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Magnesium(II) complexes supported by indole- and pyrrole-containing Schiff-base ligands: syntheses, structures, and applications as precatalysts in the hydroboration of nitriles and alkynes

New J. Chem., 2024, 48,7125-7133
DOI: 10.1039/D4NJ00492B, Paper
Mengxiang Wu, Ling Chen, Xiaohan Yang, Yahong Li
Five magnesium compounds were synthesized. They are active precatalysts for the hydroboration of nitriles and alkynes. The catalytic reactions feature mild reaction conditions, excellent functional group tolerance, and high yields.
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Modification of a MoS2 composite membrane using nano-silica for high-efficiency dye separation

New J. Chem., 2024, 48,7439-7448
DOI: 10.1039/D3NJ05932D, Paper
Xiaoyu Yang, Hongdan Wu, Zhihui Zhou, Yehao Zhao, Yuedong Li
A novel MoS2/SiO2 composite membrane with larger interlayer spacing intercalation was prepared by vacuum-assisted self-assembly process using SiO2 nanoparticles, which showed high-efficiency dye separation performance and aqueous stability.
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Effective synthesis of diethyl carbonate over Mg–Y composite oxides via alcoholysis of ethyl carbamate

New J. Chem., 2024, 48,7489-7496
DOI: 10.1039/D3NJ05757G, Paper
Peixue Wang, Shimin Liu, Xinjiang Cui, Yang Wu, Feng Shi
Effective synthesis of diethyl carbonate from ethyl carbamate and ethanol using Mg–Y composite oxides.
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Tannic acid induced in situ growth of an underwater superoleophobic ZIF-8 composite membrane for emulsion separation

New J. Chem., 2024, 48,7384-7393
DOI: 10.1039/D4NJ00623B, Paper
Wanyu Lu, Qijin Tang, Huajing Cheng, Shudi Li, Cailong Zhou, Hao Yang
Tannic acid induced in situ growth of ZIF-8 crystals on a nylon membrane, creating a multifunctional composite membrane that exhibits remarkable underwater superhydrophobicity and resistance to oil adhesion.
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Copper(II) complexes of sterically hindered phenolic Schiff bases: synthesis, characterization, interaction with biomolecules, and antioxidant and antimicrobial activity

New J. Chem., 2024, 48,7134-7147
DOI: 10.1039/D4NJ00430B, Paper
Iveta S. Turomsha, Maxim Y. Gvozdev, Nikolai P. Osipovich, Viktoryia A. Staravoitava, Dmitriy I. Shiman, Natalia V. Loginova
Phenolic Schiff bases and their Cu(II) complexes have been synthesized and characterized by physicochemical methods. The complexes exhibit low cell toxicity and high antioxidant and antibacterial activity, as evidenced by molecular docking studies.
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Hydroquinone colorimetric sensing based on core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites as oxidase mimics

New J. Chem., 2024, 48,7323-7333
DOI: 10.1039/D4NJ00284A, Paper
Xuefang Lei, Yujin Li, Peiqing Guo, Mingzhu Qiu, Rang Meng, Shaohui Li, Dongxia Zhang, Nali Chen, Xibin Zhou
The core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites were successfully synthesized by co-precipitation method, and CeO2 was uniformly dispersed on the shell layer with the help of nitrogen-doped graphene quantum dots (N-GQDs).
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Influence of the secondary ligand, phenanthroline, on the antioxidant and pro-oxidant and cytotoxic effects of the oxidovanadium(IV)/naringin complex

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00655K, Paper
Andrés G. Restrepo, Angel L. Huamani, Alexandra Velásquez Bravo, Pablo J. González, Luciana G. Naso, Evelina G. Ferrer, Patricia A. M. Williams
Replacement of phen in [VO(Narg)2] induces greater π electronic delocalization, thus improving antioxidant action. However, due to its lipophilic character, cellular uptake of V is increased, leading to enhanced pro-oxidant and anticancer effects.
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KOH-mediated synthesis of amides from azides and 1,3-dicarbonyl compounds

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05813A, Paper
Zhuoran Yang, Yao Xu, Xiaoming Liao, Wenjun Wang, Chang Lyu, Xiaoxiang Zhang
Aryl amides were prepared through KOH-mediated [3+2] cycloaddition/Wolff rearrangement from organic azides and 1,3-dicarbonyl compounds.
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Catalytic decomposition of hydrazine nitrate and hydroxylamine nitrate in radioactive nitric acid waste liquid using Ru/AC catalyst

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00916A, Paper
Deyan Yu, Baole Li, Zhi Cao, Qi Chen, Chen Zuo, Tiansheng He, Taihong Yan, Weifang Zheng
The 5 wt% Ru/AC catalysts were prepared using the impregnation method.
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Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00864B, Paper
Zhiqiang Wu, Yueyi Li, Pengxi Jiang, Sisi Ma, Wenfei Dong, Hongjian Zhao, Enke Feng, Xuming Wang
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkage polymerization method. The samples underwent characterization through the X-ray diffraction (XRD), the fourier transform infrared...
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Compare Mode in Google AI Studio: Your Companion for Choosing the Right Gemini Model

Compare Mode is a powerful new feature designed to help you make informed decisions about which Gemini model best suits your needs.




com

English dystopian thriller ‘Edgar and Annabel’ comes to Chennai

British playwright Sam Holcroft’s Edgar and Annabel, a dystopian story of dissenters fighting against the establishment, comes to Chennai, directed by Sunandha Raghunathan




com

How Cubbon Park’s book clubs are connecting Bengaluru’s reading community

The outdoor setting of Cubbon Reads and Cubbon Book Club fosters reading as well as social connections




com

Vizag Reads: A silent book-reading community in Visakhapatnam

Vizag Reads, a quiet reading community, meets every Sunday at VMRDA Central Park. It is the Visakhapatnam chapter of Cubbon Reads in Bengaluru, an initiative that has turned into a worldwide silent reading movement with more than 30 chapters across India and around 15 internationally




com

Watch | Did you know Vizag has a silent reading community?

A weekend book reading initiative - Vizag reads - at the VMRDA Central Park in Visakhapatnam, is giving an opportunity for book-lovers to come together and read in peace.




com

Coimbatore Reads: A silent reading community to find new books and friends

Coimbatore Reads is one of the many chapters of Cubbon Reads, which has sparked a silent reading movement in several parts of the world




com

When Ganesha, culture and food come together

This year, the Sri Vidyaranya Yuvaka Sangha, is celebrating their 61st Bengaluru Utsava. A peek at their line up...



  • Life & Style

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Committed to keep the crafts alive

Padmaja Sakhamuri, the convener of Vastrabharana says there is a lot to look forward to in the 31st edition of Vastrabharana, which begins on September 28 in Bengaluru




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Constructing a core–shell Pt@MnOx/SiO2 catalyst for benzene catalytic combustion with excellent SO2 resistance: new insights into active sites

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00071D, Paper
Dan Yang, Fang Dong, Jie Wang, Zhicheng Tang, Jiyi Zhang
The construction of a core–shell Pt@MnOx/SiO2 protective structure catalyst can protect the active Pt site well from SO2 toxicity.
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Regulating water decontamination and food safety by a reusable, nano-sized MOF@cotton@chitosan composite through nanomolar detection of the drug nitroxinil and organoarsenic feed additive p-arsanilic acid

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00066H, Paper
Subhrajyoti Ghosh, Debjit Mal, Shyam Biswas
MOF@cotton@chitosan composite for nanomolar fluorescence sensing of nitroxinil drug and p-arsanilic acid in real samples is presented.
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Comparative analysis of the insecticidal activity against Sitophilus oryzae (L.) and agro-morphological characteristics of maize using non-biogenic and biogenic ZnO nanoparticles

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00839H, Paper
S. Aisvarya, M. Kalyanasundaram, M. Kannan, P. Arunkumar, S. Preetha, K. Elango, K. Govindaraju
Utilizing environmentally friendly nanomaterials to address insect pests and promote plant growth is imperative.
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3D architectured zinc–chromium layered double hydroxide with nickel cobalt sulfide composite for the electrochemical detection of ronidazole

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00804E, Paper
Thangavelu Sakthi Priya, Tse-Wei Chen, Shen-Ming Chen, Thangavelu Kokulnathan, Bih-Show Lou, Riaz Ullah, Wedad A. Al-onazi, Mohamed S. Elshikh
Antibiotic overuse prompts mutation, and ecotoxicity, requiring precise ronidazole (RZ) detection; we developed zinc chromium layered double hydroxide with nickel cobalt sulfide (ZC/NCS) based electrochemical sensor to monitor RZ in diverse matrices.
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Facile fabrication of Z-scheme g-C3N5/Gd-MOF/silver nanocubes composite as new generation visible light active photocatalyst for abatement of persistent toxic pollutants

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00913K, Paper
Varsha UshaVipinachandran, Susanta Kumar Bhunia
Some of the persistent hazardous contaminants that readily dissolve in water with a recognizable hue are hexavalent chromium and neomycin antibiotic. Herein, a Z-scheme g-C3N5/Gd-MOF/silver nanocubes (CNGdAg) ternary composite was...
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Rapid Synthesis of MXenes and Its Potential Risk to Bacterial Communities in Tomato Rhizosphere

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00827D, Communication
cheng chen, Yuchen Liu, Houpu Zhang, Jie Ren, Chao Zhang, Mao Xu, Dan Liu, Yuru Wang, Weiwei Lei, Xiaoli Zhao
As a thriving group of two-dimensional (2D) nanomaterials, MXenes offer tremendous application and development prospects because of their excellent physical and chemical properties. Rhizosphere bacteria colonize the narrow ecosystem region...
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High-efficiency removal of Cd(II) and As(III) from irrigation water using a S–Fe–C composite: performance and mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00863K, Paper
Zihao Liang, Yanpeng Liang, Hua Lin, Yuxi Lu, Huawei Li, Jie Zhang, Honghu Zeng, Gongning Chen
SFC showcased exceptional Cd(II) and As(III) removal capacities of 405 mg g−1 and 349 mg g−1, respectively, while preserving magnetic recovery properties after repeated adsorption cycles, making it an environmentally sustainable functional material.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Biomass@MOF nanohybrid materials for competitive drug adsorption: analysis by conventional macroscopic models and statistical physical models

Environ. Sci.: Nano, 2024, 11,1543-1558
DOI: 10.1039/D3EN00843F, Paper
Bryan Fernando Rivadeneira-Mendoza, Luis Santiago Quiroz-Fernández, Fausthon Fred da Silva, Rafael Luque, Alina M. Balu, Joan Manuel Rodríguez-Díaz
This study discloses the design of nanohybrid Biomass@MOF resulting from the functionalization of a hydrochar (HC) through hydrothermal treatment (HT) of corn cob residues and MIL-53(Al).
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Doped carbon dots affect heavy metal speciation in mining soil: changes of dissimilated iron reduction processes and microbial communities

Environ. Sci.: Nano, 2024, 11,1724-1739
DOI: 10.1039/D3EN00823A, Paper
Xinyi Huang, Shaobo Liu, Xuanming Liu, Xiaofei Tan, Shuai Guo, Mingyang Dai, Qiang Chen, Gaobin Chen, Chenzhi Feng
Carbon dots (CDs) inevitably accumulate in soils due to their widespread use, affecting soil enzyme activities and microbial community structure.
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Composite materials based on halloysite clay nanotubes and cellulose from Posidonia oceanica sea balls: from films to geopolymers

Environ. Sci.: Nano, 2024, 11,1508-1520
DOI: 10.1039/D3EN00879G, Paper
Martina Maria Calvino, Giuseppe Cavallaro, Stefana Milioto, Giuseppe Lazzara
The combination of natural halloysite nanotubes and cellulose recovered from egagropili is effective to fabricate composite films and geopolymers promising for packaging and building applications, respectively.
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The effects of CdSe/ZnS quantum dots on autofluorescence properties and growth of algae Desmodesmus communis: dependence on cultivation medium

Environ. Sci.: Nano, 2024, 11,1701-1712
DOI: 10.1039/D3EN00955F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Agnė Kalnaitytė-Vengelienė, Danguolė Montvydienė, Emilija Januškaitė, Živilė Jurgelėnė, Mindaugas Kazlauskas, Nijolė Kazlauskienė, Saulius Bagdonas
The cultivation media markedly influence the quantum dot induced effects on photosynthesis properties and growth of green freshwater microalgae.
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Functional silver-based nanomaterials affecting zebrafish development: the adverse outcomes in relation to the nanoparticle physical and chemical structure

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00813D, Paper
Open Access
Patrizia Bonfanti, Anita Colombo, Rossella Daniela Bengalli, Maurizio Gualtieri, Ilaria Zanoni, Magda Blosi, Anna Costa, Paride Mantecca
The growing demand for effective antimicrobials determined a significant increase of new nanoformulated materials to fight against bacteria and viruses, to be used in many industrial sectors including textiles, cosmetics,...
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Anatase TiO2 nanomaterials are much more effective in enhancing hydrolysis of organophosphorus compounds than their rutile counterparts

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00138A, Paper
Tong Li, Yiting Ju, Tingting Du, Chuanjia Jiang, Tong Zhang, Wei Chen
The crystalline phase significantly affects the efficiency of TiO2 nanomaterials in catalyzing hydrolysis reactions of organophosphates, primarily by modulating the surface Lewis acidity of TiO2.
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Correction: Nano-pelargonidin modulates p53/PARP/HSP 90/XRCC1 signaling axis to combat cypermethrin-induced genotoxicity and metabolic dysfunction in fish: a molecular docking predicted in vivo approach

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN90017K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Priyanka Sow, Sudatta Dey, Rishita Dey, Asmita Samadder, Sisir Nandi, Debojyoti Tarafdar, Anisur Rahman Khuda-Bukhsh
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“Feather-duster” like ZnIn2S4/TiO2 heterostructured nanocomposites with enhanced visible-light photocatalytic performance

CrystEngComm, 2024, 26,2025-2032
DOI: 10.1039/D3CE01239E, Paper
Wenjie Liu, Lei Li, Jingru Li, Fang Wang, Chun-Shuai Cao, Jianzhou Gui, Alex T. Kuvarega, Bhekie B. Mamba, Dan Liu
The ZnIn2S4/TiO2 heterostructures show an increased surface area and strengthened interface contacts, facilitating efficient photogenerated carrier separation and leading to high photocatalytic performance under visible light irradiation.
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Synthesis, structure, and properties of helical bis-Zn(II) complexes of hexapyrrolic ligands

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00019F, Paper
Pinky Chauhan, Poornenth Pushpanandan, Mangalampalli Ravikanth
Bis(3-pyrrolyl BODIPY)s were used to prepare rare examples of hexapyrrolic ligands by demasking BF2 units. The hexapyrrolic ligands, without isolating, were used to prepare novel examples of double-stranded bis-Zn(II) helicate complexes.
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Solvent-polarity-controlled assembly of polynuclear titanium-calixarene complexes: constructing isolated {Ti7}, {Ti13}, {Ti24} and {Tb2Ti13} clusters

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01275A, Paper
Yanyan Wang, Ying Xiong, Wuping Liao
The assembly of polynuclear titanium-calixarene complexes is based on Ti4–C8A SBUs.
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Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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The structural evolution of CL-20-based energetic host–guest solvates at decomposition temperature according to the perceptions of THz spectroscopy

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01310C, Paper
Lu Shi, XiaoHui Duan, Hongzhen Li
This work employed variable-temperature THz spectroscopy to analyze the structural evolution of host–guest energetic CL-20/H2O2 and CL-20/H2O solvates, as well as the mechanism of intermolecular interactions using DFT calculation and MD simulation.
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Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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First-principles prediction of a direct Z-scheme WSe2/HfS2 van der Waals heterostructure for overall photocatalytic water decomposition

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00267A, Paper
Yan Zhang, Zhi-Bo Qiang, Jian-Xin Ding, Kang-Xin Xie, Li Duan, Lei Ni
The direct Z-scheme heterostructures photocatalyst has been validated as an efficacious approach for addressing the energy source issues and environmental challenges. This manuscript employs the first-principles to scrutinize singular-layer WSe2...
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Enhanced Zn ion storage performance of polypyrrole coated Mn3O4 composites electrode

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00252K, Paper
Shilong Li, Ming Zhao, Weichao Zhang, Xiang Wu
Aqueous zinc ion batteries (AZIBs) possess significant application potential in energy storage field due to their large capacity, low redox potential and high safety. Among various materials, Mn3O4 electrode has...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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Twitter is testing Community Notes for images, videos

Twitter feature will soon expand to support multiple images, GIFs and videos.




com

Elon Musk says Twitter video app for smart TVs is 'coming'

Musk responded to a tweet suggesting that a Twitter video app is needed.




com

Musk sets tweet-viewing limits to combat data scraping from large AI companies

Temporary limits to address “extreme levels of data scraping and system manipulation”




com

Meta's social media apps back up after brief outage - Downdetector.com

At the peak of the outage, lasting over an hour, over 14,000 users reported issues with accessing Instagram, while around 7,000 and 2,700 users faced issues with Facebook and WhatsApp, respectively




com

Musk says Twitter is losing cash because advertising is down; company is carrying heavy debt

Need to reach positive cash flow before we have the luxury of anything else: Elon Musk




com

Community norm violation: YouTube removed 1.9 million videos in Jan-Mar 2023 in India

In the same period, YouTube removed over 6.48 million videos globally for violation of the norms




com

Elon Musk congratulates PM Modi for becoming most followed leader on X

Modi recently reached 100.1 million followers on X, surpassing other global leaders such as US President Joe Biden and Turkiye’s Recep Tayyip Erdogan.