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A three-dimensional Cu nanobelt cathode for highly efficient electrocatalytic nitrate reduction

Nanoscale, 2020, 12,9385-9391
DOI: 10.1039/C9NR10743F, Paper
Xiaodan Wang, Mengqi Zhu, Guoshen Zeng, Xun Liu, Chihhsiang Fang, Chuanhao Li
A three-dimensional Cu nanobelt cathode was developed to efficiently catalyze the electrocatalytic nitrate reduction process.
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Boosting the photocatalytic CO2 reduction of metal–organic frameworks by encapsulating carbon dots

Nanoscale, 2020, 12,9533-9540
DOI: 10.1039/D0NR01696A, Paper
Shumin Li, Kang Ji, Meng Zhang, Cangshuang He, Jin Wang, Zhengquan Li
Small carbon dots as cocatalysts were loaded in MOF particles for CO2 reduction and their location effect was explored.
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Strong plasmon–exciton coupling between lithographically defined single metal nanoparticles and monolayer WSe2

Nanoscale, 2020, 12,9708-9716
DOI: 10.1039/D0NR01056A, Paper
Xiaohong Yan, Hong Wei
Strong coupling between monolayer WSe2 and lithographically defined single gold nanobowties is realized for the first time, and smaller nanobowties lead to larger coupling strength.
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Analysis of sparse molecular distributions in fibrous arrangements based on the distance to the first neighbor in single molecule localization microscopy

Nanoscale, 2020, 12,9495-9506
DOI: 10.1039/C9NR10805J, Paper
Alan M. Szalai, Lucía F. Lopez, Miguel Ángel Morales-Vásquez, Fernando D. Stefani, Pedro F. Aramendía
We introduce a robust and sensitive metric to characterize the underlying structure responsible for the molecular distribution, even at a very low labeling density.
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The CpG molecular structure controls the mineralization of calcium phosphate nanoparticles and their immunostimulation efficacy as vaccine adjuvants

Nanoscale, 2020, 12,9603-9615
DOI: 10.1039/C9NR09782A, Paper
Razieh Khalifehzadeh, Hamed Arami
Effects of the CpG molecular structure on the mineralization and immunostimulation efficacy of calcium phosphate nanoparticles are explored for vaccine delivery applications.
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Oxygen vacancy-rich amorphous porous NiFe(OH)x derived from Ni(OH)x/Prussian blue as highly efficient oxygen evolution electrocatalysts

Nanoscale, 2020, 12,9557-9568
DOI: 10.1039/D0NR00607F, Paper
Shuang Wang, Xingbo Ge, Chao Lv, Cun Hu, Hongtai Guan, Jing Wu, Zhengnan Wang, Xianhui Yang, Yan Shi, Jiangfeng Song, Zhi Zhang, Akira Watanabe, Jinguang Cai
Oxygen vacancy-rich amorphous porous NiFe(OH)x on carbon paper is prepared through a two-step electrochemical depostion of Prussian blue nanocrystal layer and Ni(OH)x layer followed by an alkaline etching process for efficient OER catalysis.
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A broadband and low-power light-control-light effect in a fiber-optic nano-optomechanical system

Nanoscale, 2020, 12,9800-9809
DOI: 10.1039/C9NR10953F, Paper
Yu Zhang, Wenguo Zhu, Pengpeng Fan, Yelin He, Linqing Zhuo, Zhen Che, Dongquan Li, Huadan Zheng, Linpeng Dong, Jieyuan Tang, Wentao Qiu, Jun Zhang, Yongchun Zhong, Jianhui Yu, Zhe Chen
A tapered-nanofibre optomechanical scheme, together with the pump–probe technique, is exploited to implement a broadband and low-power light-control-light effect.
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N- & S-co-doped carbon nanofiber network embedded with ultrafine NiCo nanoalloy for efficient oxygen electrocatalysis and Zn–air batteries

Nanoscale, 2020, 12,9581-9589
DOI: 10.1039/D0NR01516D, Paper
Chaojun Liu, Zhuang Wang, Xin Zong, Yingmin Jin, Dong Li, Yueping Xiong, Gang Wu
A 3D carbon nanofiber network embedded with ultrafine nanoparticles is prepared by electrospinning. Thioacetamide is used to prevent the aggregation of active sites.
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Reply to the ‘Comment on “Hierarchically porous, ultra-strong reduced graphene oxide–cellulose nanocrystal sponges for exceptional adsorption of water contaminants”’ by J. Ma, Y. Xiong and F. Yu, Nanoscale, 2019, 11, DOI: 10.1039/C8NR08780F

Nanoscale, 2020, 12,9899-9901
DOI: 10.1039/D0NR01846E, Comment
Nariman Yousefi, Nathalie Tufenkji
We respond to the comments of Ma et al. and clarify the rationale behind our methodology and why it is suitable for our work.
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CVD growth of large-area InS atomic layers and device applications

Nanoscale, 2020, 12,9366-9374
DOI: 10.1039/D0NR01104E, Communication
Chien-Liang Tu, Kuang-I Lin, Jiang Pu, Tsai-Fu Chung, Chien-Nan Hsiao, An-Ci Huang, Jer-Ren Yang, Taishi Takenobu, Chang-Hsiao Chen
Indium sulfide (InS) atomic layers made by chemical vapor deposition (CVD) are synthesized onto a mica substrate, producing a highly crystalline, large-area, and atomically thin-film InS flakes.
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Plasmonic nanopapers: flexible, stable and sensitive multiplex PUF tags for unclonable anti-counterfeiting applications

Nanoscale, 2020, 12,9471-9480
DOI: 10.1039/D0NR01223H, Paper
Hongrui Cheng, Yongfeng Lu, Dongyan Zhu, Lorenzo Rosa, Fei Han, Mingguo Ma, Wenyue Su, Paul S. Francis, Yuanhui Zheng
Highly flexible and stable plasmonic nanopaper comprised of silver nanocubes and cellulose nanofibres was fabricated through a self-assembly-assisted vacuum filtration method.
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Ternary PtFeCo alloys on graphene with high electrocatalytic activities for methanol oxidation

Nanoscale, 2020, 12,9824-9832
DOI: 10.1039/D0NR00757A, Paper
Hongfei Wang, Kefu Zhang, Jun Qiu, Juan Wu, Jingwen Shao, Huijuan Wang, Yujuan Zhang, Jie Han, Yong Zhang, Lifeng Yan
Ternary PtFeCo alloys as alternatives to conventional Pt electrocatalysts are highly important in the field of the methanol oxidation reaction.
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Characteristics of crystalline sputtered LaFeO3 thin films as photoelectrochemical water splitting photocathodes

Nanoscale, 2020, 12,9653-9660
DOI: 10.1039/D0NR01762K, Paper
Min-Kyu Son, Hyunwoong Seo, Motonori Watanabe, Masaharu Shiratani, Tatsumi Ishihara
A transparent crystalline sputtered LaFeO3 photocathode with an early onset potential for stable photoelectrochemical water splitting.
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Designing transition-metal-boride-based electrocatalysts for applications in electrochemical water splitting

Nanoscale, 2020, 12,9327-9351
DOI: 10.1039/D0NR01279C, Review Article
Yuanyuan Jiang, Yizhong Lu
Recent progresses made in transition metal boride (TMB)-based electrocatalysts for electrochemical water splitting are summarized.
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NiSe2-anchored N, S-doped graphene/Ni foam as a free-standing bifunctional electrocatalyst for efficient water splitting

Nanoscale, 2020, 12,9866-9872
DOI: 10.1039/D0NR00879F, Paper
Jinhao Zhou, Zegao Wang, Dongxu Yang, Fei Qi, Xin Hao, Wanli Zhang, Yuanfu Chen
A strategy to synthesize free-standing electrocatalysts coupling active nanostructured NiSe2 with conductive S, N-doped 3D graphene foam (3DSNG) is presented and the hybrid delivers superior performances for the HER, OER and overall water splitting.
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In situ growth of well-aligned Ni-MOF nanosheets on nickel foam for enhanced photocatalytic degradation of typical volatile organic compounds

Nanoscale, 2020, 12,9462-9470
DOI: 10.1039/D0NR01027H, Paper
Xin Ding, Hongli Liu, Jiangyao Chen, Meicheng Wen, Guiying Li, Taicheng An, Huijun Zhao
Well-aligned Ni-MOF nanosheet arrays vertically grown on nickel foam were synthesized via a facile in situ solvothermal strategy, which exhibited remarkably improved photocatalytic activities to typical VOCs under visible light irradiation.
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Efficient polyalcohol oxidation electrocatalysts enabled by PtM (M = Fe, Co, and Ni) nanocubes surrounded by (200) crystal facets

Nanoscale, 2020, 12,9842-9848
DOI: 10.1039/D0NR00163E, Paper
Tongxin Song, Fei Gao, Yangping Zhang, Chunyan Chen, Cheng Wang, Shujin Li, Hongyuan Shang, Yukou Du
The (200)-enclosed Pt4M nanocubes (NCs) exhibit ascendant catalytic property towards GOR and EGOR due to the introduction of transition metals.
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Trace metals dramatically boost oxygen electrocatalysis of N-doped coal-derived carbon for zinc–air batteries

Nanoscale, 2020, 12,9628-9639
DOI: 10.1039/C9NR10800A, Paper
Huimin Liu, Xinning Huang, Zhenjie Lu, Tao Wang, Yaming Zhu, Junxia Cheng, Yue Wang, Dongling Wu, Zhenyu Sun, Alex W. Robertson, Xingxing Chen
The commercialization of metal–air batteries requires efficient, low-cost, and stable bifunctional electrocatalysts for reversible electrocatalysis of the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER).
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Point defect induced intervalley scattering for the enhancement of interlayer electron transport in bilayer MoS2 homojunctions

Nanoscale, 2020, 12,9859-9865
DOI: 10.1039/D0NR01339K, Paper
Yang Ou, Zhuo Kang, Qingliang Liao, Shihan Gao, Zheng Zhang, Yue Zhang
The interlayer transport of MoS2 homojunctions can be enhanced by point defect induced K–Q intervalley scattering.
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Flexible pressure sensors with a highly pressure- and strain-sensitive layer based on nitroxyl radical-grafted hollow carbon spheres

Nanoscale, 2020, 12,9375-9384
DOI: 10.1039/D0NR01192D, Communication
Jie Chu, Jueping Cai
The flexible sensor based on free radical-modified hollow carbon spheres is highly sensitive to both compression and tension.
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Supramolecular chemistry of carbon nano-onions

Nanoscale, 2020, 12,9352-9358
DOI: 10.1039/D0NR01713B, Minireview
Michał Bartkowski, Silvia Giordani
An exhaustive and succinct minireview of the various reported approaches to the non-covalent surface modification of carbon nano-onions (CNOs).
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Nanosphere-shaped ammonio methacrylate copolymers: converting a pharmaceutical inactive ingredient to efficient therapeutics for experimental colitis

Nanoscale, 2020, 12,9590-9602
DOI: 10.1039/D0NR00465K, Paper
Brice Moulari, Maryam A. Shetab Boushehri, Jean-Paul Pais de Barros, Thilo Faber, Arnaud Béduneau, Laurent Lagrost, Yann Pellequer, Alf Lamprecht
Even in the absence of any drug load, nanosphere-shaped ammonio methacrylate copolymers can mitigate murine experimental colitis.
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High charge carrier mobility in solution processed one-dimensional lead halide perovskite single crystals and their application as photodetectors

Nanoscale, 2020, 12,9688-9695
DOI: 10.1039/D0NR01495H, Paper
Tianjun Liu, Weidong Tang, Sally Luong, Oliver Fenwick
Large space-charge limited mobility and a fast optical response is reported in low dimensional halide perovskite crystals. A transition between hopping transport and band-like transport is observed at 200 K.
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2D molybdenum disulphide nanosheets incorporated with single heteroatoms for the electrochemical hydrogen evolution reaction

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01295E, Minireview
Thomas H. M. Lau, John S. Foord, S. C. Edman Tsang
2D nanosheets give enhanced surface area to volume ratios in particle morphology and they can also provide defined surface sites to disperse foreign atoms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Clear observation of the formation of nanoparticles inside the ablation bubble through a laser-induced flat transparent window by laser scattering

Nanoscale, 2020, 12,9640-9646
DOI: 10.1039/C9NR10560C, Paper
Kota Ando, Takashi Nakajima
We demonstrate the clear observation of laser-scattering signals from Ag nanoparticles (NPs) inside an ablation bubble.
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Cyclodextrin-based superparamagnetic host vesicles as ultrasensitive nanobiocarriers for electrosensing

Nanoscale, 2020, 12,9884-9889
DOI: 10.1039/D0NR01702G, Paper
Jose Muñoz, Núria Crivillers, Bart Jan Ravoo, Marta Mas-Torrent
Magnetic cyclodextrin vesicles (mCDVs) have been used as novel electrochemical biorecognition probes for the picomolar determination of thyroxine (T4), using a magneto nanocomposite carbon-paste electrode (mNC-CPE) as a transducer platform.
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Quantitative encapsulation and retention of 227Th and decay daughters in core–shell lanthanum phosphate nanoparticles

Nanoscale, 2020, 12,9744-9755
DOI: 10.1039/D0NR01172J, Paper
M. Toro-González, A. N. Dame, C. M. Foster, L. J. Millet, J. D. Woodward, J. V. Rojas, S. Mirzadeh, S. M. Davern
La(227Th)PO4 core +2 shells nanoparticles retained >99.75% of activity from 227Th and decay daughters (223Ra, 211Pb) for targeted alpha therapy.
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Tuning the electronic structure of transition metals embedded in nitrogen-doped graphene for electrocatalytic nitrogen reduction: a first-principles study

Nanoscale, 2020, 12,9696-9707
DOI: 10.1039/D0NR00072H, Paper
Xiaonan Zheng, Yuan Yao, Ya Wang, Yang Liu
The Fe/Mn–N–C catalyst is a promising candidate for the NRR as it shows significantly improved NRR catalytic activity and strong selectivity against the HER.
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Molecular dynamics investigation on the nano-mechanical behaviour of C60 fullerene and its crystallized structure

Nanoscale, 2020, 12,9849-9858
DOI: 10.1039/D0NR00584C, Paper
Kuk-Jin Seo, Dae-Eun Kim
C60 fullerene has been utilized in various applications due to its unique structure. In this work, molecular dynamics simulations were conducted to assess the nano-mechanical behaviour of a single C60 fullerene and its crystallized structure.
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Triplet photosensitizer-nanotube conjugates: synthesis, characterization and photochemistry of charge stabilizing, palladium porphyrin/carbon nanotube conjugates

Nanoscale, 2020, 12,9890-9898
DOI: 10.1039/D0NR02136A, Paper
Luis M. Arellano, Habtom B. Gobeze, María J. Gómez-Escalonilla, José Luis G. Fierro, Francis D'Souza, Fernando Langa
SWCNTs covalently modified with a triplet photosensitizer, palladium porphyrin, have been newly prepared and photoinduced charge separation is reported.
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Actuated plasmonic nanohole arrays for sensing and optical spectroscopy applications

Nanoscale, 2020, 12,9756-9768
DOI: 10.1039/D0NR00761G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daria Kotlarek, Stefan Fossati, Priyamvada Venugopalan, Nestor Gisbert Quilis, Jiří Slabý, Jiří Homola, Médéric Lequeux, Frédéric Amiard, Marc Lamy de la Chapelle, Ulrich Jonas, Jakub Dostálek
We report a new approach to rapidly actuate the plasmonic characteristics of thin gold films perforated with nanohole arrays by thermo-responsive hydrogel and demonstrate its utilization to sensing with flow-through format and SPR/SERS readout.
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Whispering gallery mode emission from dye-doped polymer fiber cross-sections fabricated by near-field electrospinning

Nanoscale, 2020, 12,9873-9883
DOI: 10.1039/D0NR00147C, Paper
Joseph E. Cheeney, Stephen T. Hsieh, Nosang V. Myung, Elaine D. Haberer
Near-field electrospun polymer microfibers were utilized to support whispering gallery mode resonances. The fibers were utilized for water–ethanol sensing.
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Vertically-oriented MoS2 nanosheets for nonlinear optical devices

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR00755B, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. Bolhuis, J. Hernandez-Rueda, S. E. van Heijst, M. Tinoco Rivas, L. Kuipers, S. Conesa-Boj
We demonstrate a novel strategy for large-area fabrication of vertical MoS2 exhibiting enhanced non-linear optical signal for applications in photonics.
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Theoretical Anchoring Effect of New Phosphorus Allotropes for Lithium-sulfur Batteries

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02359K, Paper
Chunmei Li, Linxin He, Jianglei Luo, Jianfeng Tang, Nanpu Cheng, Zhiqian Chen
Lithium-sulfur battery system has appeared as a new-generation alternative to lithium-ion batteries with 5-7 times higher specific energy density than conventional lithium-ion batteries. But its commercial implementation is still impeded...
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Mild generation of surface oxygen vacancy on CeO2 for improved CO2 photoreduction activity.

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR00717J, Paper
Min Wang, Meng Shen, Xixiong Jin, Jianjian Tian, Yajun Zhou, Yiran Shao, Lingxia Zhang, Yongsheng Li, Jianlin Shi
The vacancy defects of semiconductor photocatalysts play a key role in enhancing their photocatalytic CO2 reduction activity. In this work, CeO2 was chosen as a model catalyst and oxygen vacancy...
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Single-wavelength phototheranostics for colon cancer via thiolytic reaction

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02393K, Paper
Yucheng Zhu, Chao Chen, Qinghua Wu, Guoliang Yang, Zhiyong Liu, Erhong Hao, Hongliang Cao, Yun Gao, Weian Zhang
It’s a huge challenge to develop effective nanosystems combined the capabilities of diagnoses and therapies together for colon cancer in clinic. Herein, we constructed a far-red absorbing phototheranostic nanosystem (FR-H2S)...
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Electric field triggered release of gas from a quasi-one-dimensional hydrate in the carbon nanotube

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR01113D, Paper
Jiaxian Li, Hangjun Lu, Xiaoyan Zhou
We systematically investigate the effects of an axial electric field on the formation and decomposition of quasi-one-dimensional nitrogen gas hydrates within a single-walled carbon nanotube (SWNT) by using molecular dynamics...
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MnV2O6/Graphene Nanocomposite as an Efficient Electrocatalyst for the Oxygen Evolution Reaction

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02325F, Communication
Kyeong-Ho Kim, Yun-Hyuk Choi, Seong-Hyeon Hong
MnV2O6/graphene nanocomposite was fabricated through hydrothermal synthesis and high energy mechanical milling as an electrocatalyst for oxygen evolution reaction (OER). MnV2O6/graphene (20 wt%) nanocomposite deposited on carbon fiber paper (CFP)...
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Unexpectedly high stability and surface reconstruction of PdAuAg nanoparticles for formate oxidation electrocatalysis

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR01358G, Paper
Bowei Pan, Fuyi Chen, Kou Bo, Junpeng Wang, Quan Tang, Longfei Guo, Qiao Wang, Zhen Li, Weiqi Bian, Jiali Wang
High-performance Pd-based nanocatalysts for alkaline methanol and formate fuel cells have aroused wide attention. Hence, a series of ternary Pd-Au-Ag nanoalloys are synthesized on the carbon nanotubes and demonstrate a...
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The influence of surface roughness on the adhesive interactions and phase behavior of suspensions of calcite nanoparticles

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR00834F, Paper
Open Access
Juan D. Olarte-Plata, Goran Svaland, Fernando Bresme
We investigate the impact of nanoparticle roughness on the phase behaviour of suspensions lue{in models} of calcium carbonate nanoparticles. We use a Derjaguin approach that incorporates roughness effects and interactions...
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Ultrathin Two-Dimensional Vertical Ferroelectric Tunneling Junction based on CuInP2S6 Monolayer

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR01475C, Paper
Min Zhao, Gaoyang Gou, Xiangdong Ding, Jun Sun
Ferroelectric (FE) materials, especially ABO3 FE perovskite oxides have been extensively studied for their important applications in memories, electronics and sensors. However, the integration of FE perovskite oxides into minimized...
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Direct carbonization of organic solvent toward graphene quantum dots

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR01903H, Communication
Hongji Liu, Xiaotong Lv, Changwei Li, Yong Qian, Xingyu Wang, Lin Hu, Yu-Cai Wang, Wenchu Lin, Hui Wang
The bottom-up synthesis of graphene quantum dots (GQDs) using solvothermal method has attracted considerable attention because of their fewer defects and controllable size/ morphology. However, the influence of organic solvent...
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Modulation engineering of in-situ cathodic activation of FePx based on W-incorporation for hydrogen evolution

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02661A, Paper
Min Yang, Yu-Ran Zhu, Zhong-Yuan Lin, Xin-Tong Yan, Bin Dong, Ya-Nan Zhou, Qingzhong Li, Yulu Zhou, Jun Nan, Yongming Chai
In-situ electrochemical activation as a new pretreating method to adjust electrocatalytic performance attracts extensive attention. However, the activation mechanisms of electrocatalysts are still ambiguous. Herein, we propose a facile modulation...
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Topological semimetal Li2CrN2 sheet as a promising hydrogen storage material

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02180F, Paper
Lijuan Ma, Qiang Sun
An ideal electrode for electrochemical storage of hydrogen needs to be conductive for electron. The robust conductivity protected by topology in topological quantum materials just meets this requirement. However, such...
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Synthesis of monodisperse water-stable surface Pb-rich CsPbCl3 nanocrystals for efficient photocatalytic CO2 reduction

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02917C, Communication
Jingrun Zhu, Yihua Zhu, Jianfei Huang, Lu Hou, Jianhua Shen, Chunzhong Li
Surface Pb-rich lead halide perovskite nanocrystals (NCs) with high stability and monodispersity in water have been synthesized using a general and convenient liquid-solid-interpenetration (LSI) method. In this process, water molecules...
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Black in America: The Paradox of the Color Line


 
At the start of the twentieth century, the pre-eminent black sociologist, W.E.B. DuBois, identified the color line as America's great problem. While the color line is increasingly variegated beyond black and white, and more openly discussed than ever before as more racial and ethnic groups call America home, his words still ring true.
 
Today, post-racial and colorblind ideals dominate the American narrative, obscuring the reality of racism and discrimination

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Black in America: The Paradox of the Color Line


 
At the start of the twentieth century, the pre-eminent black sociologist, W.E.B. DuBois, identified the color line as America's great problem. While the color line is increasingly variegated beyond black and white, and more openly discussed than ever before as more racial and ethnic groups call America home, his words still ring true.
 
Today, post-racial and colorblind ideals dominate the American narrative, obscuring the reality of racism and discrimination

Read More...




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Digitalization of Society and Socio-political Issues 1: Digital, Communication, and Culture


 
Digitalization is a long and constant sociohistoric process in which all areas of society s activities are reconfigured. Digitalization of Society and Socio-political Issues 1 examines the transformations linked to the development of digital platforms and social media, which affect the cultural and communicational industries. It analyzes the formation of Big Data, their algorithmic processing and the societal changes which result

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Informality Revisited: Latin American Perspectives on Housing, the State and the Market


 

Informality Revisited offers an overview of recent debates about Latin American government programmes for the formalisation of informal settlements and housing provision in a neo-liberal context. Contributions from Latin American researchers analyse the contradictions in government actions and evaluate the consequences for urban poverty.



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To appreciate my role as a scientist, I had to step outside academia

This Ph.D. student learned that science policy work satisfies her desire to make an impact