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Small Industries Development Bank of India

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Economic Development Agency

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Moti Bagh Metro Station

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Bihar Medical Services & Infrastructure Corporation

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Project Investment

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Construction Equipment

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Facile fabrication of a hybrid polymer electrolyte via initiator-free thiol–ene photopolymerization for high-performance all-solid-state lithium metal batteries

Polym. Chem., 2020, 11,2732-2739
DOI: 10.1039/D0PY00203H, Paper
Cai Zuo, Binghua Zhou, Ye Hyang Jo, Sibo Li, Gong Chen, Shaoqiao Li, Wen Luo, Dan He, Xingping Zhou, Zhigang Xue
The article reports the facile fabrication of a solid polymer electrolyte via initiator-free thiol–ene photopolymerization for all-solid-state lithium metal batteries.
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A polymerization-induced self-assembly process for all-styrenic nano-objects using the living anionic polymerization mechanism

Polym. Chem., 2020, 11,2635-2639
DOI: 10.1039/D0PY00296H, Communication
Chengcheng Zhou, Jian Wang, Peng Zhou, Guowei Wang
By combination of the living anionic polymerization (LAP) mechanism with the polymerization-induced self-assembly (PISA) technique, the all-styrenic diblock copolymer poly(p-tert-butylstyrene)-b-polystyrene (PtBS-b-PS) based LAP PISA was successfully developed.
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Tin(II) 2-ethylhexanoate catalysed methanolysis of end-of-life poly(lactide)

Polym. Chem., 2020, 11,2625-2629
DOI: 10.1039/D0PY00292E, Communication
Melanie Hofmann, Christoph Alberti, Felix Scheliga, Roderich R. R. Meißner, Stephan Enthaler
The depolymerisation of end-of-life poly(lactide) (PLA) goods was studied as part of the chemical recycling of PLA.
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Correction: Dynamic covalent polymer networks via combined nitroxide exchange reaction and nitroxide mediated polymerization

Polym. Chem., 2020, 11,2761-2761
DOI: 10.1039/D0PY90053B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yixuan Jia, Yannick Matt, Qi An, Isabelle Wessely, Hatice Mutlu, Patrick Theato, Stefan Bräse, Audrey Llevot, Manuel Tsotsalas
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Correction: Block copolymer hierarchical structures from the interplay of multiple assembly pathways

Polym. Chem., 2020, 11,2762-2762
DOI: 10.1039/D0PY90057E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessandro Ianiro, Meng Chi, Marco M. R. M. Hendrix, Ali Vala Koç, E. Deniz Eren, Michael Sztucki, Andrei V. Petukhov, Gijsbertus de With, A. Catarina C. Esteves, Remco Tuinier
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Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00369G, Paper
Xun Zhang, Siping Hu, Qiang Ma, Saihu Liao
A visible light-regulated ring-opening polymerization of lactones has been developed based on the excited state acidity of ESPT molecules.
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Synthesis of star-shaped polyzwitterions with adjustable UCST and fast responsiveness by a facile RAFT polymerization

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00318B, Paper
Zhi Li, Hao Li, Zhonghe Sun, Botao Hao, Tung-Chun Lee, Anchao Feng, Liqun Zhang, San H. Thang
We describe crosslinking of polyzwitterions for the formation of novel star-shaped polymers with low polydispersities and dual-responsiveness using RAFT polymerization.
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Turning natural δ-lactones to thermodynamically stable polymers with triggered recyclability

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00270D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Linnea Cederholm, Peter Olsén, Minna Hakkarainen, Karin Odelius
Extending the use of natural δ-lactones in circular materials via a synthetic strategy yielding thermodynamically stable polyesters with triggered recyclability.
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Highly elastic, strong, and reprocessable cross-linked polyolefin elastomers enabled by boronic ester bonds

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00235F, Paper
Fei Yang, Li Pan, Zhe Ma, Yahui Lou, Yuanyuan Li, Yuesheng Li
Despite the development of new catalysts and synthetic strategies to prepare polyolefin elastomers (POEs), less progress has been made in balancing their elastomeric properties with processability and resistance to heat and solvents.
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Photo-controlled RAFT polymerization mediated by organic/inorganic hybrid photoredox catalysts: enhanced catalytic efficiency

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00171F, Paper
Wulong Wang, Sheng Zhong, Guicheng Wang, Hongliang Cao, Yun Gao, Weian Zhang
Photo-controlled RAFT polymerization mediated by an organic/inorganic hybrid photoredox catalyst (ZnTPP–POSS) was performed and showed enhanced catalytic efficiency compared with the ZnTPP photocatalyst.
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Poly(hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00088D, Review Article
Elena Gabirondo, Ainara Sangroniz, Agustin Etxeberria, Sergio Torres-Giner, Haritz Sardon
Poly(hydroxy acids) derived from the self-condensation of hydroxy acid are biodegradable and can be fully recycled in a Circular Economy approach.
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Cross-linker control of vitrimer flow

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00233J, Paper
Bassil M. El-Zaatari, Jacob S. A. Ishibashi, Julia A. Kalow
The rate of stress relaxation in a vitrimer can be modulated by changing solely the structure of the cross-linker electrophile.
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Miniemulsion polymerization of styrene using carboxylated graphene quantum dots as surfactant

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00404A, Paper
Le N. M. Dinh, Lakshmi N. Ramana, Vipul Agarwal, Per B. Zetterlund
Carboxylated graphene quantum dots (cGQDs) were synthesized from dextrose and sulfuric acid via a hydrothermal process, and subsequently used as sole surfactant in miniemulsion polymerization of styrene.
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Using the dynamic behavior of macrocyclic monomers with a bis(hindered amino)disulfide linker for the preparation of end-functionalized polymers

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00366B, Paper
Hirogi Yokochi, Rikito Takashima, Daisuke Aoki, Hideyuki Otsuka
End-functionalized polymers were synthesized by simply heating a mixture of a macrocyclic compound with one bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) moiety and bifunctional acyclic BiTEMPS compounds as sources of repeat units and terminal groups, respectively.
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Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00249F, Communication
Zhonghua Cheng, Lei Wang, Yan He, Xingjia Chen, Xiaojun Wu, Hangxun Xu, Yaozu Liao, Meifang Zhu
A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts.
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Synthesis of acrylamide-based block-copolymer brushes under flow: monitoring real-time growth and surface restructuring upon drying

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00219D, Paper
Open Access
Joydeb Mandal, Andrea Arcifa, Nicholas D. Spencer
Block-copolymer brushes of water-soluble acrylamides have been synthesised by SI-ATRP under continuous flow and their growth monitored in situ by means of a quartz-crystal microbalance with dissipation (QCM-D).
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Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00174K, Paper
Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai, Bao-Tsan Ko
Catalyst 1 was reported for the first time to be effective for nickel-catalyzed CO2/CHO copolymerization at 1 atm CO2 pressure.
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Enhanced thermomechanical property of a self-healing polymer via self-assembly of a reversibly cross-linkable block copolymer

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00310G, Paper
Hyang Moo Lee, Suguna Perumal, Gi Young Kim, Jin Chul Kim, Young-Ryul Kim, Minsoo P. Kim, Hyunhyup Ko, Yecheol Rho, In Woo Cheong
Introduction of a self-healable block copolymer increases the mechanical property whilst maintaining self-healing efficiency.
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Smart functionalized phosphonic acid based copolymers: new structures for old purposes

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00337A, Paper
Xavier Solimando, Yohann Catel, Norbert Moszner, Jean-Jacques Robin, Sophie Monge
Innovative well-defined acidic photopolymerizable phosphorus-based copolymers were prepared and tested in well-known dental applications to improve the adhesion of dental self-etch adhesives (SEAs).
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A general method to greatly enhance ultrasound-responsiveness for common polymeric assemblies

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00254B, Paper
Jinkang Dou, Ruiqi Yang, Kun Du, Li Jiang, Xiayun Huang, Daoyong Chen
Ultrasound-controlled drug release is a very promising technique for controlled drug delivery due to the unique advantages of ultrasound as the stimulus.
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Pillar[5]arene-based self-assembled linear supramolecular polymer driven by guest halogen–halogen interactions in solid and solution states

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00327A, Paper
Talal F. Al-Azemi, Mickey Vinodh
A pillar[5]arene-based linear supramolecular polymer mediated by guest halogen–halogen interactions (C–Br⋯Br–C) was studied in both the solution and solid states.
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Hydrogen-bonded supramolecular micelle-mediated drug delivery enhances the efficacy and safety of cancer chemotherapy

Polym. Chem., 2020, 11,2791-2798
DOI: 10.1039/D0PY00082E, Paper
Chih-Chia Cheng, Ya-Ting Sun, Ai-Wei Lee, Shan-You Huang, Wen-Lu Fan, Yu-Hsuan Chiao, Chih-Wei Chiu, Juin-Yih Lai
Multiple hydrogen-bonded supramolecular polymers tend to form stable spherical micelles with oppositely charged anticancer drugs in biological environments, which improves cellular drug uptake and more effectively induces apoptosis in cancer cells.
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Temporal control of RAFT polymerization via magnetic catalysis

Polym. Chem., 2020, 11,2838-2846
DOI: 10.1039/D0PY00220H, Paper
Amin Reyhani, Omid Mazaheri, Masood S. Alivand, Kathryn A. Mumford, Greg Qiao
Magnetic core–shell structured Fe3O4@Fe(II)–MOF nanoparticles have enabled the temporal control of RAFT polymerization via an “on–off” process.
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Polymerization of dopamine accompanying its coupling to induce self-assembly of block copolymer and application in drug delivery

Polym. Chem., 2020, 11,2811-2821
DOI: 10.1039/D0PY00085J, Paper
Yudian Qiu, Zongyuan Zhu, Yalei Miao, Panke Zhang, Xu Jia, Zhongyi Liu, Xubo Zhao
The polymerization of dopamine and its coupling occur in succession, which synergistically induces the self-assembly of block copolymer to yield ordered structures, including micelles and vesicles.
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Mussel-inspired coordination functional polymer brushes-decorated rGO-stabilized silver nanoparticles composite for antibacterial application

Polym. Chem., 2020, 11,2822-2830
DOI: 10.1039/D0PY00180E, Paper
Shengnan Zhou, Haixun Ji, Linjing Liu, Sijia Feng, Yuqin Fu, Yu Yang, Changli Lü
A catechol-terminated coordination functional polymer-modified rGO supported AgNPs composite was fabricated. Grafted polymer brushes improve the material's hydrophilicity and dispersion stability of AgNPs on rGO, enhancing antibacterial activity.
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Simple improvements to Gilch synthesis and molecular weight modulation of MEH-PPV

Polym. Chem., 2020, 11,2831-2837
DOI: 10.1039/D0PY00072H, Paper
Riley O'shea, Wallace W. H. Wong
The solvent and temperature used in the Gilch synthesis of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) were varied to achieve an improved set of reaction conditions.
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Vesicular assemblies of thermoresponsive amphiphilic polypeptide copolymers for guest encapsulation and release

Polym. Chem., 2020, 11,2889-2903
DOI: 10.1039/D0PY00135J, Paper
Mahammad Anas, Somdeb Jana, Tarun K. Mandal
Thermoresponsive amphiphilic polypeptide copolymers are synthesized via different polymerization techniques for their self-assembly into vesicular aggregates for guest encapsulation and release.
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Self-supported rhodium catalysts based on a microporous metal–organic framework for polymerization of phenylacetylene and its derivatives

Polym. Chem., 2020, 11,2904-2913
DOI: 10.1039/D0PY00170H, Paper
Li Zhang, Qingbin Cao, Fei Gao, Yuping Dong, Xiaofang Li
Highly efficient, cis-selective, stable, recyclable and reusable heterogeneous single-site MOF-supported rhodium catalysts polymerize PA and its derivatives, producing cis-transoidal PPAs and their functional derivatives having a helical configuration or AIE properties.
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Synthesis of a side-chain hole transporting polymer through Mitsunobu post-functionalization for efficient inverted perovskite solar cells

Polym. Chem., 2020, 11,2883-2888
DOI: 10.1039/D0PY00134A, Paper
Liuyuan Lan, Xiang Deng, Jie Zhang, Jingdong Luo, Alex K.-Y. Jen
Mitsunobu post-functionalization was utilized to construct a new efficient dopant-free side-chain hole transporting polymer for inverted perovskite solar cells, exhibiting a power conversion efficiency of 17.75% and a high fill factor over 81%.
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Synthesis of biscarboxylic acid functionalised EDTA mimicking polymers and their ability to form Zr(IV) chelation mediated nanostructures

Polym. Chem., 2020, 11,2799-2810
DOI: 10.1039/D0PY00304B, Paper
Meike N. Leiske, Julia A. Walker, Aadarash Zia, Nicholas L. Fletcher, Kristofer J. Thurecht, Thomas P. Davis, Kristian Kempe
We present a new biscarboxylic acid acrylate, which is used for the synthesis of double hydrophilic EDTA-mimicking block copolymers capable of self-assembly upon zirconium complexation.
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Well-controlled polymerization of tri-vinyl dynamic covalent boroxine monomer: one dynamic covalent boroxine moiety toward a tunable penta-responsive polymer

Polym. Chem., 2020, 11,2914-2922
DOI: 10.1039/D0PY00401D, Paper
Shun-Shun Li, Xin-Hu Lv, Xiao-Li Sun, Wen-Ming Wan, Hongli Bao
Attributed to dynamic characteristics of dynamic covalent boroxine, well-controlled polymerization of tri-vinyl monomer and molecular design of penta-responsive polymer with only one functional moiety are achieved.
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A high performance phenyl-free LED photoinitiator for cationic or hybrid photopolymerization and its application in LED cationic 3D printing

Polym. Chem., 2020, 11,2855-2863
DOI: 10.1039/D0PY00142B, Paper
Liqun Tang, Jun Nie, Xiaoqun Zhu
In this work, a high performance LED photoinitiator, 1,3-bis(1-methyl-1H-pyrrol-2-yl)prop-2-en-1-one (BMO), without a benzene ring was synthesized through a one-step aldehyde–ketone condensation reaction.
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Tuning polymer properties of non-covalent crosslinked PDMS by varying supramolecular interaction strength

Polym. Chem., 2020, 11,2847-2854
DOI: 10.1039/D0PY00139B, Paper
Open Access
Brigitte A. G. Lamers, Marcin L. Ślęczkowski, Fabian Wouters, Tom A. P. Engels, E. W. Meijer, Anja R. A. Palmans
Linear polydimethylsiloxane (PDMS) is crosslinked by supramolecular grafts to obtain materials with strikingly different mechanical properties by tuning the strength of the non-covalent interactions.
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Thermally triggerable, anchoring block copolymers for use in aqueous inkjet printing

Polym. Chem., 2020, 11,2869-2882
DOI: 10.1039/D0PY00244E, Paper
George E. Parkes, Helena J. Hutchins-Crawford, Claire Bourdin, Stuart Reynolds, Laura J. Leslie, Matthew J. Derry, Josephine L. Harries, Paul D. Topham
Towards the goal of shifting from toxic organic solvents to aqueous-based formulations in commercial inkjet printing, a series of well-defined amphiphilic block copolymers have been synthesized via RAFT polymerization.
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Mechanical activation of polymers containing two adjacent mechanophores

Polym. Chem., 2020, 11,2864-2868
DOI: 10.1039/D0PY00279H, Paper
Richard Stevenson, Min Zhang, Guillaume De Bo
Polymers containing two adjacent mechanophores cleave at the same as a single-mechanophore chains.
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Biosignal-responsive polymer nanorods that specifically recognize hydrogen polysulfide (H2Sn) from reactive sulfur species

Polym. Chem., 2020, 11,2781-2785
DOI: 10.1039/D0PY00360C, Communication
Xi Liu, Wei Sang, Kunbing Ouyang, Qiang Yan
We report a new block copolymer bearing p-fluoronitrobenzoate (FNB) pendants that is capable of responding to the H2Sn biosignal in an extraordinarily selective and sensitive manner.
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Incorporating trifunctional 1,6-heptadiyne moiety into polyacetylene ionomer for improving its physical and conductive properties

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00109K, Paper
Hongfei Li, Hengchen Zhang, Xiaojuan Liao, Ruyi Sun, Meiran Xie
A trifunctional diyne comonomer can regulate the structure and optimize the physical state of polyacetylene ionomers, which exhibit a high ionic conductivity of 2.6 × 10−5–1.0 × 10−3 S cm−1 at 30 °C.
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