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Semi-sacrificial template synthesis of single-atom Ni sites supported on hollow carbon nanospheres for efficient and stable electrochemical CO2 reduction

Inorg. Chem. Front., 2020, 7,1719-1725
DOI: 10.1039/C9QI01688K, Research Article
Cheng-Zong Yuan, Li-Yuan Zhan, Shou-Jie Liu, Feng Chen, Hongjun Lin, Xi-Lin Wu, Jianrong Chen
Atomically dispersed Ni species on nitrogen-doped hollow carbon spheres (SA-Ni/N-CS) were synthesized via a semi-sacrificial template assisted strategy for an efficient and stable CO2RR.
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Construction of well-designed 1D selenium–tellurium nanorods anchored on graphene sheets as a high storage capacity anode material for lithium-ion batteries

Inorg. Chem. Front., 2020, 7,1750-1761
DOI: 10.1039/C9QI01701A, Research Article
Sadeeq Ullah, Ghulam Yasin, Aftab Ahmad, Lei Qin, Qipeng Yuan, Arif Ullah Khan, Usman Ali Khan, Aziz Ur Rahman, Yassine Slimani
The graphical illustration of the preparation of the SeTe@rGO composite material and its electrochemical application in Li-ion batteries.
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The effects of Zr-doping on improving the sensitivity and selectivity of a one-dimensional α-MoO3-based xylene gas sensor

Inorg. Chem. Front., 2020, 7,1704-1712
DOI: 10.1039/D0QI00019A, Research Article
Xin Li, Dingsheng Jiang, Yizhuo Fan, Nan Zhang, Caixia Liu, Samira Adimi, Jingran Zhou, Shanpeng Wen, Shengping Ruan
One dimensional Zr-doped α-MoO3 nanobelts were synthesized, and the influence of Zr doping on xylene sensing properties was studied.
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Strained lattice platinum–palladium alloy nanowires for efficient electrocatalysis

Inorg. Chem. Front., 2020, 7,1713-1718
DOI: 10.1039/D0QI00094A, Research Article
Mengyun Ren, Fangfang Chang, Ruifang Miao, Xianhong He, Lin Yang, Xiaolei Wang, Zhengyu Bai
The ability to manipulate Pt-based alloy catalysts with controllable compositions and the type of surface facet is important for advancing direct alcohol fuel cells (DAFEs).
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Anisotropic proton conduction realized by a layered vanadium selenite single crystal

Inorg. Chem. Front., 2020, 7,1699-1703
DOI: 10.1039/D0QI00040J, Research Article
Hai-Yan Sun, Shi-Hao Sun, Bing Hu, Liao-Kuo Gong, Yan-Min Zou, Ji-Long Li, Mei-Ling Feng, Xiao-Ying Huang
A new layered vanadium selenite single crystal exhibits anisotropic proton conductivities along the [100] and [001] directions with the Grotthuss and Vehicle mechanisms, respectively.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Excellent lightweight carbon-based microwave absorbers derived from metal–organic frameworks with tunable electromagnetic properties

Inorg. Chem. Front., 2020, 7,1667-1675
DOI: 10.1039/D0QI00099J, Research Article
Weihua Gu, Jing Zheng, Xiaohui Liang, Xiaoqing Cui, Jiabin Chen, Zhu Zhang, Guangbin Ji
Upon introducing Gibbs free energy to effectively control the final products, the as-prepared carbon-based composites show excellent absorbing ability at 1.4 mm.
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Unraveling the complexation mechanism of actinide(III) and lanthanide(III) with a new tetradentate phenanthroline-derived phosphonate ligand

Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article
Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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[NH2CHNH2]3Sb2I9: a lead-free and low-toxicity organic–inorganic hybrid ferroelectric based on antimony(III) as a potential semiconducting absorber

Inorg. Chem. Front., 2020, 7,1780-1789
DOI: 10.1039/D0QI00137F, Research Article
Przemysław Szklarz, Ryszard Jakubas, Anna Gągor, Grażyna Bator, Jakub Cichos, Mirosław Karbowiak
A novel room-temperature ferroelectric crystal with the complex sequence of phase transitions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile assembly of a graphitic carbon nitride film at an air/water interface for photoelectrochemical NADH regeneration

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00182A, Research Article
Open Access
Changchao Jia, Wenjuan Hu, Yuanyuan Zhang, Chao Teng, Zupeng Chen, Jian Liu
A graphitic carbon nitride film electrode could be assembled at an air/water interface from nanosheets which exhibits improved photoelectrochemical coenzyme regeneration by further coupling with graphene during the interfacial self-assembly.
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Correlation between crystal structures and polar (ferroelectric) properties of hybrids of haloantimonates(III) and halobismuthates(III)

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00265H, Review Article
R. Jakubas, M. Rok, K. Mencel, G. Bator, A. Piecha-Bisiorek
Halogenoantimonates(III) and halogenobismuthates(III) are a highly versatile class of organic–inorganic hybrid materials, applicable in optoelectronics and switchable dielectric devices.
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Highly efficient and stable CsPbBr3 perovskite quantum dots by encapsulation in dual-shell hollow silica spheres for WLEDs

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00208A, Research Article
Lei Qiu, Hang Yang, Zhigao Dai, Fengxu Sun, Jiarui Hao, Mengyu Guan, Peipei Dang, Chunjie Yan, Jun Lin, Guogang Li
A highly stable and efficient CsPbBr3@SiO2 composite phosphor is achieved by protecting the CsPbBr3 QDs from direct exposure to the atmosphere by encapsulating CsPbBr3 into dual-shell hollow silica nanospheres.
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Intermetallic borides: structures, synthesis and applications in electrocatalysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00146E, Review Article
Hui Chen, Xiaoxin Zou
This review summarizes structural features and recent synthesis methods of structurally ordered intermetallic borides, and the theoretical–experimental advances in the emerging boride-catalyzed reactions.
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Controllable synthesis of a mesoporous NiO/Ni nanorod as an excellent catalyst for urea electro-oxidation

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00316F, Research Article
Qing Li, Nan Li, Jing An, Huan Pang
Mesoporous rod-like structured composites of NiO/Ni have been successfully prepared via a low temperature heat treatment of the precursor NiC2O4·2H2O in N2.
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A slowly magnetic relaxing SmIII monomer with a D5h equatorial compressed ligand field

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00326C, Research Article
Ji-Dong Leng, Qiu-Yan Hua, Li-Shan Lin, Wei-Quan Lin, Jun-Liang Liu, Yong-Ze Pan, Yi-Bo Qiu, Ai-Ju Zhou
By using a bi-dentate phosphine oxide ligand L (L = bis(diphenylphosphino)methane dioxide), two mono-nuclear lanthanide complexes [LnL2(DMF)Cl2]Cl (Ln = Sm, 1; Dy, 2) with a D5h equatorial ligand field (LF)...
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Ag nanoparticle embedded Cu nanoporous hybrid arrays for the selective electrocatalytic reduction of CO2 towards ethylene

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article
Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO2 to C2H4, and exhibit a maximum Faraday Efficiency 41.3%.
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Phosphine-substituted Fe-Te clusters related to the active site of [FeFe]-H2ases

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00276C, Research Article
Shuang Lü, Hongli Huang, Ru-Fen Zhang, Chunlin Ma, Qianli Li, Jiao He, Ting Li, jun yang, Yulong Li
In order to enrich the chemistry of the Fe/Te cluster compounds related to the active site of [FeFe]-hydrogenase, the reactions of compound Fe2(μ-TeAr)2(CO)6 with tertiary phosphines were described. Three types...
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Highly efficient water splitting over a RuO2/F-doped graphene electrocatalyst with ultra-low ruthenium content

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article
Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO2/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm−2 for electrocatalytic water splitting.
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Electrochemical behavior of NiCl2/Ni in acidic AlCl3-based ionic liquid electrolyte

Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article
Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl2 cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl2 during discharging in acidic AlCl3-based electrolyte.
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Restricted active space simulations of the metal L-edge X-ray absorption spectra and resonant inelastic X-ray scattering: revisiting [CoII/III(bpy)3]2+/3+ complexes

Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article
Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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A new honeycomb metal–carboxylate-tetrazolate framework with multiple functions for CO2 conversion and selective capture of C2H2, CO2 and benzene

Inorg. Chem. Front., 2020, 7,1957-1964
DOI: 10.1039/D0QI00181C, Research Article
Gang-Ding Wang, Yong-Zhi Li, Wen-Juan Shi, Lei Hou, Zhonghua Zhu, Yao-Yu Wang
A stable Cd-MOF was built by a carboxylate-tetrazolate ligand, which contains hexagonal channels and reveals multiple functions including separation of CO2/CH4, C2H2/CO2, C2H2/CH4 and benzene/cyclohexane, and catalytic conversion of CO2 with epoxides.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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π-Type halogen bonding enhanced the long-lasting room temperature phosphorescence of Zn(II) coordination polymers for photoelectron response applications

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article
Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Interconnected porous nanoflakes of CoMo2S4 as an efficient bifunctional electrocatalyst for overall water electrolysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article
Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo2S4 are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

1 videodisc (101 min.) : sound, color ; 4 3/4 in




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Roxanne [videorecording] / Columbia Pictures presents a Daniel Melnick Indieprod & LA Films production ; screenplay by Steve Martin ; produced by Michael Rachmil & Daniel Melnick ; directed by Fred Schepisi

1 videodisc (approximately 107 min.) : sound, color ; 4 3/4 in




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Crimson tide [videorecording] / Hollywood Pictures presents a Don Simpson/Jerry Bruckheimer production ; produced by Don Simpson, Jerry Bruckheimer ; story by Michael Schiffer and Richard P. Henrick ; screenplay by Michael Schiffer ; directed by Tony Scot

1 videodisc (116 min.) sound, color; 4 3/4 in




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Professor Marston and the Wonder Women [videorecording]/ Annapurna Pictures presents in association with Stage 6 Films ; a Topple Pictures & Boxspring Entertainment production ; produced by Terry Leonard, Amy Redford ; written and directed by Angela R

1 videodisc (approximately 108 minutes) : sound, color ; 4 3/4 in




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We cannot run away to moon, need to develop herd immunity: Epidemiologist

Muliyil tells Somesh Jha that the days of eradicating the disease is over and the country should move towards developing 'herd immunity'




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Will consider raising duties on fuel and liquor: Manpreet Badal, Punjab FM

Punjab would like to help the Centre in any way possible to deal with the coronavirus disease (Covid-19) pandemic, said state Finance Minister Manpreet Singh Badal




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Article :: Geometry for Modeling and Design

This excerpt from Technical Drawing with Engineering Graphics shows how to identify and specify basic geometric elements and shapes.




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Article :: Relevance

Learn how to optimize the content of your presentation by focusing on relevance. In this sample chapter from The Non-Designer's Presentation Book: Principles for effective presentation design, 2nd Edition, Robin Williams shows you how to remove superfluous items, choose a complementary background, select high-impact photos, and more.




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How nature’s recipes help in combating cholesterol




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Lifestyle changes may help prevent half of Alzheimer’s cases




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In new report, list of smoking-related illnesses grows




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Elevated BP may lead to stroke: Study




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Low vitamin D levels in body linked to cancer, heart disease




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Drinking milk linked to arthritis relief




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Take a walk to release your creative juices




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British experiment shows food companies can help to reduce hypertension





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Short course: Pelvic exercises are good for men too





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Drug for bone-marrow disorder helps to grow hair




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No celiac disease? You could still be gluten-sensitive




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‘Eating well could cut incidence of TB by half’




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Healthy diet can delay and reverse autoimmune diseases




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Sunny side up: Vitamin D deficiency can affect your well-being