and General and selective synthesis of primary amines using Ni-based homogeneous catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4332-4339DOI: 10.1039/D0SC01084G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. JagadeeshA Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and SAXS studies of the thermally-induced fusion of diblock copolymer spheres: formation of hybrid nanoparticles of intermediate size and shape By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4312-4321DOI: 10.1039/D0SC00569J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.E. J. Cornel, P. S. O'Hora, T. Smith, D. J. Growney, O. O. Mykhaylyk, S. P. ArmesDilute dispersions of poly(lauryl methacrylate)-poly(benzyl methacrylate) diblock copolymer spheres of differing mean diameter are mixed and thermally annealed at 150 °C to produce either spherical or non-spherical nanoparticles of intermediate size.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4297-4304DOI: 10.1039/D0SC00735H, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Eike Brunner, Marcus RaucheMetal–organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4397-4402DOI: 10.1039/D0SC00844C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong LiA novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4381-4390DOI: 10.1039/D0SC01026J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen NiemeyerSupramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Intramolecular Csp3–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4482-4487DOI: 10.1039/C9SC05522C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaojin Wen, Xinyao Li, Xiao Luo, Weijin Wang, Song Song, Ning JiaoA novel intramolecular cyclization of alkyl azides for the synthesis of cyclic imines and tertiary amines has been developed. The aliphatic C–H or C–C bond was selectively cleaved with the efficient formation of two C–N single bonds or a CN double bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4488-4498DOI: 10.1039/D0SC00544D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-TejadaA fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4516-4524DOI: 10.1039/D0SC01319F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar WillnerBiocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4499-4507DOI: 10.1039/D0SC00135J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming HuMetal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Machine-enabled inverse design of inorganic solid materials: promises and challenges By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00594K, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juhwan Noh, Geun Ho Gu, Sungwon Kim, Yousung JungThe grand challenge of materials science, discovery of novel materials with target properties, can be greatly accelerated by machine-learned inverse design strategies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Small-molecule fluorescent probes for imaging gaseous signaling molecules: current progress and future implications By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01482F, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mingwang Yang, Jiangli Fan, Jianjun Du, Xiaojun PengThis perspective article aims to introduce the design principles and recognition strategies of small-molecule fluorescent probes which are applied for the detection of gas signaling molecules including NO, CO and H2S in biological systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Enantioselective total synthesis of (−)-myrifabral A and B By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01141J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tyler J. Fulton, Anthony Y. Chen, Michael D. Bartberger, Brian M. StoltzA catalytic enantioselective approach to the Myrioneuron alkaloids (−)-myrifabral A and (−)-myrifabral B is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00002G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi NakanoStructural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Geometric landscapes for material discovery within energy–structure–function maps By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00049C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seyed Mohamad Moosavi, Henglu Xu, Linjiang Chen, Andrew I. Cooper, Berend SmitWe introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00266F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yunyi Wang, Jihyun Kim, Christian HiltyElucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01544J, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rebecca A. Olson, Angie B. Korpusik, Brent S. SumerlinLight-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC90081H, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Leslie A. Nickerson, Benjamin D. Bergstrom, Mingchun Gao, Yuan-Shin Shiue, Croix J. Laconsay, Matthew R. Culberson, Walker A. Knauss, James C. Fettinger, Dean J. Tantillo, Jared T. ShawTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01025A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor AlabuginHow far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01763A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal KhanThe first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00021C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Koichiro Masuda, Shū KobayashiA direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01213K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong TangWe present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and Observations of tetrel bonding between sp3–carbon and THF By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01559H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Victoria V. L. Heywood, T. P. J. Alford, Julius J.J. Roeleveld, Siebe S. J. Lekanne-Deprez, Abraham A. Verhoofstad, Jarl Ivar van der Vlugt, Melanie Schnell, Sérgio R Domingos, Anthony P. Davis, Tiddo Jonathan MooibroekWe report the direct observation of tetrel bonding interactions between sp3-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00968G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. LipshutzA new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
and BS Insurance Round Table: Sandbox opens up avenues for bundling services By www.business-standard.com Published On :: Thu, 27 Feb 2020 22:38:00 +0530 A power-packed panel said that AI is the game changer in the non-life insurance business and underlined the need to generate underwriting profits and rely less on investment gains Full Article
and LCH colors in CSS: what, why, and how? By feedproxy.google.com Published On :: Sat, 04 Apr 2020 13:23:31 +0000 I was always interested in color science. In 2014, I gave a talk about CSS Color 4 at various conferences around the world called “The Chroma Zone”. Even before that, in 2009, I wrote a color picker that used a hidden Java applet to support ICC color profiles to do CMYK properly, a first on […] Full Article Apps & scripts Articles CSS WG Original colors css-color-4 css-color-5 csswg lch specs
and Weather Warnings for Queensland - land areas. Issued by the Australian Bureau of Meteorology By www.bom.gov.au Published On :: Full Article
and Bihar hands over 68-bed AES ward to SKMCH By timesofindia.indiatimes.com Published On :: Fri, 08 May 2020 04:00:00 IST A fully-equipped 68-bed AES ward was formally handed over to the Sri Krishna Medical College and Hospital (SKMCH) at Muzaffarpur by the state government on Thursday. Full Article
and Bihar to go for 1,000 random Covid tests a day By timesofindia.indiatimes.com Published On :: Fri, 08 May 2020 04:15:00 IST With the increase in inflow of migrants to Bihar, the state government has decided to go for a new strategy to contain the spread of Covid-19 pandemic — random samplings of 1,000 migrants in a day with focus on those coming from red zones. Full Article
and Who decides the price band of an IPO? By economictimes.indiatimes.com Published On :: 2020-04-06T13:05:21+05:30 For the announcement of the price band and the bid offer period, working day means all days, excluding all Saturdays, Sundays and public holidays on which commercial banks in Mumbai are open for business. Full Article
and We are buying in this market on a daily basis, says LIC MD Vipin Anand By economictimes.indiatimes.com Published On :: 2020-04-08T13:39:26+05:30 The IPO is a time-consuming thing, which is going to be there, says Vipin Anand. Full Article
and Preschool in three cultures revisited : China, Japan, and the United States / Joseph Tobin, Yeh Hsueh, and Mayumi Karasawa By prospero.murdoch.edu.au Published On :: Tobin, Joseph Jay Full Article
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and Reflective teaching in higher education / Paul Ashwin and [and 10 others] By prospero.murdoch.edu.au Published On :: Ashwin, Paul, 1970- Full Article
and Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman By prospero.murdoch.edu.au Published On :: Full Article
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and Understanding the University : institution, idea, possibilities / Ronald Barnett By prospero.murdoch.edu.au Published On :: Barnett, Ronald, 1947- author Full Article
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and The inside story [videorecording] : developing children's understanding about their bodies By prospero.murdoch.edu.au Published On :: Full Article
and Wondrous words : writers and writing in the elementary classroom / Katie Wood Ray By prospero.murdoch.edu.au Published On :: Ray, Katie Wood, 1964- author Full Article
and Professional development, instructional intelligence and teacher emotions : a mixed methods study of a four-year systemic change initiative / by Rebecca Ann Saunders By prospero.murdoch.edu.au Published On :: Saunders, Rebecca Ann, author Full Article
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and The abandoned generation : democracy beyond the culture of fear / Henry A. Giroux By prospero.murdoch.edu.au Published On :: Giroux, Henry A Full Article
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