Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90181D, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Huiwu Yu, Xiangyou Li, Xiaoyan Zeng, Yongfeng Lu
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02107E, Communication

Jiaxing Wang, Beverly A Ellis, Bin Zhou, Lisa M. Eubanks, Steven Blake, Kim D Janda
A double conjugation strategy was implemented to produce an anti-fentanyl vaccine, which was predicated upon preformed-antibody-assisted antigen presentation. The new vaccine was found to reduce the psychoactive effects of fentanyl...
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Chem. Commun., 2020, 56,4922-4925
DOI: 10.1039/D0CC00513D, Communication

Zhongyan Wang, Chuanrui Ma, Yuna Shang, Lijun Yang, Jing Zhang, Cuihong Yang, Chunhua Ren, Jinjian Liu, Guanwei Fan, Jianfeng Liu
An ingenious co-assembled nanosystem based on fenofibrate and ketoprofen peptide for the dual-targeted treatment of NAFLD by reducing hepatic lipid accumulation and inflammatory responses.
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Chem. Commun., 2020, 56,4954-4957
DOI: 10.1039/D0CC00427H, Communication

Qingqing Zhao, Qizhou Liu, Chao Li, Lei Cao, Lei Ma, Xiyu Wang, Yuanli Cai
The noncovalent locking of nanostructured thermoresponsive polyion complexes can be achieved via polymerization-induced electrostatic self-assembly (PIESA) using an arginine-like cationic monomer.
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Chem. Commun., 2020, 56,4926-4929
DOI: 10.1039/D0CC01518K, Communication

Ji Bian, Jiannan Feng, Ziqing Zhang, Jiawen Sun, Mingna Chu, Ling Sun, Xin Li, Dongyan Tang, Liqiang Jing
Graphene-modulated ZnPc/BiVO₄ Z-scheme heterojunctions for efficient visible-light catalytic CO₂ conversion are achieved by increasing the optimized amount of highly dispersed ZnPc.
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Chem. Commun., 2020, 56,4934-4937
DOI: 10.1039/D0CC01220C, Communication

Gongyi Liu, Xianghe Zhang, Heng Wang, Hengjiang Cong, Xumu Zhang, Xiu-Qin Dong
Efficient Ni-catalyzed asymmetric hydrogenation of cyclic N-sulfonyl ketimino esters and ketimines was successfully developed to prepare a series of chiral α-monosubstituted α-amino acid derivatives and amine derivatives with excellent results.
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Chem. Commun., 2020, 56,4894-4897
DOI: 10.1039/D0CC01532F, Communication

Qi Wu, Xian Liu, Yeshuang Du, Chunlin Teng, Fei Liang
A first example of monovalent-metal-based hybrid halides [N(CH₃)₄]MCl₂ (M = Ga⁺, In⁺) with zero-dimensional configuration containing unprecedented linear [GaCl₂]/[InCl₂] units have been designed and synthesized.
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Chem. Commun., 2020, 56,4886-4889
DOI: 10.1039/D0CC00327A, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Jing Lai, Jun Zhang, Zuowei Li, Yao Xiao, Weibo Hua, Zhenguo Wu, Yanxiao Chen, Yanjun Zhong, Wei Xiang, Xiaodong Guo
A splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO₂ electrode, was discovered in the LiNi_0.85Co_0.10Mn_0.05O₂ at high-voltage region (>4.6 V) by in situ high-resolution synchrotron radiation diffraction.
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Chem. Commun., 2020, 56,4898-4901
DOI: 10.1039/D0CC00895H, Communication

Danke Chen, Zhuoyi Li, Yu Zhou, Xu Ma, Hanqing Lin, Wen Ying, Xinsheng Peng
N-Doped mesoporous carbon catalysts dispersed with Fe₃Pt intermetallic nanoparticles, exhibiting excellent ORR performance, were synthesised by direct pyrolysis of Pt–Fe co-functionalized ZIF-8.
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Chem. Commun., 2020, 56,4906-4909
DOI: 10.1039/D0CC00548G, Communication

Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
Ligand-based successive reductions in a heteroleptic Cr(III) complex give rise to intended extremely strong metal–radical magnetic interactions.
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Chem. Commun., 2020, 56,4902-4905
DOI: 10.1039/D0CC01374A, Communication

Dominik Kurzydłowski, Serhiy Kobyakov, Zoran Mazej, Sharad Babu Pillai, Brahmananda Chakraborty, Prafulla K. Jha
Raman scattering measurements and DFT calculations indicate that solid AuF₃ adopts a metastable cis-bridge structure upon room-temperature compression.
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Chem. Commun., 2020, 56,4918-4921
DOI: 10.1039/D0CC00274G, Communication

Xiaodong Xin, Lihui Wang, Kaiwei Wang, Lizhi Dai, Hai Cao, Zheng Li, Ye Tian
We propose two strategies to construct nanoclusters efficiently with explicit positions of nanoparticles by the surface-encoded method.
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Chem. Commun., 2020, 56,4950-4953
DOI: 10.1039/D0CC01174F, Communication

Samuel Lim, Jiwoo Kim, Yujin Kim, Dawei Xu, Douglas S. Clark
We describe a versatile CRISPR/Cas-based strategy to construct precisely organized, scaffolded multi-enzyme systems with improved productivity.
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Chem. Commun., 2020, 56,4938-4941
DOI: 10.1039/D0CC01002B, Communication

Robert T. Woodward
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes.
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Chem. Commun., 2020, 56,4914-4917
DOI: 10.1039/D0CC01456G, Communication

Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi S. Datta, Kibret A. Messalea, Bao Yue Zhang, Muhammad Waqas Khan, Aaron Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke
The library of two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Liquid metal-based synthesis provides a new approach to overcome this limitation.
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Chem. Commun., 2020, 56,4878-4881
DOI: 10.1039/D0CC01162B, Communication

Kazuki Yoshii, Noboru Taguchi, Takeshi Miyazaki, Masahiro Shikano, Hikari Sakaebe
A designed two-compartment cell revealed the degradation mechanism and an essentially effective additive for the FeF₃ composite electrode.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication

Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from Pd^IV to Au^I, which allows subsequent reductive elimination of LAuI at Pd and Au.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication

Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication

Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication

Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02001J, Feature Article

Kui Yang, Zhihua Zhang, Jie Du, Wei Li, Zhichao Pei
Owing to its spatiotemporal selectivity and noninvasive nature, photodynamic therapy (PDT) has become a promising approach for the treatment of cancer. However, the non-targeting capability and the accompanying side effects...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication

Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01164A, Communication

Changjin Ou, Yewei Zhang, Wei Ge, Liping Zhong, Yong Huang, Weili Si, Wenjun Wang, Yongxiang Zhao, Xiaochen Dong
3D boron dipyrromethene (BODIPY)–Fe(III) coordination polymer nanoparticles with NIR-II absorption were developed as photothermal and chemodynamic agent to effectively kill cancer cells.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01505A, Communication

Jian-Xin Wang, Yi-Shuai Yu, Li-Ya Niu, Bo Zou, Kai Wang, Qing-Zheng Yang
Difluoroboron β-diketonate complexes that manifested temperature-dependent emission wavelength are reported.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication

Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01930E, Communication

Yanfei Qin, Lingjing Chen, Gui Chen, Zhenguo Guo, Lei Wang, Hongbo Fan, Marc Robert, Tai-Chu Lau
[Fe(qnpy)(H₂O)₂]²⁺ is a highly efficient and robust catalyst for visible-light-driven reduction of CO₂ to CO, with a TON for CO of up to 14 095 and selectivity of 98% using Ru(phen)₃Cl₂ as photosensitizer and BIH as sacrificial reductant.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication

Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication

Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01936D, Communication

Yunfei Fan, Yahang Xie, Zhen Zhao, Yang Zhao, Rui Yu, Xiang-yang Liu, Youhui Lin, Changxu Lin
A wettability read-out strategy for an aptasensor is setup with a bilayer surface. It targets on methamphetamine and uses hydrophobicity reduction as the signal induced by recognition by the supporting aptamer layer.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02550J, Communication

Hao Zeng, Chuanle Zhu, Chi Liu, Yingying Cai, Fulin Chen, Huanfeng Jiang
The three component hydroxyletherification and hydroxylazidation reactions of (trifluoromethyl)alkenes are reported, providing various useful α-trifluoromethyl β-heteroatom substituted tertiary alcohols in high yields.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01951H, Communication

Lu Sun, Qiao Zhao, Xinli Liu, Yongchun Pan, Yanfeng Gao, Jingjing Yang, Yuzhen Wang, Yujun Song
Here, we propose an amplification strategy of enzyme-mimicking accelerated signal enhancement integrated with triple-channel volumetric bar-chart chip for visually multiplexed quantitation of telomerase activity. This platform was used for evaluating...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication

Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication

Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication

Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09589F, Communication

Pei-Qin Liao, Ningyu Huang, Hai He, Hao Li, Xiao-Ming Chen
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic...
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Chem. Commun., 2020, 56,4994-4997
DOI: 10.1039/D0CC00011F, Communication

Jonathan A. Kephart, Zachary Hecht, Brooke N. Livesay, Indrani Bhowmick, Matthew P. Shores, V. Codrina Popescu, Navamoney Arulsamy, Elliott B. Hulley
Aerobic oxidation of (tmeda)Fe(CH₂^tBu)₂ in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe₉O₆ subunit and bearing organometallic and diamine ligands.
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Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication

Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication

Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication

Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication

Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Chem. Commun., 2020, 56,5042-5045
DOI: 10.1039/D0CC01219J, Communication

Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.
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Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication

Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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Chem. Commun., 2020, 56,5034-5037
DOI: 10.1039/D0CC01796E, Communication

Fatimat O. Badmus, Joshua A. Malone, Frank R. Fronczek, Rendy Kartika
An expedient synthesis of highly substituted tetrahydrobenzofuran via an unsymmetrical silyloxyallyl cation is reported.
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Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication

Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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