Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication

Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from Pd^IV to Au^I, which allows subsequent reductive elimination of LAuI at Pd and Au.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication

Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02300K, Communication

ZHILONG LI, Vincent Gandon, Christophe Bour
Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF₃)₃)₄] as a catalyst and LiHMDS as a base. This transformation is likely to...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02001J, Feature Article

Kui Yang, Zhihua Zhang, Jie Du, Wei Li, Zhichao Pei
Owing to its spatiotemporal selectivity and noninvasive nature, photodynamic therapy (PDT) has become a promising approach for the treatment of cancer. However, the non-targeting capability and the accompanying side effects...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication

Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02029J, Communication

M. T. Jeena, Seokyoung Lee, Ayan Kumar Barui, Seongeon Jin, Yuri Cho, Suk-Won Hwang, Sehoon Kim, Ja-Hyoung Ryu
The design of peptide-based therapeutics is generally based on the replacement of L-amino acids with D-isomers to obtain improved therapeutic efficiency.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication

Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication

Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication

Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01936D, Communication

Yunfei Fan, Yahang Xie, Zhen Zhao, Yang Zhao, Rui Yu, Xiang-yang Liu, Youhui Lin, Changxu Lin
A wettability read-out strategy for an aptasensor is setup with a bilayer surface. It targets on methamphetamine and uses hydrophobicity reduction as the signal induced by recognition by the supporting aptamer layer.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02550J, Communication

Hao Zeng, Chuanle Zhu, Chi Liu, Yingying Cai, Fulin Chen, Huanfeng Jiang
The three component hydroxyletherification and hydroxylazidation reactions of (trifluoromethyl)alkenes are reported, providing various useful α-trifluoromethyl β-heteroatom substituted tertiary alcohols in high yields.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication

Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication

Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication

Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02382E, Communication

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Mark Murrie, Moya Hay, Arup Sarkar, Gavin Craig, Katie Marriott, Claire Wilson, Gopalan Rajaraman
The first trigonal bipyramidal Fe(II) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D...
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Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication

Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication

Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication

Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Chem. Commun., 2020, 56,5006-5009
DOI: 10.1039/D0CC01197E, Communication

Wenhuai Feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu
Anchoring of amine ligands with different alkyl chain lengths on perovskites mitigates non-radiative charge recombination in perovskite solar cells.
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Chem. Commun., 2020, 56,5042-5045
DOI: 10.1039/D0CC01219J, Communication

Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.
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Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication

Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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Chem. Commun., 2020, 56,5014-5017
DOI: 10.1039/D0CC01643H, Communication

Lixia Zhang, Zhenhua Li, Zhijun Chen
A curli fluorescent light-up probe called bromophenol blue, which binds to curli via recognizing CsgA.
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Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication

Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Chem. Commun., 2020, 56,5038-5041
DOI: 10.1039/D0CC01316A, Communication

Ruzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo Xue
Pt-catalyzed hydrosilylation of equilibrating allylic azides provides 3-azidopropansilanes with high chemoselectivity, regioselectivity, and excellent functional group tolerance.
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Chem. Commun., 2020, 56,5050-5053
DOI: 10.1039/D0CC01061H, Communication

Alba Molina, Sergio Díaz-Tendero, Javier Adrio, Juan C. Carretero
A practical Cu^I/(R)-Fesulphos catalyzed 1,3-dipolar cycloaddition of azomethine ylides with azirines has been developed to produce highly valuable enantioenriched diazabicyclo[3.1.0]hexanes.
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Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight

Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication

Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00536C, Communication

Xiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram Yasin
We herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02943B, Communication

Le Yu, Jun Feng Zhang, Mingle Li, Dewei Jiang, Ying Zhou, Peter Verwilst, Jong Seung Kim
We report a novel fluorescent molecular conjugate V-M1 enabling an accurate visualization of tumor tissues. The emission wavelength of V-M1 exceeds 650 nm, well within the near-infrared therapeutic window. Tumor...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00176G, Communication

Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng
A rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01906B, Communication

Amina Benchohra, Christophe Méthivier, david kreher, Jessem Landoulsi, rodrigue lescouezec
Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule’s integrity is monitored by PM-IRRAS and XPS. This approach...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02437F, Communication

Xiaohong Yang, Lian Wu, Aipeng Li, Lidan Ye, Jiahai Zhou, Hongwei Yu
Combinatorial modulation of inter- and intra-subunit interactions on decameric D-fructose-6-phosphate aldolase A (FSAA) generated a triple-site variant I31T/Q59T/I195Q FSAA with 27 to 278-fold activity improvement towards target heteroaromatic aldehydes. X-ray...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01854F, Communication

Indrani Bhowmick, David Washburn Shaffer, Jenny Y Yang, Matthew Shores
We report the first example of field-induced single molecule magnet (SMM) behaviour in a square-planar S = ½ Co(II) pincer complex [(P^NN^NP)CoBr]Br (2). The related five-coordinate complexes [(P^CN^CP)CoBr₂] (1) and...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02506B, Communication

Takehiro Hirao, Yoshiki Iwabe, Naoyuki Hisano, Takeharu HAINO
Chiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02252G, Communication

Batul Ismail Habibullah, Vasvi Tripathi, Parag Surana, Ranabir Das
Ubiquitin (Ub) is a highly conserved 76-amino acid polypeptide that is abundant throughout the eukaryotes. The covalent conjugation of Ub and Ub polymers to substrate proteins governs a variety of...
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