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Enzyme-mimicking accelerated signal enhancement for visually multiplexed quantitation of telomerase activity

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01951H, Communication
Lu Sun, Qiao Zhao, Xinli Liu, Yongchun Pan, Yanfeng Gao, Jingjing Yang, Yuzhen Wang, Yujun Song
Here, we propose an amplification strategy of enzyme-mimicking accelerated signal enhancement integrated with triple-channel volumetric bar-chart chip for visually multiplexed quantitation of telomerase activity. This platform was used for evaluating...
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Resistance to the “Last Resort” Antibiotic Colistin: A Single-Zinc Mechanism for Phosphointermediate Formation in MCR Enzymes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication
Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Liquid metal exfoliation of two dimensional polydopamine nanosheets for templated assembly of noble metal nanoparticles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication
Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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Correction: Colloidal synthesis of porous red phosphorus nanoparticles as a metal-free electrocatalyst for the hydrogen evolution reaction

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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Highly dispersed nickel anchored on N-doped carbon molecular sieve derived from metal-organic frameworks for efficient hydrodeoxygenation in aqueous-phase

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication
Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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A metal-organic framework with in-situ generated low-coordinate binuclear Cu(I) units as the highly effective catalyst for photodriven hydrogen production

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09589F, Communication
Pei-Qin Liao, Ningyu Huang, Hai He, Hao Li, Xiao-Ming Chen
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic...
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Self-assembly of an organometallic Fe9O6 cluster from aerobic oxidation of (tmeda)Fe(CH2tBu)2

Chem. Commun., 2020, 56,4994-4997
DOI: 10.1039/D0CC00011F, Communication
Jonathan A. Kephart, Zachary Hecht, Brooke N. Livesay, Indrani Bhowmick, Matthew P. Shores, V. Codrina Popescu, Navamoney Arulsamy, Elliott B. Hulley
Aerobic oxidation of (tmeda)Fe(CH2tBu)2 in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands.
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para-Selective arylation and alkenylation of monosubstituted arenes using thianthrene S-oxide as a transient mediator

Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication
Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication
Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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1,6-Conjugate addition initiated formal [4+2] annulation of p-quinone methides with sulfonyl allenols: a unique access to spiro[5.5]undeca-1,4-dien-3-one scaffolds

Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication
Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Synthetic method, growth mechanism and electrochemical properties of PbSnS2 nanosheets for supercapacitors

Chem. Commun., 2020, 56,5062-5065
DOI: 10.1039/D0CC01011A, Communication
Yuhan Zeng, Hehe Huang, Shenhu Huang, Tongtong Jiang, Zekai Fang, Lin Li, Yuming Dai
Facile hydrothermally synthesized PbSnS2 nanosheets with various morphologies were developed to obtain high performance electrode materials for supercapacitors.
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High performance zinc stannate photoanodes in dye sensitized solar cells with cobalt complex mediators

Chem. Commun., 2020, 56,5042-5045
DOI: 10.1039/D0CC01219J, Communication
Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.
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Solvent-driven migration of highly polar monomers into hydrophobic PDMS produces a thick graft layer via subsurface initiated ATRP for efficient antibiofouling

Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication
Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction

Chem. Commun., 2020, 56,5026-5029
DOI: 10.1039/D0CC01339K, Communication
Ignacio Rosa-Pardo, Carla Casadevall, Luciana Schmidt, Miguel Claros, Raquel E. Galian, Julio Lloret-Fillol, Julia Pérez-Prieto
The cooperative action between the CsPbBr3 surface and capping makes the photoredox homo-/cross-coupling of benzyl bromides under mild conditions possible.
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Synthesis of functionalized tetrahydropyrans via cascade cycloaddition involving silyloxyallyl cation intermediates

Chem. Commun., 2020, 56,5034-5037
DOI: 10.1039/D0CC01796E, Communication
Fatimat O. Badmus, Joshua A. Malone, Frank R. Fronczek, Rendy Kartika
An expedient synthesis of highly substituted tetrahydrobenzofuran via an unsymmetrical silyloxyallyl cation is reported.
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Modulation of an intermediate layer between NiCoP and Ni foam substrate in a microwire array electrode for enhancing the hydrogen-evolution reaction

Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication
Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Modified cation-exchange membrane for phosphate recovery in an electrochemically assisted adsorption–desorption process

Chem. Commun., 2020, 56,5046-5049
DOI: 10.1039/C9CC09563B, Communication
Kostadin V. Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis C. P. M. de Smet, Ernst J. R. Sudhölter
A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe3O4 NPs) coated with polyhexamethylene guanidine (PHMG) is proposed.
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A multipedal DNA walker for amplified detection of tumor exosomes

Chem. Commun., 2020, 56,4982-4985
DOI: 10.1039/D0CC01817A, Communication
Peng Miao, Yuguo Tang
A novel electrochemical biosensor for exosomes is proposed based on a multipedal DNA walking strategy. A limit of detection down to 6/μL is obtained with excellent selectivity.
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Catalytic asymmetric synthesis of diazabicyclo[3.1.0]hexanes by 1,3-dipolar cycloaddition of azomethine ylides with azirines

Chem. Commun., 2020, 56,5050-5053
DOI: 10.1039/D0CC01061H, Communication
Alba Molina, Sergio Díaz-Tendero, Javier Adrio, Juan C. Carretero
A practical CuI/(R)-Fesulphos catalyzed 1,3-dipolar cycloaddition of azomethine ylides with azirines has been developed to produce highly valuable enantioenriched diazabicyclo[3.1.0]hexanes.
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Halogen bonding for molecular recognition: new developments in materials and biological sciences

Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight
Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
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Al centre-powered graphitic nanozyme with high catalytic efficiency for pH-independent chemodynamic therapy of cancer

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01331E, Communication
Jun Li, Ke Yi, Yanli Lei, Zhihe Qing, Zhen Zou, Yuedong Zhang, Haiyan Sun, Ronghua Yang
In this work, an Al centre-powered graphitic nanozyme (Fe/Al-GNE) was developed for chemodynamic cancer therapy, which afforded pH-independent catalytic activity and high reaction kinetics.
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Facile construction of double network cross-linked luminescent supramolecular elastomer from hydrosilylation and pillar[5]arene host–guest recognition

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication
Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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Photo-regulated supramolecular star with a pillar[6]arene-coated metal-organic polyhedron (MOP) core

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00536C, Communication
Xiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram Yasin
We herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.
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Control of microenvironment around enzymes by hydrogels

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01332C, Communication
Yuichiro Kobayashi, Kenji Kohara, Yusuke Kiuchi, Hiroki Onoda, Osami Shoji, Hiroyasu Yamaguchi
We prepared enzyme immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme immobilized hydrogels increased as...
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Electrospray Ionization: an efficient approach to deposit polymetallic molecular switches onto gold surfaces

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01906B, Communication
Amina Benchohra, Christophe Méthivier, david kreher, Jessem Landoulsi, rodrigue lescouezec
Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule’s integrity is monitored by PM-IRRAS and XPS. This approach...
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Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π(-)−π stacking

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02671A, Communication
Shweta P. Yelgaonkar, Daniyal Kiani, Jonas Baltrusaitis, Len R MacGillivray
Salt cocrystals with components that assemble by hydrogen bonds and aromatic anion-molecule stacks (π(−)−π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and...
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Engineering of Decameric D-fructose-6-phosphate Aldolase A by Combinatorial Modulation of Inter- and Intra-subunit Interactions

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02437F, Communication
Xiaohong Yang, Lian Wu, Aipeng Li, Lidan Ye, Jiahai Zhou, Hongwei Yu
Combinatorial modulation of inter- and intra-subunit interactions on decameric D-fructose-6-phosphate aldolase A (FSAA) generated a triple-site variant I31T/Q59T/I195Q FSAA with 27 to 278-fold activity improvement towards target heteroaromatic aldehydes. X-ray...
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A directing group assisted ruthenium catalyzed approach to access meta nitrated phenol

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02851G, Communication
Sheuli Sasmal, Soumya Kumar Sinha, Goutam Kumar Lahiri, Debrabrata Maiti
A meta selective C‒H nitration of phenol derivatives have been developed using a Ru-catalyzed σ-activation strategy. Cu(NO3)2.3H2O has been employed as the nitrating source while Ru3(CO)12 was found to be...
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Integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02329A, Communication
Lijian Zhang, Fei Ma, Ao Qi, Lulu Liu, Junjie Zhang, Simin Xu, Qisheng Zhong, Yusen Chen, Chun-yang Zhang, Chun Cai
We report for the first time the integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke. Especially, we develop an...
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Rotation of a helical coordination polymer by mechanical grinding

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02158J, Communication
Bibhuti Bhusan Rath, Goutam Kumar Kole, Samuel Alexander Morris, Jagadese J. Vittal
Mechanical grinding causes anisotropic cell volume expansion, which facilitates the misaligned arms containing olefin functional groups in the neighbouring strands of the photo-inert helical coordination polymer to align to undergo [2+2] cycloaddition reaction.
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Single molecule magnet behaviour in a square planar S = 1/2 Co(II) complex and spin-state assignment of multiple relaxation modes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01854F, Communication
Indrani Bhowmick, David Washburn Shaffer, Jenny Y Yang, Matthew Shores
We report the first example of field-induced single molecule magnet (SMM) behaviour in a square-planar S = ½ Co(II) pincer complex [(PNNNP)CoBr]Br (2). The related five-coordinate complexes [(PCNCP)CoBr2] (1) and...
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Monitoring Protein Ubiquitination and SUMOylation in real-time by NMR

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02252G, Communication
Batul Ismail Habibullah, Vasvi Tripathi, Parag Surana, Ranabir Das
Ubiquitin (Ub) is a highly conserved 76-amino acid polypeptide that is abundant throughout the eukaryotes. The covalent conjugation of Ub and Ub polymers to substrate proteins governs a variety of...
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Living pictures : perspectives on the film poster in India / edited by David Blamey & Robert D'Souza ; [writers, Sara Dickey ... et al.]




me

How to do everything with Dreamweaver 8 / Michael Meadhra

Meadhra, Michael




me

Typo survival kit for all type emergencies / Jill Yeland

Yelland, Jill




me

3D math primer for graphics and game development / Fletcher Dunn, Ian Parberry

Dunn, Fletcher




me

GPU computing gems / [edited by] Wen-mei W. Hwu




me

The enigma of web interfaces : cultural aspects of web site design / by Linda Lim Mei Luan

Lim, Linda Mei Luan




me

Multimedia security : watermarking, steganography, and forensics / edited by Frank Y. Shih




me

NoSQL distilled : a brief guide to the emerging world of polyglot persistence / Pramod J. Sadalage, Martin Fowler

Sadalage, Pramod J




me

An integrated approach for content extraction, word segmentation and information presentation from Thai websites / Wigrai Thanadechteemapat

Thanadechteemapat, Wigrai




me

An integrated mobile content recommendation system / Worapat Paireekreng

Paireekreng, Worapat




me

Handbook of Augmented Reality / Borko Furht, editor




me

Techniques and principles in three-dimensional imaging : an introductory approach / [compiled] by Martin Richardson




me

Purity and provocation : Dogma 95 / edited by Mette Hjort and Scott MacKenzie




me

Dogme uncut : Lars von Trier, Thomas Vinterburg, and the gang that took on Hollywood / Jack Stevenson

Stevenson, Jack, 1955-




me

Researching virtual worlds : methodologies for studying emergent practices / edited by Ursula Plesner and Louise Phillips




me

Graphic design : history in the writing (1983-2011) / [edited by Sara De Bondt and Catherine de Smet]




me

Grid systems in graphic design : a visual communication manual for graphic designers, typographers and three dimensional designers = Raster Systeme für die visuelle Gestaltung: ein Handbuch für Grafiker, Typografen und Ausstellungsgestalter / Jo

Müller-Brockmann, Josef, 1914-1996, author




me

How to design logos, symbols, and icons : 23 internationally renowned studios reveal how they develop trademarks for print and new media / Gregory Thomas

Thomas, Gregory, 1949-