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Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01911A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech Pisula
The solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.
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Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01349H, Edge Article
Open Access
Michael Fairley, Leonie Bole, Florian Mulks, Laura Main, Alan Kennedy, Charles T. O'Hara, Joaquín García-Álvarez, Eva Hevia
Lithium amides constitute one of the most commonly used class of reagents in synthetic chemisty. However, despite many applications, their use is handicapped by their requirements of low temperatures, in...
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Covalent Organic Frameworks as Microreactors: Confinement-enhanced Electrochemiluminescence

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01817A, Edge Article
Open Access
Wei-Jia Zeng, Kun Wang, Wenbin Liang, Yaqin Chai, Ruo Yuan, Ying Zhuo
Herein, the electrochemiluminescence (ECL) microreactors with enhanced intensity and extreme stability were firstly established by the assembly of tris(2,2’-bipyridyl) ruthenium (II) (Ru(bpy)32+) onto the covalent organic frameworks (COFs) where a...
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Thermal effects – an alternative mechanism for plasmon-assisted photocatalysis

Chem. Sci., 2020, Advance Article
DOI: 10.1039/C9SC06480J, Edge Article
Open Access
Yonatan Dubi, Ieng Wai Un, Yonatan Sivan
A simple Arrhenius-based theory of heating, rather than “hot electrons”, can reproduce some high-profile photocatalysis experimental results to remarkable accuracy. Flaws in temperature measurement may have led to wrong conclusions.
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Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01572E, Edge Article
Open Access
Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj Kumar
Base-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.
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Dynamic reaction-induced phase separation in tunable, adaptive covalent networks

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00605J, Edge Article
Open Access
Katie M. Herbert, Patrick T. Getty, Neil D. Dolinski, Jerald E. Hertzog, Derek de Jong, James H. Lettow, Joy Romulus, Jonathan W. Onorato, Elizabeth M. Foster, Stuart J. Rowan
Dynamic covalent networks comprised of tunable thia-Michael bonds result in phase separated networks with tailorable mechanical and adaptive properties.
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Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00463D, Edge Article
Open Access
Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. Williams
A new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.
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Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01534B, Edge Article
Open Access
Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie Zhu
Quantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...
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Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01833C, Edge Article
Open Access
Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D Bloch
We describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...
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Highly efficient non-doped blue fluorescent OLEDs with low efficiency roll-off based on hybridized local and charge transfer excited state emitters

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01341B, Edge Article
Open Access
Xianhao Lv, Mizhen Sun, Lei Xu, Runzhe Wang, Huayi Zhou, Yuyu Pan, Shitong Zhang, Qikun Sun, Shanfeng Xue, Wenjun Yang
A new pure fluorescent blue HLCT-emitter was designed and synthesized. Highly efficient non-doped blue OLEDs with low efficiency roll-off were achieved.
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Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC02253E, Edge Article
Open Access
Juan Mangas-Sanchez, Mahima Sharma, Sebastian C. Cosgrove, Jeremy I. Ramsden, James R. Marshall, Thomas W. Thorpe, Ryan B. Palmer, Gideon Grogan, Nicholas J. Turner
Fungal reductive aminases as effective biocatalysts for the preparation of chiral primary amines.
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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts

Chem. Sci., 2020, 11,4381-4390
DOI: 10.1039/D0SC01026J, Edge Article
Open Access
Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen Niemeyer
Supramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.
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Tetrazine as a general phototrigger to turn on fluorophores

Chem. Sci., 2020, 11,4410-4415
DOI: 10.1039/D0SC01009J, Edge Article
Open Access
Axel Loredo, Juan Tang, Lushun Wang, Kuan-Lin Wu, Zane Peng, Han Xiao
Tetrazine was demonstrated for the first time as a general phototrigger to design photoactivatable fluorophore probes.
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Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue

Chem. Sci., 2020, 11,4488-4498
DOI: 10.1039/D0SC00544D, Edge Article
Open Access
Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-Tejada
A fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents

Chem. Sci., 2020, 11,4374-4380
DOI: 10.1039/D0SC00206B, Edge Article
Open Access
Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. Cozzolino
A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin

Chem. Sci., 2020, 11,4516-4524
DOI: 10.1039/D0SC01319F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar Willner
Biocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.
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Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

Chem. Sci., 2020, 11,4499-4507
DOI: 10.1039/D0SC00135J, Edge Article
Open Access
Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming Hu
Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.
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Correction: Metal complexes as a promising source for new antibiotics

Chem. Sci., 2020, 11,4531-4531
DOI: 10.1039/D0SC90075C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angelo Frei, Johannes Zuegg, Alysha G. Elliott, Murray Baker, Stefan Braese, Christopher Brown, Feng Chen, Christopher G. Dowson, Gilles Dujardin, Nicole Jung, A. Paden King, Ahmed M. Mansour, Massimiliano Massi, John Moat, Heba A. Mohamed, Anna K. Renfrew, Peter J. Rutledge, Peter J. Sadler, Matthew H. Todd, Charlotte E. Willans, Justin J. Wilson, Matthew A. Cooper, Mark A. T. Blaskovich
The content of this RSS Feed (c) The Royal Society of Chemistry




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Small-molecule fluorescent probes for imaging gaseous signaling molecules: current progress and future implications

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01482F, Perspective
Open Access
Mingwang Yang, Jiangli Fan, Jianjun Du, Xiaojun Peng
This perspective article aims to introduce the design principles and recognition strategies of small-molecule fluorescent probes which are applied for the detection of gas signaling molecules including NO, CO and H2S in biological systems.
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A highly stable RNA aptamer probe for the retinoblastoma protein in live cells

Chem. Sci., 2020, 11,4467-4474
DOI: 10.1039/D0SC01613F, Edge Article
Open Access
Thao T. Le, Andreas Bruckbauer, Bogachan Tahirbegi, Alastair J. Magness, Liming Ying, Andrew D. Ellington, Anthony E. G. Cass
An RNA G-quadruplex aptamer, specific for the human retinoblastoma protein (RB) and highly stable inside cells, is selected and its application to live cell probing of the protein illustrated.
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Ultraviolet photochemistry of ethane: implications for the atmospheric chemistry of the gas giants

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01746A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yao Chang, Jiayue Yang, Zhichao Chen, Zhiguo Zhang, Yong Yu, Qingming Li, Zhigang He, Weiqing Zhang, Guorong Wu, Rebecca A. Ingle, Matthew Bain, Michael N. R. Ashfold, Kaijun Yuan, Xueming Yang, Christopher S. Hansen
The vacuum ultraviolet photodissociation dynamics of ethane provide clues for modelling the atmospheric chemistry of the gas giants.
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as

Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00266F, Edge Article
Open Access
Yunyi Wang, Jihyun Kim, Christian Hilty
Elucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...
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Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01544J, Perspective
Open Access
Rebecca A. Olson, Angie B. Korpusik, Brent S. Sumerlin
Light-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.
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Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
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Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
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Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
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N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00968G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. Lipshutz
A new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.
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YES Bank okays board reconstitution; Prashant Kumar to be new MD & CEO

The other board members will be Sunil Mehta, former non-executive chairman of Punjab National Bank, as the non executive chairman of YES Bank




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Weather Warnings for Queensland - land areas. Issued by the Australian Bureau of Meteorology




as

What is ASBA with respect to IPOs?

As of April 1, 2019, there were 66 SCSBs such as HDFC Bank, SBI, ICICI Bank, PNB, Kotak Mahindra Bank, SBI and Axis Bank, among others, which are recognised as being capable of providing ASBA services to customers.




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We are buying in this market on a daily basis, says LIC MD Vipin Anand

The IPO is a time-consuming thing, which is going to be there, says Vipin Anand.




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Preschool in three cultures revisited : China, Japan, and the United States / Joseph Tobin, Yeh Hsueh, and Mayumi Karasawa

Tobin, Joseph Jay




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Reflective teaching in higher education / Paul Ashwin and [and 10 others]

Ashwin, Paul, 1970-




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Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman




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The Humboldtian tradition : origins and legacies / edited by Peter Josephson, Thomas Karlsohn, Johan Östling




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Wondrous words : writers and writing in the elementary classroom / Katie Wood Ray

Ray, Katie Wood, 1964- author




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Education and the crisis of public values : challenging the assault on teachers, students, and public education / Henry A. Giroux

Giroux, Henry A, author




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The skillful teacher : on technique, trust, and responsiveness in the classroom / Stephen D. Brookfield

Brookfield, Stephen, author




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Das Fernstudium an den Universitäten und Fachhochschulen Australiens / Anno Ortmeier

Ortmeier, Anno




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Evolving entrepreneurial education : innovation in the Babson classroom / edited by Victoria L. Crittenden, Kathryn Esper, Nathaniel Karst, Rosa Siegers, Babson College, USA




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Learning English as a second language in the early years : hundreds of ideas for supporting children with English as an additional language / Anita Soni & Liz Rouse

Soni, Anita, (Educational psychologist), author




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You're telling the story : how to develop useful assessments for learning in early childhood / Janet Moles

Moles, Janet




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Case studies in multiliteracies and inclusive pedagogy : facilitating meaningful literacy learning / Rachel Drewry

Drewry, Rachel, author




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Numeracy and learning difficulties : approaches to teaching and assessment / Peter Westwood

Westwood, Peter S. (Peter Stuart), 1936- author




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50 fantastic ideas for exploring emotions / Sally and Phill Featherstone

Featherstone, Sally, author




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What is it about Tribes? : the research-based components of the developmental process of Tribes Learning Communities / Bonnie Benard (WestEd)

Benard, Bonnie, author




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Video-conferencing in rural and remote secondary education in Canada : a mixed-method collective case study of teachers' perceptions around presence, process and professional learning / Nicole A. Rehn

Rehn, Nicole A., author




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Educational psychology : windows on classrooms / Paul Eggen, Don Kauchak

Eggen, Paul D., 1940- author




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Assessment for teaching / edited by Patrick Griffin