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[ASAP] Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere

Organometallics
DOI: 10.1021/acs.organomet.9b00815




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[ASAP] A Positive Charge in the Outer Coordination Sphere of an Artificial Enzyme Increases CO<sub>2</sub> Hydrogenation

Organometallics
DOI: 10.1021/acs.organomet.9b00843




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[ASAP] CO<sub>2</sub> (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases

Organometallics
DOI: 10.1021/acs.organomet.9b00838




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[ASAP] Synthesis and Reactivity of (NHC)Au<sup>I</sup>–Mercaptopyridine Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00118




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[ASAP] Activation of C–C Bonds via s-Bond Metathesis: Hydroborenium-Catalyzed Hydrogenolysis of Cyclopropanes

Organometallics
DOI: 10.1021/acs.organomet.0c00099




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[ASAP] Metal-Free Room-Temperature Phosphorescence from Amorphous Triarylborane-Based Biphenyl

Organometallics
DOI: 10.1021/acs.organomet.0c00068




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[ASAP] Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation

Organometallics
DOI: 10.1021/acs.organomet.0c00148




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[ASAP] Carboxylation of the Ni–Me Bond in an Electron-Rich Unsymmetrical PCN Pincer Nickel Complex

Organometallics
DOI: 10.1021/acs.organomet.9b00817




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[ASAP] Electrochemical CO<sub>2</sub> Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00129




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[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




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[ASAP] Dibromine Promoted Transmetalation of an Organomercurial by Fe(CO)<sub>5</sub>: Synthesis, Properties, and Cytotoxicity of Bis(2-C<sub>6</sub>H<sub>4</sub>-2'-py-<italic toggle="yes">?C,N</

Organometallics
DOI: 10.1021/acs.organomet.0c00107




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[ASAP] (Isonitrile)platinum(II) Complexes of an Amido Bis(N-heterocyclic carbene) Pincer Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00065




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[ASAP] Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization

Organometallics
DOI: 10.1021/acs.organomet.0c00112




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[ASAP] Potentiostatically Controlled Olefin Metathesis

Organometallics
DOI: 10.1021/acs.organomet.0c00052




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[ASAP] [2 + 2] Cycloaddition of <italic toggle="yes">o</italic>-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes

Organometallics
DOI: 10.1021/acs.organomet.0c00163




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[ASAP] Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00154




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[ASAP] Fe(0)-Mediated Reductive Disproportionation of CO<sub>2</sub>

Organometallics
DOI: 10.1021/acs.organomet.0c00175




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[ASAP] Update to Our Reader, Reviewer, and Author Communities—April 2020

Organometallics
DOI: 10.1021/acs.organomet.0c00266




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[ASAP] S<sub>N</sub>2 and E2 Branching of Main-Group-Metal Alkyl Intermediates in Alkane CH Oxidation: Mechanistic Investigation Using Isotopically Labeled Main-Group-Metal Alkyls

Organometallics
DOI: 10.1021/acs.organomet.0c00120




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[ASAP] Synthesis, Characterization, and Catalytic Reactivity of {CoNO}<sup>8</sup> PCP Pincer Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00167




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[ASAP] Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based <italic toggle="yes">N</italic>^<italic toggle="yes">N</italic><sup><italic tog

Organometallics
DOI: 10.1021/acs.organomet.0c00161




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[ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency

Organometallics
DOI: 10.1021/acs.organomet.0c00117




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[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




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[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




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[ASAP] C–F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

Organometallics
DOI: 10.1021/acs.organomet.0c00176




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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

Organometallics
DOI: 10.1021/acs.organomet.0c00096




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[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




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[ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

Organometallics
DOI: 10.1021/acs.organomet.0c00196




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[ASAP] Sila-Peterson Reaction of Cyclic Silanides

Organometallics
DOI: 10.1021/acs.organomet.0c00106




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[ASAP] Improving Redox Reversibility and Intermetallic Coupling of Co(III) Alkynyls through Tuning of Frontier Orbitals

Organometallics
DOI: 10.1021/acs.organomet.0c00183




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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




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[ASAP] A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst

Organometallics
DOI: 10.1021/acs.organomet.0c00193




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[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




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[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




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[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

Organometallics
DOI: 10.1021/acs.organomet.0c00078




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[ASAP] Reactivity of [Ce(NR<sub>2</sub>)<sub>3</sub>] (R = SiMe<sub>3</sub>) with Prospective Carbon Atom Transfer Reagents

Organometallics
DOI: 10.1021/acs.organomet.0c00186




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[ASAP] Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00021




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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] C5 Metalation of Imidazole-Based Monothiolates en Route to Selenothiolates

Organometallics
DOI: 10.1021/acs.organomet.0c00201




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[ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds

Organometallics
DOI: 10.1021/acs.organomet.0c00102




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[ASAP] Catalytic Dimerization of Alkynes via C–H Bond Cleavage by a Platinum–Silylene Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00195




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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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The 2014 BAFTAS

It’s that time of the year when we look back on the past 12 months and dish out our (cough, cough) highly prized awards! This year in the 2014 BAFTAS we have eight categories and round off the show with a little bit of crystal ball gazing in which we both make our predictions for 2015.

Without further ado here are the categories and winners:

  1. The award for not being a very good year in the industry: 2014
  2. Conference/event of the year: Web Teaching Day & Beyond Tellerrand Berlin
  3. Podcast of the year: Startup
  4. Most hyped app of the year: Slack
  5. Man of the year: Sean McCabe
  6. Woman of the year: Rachel Andrew
  7. Trend of the year: Privacy & Security
  8. Foo Bar of the year: #VATMOSS

Happy holidays to our all listeners. We really do appreciate including us in your weekly audio listening. See you in 2015.




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25% jump in mental health cases in Gujarat

(This story originally appeared in AhmedabadMirror on May 8, 2020)




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Saurashtra on edge over infection due to influx

The district administration in Saurashtra is jittery fearing import of coronavirus cases into the district with the permission for intrastate travel granted by the state government. Jamnagar, which had only one Covid case till now reported five new cases in the past one week.