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[ASAP] Ruthenium-Catalyzed Asymmetric <italic toggle="yes">N</italic>-Acyl Nitrene Transfer Reaction: Imidation of Sulfide

Organic Letters
DOI: 10.1021/acs.orglett.0c01373




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[ASAP] Self-Catalyzed Rapid Synthesis of <italic toggle="yes">N</italic>-Acylated/<italic toggle="yes">N</italic>-Formylated a-Aminoketones and <italic toggle="yes">N</italic>-Hydroxymethyl

Organic Letters
DOI: 10.1021/acs.orglett.0c01206




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[ASAP] Acylation of Aryl Halides and a-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis

Organic Letters
DOI: 10.1021/acs.orglett.0c01121




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[ASAP] Pd-Catalyzed Regiodivergent Synthesis of Diverse Oxindoles Enabled by the Versatile Heck Reaction of Carbamoyl Chlorides

Organic Letters
DOI: 10.1021/acs.orglett.0c01197




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[ASAP] Carbocation versus Carbene Controlled Chemoselectivity: DFT Study on Gold- and Silver-Catalyzed Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters

Organic Letters
DOI: 10.1021/acs.orglett.0c01476




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[ASAP] Copper-Catalyzed Oxyvinylation of Diazo Compounds

Organic Letters
DOI: 10.1021/acs.orglett.0c01150




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[ASAP] K<sub>2</sub>S as Sulfur Source and DMSO as Carbon Source for the Synthesis of 2-Unsubstituted Benzothiazoles

Organic Letters
DOI: 10.1021/acs.orglett.0c00994




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[ASAP] Palladium-Catalyzed Cascade Decarboxylative Amination/6-<italic toggle="yes">endo-dig</italic> Benzannulation of <italic toggle="yes">o</italic>-Alkynylarylketones with <italic toggle="yes"&g

Organic Letters
DOI: 10.1021/acs.orglett.0c01183




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[ASAP] DNA Compatible Intermolecular Wittig Olefination for the Construction of a, ß-Unsaturated Carbonyl Compounds

Organic Letters
DOI: 10.1021/acs.orglett.0c01215




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[ASAP] Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01416




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[ASAP] Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01273




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[ASAP] Stereoselective Asymmetric Synthesis of Pyrrolidines with Vicinal Stereocenters Using a Memory of Chirality-Assisted Intramolecular S<sub>N</sub>2' Reaction

Organic Letters
DOI: 10.1021/acs.orglett.0c01307




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[ASAP] Nickel-Catalyzed Cyclization Strategy for the Synthesis of Pyrroloquinolines, Indoloquinolines, and Indoloisoquinolines

Organic Letters
DOI: 10.1021/acs.orglett.0c01055




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[ASAP] Enantioselective Copper-Catalyzed Remote C(sp<sup>3</sup>)–H Alkynylation of Linear Primary Sulfonamides

Organic Letters
DOI: 10.1021/acs.orglett.0c01325




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[ASAP] Nickel(II)-Catalyzed Addition of Aryl-, Alkenyl-, and Alkylboronic Acids to Alkenylazaarenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01425




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[ASAP] Iron-Catalyzed Oxidative Coupling of Indoline-2-ones with Aminobenzamides via Dual C–H Functionalization

Organic Letters
DOI: 10.1021/acs.orglett.0c01066




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[ASAP] Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin

Organic Letters
DOI: 10.1021/acs.orglett.0c01168




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[ASAP] Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation

Organic Letters
DOI: 10.1021/acs.orglett.0c01421




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[ASAP] Oxidative Coupling of Aldehydes with Alcohol for the Synthesis of Esters Promoted by Polystyrene-Supported N-Heterocyclic Carbene: Unraveling the Solvent Effect on the Catalyst Behavior Using NMR Relaxation

Organic Letters
DOI: 10.1021/acs.orglett.0c01188




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[ASAP] Copper-Catalyzed 1,2-Aminocyanation of Unactivated Alkenes via Cyano Migration

Organic Letters
DOI: 10.1021/acs.orglett.0c01217




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[ASAP] Phosphorus(III)-Mediated, Tandem Deoxygenative Geminal Chlorofluorination of 1,2-Diketones

Organic Letters
DOI: 10.1021/acs.orglett.0c01258




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[ASAP] Copper-Mediated DNA-Compatible One-Pot Click Reactions of Alkynes with Aryl Borates and TMS-N<sub>3</sub>

Organic Letters
DOI: 10.1021/acs.orglett.0c01219




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[ASAP] Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process

Organic Letters
DOI: 10.1021/acs.orglett.0c01297




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[ASAP] A General One-Pot Protocol for Hindered <italic toggle="yes">N</italic>-Alkyl Azaheterocycles from Tertiary Carboxylic Acids

Organic Letters
DOI: 10.1021/acs.orglett.0c01254




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[ASAP] Studies of the Enantiocontrolled Synthesis of the C(10)–C(25) Subunit of Amphidinolide C

Organic Letters
DOI: 10.1021/acs.orglett.0c01177




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[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




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[ASAP] Nickel-Catalyzed Formal Aminocarbonylation of Secondary Benzyl Chlorides with Isocyanides

Organic Letters
DOI: 10.1021/acs.orglett.0c01284




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[ASAP] Benzo- and Thieno-Annulated Tetracenes: A One-Pot Synthesis via Cross-Dehydrogenative Annulation

Organic Letters
DOI: 10.1021/acs.orglett.0c01244




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[ASAP] Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Noncovalent Chirality

Organic Letters
DOI: 10.1021/acs.orglett.0c01200




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[ASAP] Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

Organic Letters
DOI: 10.1021/acs.orglett.0c01277




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Beyond Cedarville: Why Do Pastors Keep Getting Rehired After Abuse?

Victims’ advocates caution institutions against plans to “restore” fallen leaders.

Update (May 1): Cedarville University president Thomas White has been placed on administration leave by the school’s board of trustees. A week after Anthony Moore was fired by White over “additional information related to [his] past,” the board announced it will commission an independent investigation of Moore and an audit of his hiring.

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Another case of a leader with an abusive past moving from one evangelical institution to another has intensified scrutiny on Christian hiring practices and responses to abuse.

In ministry contexts, the desire to keep fallen leaders out of positions where they might again abuse their authority is sometimes met with another perspective—a hope that a redemptive and forgiving God would allow people to be restored to leadership. Both victims’ advocates and community members worry that administrators weighing those considerations at Cedarville University made the wrong call.

In 2017, Cedarville welcomed Anthony Moore six months after he was fired from the lead pastor position of The Village Church’s Fort Worth campus. President Thomas White wrote that he offered to shepherd Moore through a five-year plan of restoration at the conservative Baptist school while he taught theology, helped coach basketball, and served as a special advisor on diversity.

CT spoke with four current and former Cedarville professors who said they knew Moore had made a “mistake” related to same-sex attraction and technology, based on White’s introduction and Moore’s own telling. Some assumed pornography or an online relationship. They had no idea that he had reportedly filmed a subordinate at his previous church in the shower. The revelation, detailed by multiple ...

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Report: ‘Tremendous Progress’ Ahead for Religious Freedom Worldwide

USCIRF chair Tony Perkins gives CT a behind-the-scenes look at today’s annual report on “systematic, ongoing, and egregious” violations.

A new report aims to “unflinchingly criticize the records of US allies and adversaries alike” on religious freedom.

And there’s a lot to report, with more headlines each month confirming the Pew Research Center’s 10-year analysis that government restrictions and social hostilities involving religion have reached record levels worldwide.

Today’s 21st annual report by the US Commission on International Religious Freedom (USCIRF) identifies significant problems in 29 countries—but sees “an upward trajectory overall.”

“Our awareness is going to grow greater, and the problem will appear more pronounced,” USCIRF chair Tony Perkins told CT. “But as we continue to work on it, I think we will see tremendous progress in the next few years if we stay the present course.”

Created as an independent, bipartisan federal commission by the 1998 International Religious Freedom Act, USCIRF casts a wider net than the US State Department, which annually designates Countries of Particular Concern (CPC) for such nations’ violations of religious freedom, or places them on a Special Watch List (SWL) if less severe.

Last December, Secretary of State Mike Pompeo announced CPC status for Burma, China, Eritrea, Iran, North Korea, Pakistan, Saudi Arabia, Tajikistan, and Turkmenistan.

USCIRF now recommends adding India, Nigeria, Russia, Syria, and Vietnam.

And where the State Department put only Cuba, Nicaragua, Sudan, and Uzbekistan on the watch list, USCIRF recommends also including Afghanistan, Algeria, Azerbaijan, Bahrain, Central African Republic, Egypt, Indonesia, Iraq, Kazakhstan, Malaysia, and Turkey.

USCIRF’s mandate is to provide oversight and advice to the State Department. ...

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After SAT and ACT Cancel, Registrations Soar for Classical Education Exam

An alternative college admissions test, used by some Christian schools, draws a record 50,000 students.

The Classic Learning Test (CLT), a niche college entrance exam aspiring to bring a sense of virtue to standardized tests, saw a 1,000 percent increase in registrations over its short history when the SAT and ACT canceled testing for the remainder of the school year due to COVID-19.

“Because we are able to administer the test remotely, we’re kind of the only game in town,” said Jeremy Tate, who created the CLT four years ago amid a renaissance in Classical education, including among Christians.

At its first administration in June 2016, 47 students took the CLT. With the bump in registration, 50,000 students will take its suite of tests—the CLT, and the CLT-8 and CLT-10, designed for lower grades—during the 2019-2020 academic year. That’s more than double last year’s total.

Though not a Christian company, CLT references figures including John Henry Newman and C. S. Lewis in its promotional materials and stresses the moral, formational dimension to education. The exam has been popular among classical Christian schools, which educate over 40,000 students in the US, and homeschoolers, who make up about 40 percent of CLT test-takers.

So far, 178 colleges and universities in the US accept the exam, mostly Catholic and Protestant schools. For other institutions, the CLT can serve as a supplemental assessment.

The College Board and ACT Inc., the companies that administer the SAT and ACT, respectively, have canceled or postponed in-person testing until the fall, leading many colleges to make the admissions exams an optional part of their applications. In 2018, around 2 million students took the SAT and 1.9 million took the ACT.

While some registrants may turn to the CLT this year for the convenience ...

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Why We Opened a Christian University in Iraq Amid ISIS’ Genocide

CT interviews Stephen Rasche on Erbil’s Catholic presence, the need for Christian unity, and why Christians will “no longer be shy” with the gospel.

For 25 years, Stephen Rasche was a “bare knuckles” international lawyer. But in 2010, he offered his services to the Chaldean Catholic Church of Erbil in Iraqi Kurdistan and has increasingly dedicated his life to the preservation of this ancient community.

Under the leadership of Archbishop Bashar Matti Warda, in 2015 Rasche helped found the Catholic University of Erbil, where he serves as vice chancellor. Also the director of its Institute for Ancient and Threatened Christianity, Rasche lived this title as ISIS ravaged Iraq’s Christian homelands in the Nineveh Plains and many believers fled to Erbil.

After testifying on their behalf before the United Nations and the US Congress, Rasche allows them to represent themselves in his recent book, The Disappearing People: The Tragic Fate of Christians in the Middle East. The book has won a diverse range of endorsements, from leaders such as Matthew Hassan Kukah, bishop of the Catholic Diocese of Sokoto, Nigeria; Yahya Cholil Staquf, general secretary of Nahdlatul Ulama, the largest Muslim organization in the world; and Thomas Farr, president of the Religious Freedom Institute.

The US State Department’s Office of International Religious Freedom reports that less than 250,000 Christians are living in Iraq, most in Kurdistan or on the Nineveh Plains. Two-thirds belong to the Chaldean Catholic Church.

CT interviewed Rasche about the logic of establishing a university during a genocide, how its Catholic identity functions in a Muslim society, and his enduring optimism for Christianity in Iraq.

What led you personally to invest your life in this endeavor?

In 2010, Bishop Warda had just been made archbishop, and I went to pay him a visit of respect, asking if there ...

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Died: Darrin Patrick, Who Used His Fall and Restoration to Help Struggling Pastors

(UPDATED) The St. Louis pastor spoke up about the difficulties faced by leaders and critiqued “celebrity culture” in ministry.

Darrin Patrick, a megachurch pastor, author, and speaker, has died.

Patrick was a teaching pastor at Seacoast Church, a multi-site megachurch based in Mount Pleasant, South Carolina, and the founding pastor of the Journey Church in St. Louis, where he lived.

In a Friday evening update, Seacoast Church stated: “Darrin was target shooting with a friend at the time of his death. An official cause of death has not been released but it appears to be a self-inflicted gunshot wound. No foul play is suspected.”

Patrick’s unexpected death came as a shock to friends and colleagues. Robby Gallaty, pastor of Long Hollow Baptist, in Hendersonville, Tennessee, said that Patrick was scheduled to speak at his church next weekend.

“I just talked to him Tuesday and Wednesday,” said Gallaty. “This is the second close friend I have lost in a year.”

Gallaty first met Patrick in 2015 and had invited him to speak the following year at a men’s ministry event at Long Hollow. Just before the event, he said, Patrick called and said he was leaving the ministry.

At the time, Patrick had been a rising star among Reformed evangelical circles and was serving as vice-president of the Acts 29 church planting network. He was fired from Journey for what church elders called misconduct including “inappropriate meetings, conversations, and phone calls with two women” and an abuse of power.

Despite Patrick’s fall from ministry, the two stayed friends. Patrick admitted his faults and got counseling. He went through a restoration process that lasted 26 months, according to a 2019 blog interview posted at Christianity Today. He returned to the ministry as a preacher but not as a senior pastor of a church. ...

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NLC India TPS II, all about the company where boiler blast occurred in Neyveli

The power stations of the NLC integrated mining-cum-power generating company are located at Neyveli in Cuddalore.




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Palm / Fred Gray

Browsery QK495.P17 G739 2018




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Proust's duchess: how three celebrated women captured the imagination of fin-de-siècle Paris / Caroline Weber

Browsery PQ2631.R63 Z9818 2018




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Asperger's children: the origins of autism in Nazi Vienna / Edith Sheffer

Browsery RJ506.A9 S5257 2018




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The apparitionists: a tale of phantoms, fraud, photography, and the man who captured Lincoln's ghost / Peter Manseau

Browsery BF1027.M86 M36 2017




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How to hide an empire: a history of the greater United States / Daniel Immerwahr

Browsery F965.I46 2019




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The good neighbor: the life and work of Fred Rogers / Maxwell King

Browsery PN1992.4.R56 K56 2018




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The eight mountains: a novel / Paolo Cognetti ; translated by Simon Carnell and Erica Segre

Browsery PQ4903.O36 O8813 2018




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Swallowing mercury / Wioletta Greg ; translated from the Polish by Eliza Marciniak

Browsery PG7158.G8427 G8413 2017b




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Paper: material, medium and magic / edited by Neil Holt, Nicola von Velsen and Stephanie Jacobs ; with photographs by Thorsten Kern

Browsery TS1105.P134 2018




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Love in the new millennium / Can Xue ; foreword by Eileen Myles ; translated from the Chinese by Annelise Finegan Wasmoen

Browsery PL2912.A5174 X5613 2018




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Ten drugs: how plants, powders, and pills have shaped the history of medicine / by Thomas Hager

Browsery RM45.H34 2019




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The strange case of Dr. Couney: how a mysterious European showman saved thousands of American babies / Dawn Raffel

Browsery RJ250.R355 2018




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Technology, activism, and social justice in a digital age / edited by John G. McNutt

Browsery HM851.T42995 2018




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Food on the move: dining on the legendary railway journeys of the world / edited by Sharon Hudgins

Browsery TF668.F663 2019