el

[ASAP] From Industrial Method to the Use of Silylated P(III) Reagents for the Synthesis of Relevant Phosphonylated Molecules

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00490




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[ASAP] Straightforward Access to a Great Diversity of Complex Biorelevant ?-Lactams Thanks to a Tunable Cascade Multicomponent Process

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00438




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[ASAP] What Elements Contribute to a High-Quality Continuous Processing Submission for <italic toggle="yes">OPR&D</italic>?

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00020




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[ASAP] Continuous Flow Conditions for High Temperature Formation of a Benzodioxan Pharmaceutical Intermediate: Rapid Scaleup for Early Phase Material Delivery

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00499




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[ASAP] An Economical Route to Lamivudine Featuring a Novel Strategy for Stereospecific Assembly

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00083




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[ASAP] Nontraditional Application of the Photo-Fenton Process: A Novel Strategy for Molecular Construction Using Formamide and Flow Chemistry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00057




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[ASAP] Development of an Efficient Synthetic Process for Broflanilide

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00028




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[ASAP] Development of a Robust and Highly Selective Ru(II)-Catalyzed Dynamic Kinetic Resolution Used to Manufacture AMG 232

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00427




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[ASAP] Investigating Process Variables and Additive Selection To Optimize Polymorphic Control of Carbamazepine in a CO<sub>2</sub> Antisolvent Crystallization Process

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00545




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[ASAP] Efficient Kinetic Data Acquisition and Model Prediction: Continuous Flow Microreactors, Inline Fourier Transform Infrared Spectroscopy, and Self-Modeling Curve Resolution

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00037




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[ASAP] Process Development and Large-Scale Synthesis of BTK Inhibitor BIIB068

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00087




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[ASAP] A Versatile Electrochemical Batch Reactor for Synthetic Organic and Inorganic Transformations and Analytical Electrochemistry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00091




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[ASAP] Upscaling Photoredox Cross-Coupling Reactions in Batch Using Immersion-Well Reactors

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00070




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[ASAP] Optimized Synthesis of 7-Azaindazole by a Diels–Alder Cascade and Associated Process Safety

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00184




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[ASAP] Enzymatic Preparation of the Chiral (<italic toggle="yes">S</italic>)-Sulfoxide Drug Esomeprazole at Pilot-Scale Levels

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00115




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[ASAP] Development and Production of an Enantioselective Tetrahydroisoquinoline Synthesis Enabled by Continuous Cryogenic Lithium–Halogen Exchange

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00141




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[ASAP] <sc>d</sc>-Serine as a Key Building Block: Enzymatic Process Development and Smart Applications within the Cascade Enzymatic Concept

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00024




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Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00322K, Paper
Open Access
Elba Ochoa, Wilson Henao, Sara Fuertes, Daniel Torres, Tomas van Haasterecht, Elinor Scott, Harry Bitter, Isabel Suelves, Jose Luis Pinilla
Evaluation of the dispersion of Pd active sites on the catalyst performance during fatty acids decarbonylation to α-olefins was explored in this work. Pd subnanometric particles, clusters and aggregates were found to modulate the catalyst activity.
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Enhancing aqueous pollutants photodegradation via Fermi level matched Z-scheme BiOI/Pt/g-C3N4 photocatalyst: unobstructed photogenerated charge behavior and degradation pathway exploration

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00429D, Paper
Jingjing Jiang, Yueyu Song, Xingyue Wang, Tianren Li, Mingyu Li, Yanhong Lin, Tengfeng Xie, Shuangshi Dong
Z-scheme photocatalytic system was widely requisited to solve water pollution problem. However, the degradation mechanism for pollutants with Z-scheme photocatalyst has been ambiguous. In this work, an efficient all solid-state...
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Computational investigation of the ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02562F, Paper
Pan Li, Chaoren Shen, Jie Min, Jing-Yuan Mei, Huan Zheng, Lin He, Xinxin Tian
The ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation has been discussed.
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Superior adsorption capability and excellent photocatalytic activity derived from the ferroelectric external screening effect in Bi3TiNbO9 single-crystal nanosheets

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02513H, Paper
Xiaofeng Yin, Yingjie Sun, Xiaojun Wu, Xiaoning Li, Huan Liu, Wen Gu, Wei Zou, Liuyang Zhu, Zhengping Fu, Yalin Lu
A new strategy based on the ferroelectric external screening effect was used to enhance dye adsorption and degradation activity.
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Oxidation of lignocellulosic platform molecules to value-added chemicals using heterogeneous catalytic technologies

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00240B, Minireview
Pedro L. Arias, Juan A. Cecilia, Iñaki Gandarias, José Iglesias, Manuel López Granados, Rafael Mariscal, Gabriel Morales, Ramón Moreno-Tost, Pedro Maireles-Torres
This minireview gives an overview about heterogeneous catalytic technologies for the oxidation of key platform molecules (glucose, 5-hydroxymethylfurfural, furfural and levulinic acid) into valuable chemicals.
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Integrated design for electrocatalytic carbon dioxide reduction

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00453G, Minireview
Xin Zhao, Lijie Du, Bo You, Yujie Sun
We have summarized three novel strategies for electrocatalytic carbon dioxide reduction, including concurrent CO2 electroreduction, tandem CO2 electroreduction and hybrid CO2 electroreduction.
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Seaweed bio-inspired ZnO piezoelectric cilia array applied in microreactors for enhanced photocatalytic performance

Catal. Sci. Technol., 2020, 10,2337-2342
DOI: 10.1039/C9CY02509J, Paper
Yukai Chen, Jiaojiao Fang, Baoying Dai, Huimin Wei, Jiahui Kou, Chunhua Lu
A piezoelectric built-in electric field is believed to be an effective way to separate photoinduced carriers and enhance photocatalytic performance.
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Development of an engineered thermostable amine dehydrogenase for the synthesis of structurally diverse chiral amines

Catal. Sci. Technol., 2020, 10,2353-2358
DOI: 10.1039/D0CY00071J, Paper
Lei Liu, Dong-Hao Wang, Fei-Fei Chen, Zhi-Jun Zhang, Qi Chen, Jian-He Xu, Zhi-Long Wang, Gao-Wei Zheng
Structurally diverse chiral amines and amino alcohols were synthesized using an engineered thermostable amine dehydrogenase, demonstrating its extensive synthesis potential.
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Synergistic photocatalysis–Fenton reaction for selective conversion of methane to methanol at room temperature

Catal. Sci. Technol., 2020, 10,2329-2332
DOI: 10.1039/D0CY00028K, Communication
Yi Zeng, Hang Chen Liu, Jing Sheng Wang, Xing Yang Wu, Song Ling Wang
Combining the photocatalysis and Fenton reaction highly promote the yield and selectivity of CH3OH from CH4 with solar light at room temperature, up to 471 μmol g−1 h−1 and 83%, respectively.
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Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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Path of electron transfer created in S-doped NH2-UiO-66 bridged ZnIn2S4/MoS2 nanosheet heterostructure for boosting photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, 10,2531-2539
DOI: 10.1039/D0CY00127A, Paper
Qi Ran, Zebin Yu, Ronghua Jiang, Lun Qian, Yanping Hou, Fei Yang, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang
This work introduces the synthesis of ZnIn2S4/NH2-UiO-66/MoS2 sheet heterostructure photocatalysts and their application to photocatalytic hydrogen evolution.
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Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
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Construction of heterostructure based on hierarchical Bi2MoO6 and g-C3N4 with ease for impressive performance in photoelectrocatalytic water splitting and supercapacitor

Catal. Sci. Technol., 2020, 10,2427-2442
DOI: 10.1039/D0CY00211A, Paper
C. Murugan, M. Karnan, M. Sathish, A. Pandikumar
This work demonstrates the formation of g-C3N4/Bi2MoO6 heterostructure for water splitting and supercapacitor; which shows highest PEC efficiency and symmetric device delivered a energy density and power density of 47 W h kg−1 and 4.5 kW kg−1.
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Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
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Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
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Loop engineering of aryl sulfotransferase B for improving catalytic performance in regioselective sulfation

Catal. Sci. Technol., 2020, 10,2369-2377
DOI: 10.1039/D0CY00063A, Paper
Yu Ji, Shohana Islam, Haiyang Cui, Gaurao V. Dhoke, Mehdi D. Davari, Alan M. Mertens, Ulrich Schwaneberg
Loop engineering of aryl sulfotransferase B improves catalytic performance in regioselective sulfation.
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Adjustable anchoring of Ni/Co cations by oxygen-containing functional groups on functionalized graphite paper and accelerated mass/electron transfer for overall water splitting

Catal. Sci. Technol., 2020, 10,2627-2643
DOI: 10.1039/D0CY00181C, Paper
Yiyi Huang, Lei Sun, Zebin Yu, Ronghua Jiang, Jun Huang, Yanping Hou, Fei Yang, Boge Zhang, Runzhi Zhang, Yalan Zhang
NCS–NCO/FGP0.44 with a cellular network of porous nanosheets and close-contact heterointerface reveals accelerated interfacial mass/electron transportation for overall water splitting.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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Carbon nanotube/PTFE as a hybrid platform for lipase B from Candida antarctica in transformation of α-angelica lactone into alkyl levulinates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00545B, Paper
Anna Szelwicka, Anna Kolanowska, Piotr Latos, Sebastian Jurczyk, Slawomir Boncel, Anna Chrobok
A highly active biocatalyst based on a hybrid platform was designed for the conversion of α-angelica lactone to alkyl levulinates.
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Origin of CO2 as the main carbon source in syngas-to-methanol process over Cu: theoretical evidence from a combined DFT and microkinetic modeling study

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00602E, Paper
Dongyang Xu, Panpan Wu, Bo Yang
A theoretical study combining DFT and microkinetic modeling provides evidence that CO2 is the main carbon source in methanol synthesis from syngas (CO, CO2 and H2) over Cu.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00593B, Paper
Marta Navarro, Luis F. Sánchez-Barba, Andrés Garcés, Juan Fernández-Baeza, Israel Fernández, Agustín Lara-Sánchez, Ana M. Rodríguez
The binuclear aluminum complexes [AlR22-NN';κ2-NN')AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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