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New Insights into Disability Beneficiaries' Pursuit of Work

Significant attention has been focused on helping beneficiaries of Supplemental Security Income (SSI) and Social Security Disability Insurance (SSDI) participate in the work force. Increased work activity for these beneficiaries can increase self-sufficiency and reduce reliance on federal benefits, while simultaneously reducing federal outlays. Despite these efforts, work activity among beneficiaries has not increased substantially in recent decades. Three studies sponsored by the Social Security Administration’s Disability Research Consortium provide new information on work activity among SSI and SSDI beneficiaries and offer insights about the barriers they face in pursuing work.




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Testing New Earnings Rules for Social Security Disability Insurance: Findings from the Benefit Offset National Demonstration

The current earnings rules for Social Security Disability Insurance (DI) specify that, after using available work incentives, DI beneficiaries are not owed a DI benefit check if they earn more than a certain threshold. The Benefit Offset National Demonstration (BOND) tested a design intended to encourage DI beneficiaries to work by replacing the so-called cash cliff with a ramp—a $1 reduction in benefits for every $2 of additional earnings. BOND simultaneously tested the new rules with two groups: a nationally representative sample of DI beneficiaries and a group of recruited and informed volunteers—those thought to be most likely to earn more than the earnings threshold. Results from the five-year evaluation of BOND are now available for both groups.




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New Evidence of the ACA’s Effect on People with Disabilities: Health Insurance, Employment, and Benefits

The Patient Protection and Affordable Care Act (ACA) of 2010 changed several aspects of the law concerning access to health insurance that were particularly salient for people with disabilities. These changes included removing limits on preexisting conditions, extending parent’s health insurance coverage of young adults until the age of 26, expanding Medicaid to more adults with low incomes, and making it easier to obtain affordable coverage outside the traditional employer-sponsored benefit system.




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Seeing Is Believing: Visualizing Data for Evidence-Based Policymaking

While many industries have increasingly turned to data science to make informed business decisions, social service organizations and government agencies have been slower to fully embrace the potential of current and emerging data science methods. The challenges are real.




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Implementing District and School Policies and Practices to Support Culturally Responsive Pedagogy

This webinar explored how a school and district have approached the challenge of implementing culturally responsive practice. It elaborated on programs, policies, and practices that were implemented to support efforts to achieve equity and use culturally responsive pedagogy.




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Innovations in Medicare ACOs’ Approaches to Care Delivery Improvement

Hear from ACOs about their approaches to improving care delivery, and from CMS about new policy opportunities.




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Join Us and Partners for a Grantmakers for Education Webinar—Making the Case: Establishing Evidence to Support Practitioners, Strategy, and Outcomes

Interested in learning how to build more evidence into philanthropic practice? Join Mathematica, The Wallace Foundation, and the Afterschool Alliance for a Grantmakers for Education webinar.




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SSI Youth Solutions Project: Informational Webinar for Applicants on the Call for Policy Proposals

Mathematica is seeking innovative ideas on how to help youth who receive Supplemental Security Income (SSI) improve their employment outcomes as they transition to adulthood.




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Q-CCIIT: Measuring the Quality of Caregiver–Child Interactions: Free Webinar for Early Childhood Professionals

Mathematica will launch a groundbreaking new quality measurement observation tool, now available to the early childhood community (including program administrators, professional development providers, researchers, and others) during a webinar.




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Macrocyclization of 3-Triflyloxybenzynes with Tetrahydrofuran via Anionic Thia-Fries Rearrangement

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00135J, Communication
Chaorong Qi, Ruixiang Cheng, Wenfang Xiong, Lu Wang, Yanwei Ren, Huanfeng Jiang
A novel and uncommon macrocyclization reaction between 3-triflyloxybenzynes and tetrahydrofuran has been developed for the first time, providing a direct method for the synthesis of a range of functionalized 19-membered...
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Simultaneous co-assembly of fenofibrate and ketoprofen peptide for the dual-targeted treatment of nonalcoholic fatty liver disease (NAFLD)

Chem. Commun., 2020, 56,4922-4925
DOI: 10.1039/D0CC00513D, Communication
Zhongyan Wang, Chuanrui Ma, Yuna Shang, Lijun Yang, Jing Zhang, Cuihong Yang, Chunhua Ren, Jinjian Liu, Guanwei Fan, Jianfeng Liu
An ingenious co-assembled nanosystem based on fenofibrate and ketoprofen peptide for the dual-targeted treatment of NAFLD by reducing hepatic lipid accumulation and inflammatory responses.
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Photochemical α-carboxyalkylation of tryptophols and tryptamines via C–H functionalization

Chem. Commun., 2020, 56,4930-4933
DOI: 10.1039/D0CC00847H, Communication
Zhiqiang Pan, Yuchang Liu, Fengchi Hu, Qinglong Liu, Wenbin Shang, Chengfeng Xia
A process for the α-carboxyalkylation of tryptophols and tryptamines by the functionalization of C–H bonds under visible light irradiation has been developed.
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On-surface synthesis of planar acenes via regioselective aryl–aryl coupling

Chem. Commun., 2020, 56,4890-4893
DOI: 10.1039/D0CC01043J, Communication
Lin Feng, Tao Wang, Hongxing Jia, Jianmin Huang, Dong Han, Wenzhao Zhang, Honghe Ding, Qian Xu, Pingwu Du, Junfa Zhu
The reaction of 2,2'-dibromo-biphenyl (DBBP) on a Ag(111) surface leads to the generation of planar dibenzo[e,l]pyrene, in contrast to the nonplanar saddle-shaped tetraphenylene formed in solution.
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Noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles via polymerization-induced electrostatic self-assembly using an arginine-like monomer

Chem. Commun., 2020, 56,4954-4957
DOI: 10.1039/D0CC00427H, Communication
Qingqing Zhao, Qizhou Liu, Chao Li, Lei Cao, Lei Ma, Xiyu Wang, Yuanli Cai
The noncovalent locking of nanostructured thermoresponsive polyion complexes can be achieved via polymerization-induced electrostatic self-assembly (PIESA) using an arginine-like cationic monomer.
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Graphene-modulated assembly of zinc phthalocyanine on BiVO4 nanosheets for efficient visible-light catalytic conversion of CO2

Chem. Commun., 2020, 56,4926-4929
DOI: 10.1039/D0CC01518K, Communication
Ji Bian, Jiannan Feng, Ziqing Zhang, Jiawen Sun, Mingna Chu, Ling Sun, Xin Li, Dongyan Tang, Liqiang Jing
Graphene-modulated ZnPc/BiVO4 Z-scheme heterojunctions for efficient visible-light catalytic CO2 conversion are achieved by increasing the optimized amount of highly dispersed ZnPc.
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Nonlinear organic–inorganic halide hybrids containing unprecedented linear [MIX2]− coordination units and quasi-two-dimensional lone pairs

Chem. Commun., 2020, 56,4894-4897
DOI: 10.1039/D0CC01532F, Communication
Qi Wu, Xian Liu, Yeshuang Du, Chunlin Teng, Fei Liang
A first example of monovalent-metal-based hybrid halides [N(CH3)4]MCl2 (M = Ga+, In+) with zero-dimensional configuration containing unprecedented linear [GaCl2]/[InCl2] units have been designed and synthesized.
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Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

Chem. Commun., 2020, 56,4886-4889
DOI: 10.1039/D0CC00327A, Communication
Open Access
Jing Lai, Jun Zhang, Zuowei Li, Yao Xiao, Weibo Hua, Zhenguo Wu, Yanxiao Chen, Yanjun Zhong, Wei Xiang, Xiaodong Guo
A splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2 electrode, was discovered in the LiNi0.85Co0.10Mn0.05O2 at high-voltage region (>4.6 V) by in situ high-resolution synchrotron radiation diffraction.
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Fe3Pt intermetallic nanoparticles anchored on N-doped mesoporous carbon for the highly efficient oxygen reduction reaction

Chem. Commun., 2020, 56,4898-4901
DOI: 10.1039/D0CC00895H, Communication
Danke Chen, Zhuoyi Li, Yu Zhou, Xu Ma, Hanqing Lin, Wen Ying, Xinsheng Peng
N-Doped mesoporous carbon catalysts dispersed with Fe3Pt intermetallic nanoparticles, exhibiting excellent ORR performance, were synthesised by direct pyrolysis of Pt–Fe co-functionalized ZIF-8.
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A heteroleptic diradical Cr(III) complex with extended spin delocalization and large intramolecular magnetic exchange

Chem. Commun., 2020, 56,4906-4909
DOI: 10.1039/D0CC00548G, Communication
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
Ligand-based successive reductions in a heteroleptic Cr(III) complex give rise to intended extremely strong metal–radical magnetic interactions.
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Oxyanion transport across lipid bilayers: direct measurements in large and giant unilamellar vesicles

Chem. Commun., 2020, 56,4910-4913
DOI: 10.1039/C9CC09888G, Communication
Krzysztof M. Bąk, Bartjan van Kolck, Krystyna Maslowska-Jarzyna, Panagiota Papadopoulou, Alexander Kros, Michał J. Chmielewski
A simple, carbazole-based dithioamide receptor transports a variety of biologically relevant anions through lipid bilayers, as shown by direct fluorescent assays in LUVs and GUVs.
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A dual-round signal amplification strategy for colorimetric/photoacoustic/fluorescence triple read-out detection of prostate specific antigen

Chem. Commun., 2020, 56,4942-4945
DOI: 10.1039/D0CC01086C, Communication
Chao Jiang, Yan Huang, Ting He, Peng Huang, Jing Lin
A colorimetric/fluorescence/photoacoustic triple read-out detection of prostate specific antigen (PSA) was developed by using a silica coated Au@Ag core–shell nanorod (denoted Au@Ag@SiO2) based enzyme-linked immunosorbent assay (ELISA) system.
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The design of hypercrosslinked polymers from benzyl ether self-condensing compounds and external crosslinkers

Chem. Commun., 2020, 56,4938-4941
DOI: 10.1039/D0CC01002B, Communication
Robert T. Woodward
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes.
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Atomically thin TiO2 nanosheets synthesized using liquid metal chemistry

Chem. Commun., 2020, 56,4914-4917
DOI: 10.1039/D0CC01456G, Communication
Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi S. Datta, Kibret A. Messalea, Bao Yue Zhang, Muhammad Waqas Khan, Aaron Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke
The library of two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Liquid metal-based synthesis provides a new approach to overcome this limitation.
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Beyond temperature: controlling collagen fibrillogenesis under physiological conditions via interaction with cucurbit[7]uril

Chem. Commun., 2020, 56,4946-4949
DOI: 10.1039/D0CC01444C, Communication
Qiuping Xie, Delong Hou, Jinming Chang, Zhou Xu, Qi Zeng, Zhonghui Wang, Yi Chen
A supramolecular strategy as efficient as temperature that enabled facile control over collagen fibrillogenesis under physiological conditions was reported.
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Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication
Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from PdIV to AuI, which allows subsequent reductive elimination of LAuI at Pd and Au.
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Chemically synthesized circular RNAs with phosphoramidate linkages enable rolling circle translation

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication
Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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Construction of Nanocage-Structured Heterogeneous Binary Metal Sulfides via Step-by-Step Confined Growth for Boosted Lithium Storage Properties

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication
Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Ultrasensitive DNA Electrochemical Biosensor Based on MnTBAP Biomimetic Catalyzed AGET ATRP Signal Amplification Reaction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication
Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Deep imaging for visualizing nitric oxide in lipid droplets: discovering the relationship between nitric oxide and resistance to cancer chemotherapy drugs

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication
Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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An ultrasensitive electrochemical biosensor for Pseudomonas aeruginosa assay based on a rolling circle amplification-assisted multipedal DNA walker

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication
Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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A radical-mediated 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite: facile access to sulfonyl isoxazoles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication
Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Enhancing the catalytic properties of well-defined electrophilic platinum complexes

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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Wettability read-out strategy for aptamer target binding based on a recognition/hydrophobic bilayer surface

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01936D, Communication
Yunfei Fan, Yahang Xie, Zhen Zhao, Yang Zhao, Rui Yu, Xiang-yang Liu, Youhui Lin, Changxu Lin
A wettability read-out strategy for an aptasensor is setup with a bilayer surface. It targets on methamphetamine and uses hydrophobicity reduction as the signal induced by recognition by the supporting aptamer layer.
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Resistance to the “Last Resort” Antibiotic Colistin: A Single-Zinc Mechanism for Phosphointermediate Formation in MCR Enzymes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication
Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Liquid metal exfoliation of two dimensional polydopamine nanosheets for templated assembly of noble metal nanoparticles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication
Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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Self-assembly of an organometallic Fe9O6 cluster from aerobic oxidation of (tmeda)Fe(CH2tBu)2

Chem. Commun., 2020, 56,4994-4997
DOI: 10.1039/D0CC00011F, Communication
Jonathan A. Kephart, Zachary Hecht, Brooke N. Livesay, Indrani Bhowmick, Matthew P. Shores, V. Codrina Popescu, Navamoney Arulsamy, Elliott B. Hulley
Aerobic oxidation of (tmeda)Fe(CH2tBu)2 in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands.
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Investigation of the cathodic interfacial stability of a nitrile electrolyte and its performance with a high-voltage LiCoO2 cathode

Chem. Commun., 2020, 56,4998-5001
DOI: 10.1039/D0CC00049C, Communication
Fang Xian, Jiedong Li, Zhenglin Hu, Qian Zhou, Chen Wang, Chenglong Lu, Zhongyi Zhang, Shanmu Dong, Chunbo Mou, Guanglei Cui
We adopted a SN based deep eutectic electrolyte with the SN as the only solvent and found that the high-state Co ion could be reduced by the SN solvent on the interface of the LiCoO2 electrode, causing a reverse phase change of the LiCoO2.
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Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication
Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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Solvent-driven migration of highly polar monomers into hydrophobic PDMS produces a thick graft layer via subsurface initiated ATRP for efficient antibiofouling

Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication
Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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Live cell fluorescent stain of bacterial curli and biofilm through supramolecular recognition between bromophenol blue and CsgA

Chem. Commun., 2020, 56,5014-5017
DOI: 10.1039/D0CC01643H, Communication
Lixia Zhang, Zhenhua Li, Zhijun Chen
A curli fluorescent light-up probe called bromophenol blue, which binds to curli via recognizing CsgA.
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The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction

Chem. Commun., 2020, 56,5026-5029
DOI: 10.1039/D0CC01339K, Communication
Ignacio Rosa-Pardo, Carla Casadevall, Luciana Schmidt, Miguel Claros, Raquel E. Galian, Julio Lloret-Fillol, Julia Pérez-Prieto
The cooperative action between the CsPbBr3 surface and capping makes the photoredox homo-/cross-coupling of benzyl bromides under mild conditions possible.
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Synthesis of functionalized tetrahydropyrans via cascade cycloaddition involving silyloxyallyl cation intermediates

Chem. Commun., 2020, 56,5034-5037
DOI: 10.1039/D0CC01796E, Communication
Fatimat O. Badmus, Joshua A. Malone, Frank R. Fronczek, Rendy Kartika
An expedient synthesis of highly substituted tetrahydrobenzofuran via an unsymmetrical silyloxyallyl cation is reported.
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Highly selective hydrosilylation of equilibrating allylic azides

Chem. Commun., 2020, 56,5038-5041
DOI: 10.1039/D0CC01316A, Communication
Ruzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo Xue
Pt-catalyzed hydrosilylation of equilibrating allylic azides provides 3-azidopropansilanes with high chemoselectivity, regioselectivity, and excellent functional group tolerance.
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A multipedal DNA walker for amplified detection of tumor exosomes

Chem. Commun., 2020, 56,4982-4985
DOI: 10.1039/D0CC01817A, Communication
Peng Miao, Yuguo Tang
A novel electrochemical biosensor for exosomes is proposed based on a multipedal DNA walking strategy. A limit of detection down to 6/μL is obtained with excellent selectivity.
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All solid state electrochromic devices based on the LiF electrolyte

Chem. Commun., 2020, 56,5018-5021
DOI: 10.1039/D0CC00697A, Communication
Xi Chen, Shuliang Dou, Wenjie Li, Dongqi Liu, Yongfu Zhang, Yingming Zhao, Yao Li, Jiupeng Zhao, Xiang Zhang
A high performance ECD with a structure of glass/ITO/WO3/LiF/NiO/ITO has been prepared by electron beam and resistance evaporation methods.
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Catalytic asymmetric synthesis of diazabicyclo[3.1.0]hexanes by 1,3-dipolar cycloaddition of azomethine ylides with azirines

Chem. Commun., 2020, 56,5050-5053
DOI: 10.1039/D0CC01061H, Communication
Alba Molina, Sergio Díaz-Tendero, Javier Adrio, Juan C. Carretero
A practical CuI/(R)-Fesulphos catalyzed 1,3-dipolar cycloaddition of azomethine ylides with azirines has been developed to produce highly valuable enantioenriched diazabicyclo[3.1.0]hexanes.
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Improving the structural and cyclic stabilities of P2-type Na0.67MnO2 cathode material via Cu and Ti co-substitution for sodium ion batteries

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01442G, Communication
Xueping Zhang, Feilong Qiu, Kezhu Jiang, Ping He, Min Han, Shaohua Guo, Haoshen Zhou
An air-stable Na0.67Mn0.7Cu0.15Ti0.15O2 (NMCT) has been synthesized using a solid-state method. And it showed the excellent performance as a cathode material for sodium ion batteries.
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Facile construction of double network cross-linked luminescent supramolecular elastomer from hydrosilylation and pillar[5]arene host–guest recognition

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication
Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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A combined viscosity-restricted intramolecular motion and mitochondrial targeting leads to selective tumor visualization

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02943B, Communication
Le Yu, Jun Feng Zhang, Mingle Li, Dewei Jiang, Ying Zhou, Peter Verwilst, Jong Seung Kim
We report a novel fluorescent molecular conjugate V-M1 enabling an accurate visualization of tumor tissues. The emission wavelength of V-M1 exceeds 650 nm, well within the near-infrared therapeutic window. Tumor...
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Rh(III)-catalyzed sequential ortho- C–H oxidative arylation/cyclization of sulfoxonium ylides with quinones toward 2-hydroxy-dibenzo[b,d]pyran-6-ones

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00176G, Communication
Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng
A rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...
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