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[ASAP] Acylation of Aryl Halides and a-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis

Organic Letters
DOI: 10.1021/acs.orglett.0c01121




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[ASAP] Pd-Catalyzed Regiodivergent Synthesis of Diverse Oxindoles Enabled by the Versatile Heck Reaction of Carbamoyl Chlorides

Organic Letters
DOI: 10.1021/acs.orglett.0c01197




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[ASAP] Carbocation versus Carbene Controlled Chemoselectivity: DFT Study on Gold- and Silver-Catalyzed Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters

Organic Letters
DOI: 10.1021/acs.orglett.0c01476




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[ASAP] Copper-Catalyzed Oxyvinylation of Diazo Compounds

Organic Letters
DOI: 10.1021/acs.orglett.0c01150




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[ASAP] K<sub>2</sub>S as Sulfur Source and DMSO as Carbon Source for the Synthesis of 2-Unsubstituted Benzothiazoles

Organic Letters
DOI: 10.1021/acs.orglett.0c00994




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[ASAP] Palladium-Catalyzed Cascade Decarboxylative Amination/6-<italic toggle="yes">endo-dig</italic> Benzannulation of <italic toggle="yes">o</italic>-Alkynylarylketones with <italic toggle="yes"&g

Organic Letters
DOI: 10.1021/acs.orglett.0c01183




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[ASAP] DNA Compatible Intermolecular Wittig Olefination for the Construction of a, ß-Unsaturated Carbonyl Compounds

Organic Letters
DOI: 10.1021/acs.orglett.0c01215




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[ASAP] Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01416




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[ASAP] Organocatalytic Regiodivergent Ring Expansion of Cyclobutanones for the Enantioselective Synthesis of Azepino[1,2-<italic toggle="yes">a</italic>]indoles and Cyclohepta[<italic toggle="yes">b</italic>]ind

Organic Letters
DOI: 10.1021/acs.orglett.0c01406




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[ASAP] Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01273




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[ASAP] Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01112




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[ASAP] Stereoselective Asymmetric Synthesis of Pyrrolidines with Vicinal Stereocenters Using a Memory of Chirality-Assisted Intramolecular S<sub>N</sub>2' Reaction

Organic Letters
DOI: 10.1021/acs.orglett.0c01307




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[ASAP] Nickel-Catalyzed Cyclization Strategy for the Synthesis of Pyrroloquinolines, Indoloquinolines, and Indoloisoquinolines

Organic Letters
DOI: 10.1021/acs.orglett.0c01055




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[ASAP] Enantioselective Copper-Catalyzed Remote C(sp<sup>3</sup>)–H Alkynylation of Linear Primary Sulfonamides

Organic Letters
DOI: 10.1021/acs.orglett.0c01325




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[ASAP] Synthesis of Aspidodispermine via Pericyclic Framework Reconstruction

Organic Letters
DOI: 10.1021/acs.orglett.0c01242




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[ASAP] Nickel(II)-Catalyzed Addition of Aryl-, Alkenyl-, and Alkylboronic Acids to Alkenylazaarenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01425




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[ASAP] Designing Homogeneous Copper-Free Sonogashira Reaction through a Prism of Pd–Pd Transmetalation

Organic Letters
DOI: 10.1021/acs.orglett.0c01227




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[ASAP] Iron-Catalyzed Oxidative Coupling of Indoline-2-ones with Aminobenzamides via Dual C–H Functionalization

Organic Letters
DOI: 10.1021/acs.orglett.0c01066




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[ASAP] Total Synthesis of Echinomycin and Its Analogues

Organic Letters
DOI: 10.1021/acs.orglett.0c01268




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[ASAP] Total Synthesis of (±)-Sceptrin

Organic Letters
DOI: 10.1021/acs.orglett.0c01381




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[ASAP] Sequential Visible-Light and <italic toggle="yes">N</italic>-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-<italic toggle="yes">b</italic>]indoles

Organic Letters
DOI: 10.1021/acs.orglett.0c01447




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[ASAP] Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin

Organic Letters
DOI: 10.1021/acs.orglett.0c01168




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[ASAP] Synthesis of Spiroisoxazolines via an Oximation/Dearomatization Cascade under Air

Organic Letters
DOI: 10.1021/acs.orglett.0c01429




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[ASAP] Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation

Organic Letters
DOI: 10.1021/acs.orglett.0c01421




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[ASAP] Oxidative Coupling of Aldehydes with Alcohol for the Synthesis of Esters Promoted by Polystyrene-Supported N-Heterocyclic Carbene: Unraveling the Solvent Effect on the Catalyst Behavior Using NMR Relaxation

Organic Letters
DOI: 10.1021/acs.orglett.0c01188




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[ASAP] Copper-Catalyzed 1,2-Aminocyanation of Unactivated Alkenes via Cyano Migration

Organic Letters
DOI: 10.1021/acs.orglett.0c01217




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[ASAP] Phosphorus(III)-Mediated, Tandem Deoxygenative Geminal Chlorofluorination of 1,2-Diketones

Organic Letters
DOI: 10.1021/acs.orglett.0c01258




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[ASAP] Copper-Mediated DNA-Compatible One-Pot Click Reactions of Alkynes with Aryl Borates and TMS-N<sub>3</sub>

Organic Letters
DOI: 10.1021/acs.orglett.0c01219




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[ASAP] Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process

Organic Letters
DOI: 10.1021/acs.orglett.0c01297




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[ASAP] A General One-Pot Protocol for Hindered <italic toggle="yes">N</italic>-Alkyl Azaheterocycles from Tertiary Carboxylic Acids

Organic Letters
DOI: 10.1021/acs.orglett.0c01254




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[ASAP] Studies of the Enantiocontrolled Synthesis of the C(10)–C(25) Subunit of Amphidinolide C

Organic Letters
DOI: 10.1021/acs.orglett.0c01177




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[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




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[ASAP] Addition to “Selective Methylation of Amides, <italic toggle="yes">N</italic>-Heterocycles, Thiols, and Alcohols with Tetramethylammonium Fluoride”

Organic Letters
DOI: 10.1021/acs.orglett.0c01524




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[ASAP] Nickel-Catalyzed Formal Aminocarbonylation of Secondary Benzyl Chlorides with Isocyanides

Organic Letters
DOI: 10.1021/acs.orglett.0c01284




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[ASAP] Benzo- and Thieno-Annulated Tetracenes: A One-Pot Synthesis via Cross-Dehydrogenative Annulation

Organic Letters
DOI: 10.1021/acs.orglett.0c01244




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[ASAP] Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Noncovalent Chirality

Organic Letters
DOI: 10.1021/acs.orglett.0c01200




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[ASAP] Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

Organic Letters
DOI: 10.1021/acs.orglett.0c01277




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Welcome, New Pastor, to Our Empty Church

Congregations and pastoral candidates are adapting the hiring process and getting to know each other online.

Phillip Bethancourt’s kids aren’t convinced other children actually live in College Station, Texas. They moved from Nashville a few weeks ago for their dad’s new job as pastor of Central Church, but because of the coronavirus shutdowns, the four boys have yet to go school, make friends in the neighborhood, or meet the kids at their new church.

Bethancourt too is living in his own strange parallel reality, preaching to a video camera in an empty auditorium and waiting for a congregation he hasn’t seen to officially vote him in. If all goes as planned on Sunday, he’ll become a lead pastor for the first time while his flock is still social distancing.

“Nothing matches the opportunity to be with people in person,” said Bethancourt, who left his job as vice president of the Ethics and Religious Liberty Commission to pursue the call at Central Church. “But I would say the process we’ve been using so far is the best substitute we can create.”

Several other pastors and churches are in the same predicament, caught in the process of applying, interviewing, and onboarding during the coronavirus pandemic.

“This is not the time to be without a pastor,” said William Vanderbloemen, who runs a consulting agency that helps Christian organizations with hiring. His phone has been “ringing off the hook” with churches wanting to get serious about their pastoral search.

Many have decided to forge ahead with the process despite the unique challenges of social restrictions and shutdowns due to the pandemic. Several congregations, including high-profile megachurches Moody Church and Willow Creek Community Church, were in the midst of leadership transitions and have named ...

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Beyond Cedarville: Why Do Pastors Keep Getting Rehired After Abuse?

Victims’ advocates caution institutions against plans to “restore” fallen leaders.

Update (May 1): Cedarville University president Thomas White has been placed on administration leave by the school’s board of trustees. A week after Anthony Moore was fired by White over “additional information related to [his] past,” the board announced it will commission an independent investigation of Moore and an audit of his hiring.

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Another case of a leader with an abusive past moving from one evangelical institution to another has intensified scrutiny on Christian hiring practices and responses to abuse.

In ministry contexts, the desire to keep fallen leaders out of positions where they might again abuse their authority is sometimes met with another perspective—a hope that a redemptive and forgiving God would allow people to be restored to leadership. Both victims’ advocates and community members worry that administrators weighing those considerations at Cedarville University made the wrong call.

In 2017, Cedarville welcomed Anthony Moore six months after he was fired from the lead pastor position of The Village Church’s Fort Worth campus. President Thomas White wrote that he offered to shepherd Moore through a five-year plan of restoration at the conservative Baptist school while he taught theology, helped coach basketball, and served as a special advisor on diversity.

CT spoke with four current and former Cedarville professors who said they knew Moore had made a “mistake” related to same-sex attraction and technology, based on White’s introduction and Moore’s own telling. Some assumed pornography or an online relationship. They had no idea that he had reportedly filmed a subordinate at his previous church in the shower. The revelation, detailed by multiple ...

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Relevant Details Missing as Cameron Strang Returns

The Christian magazine had halted publication without informing subscribers and has shared little about its founder’s sabbatical.

Last month, Relevant Podcast listeners heard a familiar voice in their earbuds: founder Cameron Strang, returning to the show’s lineup—and to leadership at Relevant Media Group—six months after stepping away due to public criticism from former employees.

Though Relevant promised to be transparent with its efforts to address Strang’s alleged racial insensitivity and difficult leadership style, it did not bring up the process again until the April 10 update announcing his return as CEO.

In the meantime, the bimonthly Christian magazine had not sent out an issue to its 27,000 paid subscribers since Strang left in September, leaving fans to wonder about its future.

Strang told listeners that he’s “excited to be back” for a new era at Relevant as it prepares to revamp and expand its podcast offerings, transition to a yearly print publication, and relaunch its website, all under an advisory board newly enlisted to oversee leadership of the 10-person staff.

Relevant’s loyal followers, some of whom have been around for its entire 20-year history, are excited to hear Strang’s voice again. But as much as they hope to see the kind of progress the company has promised and prayed for, a few have questioned the lack of communication.

“When the print issues stopped coming, I was disappointed but figured the company was trying to figure out how to move forward. I suspected they had lost a lot of advertisers & revenue,” wrote Erin Bird, an Iowa pastor, in a Twitter thread responding to the April update. “I’ve patiently walked thru this w/ you, actually prayed for you guys (& those hurt), & was hoping to see a repentance from Cameron that would show the world ...

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ERLC Shifts Staff as Three Longtime Leaders Move On

Russell Moore’s earliest appointees helped define a new era for the Southern Baptist Convention’s public policy arm.

Three top leaders who served alongside Russell Moore at the Ethics & Religious Liberty Commission (ERLC) since the start of his presidency have left the Southern Baptist entity over the past six months.

Outgoing vice presidents Phillip Bethancourt and Daniel Darling and former director Andrew Walker embodied key emphases of the ERLC in recent years, as it developed new ways to equip churches to address racial justice, sexual abuse, and societal pressures around marriage and family.

The ERLC said in a news release that its mission continues uninterrupted, the staff changes providing an opportunity “to strengthen the work of the organization.”

Bethancourt—who stepped down from his position as executive vice president on April 26 to become pastor of Central Church in College Station, Texas—cited the trio’s work as evidence of “a generational shift on how Southern Baptists engage the public square.”

Days before Bethancourt’s departure, Darling, the ERLC vice president for communications, announced he too would be leaving, taking on a position as senior vice president for communications at the National Religious Broadcasters. Walker, former director of research and senior fellow in Christian ethics, departed October 31 to become a full-time ethics professor at the Southern Baptist Theological Seminary.

To fill their roles, the ERLC named former vice president for operations and chief of staff Daniel Patterson as the new executive vice president and spread Walker’s responsibilities among other staff. Darling’s replacement has not been announced.

Several additional staff shifts were announced last week, including the tapping of Travis Wussow, general counsel and vice president ...

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After SAT and ACT Cancel, Registrations Soar for Classical Education Exam

An alternative college admissions test, used by some Christian schools, draws a record 50,000 students.

The Classic Learning Test (CLT), a niche college entrance exam aspiring to bring a sense of virtue to standardized tests, saw a 1,000 percent increase in registrations over its short history when the SAT and ACT canceled testing for the remainder of the school year due to COVID-19.

“Because we are able to administer the test remotely, we’re kind of the only game in town,” said Jeremy Tate, who created the CLT four years ago amid a renaissance in Classical education, including among Christians.

At its first administration in June 2016, 47 students took the CLT. With the bump in registration, 50,000 students will take its suite of tests—the CLT, and the CLT-8 and CLT-10, designed for lower grades—during the 2019-2020 academic year. That’s more than double last year’s total.

Though not a Christian company, CLT references figures including John Henry Newman and C. S. Lewis in its promotional materials and stresses the moral, formational dimension to education. The exam has been popular among classical Christian schools, which educate over 40,000 students in the US, and homeschoolers, who make up about 40 percent of CLT test-takers.

So far, 178 colleges and universities in the US accept the exam, mostly Catholic and Protestant schools. For other institutions, the CLT can serve as a supplemental assessment.

The College Board and ACT Inc., the companies that administer the SAT and ACT, respectively, have canceled or postponed in-person testing until the fall, leading many colleges to make the admissions exams an optional part of their applications. In 2018, around 2 million students took the SAT and 1.9 million took the ACT.

While some registrants may turn to the CLT this year for the convenience ...

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Died: Darrin Patrick, Who Used His Fall and Restoration to Help Struggling Pastors

(UPDATED) The St. Louis pastor spoke up about the difficulties faced by leaders and critiqued “celebrity culture” in ministry.

Darrin Patrick, a megachurch pastor, author, and speaker, has died.

Patrick was a teaching pastor at Seacoast Church, a multi-site megachurch based in Mount Pleasant, South Carolina, and the founding pastor of the Journey Church in St. Louis, where he lived.

In a Friday evening update, Seacoast Church stated: “Darrin was target shooting with a friend at the time of his death. An official cause of death has not been released but it appears to be a self-inflicted gunshot wound. No foul play is suspected.”

Patrick’s unexpected death came as a shock to friends and colleagues. Robby Gallaty, pastor of Long Hollow Baptist, in Hendersonville, Tennessee, said that Patrick was scheduled to speak at his church next weekend.

“I just talked to him Tuesday and Wednesday,” said Gallaty. “This is the second close friend I have lost in a year.”

Gallaty first met Patrick in 2015 and had invited him to speak the following year at a men’s ministry event at Long Hollow. Just before the event, he said, Patrick called and said he was leaving the ministry.

At the time, Patrick had been a rising star among Reformed evangelical circles and was serving as vice-president of the Acts 29 church planting network. He was fired from Journey for what church elders called misconduct including “inappropriate meetings, conversations, and phone calls with two women” and an abuse of power.

Despite Patrick’s fall from ministry, the two stayed friends. Patrick admitted his faults and got counseling. He went through a restoration process that lasted 26 months, according to a 2019 blog interview posted at Christianity Today. He returned to the ministry as a preacher but not as a senior pastor of a church. ...

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LG Chem share price falls nearly 2% after deadly gas leak in India

The leak was brought under control after being discovered by a maintenance worker on the night shift at the LG Polymers plant, outside the east coast city of Visakhapatnam, in India`s southern Andhra Pradesh state, according to a company spokesman.




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Elon Musk delays release of Tesla's Roadster sports car

Tesla Inc Chief Executive Elon Musk said in a podcast interview released on Thursday that the company`s planned Roadster sports car would take a backseat to the development of other vehicle models.




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NLC India TPS II, all about the company where boiler blast occurred in Neyveli

The power stations of the NLC integrated mining-cum-power generating company are located at Neyveli in Cuddalore.




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Service charges for Post office savings a/c, issue of duplicate passport and more

Here are some details of service charges that the Post Office charges you.




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Dharmendra Pradhan hints at new gas policy, says low oil prices no answer

Pradhan also said that India favours reasonable prices that give some space to the producer countries.




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Nitin Gadkari asks traders to take loan in dollars, keep their balance sheets clean

The Union minister also offered them some remedies that are likely to earn money and will help them in increasing their business.




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Asperger's children: the origins of autism in Nazi Vienna / Edith Sheffer

Browsery RJ506.A9 S5257 2018