si Shri Karimbhai Kamrudinbhai ... vs The Assistant Commissioner Of Income ... on 11 November, 2024 By indiankanoon.org Published On :: IN THE INCOME TAX APPELLATE TRIBUNAL, RAJKOT BENCH, RAJKOT BEFORE DR. ARJUN LAL SAINI, ACCOUNTANT MEMBER AND SHRI DINESH MOHAN SINHA, JUDICIAL MEMBER आ.(खो और ज).सं./IT(SS)A Nos.103 -108/RJT/20 17 ( नधारण वष /Assessment Years: (2007-08 to 20 12 -13) Deputy Commissioner of Income Karim K. Makhani Tax, Central Circle-1, "Amruta Vs. Flat No.201, Block No.37, Race Estate", 2nd Floor, M.G. Road, Course Park, Rajkot Rajkot-360001 थायीले खासं . /जीआइआरसं . /P AN/GIR No.: AMBPM 6370 J (अपीलाथ /Assessee) ( यथ /Respondent) आ.(खो और ज). सं./IT(SS)A Nos.1 25-130/RJT/20 17 ( नधारणवष / Assessment Years: (2007-08 to 20 12 -13) Karim K. Makhani Assistant Commissioner of Income C/o SADP & Co. Chart ered Vs. Tax, Central Circle-1, 2nd Floor, Accountants, BB House, 5- Amruta Estate, Room No.215, M.G Collegewadi, Near Kathiyawad Road, Rajkot-360001 Gymkhana, R ajkot-360001 थायीले खासं . /जीआइआरसं . /P AN/GIR No.: AMBPM 6370 J (अपीलाथ /Assessee) ( यथ /Respondent) आयकर अपील सं./ITA Nos.210 -213/RJT/2018 ( नधारण वष /Assessm ent Years: (2 008-09 to 20 09 -10, 2011-12 & 2013-14) Deputy Commissioner of Income Karim K. Makhani Tax, Central Circle-1, "Amruta Vs. 37/301, Race Course Park, Airport Estate", 2nd Floor, M.G. Road, Road, Rajkot Rajkot-360001 थायीले खासं . /जीआइआरसं . /P AN/GIR No.: AMBPM 6370 J (अपीलाथ /Assessee) ( यथ /Respondent) IT(SS)A Nos.103-108/Rjt/2017, 125-130/Rjt/2017 & ITA Nos.210- Full Article
si Shri Karimbhai Kamrudinbhai ... vs The Assistant Commissioner Of Income ... on 11 November, 2024 By indiankanoon.org Published On :: IN THE INCOME TAX APPELLATE TRIBUNAL, RAJKOT BENCH, RAJKOT BEFORE DR. ARJUN LAL SAINI, ACCOUNTANT MEMBER AND SHRI DINESH MOHAN SINHA, JUDICIAL MEMBER आ.(खो और ज).सं./IT(SS)A Nos.103 -108/RJT/20 17 ( नधारण वष /Assessment Years: (2007-08 to 20 12 -13) Deputy Commissioner of Income Karim K. Makhani Tax, Central Circle-1, "Amruta Vs. Flat No.201, Block No.37, Race Estate", 2nd Floor, M.G. Road, Course Park, Rajkot Rajkot-360001 थायीले खासं . /जीआइआरसं . /P AN/GIR No.: AMBPM 6370 J (अपीलाथ /Assessee) ( यथ /Respondent) आ.(खो और ज). सं./IT(SS)A Nos.1 25-130/RJT/20 17 ( नधारणवष / Assessment Years: (2007-08 to 20 12 -13) Karim K. Makhani Assistant Commissioner of Income C/o SADP & Co. Chart ered Vs. Tax, Central Circle-1, 2nd Floor, Accountants, BB House, 5- Amruta Estate, Room No.215, M.G Collegewadi, Near Kathiyawad Road, Rajkot-360001 Gymkhana, R ajkot-360001 थायीले खासं . /जीआइआरसं . /P AN/GIR No.: AMBPM 6370 J (अपीलाथ /Assessee) ( यथ /Respondent) आयकर अपील सं./ITA Nos.210 -213/RJT/2018 ( नधारण वष /Assessm ent Years: (2 008-09 to 20 09 -10, 2011-12 & 2013-14) Deputy Commissioner of Income Karim K. Makhani Tax, Central Circle-1, "Amruta Vs. 37/301, Race Course Park, Airport Estate", 2nd Floor, M.G. Road, Road, Rajkot Rajkot-360001 थायीले खासं . /जीआइआरसं . /P AN/GIR No.: AMBPM 6370 J (अपीलाथ /Assessee) ( यथ /Respondent) IT(SS)A Nos.103-108/Rjt/2017, 125-130/Rjt/2017 & ITA Nos.210- Full Article
si Suzlon Energy Ltd.,,Ahmedabad vs The Dy. Commissioner Of Income Tax ... on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Assessee and the Revenue as against separate appellate orders both dated I.T.A No. 198 & 199/Ahd/2023 & Ors. A.Ys. 2016-17 & 2017-18 Page No 2 Suzlon Engergy Ltd. vs. DCIT 28.02.2023 passed by the Commissioner of Income Tax (Appeals), National Faceless Appeal Centre, Delhi, (in short referred to as "CIT(A)"), arising out of the separate assessment orders passed under section 143(3) of the Income Tax Act, 1961 (hereinafter referred to as 'the Act') relating to the Assessment Years 2016-17 and 2017-18. Since common issues are involved in both the years namely disallowance u/s.14A rwr 8D and Depreciation on Goodwill, the same are disposed of by this common order for the sake of convenience. Asst. year 2016-17 is taken as the lead case. Full Article
si The Dy. Commissioner Of Income Tax ... vs Suzlon Energy Ltd.,, Ahmedabad on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Assessee and the Revenue as against separate appellate orders both dated I.T.A No. 198 & 199/Ahd/2023 & Ors. A.Ys. 2016-17 & 2017-18 Page No 2 Suzlon Engergy Ltd. vs. DCIT 28.02.2023 passed by the Commissioner of Income Tax (Appeals), National Faceless Appeal Centre, Delhi, (in short referred to as "CIT(A)"), arising out of the separate assessment orders passed under section 143(3) of the Income Tax Act, 1961 (hereinafter referred to as 'the Act') relating to the Assessment Years 2016-17 and 2017-18. Since common issues are involved in both the years namely disallowance u/s.14A rwr 8D and Depreciation on Goodwill, the same are disposed of by this common order for the sake of convenience. Asst. year 2016-17 is taken as the lead case. Full Article
si Suzlon Energy Ltd.,,Ahmedabad vs The Dy. Commissioner Of Income Tax ... on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Assessee and the Revenue as against separate appellate orders both dated I.T.A No. 198 & 199/Ahd/2023 & Ors. A.Ys. 2016-17 & 2017-18 Page No 2 Suzlon Engergy Ltd. vs. DCIT 28.02.2023 passed by the Commissioner of Income Tax (Appeals), National Faceless Appeal Centre, Delhi, (in short referred to as "CIT(A)"), arising out of the separate assessment orders passed under section 143(3) of the Income Tax Act, 1961 (hereinafter referred to as 'the Act') relating to the Assessment Years 2016-17 and 2017-18. Since common issues are involved in both the years namely disallowance u/s.14A rwr 8D and Depreciation on Goodwill, the same are disposed of by this common order for the sake of convenience. Asst. year 2016-17 is taken as the lead case. Full Article
si Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "What kind of punishment is sanctioned by the law for any Pilot who gets the RTR permit or licence on the basis of false documents?" The CPIO, Sr. DWA (COP & regulations) vide letter dated 05.10.2023 replied as under:- "- Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convinced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
si Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "To, Shri Umang Srivastva Sr.DWA (COP) I had complained on 05/05/2023 against Rahul Sinha regarding his COP permit. What action or inquiry has been conducted in this regard?" The CPIO, Sr DWA (COP & Regulation) vide letter dated 05.10.2023 replied as under:- "Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA, JWA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convir.ced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
si Devendra Singh vs Department Of Agriculture & ... on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Complainant filed an RTI application dated 12.07.2023 seeking information on following points:- "1. Total number of employees whose Pension Payment Orders (PPOs) were issued between 01.01.2018 to 30.6.2023 from the office of the PAO, PP&M, Faridabad. 2. Total number of employees whose Pension Payment Orders (PPOs) were issued after the date of their retirement or delayed due to any reason. Information may be provided from 01.01.2018 to 30.6.2023 only. 3. Photocopy of note sheet in respect of my (Devendra Singh, Applicant) pension file maintained in your office to date. 4. Photocopies of the dispatch register maintained in your office for the dates 14.3.2023 to 17.3.2023 and 20.3.2023 to 22.3.2023." Full Article
si Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:08:08 +0000 Commerzbank analizează opțiunea de a achiziționa o bancă germană de dimensiuni medii ca parte a strategiei de a evita o posibilă preluare de către UniCredit, potrivit Reuters. Planurile sunt într-o etapă incipientă, iar posibilele ținte ar putea include Hamburg Commercial Bank sau Oldenburgische Landesbank. Potrivit surselor Reuters, Commerzbank încearcă să conceapă un plan de apărare, ... The post Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
si Vânzările globale de automobile electrice și hibride, în creștere cu 35% în octombrie By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:11:40 +0000 Vânzările globale de automobile complet electrice şi vehicule hibride de tip plug-in au crescut cu 35% în luna octombrie a acestui an comparativ cu aceeaşi lună a anului trecut, graţie în primul rând unui salt de 54% al vânzărilor de pe piaţa chineză, arată cifrele publicate de firma de cercetare de piaţă Rho Motion. Potrivit ... The post Vânzările globale de automobile electrice și hibride, în creștere cu 35% în octombrie appeared first on Forbes Romania. Full Article Actualitate autovehicule electrice Rho Motion sondaj EV vehicule hibride
si Trump îl nominalizează pe veteranul și prezentatorul Fox News, Pete Hegseth, pentru funcția de secretar al apărării By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:24:11 +0000 Președintele ales Donald Trump a surprins observatorii politici marți seară prin nominalizarea prezentatorului Fox News, Pete Hegseth, pentru funcția de secretar al apărării. „Pete și-a petrecut întreaga viață ca un războinic pentru trupele noastre și pentru țară,” a declarat Trump într-un comunicat. „Pete este dur, inteligent și un adevărat susținător al politicii America First. Cu ... The post Trump îl nominalizează pe veteranul și prezentatorul Fox News, Pete Hegseth, pentru funcția de secretar al apărării appeared first on Forbes Romania. Full Article Actualitate Afaceri
si Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie By www.forbes.ro Published On :: Wed, 13 Nov 2024 16:55:16 +0000 Grupul Bitdefender, cea mai importantă companie din domeniul tehnologiei cu sediul central în România, a înregistrat venituri nete de 391,9 milioane de dolari, în creștere cu 16% comparativ cu anul anterior, și un profit operațional ajustat (EBITDA) de 85 de milioane de dolari, cu 21,7% mai mare decât în 2022. Florin Talpeș, CEO și cofondator ... The post Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii Tech
si Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” By www.forbes.ro Published On :: Wed, 13 Nov 2024 21:44:31 +0000 Moov Leasing, un start-up românesc lansat de Bogdan Speteanu și Mircea Dihel, propune o schimbare radicală în leasingul auto, transformând experiența de utilizare a unei mașini într-una simplă și accesibilă, la fel ca utilizarea unui telefon mobil. După 20 de ani de experiență la BCR, timp în care a ocupat mai multe funcții de conducere, printre care și ... The post Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” appeared first on Forbes Romania. Full Article Emisiuni Online | Proiecte Forbes Bogdan Speteanu Moov Leasing
si Who is Rajan Shaw, named in Ratan Tata's Rs 10000 crore will, now given responsibility to look after... By www.dnaindia.com Published On :: Thu, 14 Nov 2024 02:15:00 GMT Known for his humility, Ratan Tata leaves behind a legacy of compassion and generosity Full Article Business
si Actor John Krasinski named 'Sexiest Man Alive 2024' by People magazine By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:05:00 GMT Krasinski's win adds him to an esteemed group of past honourees like George Clooney, Brad Pitt, Idris Elba, and Michael B. Jordan. Full Article Entertainment
si 'Priyanka Chopra was out...': Arjun Kapoor talks about his terrific chemistry with Ranveer Singh in Gunday By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:22:00 GMT Talking about Priyanka Chopra, Arjun admitted that she was already a big star when they made the film. Full Article Entertainment
si Bigg Boss OTT-fame Bhojpuri actress Akshara Singh receives extortion threat By www.dnaindia.com Published On :: Thu, 14 Nov 2024 03:11:00 GMT Bhojpuri actress Akshara Singh receives extortion threat, investigation underway. Full Article Entertainment
si C–H activation-enabled synthesis of a piperazine-embedded azadibenzo[a,g]corannulene analogue By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00415A, Research ArticleLin Huang, Mengyu Qiu, Zhihao Chang, Duncan L. Browne, Jianhui HuangThe first example of an azadibenzo[a,g]corannulene analogue with an embedded piperazine ring on the flank of its polycyclic skeleton is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Synthesis of 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00176A, Research ArticleWeihua Qiu, Jide Zhu, Rencai Tao, Kai Yang, Qiuling SongHerein we present a practical approach for preparing 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 (the primary source of boron-10) in the presence of chlorosilane.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00386A, Research ArticleJiahua Wang, Dandan Gao, Aanuoluwapo O. Oyejobi, Na Ji, Xiang-Ying Tang, Long WangA sequential synthetic method toward 1,3-disubstituted carbazol-4-amines is reported and an interesting C–S metathesis process is disclosed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00244J, Research ArticleHui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping XuAn efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si A Pd(II)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00344F, Research ArticlePratiksha Bhorali, Deep J. Kalita, Babulal Das, Sanjib GogoiThe first denitrative Pd(II)-catalyzed alkyne annulation reaction is reported for the synthesis of cyclopenta[b]chromanes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si DBU-catalyzed substitution-controlled synthesis of oxa[3.3.1] bridged ring and naphthylamine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00012A, Research ArticleShiyu Xu, Zhihui Sun, Pengyutian Liu, Yuanlin Wei, Fan Sun, Man Zhao, Ying Wang, Ming Zhang, Guofeng Li, Hong LiangA switchable cascade cyclization reaction of ortho-alkynyl arylketones with amines has been developed, where the different reaction pathways are controlled by the substituent on the α-carbon of in-situ-generated ortho-alkynyl arylaldimines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00140K, Research ArticleQun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin ZhangHere, an unprecedented one-step modular construction of C2-symmetric N-PACs through reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be converted into a powerful organic photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Computational insights into the synergistic interplay of ligand and fluorine effects in palladium-catalyzed regiodivergent decarboxylative allylic alkylation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00147H, Research ArticleShiyu Wang, Hongli Wu, Xiangyang Tang, Genping HuangDFT calculations were performed to investigate palladium-catalyzed decarboxylative allylic alkylation of allyl difluoro-β-ketoesters. The synergistic effects of ligand and fluorine substituents on regioselectivity were uncovered.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00374H, Research ArticleYongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua LiuCyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Sustainable synthesis of long-acting local anesthetics ropivacaine and levobupivacaine under batch and continuous flow via asymmetric hydrogenation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00072B, Research ArticleZhi Yang, Hanlin Chen, Linxi Wan, Xinyi Feng, Lingshuang Ma, Pei Tang, Fen-Er ChenA sustainable synthesis method was developed for long-acting local anesthetics, ropivacaine and levobupivacaine, using both batch and continuous flow processes via asymmetric hydrogenation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00421C, Research ArticleCarina Mützel, Kazutaka Shoyama, Ana-Maria Krause, Frank WürthnerA doubly helical boron-doped polycyclic aromatic hydrocarbon was synthesized, which showed a low LUMO level, a high absorption coefficient and fluorescence (ΦF = 0.73), combined with a one-dimensional π–π stacking interaction in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Regio- and stereo-selective synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QO02078A, Research ArticleYunqing Zhuang, Jin Zhang, Kai Yang, Gehua Bi, Xin Huang, Weimin ZhangAn efficient and novel method for the direct synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00148F, Research ArticleDong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei XuThe challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00002A, Research ArticleShu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong LiuA chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00358F, Research ArticleShan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui ShaoChiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00305E, Research ArticleChen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong MaHerein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00171K, Research ArticleLi-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei WuA method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00265B, Research ArticleShuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping HuiAn efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00311J, Research ArticlePei-Ting Li, Zi-Fa Shi, Wei YuTwo triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Correction: Stereodivergent and enantioselective total syntheses of isochaetominines A–C and four pairs of isochaetominine C enantiomers: a six-step approach By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO90034K, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhong-Yi Mao, Hui Geng, Tian-Tian Zhang, Yuan-Ping Ruan, Jian-Liang Ye, Pei-Qiang HuangTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Visible-light-mediated catalyst-free synthesis of trifluoromethyl(spiro)-epoxides bearing contiguous quaternary centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00184B, Research ArticleJingchuan Lin, Yu Zhang, Jinxin Wang, Xinyu Han, Shenglan Zhu, Tong Li, Yanping Zhu, Wei-Dong ZhangHerein, we describe a non-covalent complex-mediated epoxidation strategy that can yield highly selective central spiro-epoxides by irradiation with visible light without the need for catalyst addition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2344-2350DOI: 10.1039/D3QO01955A, Research ArticleLinge Huai, Li Zhang, Zhentao Wang, Yewen FangN → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2171-2177DOI: 10.1039/D3QO02029K, Research ArticleRong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo HanAn asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Synthesis of benzothiophenes via sulfonium-[3,3]-rearrangement of aryl sulfoxides with allenenitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2208-2214DOI: 10.1039/D4QO00121D, Research ArticleLei Zhang, Kun Wan, Huanhuan Wang, Mengyao Wang, Ao Cui, Xin Huang, Bo PengA facile synthesis of benzothiophenes from readily available aryl sulfoxides and allenenitriles has been established through sulfonium-rearrangement triggered cyclization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Deoxygenation of N-heterocyclic N-oxides using isopropanol as a recyclable reductant By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2249-2268DOI: 10.1039/D4QO00208C, Research ArticleHo Kyeong Ryu, Yun Do Song, Jun Hee LeeAn organic photoredox-based recyclable strategy that facilitates the chemoselective deoxygenation of various functionalised N-heterocyclic N-oxides is presented.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si A formal (3 + 2) annulation–Cannizzaro cascade of bifunctional peroxides for the synthesis of dihydrofurans By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2215-2219DOI: 10.1039/D4QO00215F, Research ArticleYiwei Chen, Min Gao, Qianlan Xu, Jiumeng Zhang, Lin HuTunable tandem processes of bifunctional peroxides allow the divergent construction of functionalized dihydrofurans and epoxides by simply changing the basic conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2178-2181DOI: 10.1039/D4QO00269E, Research ArticleVojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, Guy BertrandChiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from L-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Visible light/copper catalysis enabled Heck-like coupling between alkenes and cyclic sulfonium salts via selective C–S bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2195-2200DOI: 10.1039/D3QO02009F, Research ArticleXianqin Liu, Xufeng Li, Linyuan Wang, Yongjia Shi, Jian Lv, Daoshan YangA Heck-like coupling of cyclic sulfonium salts with alkenes via selective C–S bond cleavage using a copper complex as a photosensitizer through a visible-light-driven redox-neutral process has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2313-2318DOI: 10.1039/D4QO00116H, Research ArticleZhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong XueThe selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Photo-induced catalyst-free formal carbon insertion of acylsilanes into B–B and B–Si bonds By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2339-2343DOI: 10.1039/D4QO00139G, Research ArticleXiongxiong Lu, Qingbin Zhao, Hao Zhang, Pan Xu, Xuenian Chen, Zhenxing LiuA formal carbon insertion of acylsilanes into B–B and B–Si bonds has been developed. The in situ formed siloxycarbene under blue LED irradiation worked as the intermediate for the reaction. When 2-furyl and 2-thiophenyl acylsilanes were used, the B(pin) ring was enlarged to a six-membered ring.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2269-2276DOI: 10.1039/D4QO00073K, Research ArticleYujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang LuTwo major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2231-2240DOI: 10.1039/D4QO00177J, Research ArticleRomain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas PoissonHerein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
si Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2241-2248DOI: 10.1039/D4QO00136B, Research ArticleXinyu Wang, Zhaobin WangWe present an approach involving Fe-catalyzed B–H and Si–H insertion of gem-dichloroalkanes. In contrast to previous strategies, our method uses gem-dihaloalkanes as non-stabilized carbene precursors and operates through a radical reaction pathway.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article