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Near-infrared electron acceptors with fused nonacyclic molecular backbones for nonfullerene organic solar cells

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00754G, Research Article
Jianquan Zhang, Yunke Li, Zhengxing Peng, Fujin Bai, Lik-Kuen Ma, Harald Ade, Zhengke Li, He Yan
Two strong electron-donating moieties were fused into the molecular backbone of small molecular acceptors showing dramatically extended absorption beyond 900 nm.
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Efficient near-infrared photosensitizer with aggregation-induced emission characteristics for mitochondria-targeted and image-guided photodynamic cancer therapy

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00170H, Research Article
Hanxiao Yang, Jiabao Zhuang, Nan Li, Yue Li, Shiyu Zhu, Jiaxin Hao, Jiayao Xin, Na Zhao
A highly efficient near-infrared photosensitizer with aggregation-induced emission characteristics was developed for mitochondria-targeted and image-guided photodynamic cancer therapy.
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Oxygen Vacancy Induced Superior Visible-light-driven Photo-catalytic Performance in BiOCl Homojunction

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00187B, Research Article
Si-Ying Niu, Ruoyu Zhang, Chongfeng Guo
The photocatalytic performance of semiconductor can be enhanced by expanding the spectral response and accelerating the photo-induced charge separation. Introduction of oxygen vacancies and construction of homo-junction in BiOCl were...
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Each phenyl group performs its own functions on luminescence: phenyl substituted effect in tetraphenylpyrazine

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00098A, Research Article
Haozhong Wu, Xiaojuan Song, Bing Zhang, Zhiming Wang, Tian Zhang, Anjun Qin, Ben Zhong Tang
Three phenyl groups of TPP derivatives affect the luminescence process in various modes. TPPs show AIE thanks to the ortho substituted groups, while meta and para groups can modulate their luminescence in different extents.
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Lithium bis(oxalate)borate additive in electrolyte to improve Li-rich layered oxide cathode materials

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00094A, Research Article
Zi Xiao, Jiuding Liu, Guilan Fan, Meng Yu, Junxiang Liu, Xinglong Gou, Mingjian Yuan, Fangyi Cheng
Lithium-rich layered oxides (LLO), as the most attractive cathode materials for high-energy lithium-ion batteries (LIBs), are plagued by poor cyclability due to structural and electrode/electrolyte interface instability. Herein, we report...
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Advanced functional polymer materials

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00025F, Review Article
Kaojin Wang, Kamran Amin, Zesheng An, Zhengxu Cai, Hong Chen, Hongzheng Chen, Yuping Dong, Xiao Feng, Weiqiang Fu, Jiabao Gu, Yanchun Han, Doudou Hu, Rongrong Hu, Die Huang, Fei Huang, Feihe Huang, Yuzhang Huang, Jian Jin, Xin Jin, Qianqian Li, Tengfei Li, Zhen Li, Zhibo Li, Jiangang Liu, Jing Liu, Shiyong Liu, Huisheng Peng, Anjun Qin, Xin Qing, Youqing Shen, Jianbing Shi, Xuemei Sun, Bin Tong, Bo Wang, Hu Wang, Lixiang Wang, Shu Wang, Zhixiang Wei, Tao Xie, Chunye Xu, Huaping Xu, Zhi-Kang Xu, Bai Yang, Yanlei Yu, Xuan Zeng, Xiaowei Zhan, Guangzhao Zhang, Jie Zhang, Ming Qiu Zhang, Xian-Zheng Zhang, Xiao Zhang, Yi Zhang, Yuanyuan Zhang, Changsheng Zhao, Weifeng Zhao, Yongfeng Zhou, Zhuxian Zhou, Jintao Zhu, Xinyuan Zhu, Ben Zhong Tang
This review presents the recent developments in the research hotspots of advanced functional polymers; their concepts, design strategies, and applications are briefly discussed.
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Single-crystalline CoFe nanoparticles encapsulated in N-doped carbon nanotubes as a bifunctional catalyst for water splitting

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00126K, Research Article
Xiaojun Zeng, Myeong Je Jang, Sung Mook Choi, Hyun-Seok Cho, Chang-Hee Kim, Nosang Vincent Myung, Yadong Yin
We utilize a simple heat-treatment process to synthesize single-crystalline CoFe alloy nanoparticles encapsulated in N-doped carbon nanotubes, which exhibit excellent catalytic activity and superior stability towards overall water splitting.
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Electrical stability study of polymer-based organic transistors in ambient air using an active semiconducting/insulating polyblend-based pseudo-bilayer

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00048E, Research Article
Bo-Ren Lin, Horng-Long Cheng, Hung-Han Lin, Fu-Chiao Wu, Jia-Hui Lin, Wei-Yang Chou, Jrjeng Ruan, Yu-Wu Wang
Polymeric transistors with unexpected nondecaying features even in ambient air are fabricated based on a P3HT/PMMA pseudo-bilayer with microphase separation morphology.
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Polydopamine sacrificial layer mediated SiOx/C@C yolk@shell structure for durable lithium storage

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00120A, Research Article
Yuanyuan Zhang, Guangwu Hu, Qiang Yu, Zhenhui Liu, Chang Yu, Longsheng Wu, Liang Zhou, Liqiang Mai
Yolk@shell structured SiOx/C@C has been constructed through a polydopamine sacrificial layer mediated strategy, and the SiOx/C@C displays high specific capacity and durable cyclability in lithium storage.
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Aromatic imide/amide-based organic small-molecule emitters for organic light-emitting diodes

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00084A, Review Article
Yuanyuan Qin, Guoping Li, Ting Qi, Hui Huang
Aromatic imide/amide-based organic small molecules as emitters in organic light-emitting diodes have caught increasing attention. This study summarized their advances in terms of device performance and molecular design rules over the past 20 years.
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Intentional modification of the optical spectral response and relative sensitivity of luminescent thermometers based on Fe3+,Cr3+,Nd3+ co-doped garnet nanocrystals by crystal field strength optimization

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00097C, Research Article
K. Kniec, K. Ledwa, K. Maciejewska, L. Marciniak
The relative sensitivity and usable temperature range of Fe3+,Cr3+-based luminescent thermometers can be tuned by modification of the crystal field strength.
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AIEgen based polymorphs with solvent regulated crystal-to-crystal switch properties

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00154F, Research Article
Liming Lai, Bing Fang, Wenyu Cheng, Pengyu Li, Yantu Zhang, Meizhen Yin
An AIEgen with tunable polymorphism-dependent emission and solvent regulated crystal-to-crystal switch properties is reported. Our study has provided insight into the relationship between molecular stacking and emission properties.
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Fluoro-alkyl substituted isothianaphthene bisimides as stable n-type semiconductors

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00137F, Research Article
Xiaolong Chen, Dongwei Zhang, Yaowu He, Muhammad Umair Ali, Yuting Wu, Changbin Zhao, Peiheng Wu, Chaoyi Yan, Fred Wudl, Hong Meng
Two fluoro-alkyl substituted isothianaphthene bisimide materials with high solubility and their applications in stable n-type OTFTs are demonstrated.
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Chain-Length Effect on Binary Superlattices of Polymer-Tethered Nanoparticles

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00194E, Research Article
Ke Wang, Fan Li, Seon-Mi Jin, Kui Wang, Di Tian, Mubashir Hussain, Jiangping Xu, Lianbin Zhang, Yonggui Liao, Eunji Lee, Gi Yi, Xiaolin Xie, Jintao Zhu
Binary inorganic nanoparticles (NPs) can be assembled into various types of superlattices depending on the size ratio, shape, and interparticle potential, which may tailor mechanical, optical and electronic properties. Here,...
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Zeolite-confined carbon dots: tuning thermally activated delayed fluorescence emission via energy transfer

Mater. Chem. Front., 2020, 4,1404-1410
DOI: 10.1039/C9QM00549H, Research Article
Hongyue Zhang, Jiancong Liu, Bolun Wang, Kaikai Liu, Guangrui Chen, Xiaowei Yu, Jiyang Li, Jihong Yu
CD@zeolite composites with tunable TADF emission via an energy transfer process between confined CDs.
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The application of hollow micro-/nanostructured cathodes for sodium-ion batteries

Mater. Chem. Front., 2020, 4,1289-1303
DOI: 10.1039/C9QM00674E, Chemistry Frontiers
Xiao-Hao Liu, Wei-Hong Lai, Shu-Lei Chou
This work will open a new view for the design of hollow micro-/nanostructures used as cathodes for sodium-ion batteries, enclosing the superiority of this unique structure to enhance the electrochemical performance.
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Nitro-graphene oxide in iridium oxide hybrids: electrochemical modulation of N-graphene redox states and charge capacities

Mater. Chem. Front., 2020, 4,1421-1433
DOI: 10.1039/C9QM00752K, Research Article
Open Access
E. Pérez, N. M. Carretero, S. Sandoval, A. Fuertes, G. Tobias, N. Casañ-Pastor
Electrochemical modulation of N-graphene oxide in IrOx hybrids results in an oxidizing range of graphenes and large charge capacities.
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The origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: excimers or a photochemical reaction?

Mater. Chem. Front., 2020, 4,1411-1420
DOI: 10.1039/C9QM00737G, Research Article
Jin Liu, Jianai Chen, Yujie Dong, Yue Yu, Shitong Zhang, Jianli Wang, Qingbao Song, Weijun Li, Cheng Zhang
Revealing the actual origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: is the photochemical reaction rather than the excimers.
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Chemically modified nucleic acid biopolymers used in biosensing

Mater. Chem. Front., 2020, 4,1315-1327
DOI: 10.1039/D0QM00026D, Review Article
Lei Zhang, Yanbing Yang, Jie Tan, Quan Yuan
This review describes the applications of chemically modified nucleic acid biopolymers in biosensing, and mainly introduces different assembly methods of chemically modified nucleic acid biopolymers.
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Blue quantum dot-based electroluminescent light-emitting diodes

Mater. Chem. Front., 2020, 4,1340-1365
DOI: 10.1039/D0QM00029A, Review Article
Fei Chen, Qingli Lin, Huaibin Shen, Aiwei Tang
This review about the development of blue QD-LEDs will provide the reference to demonstrate the excellent blue devices.
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NH4V3O8·0.5H2O nanobelts with intercalated water molecules as a high performance zinc ion battery cathode

Mater. Chem. Front., 2020, 4,1434-1443
DOI: 10.1039/D0QM00051E, Research Article
Hanmei Jiang, Yifu Zhang, Zhenghui Pan, Lei Xu, Jiqi Zheng, Zhanming Gao, Tao Hu, Changgong Meng, John Wang
NH4V3O8·0.5H2O nanobelts are synthesized by a low-temperature hydrothermal process, and exhibit high electrochemical performance in ARZIBs.
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A zinc non-halide dopant strategy enables efficient perovskite CsPbI3 quantum dot-based light-emitting diodes

Mater. Chem. Front., 2020, 4,1444-1453
DOI: 10.1039/C9QM00734B, Research Article
Jinhang Li, Jiawei Chen, Leimeng Xu, Sinan Liu, Si Lan, Xiansheng Li, Jizhong Song
A zinc non-halide dopant strategy is employed to clarify the internal mechanism of Zn2+ doping without the introduction of halide ions and enhance the emission properties evidenced by the EQE of the QLEDs from 7.5% to 14.6% after Zn2+ doping.
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Modulation of ligand conjugation for efficient FAPbBr3 based green light-emitting diodes

Mater. Chem. Front., 2020, 4,1383-1389
DOI: 10.1039/C9QM00768G, Research Article
Feng Zhang, Mengna Sun, Xiyu Luo, Dongdong Zhang, Lian Duan
We put forward a new strategy for efficient PeLEDs by understanding the effect of ligand conjugation on device performance.
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Fused-ring phenazine building blocks for efficient copolymer donors

Mater. Chem. Front., 2020, 4,1454-1458
DOI: 10.1039/D0QM00080A, Research Article
Wenting Li, Qishi Liu, Ke Jin, Ming Cheng, Feng Hao, Wu-Qiang Wu, Shengjian Liu, Zuo Xiao, Shangfeng Yang, Shengwei Shi, Liming Ding
Phenazine copolymer donors demonstrate an efficiency of 15.14% in nonfullerene organic solar cells.
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Sandwich structured dielectrics for air-stable and flexible low-voltage organic transistors in ultrasensitive pressure sensing

Mater. Chem. Front., 2020, 4,1459-1470
DOI: 10.1039/D0QM00062K, Research Article
Yue Jiang, Ziyang Liu, Zhigang Yin, Qingdong Zheng
A novel type of polymer sandwich dielectric is developed for air-stable, hysteresis-free and flexible OTFTs which can be used for low-power pressure sensors with ultrahigh sensitivity, wide detection range and fast response.
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A turn-off fluorescent probe for the detection of Cu2+ based on a tetraphenylethylene-functionalized salicylaldehyde Schiff-base

Mater. Chem. Front., 2020, 4,1500-1506
DOI: 10.1039/C9QM00759H, Research Article
Hai-Fang Xie, Chang-Jin Yu, Ya-Li Huang, Hong Xu, Qi-Long Zhang, Xiao-Hong Sun, Xing Feng, Carl Redshaw
A tetraphenylethylene-functionalized salicylaldehyde Schiff-base fluorescent probe (TPE-An-Py) with aggregation-induced enhanced emission (AIEE) characteristics exhibited high sensitivity towards copper(II) ions in aqueous media with a “turn-off” fluorescence mechanism; limit of detection is 2.36 × 10−7 mol L−1.
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Multiring-induced multicolour emission: hyperbranched polysiloxane with silicon bridge for data encryption

Mater. Chem. Front., 2020, 4,1375-1382
DOI: 10.1039/D0QM00075B, Research Article
Yuanbo Feng, Hongxia Yan, Fan Ding, Tian Bai, Yufeng Nie, Yan Zhao, Weixu Feng, Ben Zhong Tang
The presented work shows an impressive multicolour luminescence hyperbranched polysiloxane attributed to the multiring through-space conjugation named “multiring induced multicolor emission” (MIE), as well as its application in data encryption.
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The role of dipole moment in two fused-ring electron acceptor and one polymer donor based ternary organic solar cells

Mater. Chem. Front., 2020, 4,1507-1518
DOI: 10.1039/D0QM00016G, Research Article
Xunfan Liao, Yongjie Cui, Xueliang Shi, Zhaoyang Yao, Heng Zhao, Yongkang An, Peipei Zhu, Yaxiao Guo, Xiang Fei, Lijian Zuo, Ke Gao, Francis Lin, Qian Xie, Lie Chen, Wei Ma, Yiwang Chen, Alex K.-Y. Jen
The dipole moment of FREAs’ terminals has been unveiled as an important factor and its working mechanism has been thoroughly investigated. Our results demonstrate that the dipole moment should also be taken into account in designing ternary OSCs.
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The pressing-induced formation of a large-area supramolecular film for oil capture

Mater. Chem. Front., 2020, 4,1530-1539
DOI: 10.1039/D0QM00006J, Research Article
Wenkai Wang, Mengqi Xie, Hongjun Jin, Wanwan Zhi, Kaerdun Liu, Cheng Ma, Peilong Liao, Jianbin Huang, Yun Yan
A rejuvenable large-area polyelectrolyte–surfactant supramolecular film formed by applying pressure can be used in a recyclable manner to rapidly capture spilled oil.
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Design and construction of bi-metal MOF-derived yolk–shell Ni2P/ZnP2 hollow microspheres for efficient electrocatalytic oxygen evolution

Mater. Chem. Front., 2020, 4,1366-1374
DOI: 10.1039/D0QM00128G, Research Article
Jinyang Zhang, Xuan Sun, Yang Liu, Linrui Hou, Changzhou Yuan
Hierarchical yolk–shell Ni2P/ZnP2 hollow microspheres are smartly synthesized, and exhibit exceptional OER performance, benefiting from their unique compositional/structural merits.
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Optical nonlinearity of Zeolitic Imidazolate Framework-67 in the near-infrared region

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00226G, Research Article
Han Pan, Hongwei Chu, Xiao Wang, Ying Li, Shengzhi Zhao, Guiqiu Li, Dechun Li
In this paper, we report the large optical nonlinearities of Zeolitic Imidazolate Framework-67 (ZIF-67) in the near-infrared (NIR) region. Typical Z-scan techniques were carried out to determine the nonlinear optical...
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When Centipedes Dream—Sue Bracken

ISBN: 9781988040387 Pub date: Spring 2018   Sue Bracken often finds the bizarre and the beautiful in what she sees. When Centipedes Dream, her debut book of poems, is a collection of these sightings. It  ranges from the familial love in a small blue bracelet,  the roar surrounding the loss of a sibling, the balletic thoughts of a [...]




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[ASAP] Chemical Looping Gasification of Torrefied Biomass Using NiFe<sub>2</sub>O<sub>4</sub> as an Oxygen Carrier for Syngas Production and Tar Removal

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00584




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[ASAP] Enhanced Performance of Adsorptive Removal of Thiophene from Model Fuel over Micro–Mesoporous Binderless ZSM-5 Prepared by <italic toggle="yes">In Situ</italic> Crystallization

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00198




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[ASAP] Superhydrophobic Surface Fabrication for Strengthened Selective Water Shut-off Technology

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00498




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[ASAP] Pore Systems of the Different Lithofacies of the Longmaxi Formation at Depths Exceeding 3500 m in the Zigong Area, Sichuan Basin

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00456




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[ASAP] Effects of Graphene Oxide on the Mechanical and Microscopic Characteristics of Cement-Based Plugging Material for Preventing Spontaneous Combustion of Coal

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00493




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[ASAP] Oxygen Uncoupling Property and Kinetics of a Copper Manganese Composite Oxygen Carrier in a Packed-Bed Reactor

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00574




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[ASAP] Depolymerization of Wheat Straw to Produce Glucose by Self-Catalyzed Hydrolysis

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00525




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[ASAP] Interplay between Viscous Pressure and Capillary Pressure on Polymer Gel Dehydration and Water Shutoff in Hydraulically Fractured Reservoirs

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00368




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[ASAP] Designing Novel High-Performance Shale Inhibitors by Optimizing the Spacer Length of Imidazolium-Based Bola-Form Ionic Liquids

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00788




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[ASAP] Zinc Nitrate as an Activation Agent for the Synthesis of Nitrogen-Doped Porous Carbon and Its Application in CO<sub>2</sub> Adsorption

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00305




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[ASAP] Proanthocyanidin-Based Polyether Demulsifiers for the Treatment of Aging Oil Emulsions

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00550




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[ASAP] A Simple and Direct Route to High-Performance Acrylamido-Based Kinetic Gas Hydrate Inhibitors from Poly(acrylic acid)

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00726




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[ASAP] Enhanced Oil Recovery Using Oleic Acid-Modified Titania Nanofluids: Underlying Mechanisms and Oil-Displacement Performance

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00594




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[ASAP] Kinetics and Mechanism of Catalytic Oxidation of NO in Coal Combustion Flue Gas over Co-Doped Mn–Ti Oxide Catalyst

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00122




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[ASAP] Desulfurization of Spent Tire Pyrolysis Oil and Its Distillate via Combined Catalytic Oxidation using H<sub>2</sub>O<sub>2</sub> with Formic Acid and Selective Adsorption over Al<sub>2</sub>O<sub>3</sub&

Energy & Fuels
DOI: 10.1021/acs.energyfuels.9b03968




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[ASAP] Optimization of Biomass Pyrolysis Vapor Upgrading Using a Laminar Entrained-Flow Reactor System

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00649




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[ASAP] Characterization and Distillation of Pyrolysis Liquids Coming from Polyolefins Segregated of MSW for Their Use as Automotive Diesel Fuel

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00403




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[ASAP] Torrefaction of Sorghum Straw Pellets in a Stationary Reactor with a Feeding Screw

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00531