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Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(VI) separation

Chem. Commun., 2024, 60,13348-13351
DOI: 10.1039/D4CC04456H, Communication
Yun Xie, Zifan Li, Chenchen Liu, Qiming Song, Yunhai Liu, Zhibin Zhang, Bin Han
Incorporating bipyridine (BPY) units into conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity, thereby exhibiting an admired U(VI) separation rate under sacrificial agent-free conditions.
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Tuneable Sulfonated Hypercrosslinked Polymers for Selective Esterification: Insights into Performance and Stability

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05208K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paul Schweng, Dorian Guerin-Faucheur, Freddy Kleitz, Robert Thomas Woodward
We report sulfonated hypercrosslinked polymers (SHCPs) as heterogeneous catalysts for the selective esterification of hexanoic acid with benzyl alcohol. The SHCPs demonstrate tuneable catalytic activity and selectivity, outperforming conventional acid...
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Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
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Sustainable Production of Aromatic Chemicals from Lignin using Enzymes and Engineered Microbes

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05064A, Feature Article
Open Access
Timothy D.H. Bugg, Victoria Sodré
Lignin is an aromatic biopolymer found in plant cell walls, that is the must abundant source of renewable aromatic carbon in the biosphere. Hence there is considerable interest in the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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In the creative universe of Raghu Rai

The internationally-acclaimed photographer tells us how he enjoys his work and food




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In Auroville, try a mac and ‘sheeze’ as vegan chefs set up cafes and create healthy alternatives to meat

We sample inventive menus across the lush, experimental township, which draws visitors from across the world



  • Life & Style

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Bengaluru hosts Indian Cacao & Craft Chocolate Festival this weekend

The upcoming craft chocolate fest promises to be an eye-opener on the entire bean-to-bar experience




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Artisanal craft chocolates made in Rajahmundry

An artisanal craft chocolate named Bon Fiction is made from cacao beans grown here



  • Life & Style

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At Kraft, a concept store in Chennai, shop for pendant lights and wall art over a meal of crispy keema dosas and Korean burgers

Shop, eat, and try your hand at games at Kraft, the concept store that showcases around 60 different types of furniture and decor




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Creating a JavaScript promise from scratch, Part 7: Unhandled rejection tracking

When promises were introduced in ECMAScript 2015, they had an interesting flaw: if a promise didn’t have a rejection handler and was later rejected, you would have no idea. The rejection silently occurred behind the scenes and, therefore, could easily be missed. The best practice of always attaching rejection handlers to promises emerged due to...




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Introducing Env: a better way to read environment variables in JavaScript

If you write server-side JavaScript, chances are you’ve need to read information from environment variables. It’s considered a best practice to share sensitive information, such as access tokens, inside of environment variables to keep them secure. However, the way environment variables are read from JavaScript is error-prone in subtle ways that might take you hours...




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The lazy-loading property pattern in JavaScript

Traditionally, developers have created properties inside of JavaScript classes for any data that might be needed within an instance. This isn’t a problem for small pieces of data that are readily available inside of the constructor. However, if some data needs to be calculated before becoming available in the instance, you may not want to...




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Enhanced glucose-responsivity of PBA–diol hydrogel networks by reducing crosslink affinity

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00106K, Paper
Open Access
Sijie Xian, Yuanhui Xiang, Svenja Deichmann, Matthew J. Webber
New diol chemistries are explored for insulin delivery from glucose-responsive hydrogels comprised of dynamic-covalent crosslinking interactions between phenylboronic acids and diols.
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Crafting porous nanoscaled architecture as a potential frontier for drug delivery

Mol. Syst. Des. Eng., 2024, 9,1085-1106
DOI: 10.1039/D4ME00098F, Review Article
Koyeli Girigoswami, Pragya Pallavi, Agnishwar Girigoswami
Porous nanostructures exhibit remarkable nanoplatforms for payload delivery to diseased cells with high loading capacity, favorable release profiles, improved hemocompatibility, biocompatibility, and safe clearance after biodegradation.
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Le tout-en-un SÉSAME - 39 sujets blancs - Écrits et oraux - Tutos offerts

25,00 €

René Guimet, Jean-Dominique Picchiottino, Sophie Mattern, Marie-Laure Boursat, Benoît Thierry-Hildenbrand, Anne-Marie Bonnerot, Dominique Dumas, Loris Sirieix
8e édition
octobre 2024
352 pages
Visez l'excellence au Sésame grâce à notre équipe d'experts !
Ouvrage tout-en-un
Nouveau
978-2-311-21959-3
Concours 2025
Disponible
Livre




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Le tout-en-un ACCES - 24 sujets blancs - Ecrits et oraux - Tutos offerts

25,90 €

Jean-Dominique Picchiottino, Sophie Mattern, Marie-Laure Boursat, Benoît Thierry-Hildenbrand, Anne-Marie Bonnerot, Clara Vinh
8e édition
octobre 2024
344 pages
Le Tout-en-un pour réussir les épreuves du concours ACCÈS : tout le cours et des entraînements intensifs !
Ouvrage tout-en-un
Nouveau
978-2-311-21960-9
ESDES, ESSCA, IESEG - Concours 2025
Disponible
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IADE, Infirmier anesthésiste : S'entraîner à la pratique clinique avec 20 cas concrets

19,90 €

Garry Laudren, Michaël Mimouni
1re édition
novembre 2024
176 pages
Le tout premier cahier d’exercices pour s’entraîner à la pratique et au raisonnement clinique IADE
Livre
Nouveau
978-2-311-66519-2
Disponible
Livre




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Scriptural literacy




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Significance of sacrifice




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Mystery of creation




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Revealing the Influencing Mechanism of CO2 on SCR of NOx with NH3 over FeW Mixed Oxides Catalyst

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01468E, Paper
Hui Wang, Yujie Qiao, Xiang Li, Zhenping Qu
The effect of CO2, another major component of the exhaust gas, on the elimination of NOx over FeW oxides catalyst has been studied. It reveals that the presence of CO2...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solvent and Stoichiometry-dependent Versatile Organogelation and Robust Crystallization from Supramolecular Association of Adipic Acid and Triethanolamine

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00559G, Paper
Gerald Lepcha, Indrajit Pal, Santanu Majumdar, Yogesh Dhasmana, Sanjay Mondal, Ennio Zangrando, Deepak Chopra, Biswajit Dey
Supramolecular self-assembly directed two unique organogels were achieved through varying gel-immobilized solvents. One gel is comprised of adipic acid (ADP) and triethanolamine (TEA) in pure dimethylformamide medium (i.e., ADP-TEA-DMF), while...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Circularly polarized Room-Temperature Phosphorescence enhanced by Dynamic Cross-linked Networks fixation

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00510D, Paper
Bochun Wang, Yuzhan Li, ChangLi Zhang, Sirong Sun, Wanli He, Dong Wang, Hui Cao, Zhou Yang
Organic ultra-long room temperature phosphorescence (OURTP) has been widely used in applications including encryption and anti-counterfeiting. However, few research has focused on circularly polarised luminescence (CPL) with RTP materials. In...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tailoring of novel morpholine-sulphonamide linked thiazole moiety as dual targeting DHFR/DNA gyrase inhibitors: Synthesis, antimicrobial, antibiofilm activities and DFT with molecular modelling studies

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ05774G, Paper
Moaz M. Abdou, Essam Eliwa, Mohamed Abdel Reheim, Ahmed Abu-Rayyan, Shimaa M. Abd El-Gilil, Mohammed Abu-Elghait , Mohamed H. Sharaf, Mohamed Kalaba, Ahmed Halawa, Walid Elgammal
Herein, the chemical synthesis of new thiazoles-based benzenesulfonamide-linked morpholine 4a,b–7 via late-stage thiazolation of the corresponding thiosemicarbazone 3 was reported. The skeletal formulas of the new compounds were confirmed by...
The content of this RSS Feed (c) The Royal Society of Chemistry




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High-performance QLED research based on direct photo-crosslinking of PEDOT:PSS

New J. Chem., 2024, 48,7379-7383
DOI: 10.1039/D4NJ00457D, Paper
Kai Zhang, Junpeng Fan, Changfeng Han, Rui Xu, Lintao Nie, Yuhan Sun, Lei Qian, Chaoyu Xiang, Ting Zhang
By comparing the particle size of PH1000 and 4083, the problem of the HIL layer of QLED optical crosslinking was explained, and high performance QLEDs were prepared.
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Impact of Cr doping on the structural and optoelectronic properties of a CsPbIBr2 perovskite solar cell

New J. Chem., 2024, 48,7205-7212
DOI: 10.1039/D4NJ00681J, Paper
M. I. Khan, Ali Mujtaba, Saddam Hussain, Asif Hussain, Dalil Bulayis N AlResheedi, Zainab Mufarreh Elqahtani, El Sayed Yousef, Norah Alwadai
The Cr–CsPbIBr2 device showed enhanced performance, with increased grain size, reduced energy band gap, and elevated efficiency from 9.64% to 12.06%.
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Preparation of hydrogels with self-reinforced mechanical properties using ball-milled microcrystalline cellulose and regenerated cellulose from deep eutectic solvent

New J. Chem., 2024, 48,7405-7412
DOI: 10.1039/D4NJ00622D, Paper
Yi Zhang, Yingming Zhu, Kejing Wu, Yingying Liu, Houfang Lu, Bin Liang
Choline chloride–lactic acid deep eutectic solvent assisted by ball milling effectively dissolved microcrystalline cellulose. Regenerated cellulose was used to prepare novel cellulose hydrogel with self-reinforced mechanical properties.
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3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
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Highly crystalline graphite nanofibers as an anode for high-performance potassium-ion batteries

New J. Chem., 2024, 48,7497-7502
DOI: 10.1039/D4NJ00662C, Paper
Kaixuan Sun, Kun Chang, Jinshuo Tan, Chuan-Fu Sun, Qin Liu
Graphite nanofibres with high crystallinity and low defect levels for potassium-ion batteries with high initial Coulombic efficiency and long cycling stability are reported in this study.
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Depolymerization mechanism of MgO on a silicate microstructure under different CaO contents: a theoretical and experimental study

New J. Chem., 2024, 48,7480-7488
DOI: 10.1039/D4NJ00454J, Paper
Maierhaba Abudoureheman, Lanzhen He, Fangru Ma, Bo Wei, Jianjiang Wang, Quan Zhu, Hong Yao
The mechanism of the effect of MgO on the microstructure depolymerization of Zhundong coal ash under the condition of different CaO contents was studied using molecular dynamics simulation and experimental methods.
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Photocatalytic reduction of Cr(VI) on a series of defective MnmIn2S3+m (m = 1–5, integer)

New J. Chem., 2024, 48,7449-7455
DOI: 10.1039/D4NJ00161C, Paper
Yuxin Liu, Yuhang Qi, Yiqiang He
A series of defective MnmIn2S3+m microflowers were successfully synthesized via a facile hydrothermal method. The Mn4In2S7 exhibited the highest photocatalytic activity.
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Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors

New J. Chem., 2024, 48,7244-7255
DOI: 10.1039/D4NJ01100G, Paper
Jesús A. Lara-Cerón, Roberto Flores-Moreno, José A. Flores-Ramos, Gururaj K. Jayaprakash
Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors.
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Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
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Copper(II) complexes of sterically hindered phenolic Schiff bases: synthesis, characterization, interaction with biomolecules, and antioxidant and antimicrobial activity

New J. Chem., 2024, 48,7134-7147
DOI: 10.1039/D4NJ00430B, Paper
Iveta S. Turomsha, Maxim Y. Gvozdev, Nikolai P. Osipovich, Viktoryia A. Staravoitava, Dmitriy I. Shiman, Natalia V. Loginova
Phenolic Schiff bases and their Cu(II) complexes have been synthesized and characterized by physicochemical methods. The complexes exhibit low cell toxicity and high antioxidant and antibacterial activity, as evidenced by molecular docking studies.
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Self-Sacrificial templated-directed synthesis of ultrathin 0D/2D FeNi3-NC/NiFeOx Schottky junction as hydrogen evolution reaction electrode for alkaline seawater electrolysis

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01321B, Paper
Zili Xu, Yuankang Bao, Xun Xu, Ping Li, Hao Zhang, Deliang Li, Shuwang Duo
Seawater, a plentiful natural resource, is promising for hydrogen production compared to traditional electrocatalytic methods based on high-purity freshwater. This strategy shift addresses the challenge of limited freshwater resources and...
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Updated production-ready Gemini models, reduced 1.5 Pro pricing, increased rate limits, and more

Learn about the latest updates to Google's Gemini models, including reduced pricing for Gemini 1.5 Pro, increased rate limits, faster performance, enhanced quality, and more.




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CONNECTING with craft

Adults in the city are taking to crafting with as much gung-ho as they did when they were children. Crafting plays a therapeutic role, allows for me time and gadget-free time, finds BHUMIKA K.




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The Sunday Crossword No. 3228




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Creativity in clutter

The founders of Studio Clutter from Chennai talk about their journey as pet furniture makers and teaching about working with wood



  • Homes and gardens

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Queer artist Liactuallee crocheted sculptures and embroidery are on display at Method Bandra

Polish artist Liactuallee celebrates Pride Month with crocheted sculptures and embroidery




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Broadway Cinemas opens in Coimbatore with IMAX Laser and EPIQ Premium Large Format screens

With state-of-the-art laser projection and 12-channel sound with EPIQ premium large format, Broadway Cinemas offers an immersive movie experience




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Watch | Creating playgrounds using recycled tyres and pipes

Villages in Andhra Pradesh are putting discarded tyres and PVC pipes to good use... and the kids are loving it




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Committed to keep the crafts alive

Padmaja Sakhamuri, the convener of Vastrabharana says there is a lot to look forward to in the 31st edition of Vastrabharana, which begins on September 28 in Bengaluru




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Critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst systems

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00911D, Paper
Yang Luo, Hong Li, Hailan Yang, Zhiming Yang, Chuang Li, Shaoheng Liu, Qiang Chen, Weihua Xu, Wei Zhang, Xiaofei Tan
The critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst system was studied.
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Integrated microfluidic-based ultrafine water condensation particle counter (UWCPC) for monitoring of airborne nanoparticle generation and growth mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00686G, Paper
Seong-Jae Yoo, Yong-Jun Kim
This study reports a newly developed condensation particle counter for nanoparticle source tracking, growth mechanism analysis, and wide area nanoparticle monitoring.
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Impact of CeO2 nanoparticles on the microbiota of the S. flos-cuculi L. (Caryophyllaceae) rhizosphere

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00479A, Paper
Open Access
M. Civilini, A. Colautti, A. Brunello, N. Saccomanno, L. Marchiol, A. Foscari, L. Iacumin
Influence of cerium oxide nanoparticles (nCeO2) on root bacterial composition and the associated substrate (root zone soil) of Silene flos-cuculi (L.) by metabarcoding.
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Real-time assessment of the impacts of polystyrene and silver nanoparticles on the hatching process and early-stage development of Artemia using a microfluidic platform

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00116H, Paper
Preyojon Dey, Terence M. Bradley, Alicia Boymelgreen
Development of real-time in situ monitoring techniques is crucial for a mechanistic understanding of the impacts of pollution on the marine environment.
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Mechanistic approaches for crosstalk between nanomaterials and plants: plant immunomodulation, defense, stress resilience, toxicity, and perspectives

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00053F, Paper
Ragini Singh, Pinky Choudhary, Santosh Kumar, Hemant Kumar Daima
Plants are confronted with unexpected and diverse environmental pressures in the era of climate change. Plant development and metabolism are significantly hindered by both abiotic and biotic stress, which leads...
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Interaction of disposable face mask (nano)microplastics with antibiotics: performance and mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00775H, Paper
Ting Zhang, Xi Chen, Angrui Jiang, Jingfan Qi, Zhaoyang You, Kinjal J. Shah
The adsorption of ciprofloxacin (CIP), sulfamethoxazole (SMX) and tetracycline (TC) on disposable face mask (nano-)microplastics occurs in the order SMX > CIP > TC, which correlates with the octanol–water partition coefficient of antibiotics.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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