich Internet Applications (WAI-ARIA) 1.0




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