la Biomedical nanomaterials: from design to implementation / edited by Thomas J. Webster and Hilal Yazici By library.mit.edu Published On :: Sun, 16 Sep 2018 06:22:40 EDT Hayden Library - T174.7.B56 2016 Full Article
la Democratic experiments: problematizing nanotechnology and democracy in Europe and the United States / Brice Laurent By library.mit.edu Published On :: Sun, 4 Aug 2019 06:48:40 EDT Dewey Library - T174.7.L379 2017 Full Article
la Nano meets macro: social perspectives on nanoscale sciences and technologies / editors, Kamilla Lein Kjølberg, Fern Wickson By library.mit.edu Published On :: Sun, 2 Feb 2020 06:24:06 EST Online Resource Full Article
la Canadians report lower self-perceived mental health during the COVID-19 pandemic [electronic resource] / by Leanne Findlay and Rubab Arim By darius.uleth.ca Published On :: [Ottawa] : Statistics Canada = Statistique Canada, 2020 Full Article
la Synthesis of Biaryl Ketones by Arylation of Weinreb Amides with Functionalized Grignard Reagents under Thermodynamic Control vs. Kinetic Control of N,N-Boc2-Amides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00813C, CommunicationGuangchen Li, Michal SzostakA highly efficient method for chemoselective synthesis of biaryl ketones by arylation of Weinreb amides (N-methoxy-N- methylamides) with functionalized Grignard reagents is reported. This protocol offers rapid entry to functionalized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Selenium-promoted electrophilic cyclization of arylpropiolamides: synthesis of 3-organoselenyl spiro[4,5]trienones By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00609B, PaperAna Maria S. Recchi, Pedro H. P. Rosa, Davi F. Back, Gilson ZeniA synthetic approach to regioselective synthesis of 3-organochalcogenyl spiro[4,5]trienones and 3-organochalcogenyl[4,5]triene-2,6-diones is described through the reaction of arylpropiolamides with an electrophilic chalcogen source.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la A modular approach to the bisbenzylisoquinoline alkaloids tetrandrine and isotetrandrine By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3047-3068DOI: 10.1039/D0OB00078G, PaperRamona Schütz, Maximilian Meixner, Iris Antes, Franz BracherA modular short-step synthesis of the bisbenzylisoquinoline alkaloids tetrandrine and isotetrandrine was developed employing N-acyl-Pictet–Spengler reaction and Ullman diaryl ether synthesis as central steps.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums: facile access to arylazopyrrolines By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3149-3157DOI: 10.1039/D0OB00346H, PaperJing Rong, Hao Jiang, Sijing Wang, Zhenni Su, Huiyan Wang, Chuanzhou TaoA novel and facile approach to synthesize arylazopyrroline scaffolds via metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums has been developed, providing access to a variety of 4-arylazo-2-pyrrolines in a highly concise fashion.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Catalyst and solvent switched divergent C–H functionalization: oxidative annulation of N-aryl substituted quinazolin-4-amine with alkynes By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3032-3037DOI: 10.1039/D0OB00318B, CommunicationSiddi Ramulu Meesa, Praveen Kumar Naikawadi, Kishan Gugulothu, K. Shiva KumarCatalyst and solvent controlled ortho/peri site-selective oxidative annulation of C–H bonds of N-aryl substituted quinazolin-4-amines with internal alkynes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Progress in recent development of stereoselective synthesis of β2-amino acid derivatives from β-nitroacrylate derivatives By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,2991-3006DOI: 10.1039/D0OB00448K, Review ArticleHao-Wei Zeng, Ping-Yu Wu, Hsyueh-Liang Wuβ2-Amino acids: recent advances in the synthesis of β2-amino acids and their derivatives from various stereoselective transformations of β-nitroacrylates are summarized.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Regioselective hydroarylation and arylation of maleimides with indazoles via a Rh(III)-catalyzed C–H activation By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3093-3097DOI: 10.1039/D0OB00353K, PaperAsim Kumar Ghosh, Sadhanendu Samanta, Payel Ghosh, Sukanya Neogi, Alakananda HajraSwitchable Rh(III)-catalyzed highly regioselective hydroarylation and oxidative arylation of maleimides with 2-arylindazoles via C–H activation have been demonstrated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Biochemical characterisation of an α1,4 galactosyltransferase from Neisseria weaveri for the synthesis of α1,4-linked galactosides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3142-3148DOI: 10.1039/D0OB00407C, PaperKun Huang, Andrea Marchesi, Kristian Hollingsworth, Peter Both, Ashley P. Mattey, Edward Pallister, Helene Ledru, Simon J. Charnock, M. Carmen Galan, W. Bruce Turnbull, Fabio Parmeggiani, Sabine L. FlitschA new α1,4 galactosyltransferase has been characterised and used for the synthesis of natural and non-natural cell surface trisaccharide antigens.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Rh(III)-Catalyzed regioselective C4 alkylation of indoles with allylic alcohols: direct access to β-indolyl ketones By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3038-3042DOI: 10.1039/D0OB00396D, CommunicationChangduo Pan, Gao Huang, Yujia Shan, Yiting Li, Jin-Tao YuA Rh(III)-catalyzed direct C4 alkylation of indoles with allylic alcohols to access β-indolyl ketones was developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Sub-stoichiometric reductive etherification of carbohydrate substrates and one-pot protecting group manipulation By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3135-3141DOI: 10.1039/D0OB00252F, PaperChiao Wen Chen, Ching Chi Wang, Xin Ru Li, Henryk Witek, Kwok-Kong Tony MongPolymethylhydrosiloxane (PMHS): a sub-stoichiometric reducing agent for reductive etherification of carbohydrate substrates and its application for one-pot protecting group manipulationThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la C-Glycosylation enabled by N-(glycosyloxy)acetamides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3043-3046DOI: 10.1039/D0OB00561D, CommunicationMiao Liu, Bo-Han Li, Tian Li, Xia Wu, Meng Liu, De-Cai Xiong, Xin-Shan YeAn effective C-glycosylation protocol using N-(glycosyloxy)acetamides as donors promoted by SnBr4 has been developed, delivering alkyl C-glycosides and aryl-β-C-glycosides in high yields.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Synthesis, radiolabelling and initial biological characterisation of 18F-labelled xanthine derivatives for PET imaging of Eph receptors By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3104-3116DOI: 10.1039/D0OB00391C, PaperMarc Pretze, Christin Neuber, Elisa Kinski, Birgit Belter, Martin Köckerling, Amedeo Caflisch, Jörg Steinbach, Jens Pietzsch, Constantin MamatTwo new fluorine-18-labelled xanthine derivatives with high binding affinity were synthesised as PET-radioligand candidates for Eph receptors.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Enantioselective synthesis of chiral α-alkynylated thiazolidones by tandem S-addition/acetalization of alkynyl imines By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3117-3124DOI: 10.1039/D0OB00365D, PaperMei-Xin Wang, Juan Liu, Zhen Liu, Yingcheng Wang, Qi-Qiong Yang, Wenyu Shan, Yu-Hua Deng, Zhihui ShaoA SPINOL-CPA catalyzed asymmetric [2 + 3]-annulation of in situ generated alkynyl imines and 1,4-dithiane-2,5-diol has been developed to afford enantiopure α-alkynylated thiazolidones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Asymmetric synthesis of (−)-solanidine and (−)-tomatidenol By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3169-3176DOI: 10.1039/D0OB00457J, PaperYun Wang, Guanxin Huang, Yong Shi, Wei-sheng Tian, Chunlin Zhuang, Fen-Er ChenThe asymmetric synthesis of (−)-solanidine (1) and (−)-tomatidenol (2) has been achieved by employing a cascade ringswitching reaction and a cascade azide reduction/intramolecular reductive amination with 32% and 18.7% overall yields respectively.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Synthesis and aggregation behaviour of single-chain, 1,32-alkyl-branched bis(phosphocholines) – part 2: lateral chain length triggers self-assembling from sheets to fibres to vesicles By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00534G, PaperKai Gruhle, Max Tuchtenhagen, Sindy Müller, Gerd Hause, Annette Meister, Simon DrescherThe synthesis of six single-chain, alkyl-branched bolalipids and first investigations of the lyotropic behaviour of these lipids are reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Half-sandwich (η5-Cp*)Rh(III) complexes of pyrazolated organo-sulfur/selenium/tellurium ligands: efficient catalysts for base/solvent free C–N coupling of chloroarenes under aerobic conditions By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00538J, PaperCharu Sharma, Avinash Kumar Srivastava, Kamal Nayan Sharma, Raj Kumar JoshiThree new Rh(III) complexes of organochalcogen (S/Se/Te) ligands were synthesized and along with a co-catalyst Cu(OAc)2, used for the base/solvent free catalysis of Buchwald type C–N coupling of amines and aryl chlorides under aerobic conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Photocatalytic xanthate-based radical addition/cyclization reaction sequence toward 2-biphenyl isocyanides: synthesis of 6-alkylated phenanthridines By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00136H, CommunicationPedro López-Mendoza, Luis D. MirandaA photocatalytic xanthate-based radical addition/cyclization reaction cascade toward 2-biphenylisocyanides is described as a practical and modular approach to 6-alkylated phenanthridines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Study on the ArI-catalyzed intramolecular oxy-cyclization of 2-alkenylbenzamides to benzoiminolactones By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00612B, CommunicationHuixia Liu, Xiaojun Deng, Xie Huang, Nan Ji, Wei HeA metal-free synthetic method toward the preparation of benzoiminolactones through oxy-cyclization of 2-alkenylbenzamides mediated by a catalyst/oxidant (ArI/mCPBA) system was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Ni(II)-Catalyzed vinylic C–H functionalization of 2-acetamido-3-arylacrylates to access isotetronic acids By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00557F, PaperBiswajit Roy, Eshani Das, Avijit Roy, Dipakranjan MalA ligand-free Ni(II)-catalyzed cascade annulation reaction for the synthesis of 4-aryl-substituted isotetronic acids from 2-acetamido-3-arylacrylates via vinylic C–H functionalization is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Acylation of oxindoles using methyl/phenyl esters via mixed Claisen condensation – An access to 3-alkylideneoxindoles By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00789G, CommunicationRamdas Sreedharan, Purushothaman Rajeshwaran, Pradeep Kumar Reddy Panyam, Saurabh Yadav, C. M. Nagaraja, THIRUMANAVELAN GANDHIPredominantly, aggressive acid chlorides and stoichiometric coupling reagents are employed in the acylating process for synthesizing carbonyl tethered heterocycles. Herein, we report simple acyl sources, viz. methyl and phenyl esters...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la The key entity of a DCAR agonist, phosphatidylinositol mannoside Ac1PIM1: its synthesis and immunomodulatory function By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/C9OB02724F, CommunicationYohei Arai, Shota Torigoe, Takanori Matsumaru, Sho Yamasaki, Yukari FujimotoWe achieved the first synthesis of phosphatidylinositol mannoside Ac1PIM1, and a very potent agonist of an innate immune receptor DCAR is demonstrated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Catalyst- and Solvent-Free Efficient Access to N-Alkylated Amines via Reductive Amination using HBPin By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00740D, CommunicationARNAB RIT, Vipin Kumar Pandey, Somnath BauriA sustainable approach which works under catalyst- and solvent-free conditions for the synthesis of structurally diverse secondary amines has been uncovered. This one-pot protocol works efficiently at room temperature and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la A laccase-catalysed tyrosine click reaction By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00650E, CommunicationShinichi Sato, Keita Nakane, Hiroyuki NakamuraThe tyrosine click reaction of peptides/proteins with the tyrosine modification reagent, N-methyl luminol, was catalysed by a laccase in the presence of molecular oxygen (O2) at 37 °C.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Discrimination of cellular developmental states focusing on glycan transformation and membrane dynamics by using BODIPY-tagged lactosyl ceramides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00547A, PaperKenta Arai, Atsuko Ohtake, Shusaku Daikoku, Katsuhiko Suzuki, Yukishige Ito, Kazuya Kabayama, Koichi Fukase, Yoshimi Kanie, Osamu KanieDifferent cellular states were discriminated by analysing either the glycan transformation of exogenously introduced fluorescently tagged probe molecules or fluorescence recovery after photobleaching before conversion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Rhodium-Catalyzed ortho-Acrylation of Aryl Ketone O-Methyl Oximes with Cyclopropenones By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00064G, CommunicationYafeng Liu, Yuan Tian, Kexin Su, Xin Guo, Baohua ChenAn efficient Rh-catalyzed ortho-acrylation reaction for the synthesis of chalcones from O-methyl ketoximes and cyclopropenones via C–H bond activation has been described. This cross-coupling reaction exhibits high functional group tolerance...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Synthesis of unsymmetrical benzils via palladium-catalysed α-arylation–oxidation of 2-hydroxyacetophenones with aryl bromides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00575D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takanori Matsuda, Souta OyamaUnsymmetrical benzils are synthesised by a one-pot tandem palladium-catalysed α-arylation and oxidation of 2-hydroxyacetophenones with aryl bromides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Blue emissive dimethylmethylene-bridged triphenylamine derivatives appending cross-linkable groups By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00622J, PaperKangyu Zhou, Hongfei Pan, Yongjie Zhang, Houchen Wang, Xiaofei Dong, Xiangkui Ren, Xianggao Li, Shirong Wang, Zhijian ChenBlue-emissive and cross-linkable dimethylmethylene-bridged triphenylamine derivatives were synthesized and their optical and electrochemical properties were investigated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Insights into the secondary structures of lactam N-substituted stapled peptides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00767F, CommunicationAldrin Vasco Vidal, Celia Gonzalez, Stefan Gröger, W Brandt, Jochen Balbach, Carlos Perez, Ludger A. Wessjohann, Daniel G. RiveraStapled peptides derived from the Ugi macrocyclization comprise a special class of cyclopeptides with an N-substituted lactam bridge cross-linking two amino acid side chains. Herein we report a comprehensive analysis...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Protein labeling approach to improve lysosomal targeting and efficacy of antibody–drug conjugates By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3229-3233DOI: 10.1039/D0OB00265H, CommunicationYing Han, Yifan Da, Mingjia Yu, Yaping Cheng, Xin Wang, Jiale Xiong, Guoying Guo, Yan Li, Xianxing Jiang, Xiaoqing CaiAn anti-EGFR nanobody was labeled at the C-terminus with a lysosome-sorting NPGY (Asn-Pro-Gly-Tyr) motif via sortase-mediated ligation to enhance the clathrin-mediated endocytosis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Recent advances in β-L-rhamnosylation By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3216-3228DOI: 10.1039/D0OB00297F, Review ArticleDiksha Rai, Suvarn S. KulkarniThis review describes various methodologies for the stereoselective 1,2-cis glycosylation of L-rhamnose leading to β-L-rhamnosides and their applications in oligosaccharide synthesis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Direct recognition and sensitive detection of circular RNA with ligation-based PCR By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3269-3273DOI: 10.1039/D0OB00625D, CommunicationPengbo Zhang, Na Guo, Kejian Gao, Fengxia Su, Fangfang Wang, Zhengping LiA sensitive and specific method for circRNA detection is developed through the direct ligation of two ingeniously designed DNA probes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Synthesis of methylene cyclopropane-fused chromenes and dihydroquinolines by sequential [4 + 2]- and [1 + 2]-annulation By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3303-3311DOI: 10.1039/D0OB00389A, PaperTianyu Lu, Xuange Zhang, Zhiwei MiaoA base promoted sequential [4 + 2]- and [1 + 2]-annulation of 2-hydroxychalcones or 2-tosylaminochalcones with prop-2-ynylsulfonium salts was developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la A domino annulation approach to 3,4-diacylpyrrolo[1,2-a]pyrazines: decoration of pyrazine units By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3324-3333DOI: 10.1039/D0OB00444H, PaperAnuradha Dagar, Yohan Seo, Wan Namkung, Ikyon KimA new one-pot, sequential three-component access to 3,4-diacylpyrrolo[1,2-a]pyrazine was achieved from the reaction of an α-haloketone, azide, and N-substituted pyrrole-2-carboxaldehyde under mild reaction conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Modular continuous flow synthesis of orthogonally protected 6-deoxy glucose glycals By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3254-3257DOI: 10.1039/D0OB00522C, CommunicationSubbarao Yalamanchili, Tu-Anh V. Nguyen, Nicola L. B. Pohl, Clay S. BennettThe use of a continuous flow platform for the rapid and highly efficient construction of differentially protected glycals from commercial sources is described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la A visible-light-induced “on–off” one-pot synthesis of 3-arylacetylene coumarins with AIE properties By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3346-3353DOI: 10.1039/D0OB00479K, PaperXinjie Wu, Ming Jia, Mengmeng Huang, Jung Keun Kim, Zheng Zhao, Junkai Liu, Jinhu Xi, Yabo Li, Yangjie WuA mild one-pot approach to 3-arylacetylene coumarins with potential AIE activities was developed via photosensitizer-free photocatalysis and thermocatalysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Base-promoted 1,6-conjugate addition of alkylazaarenes to para-quinone methides By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3354-3359DOI: 10.1039/D0OB00419G, PaperAmritha Rayaroth, Rajat Kumar Singh, Kalyanakrishnan A. V., Krishna Hari, Alagiri Kaliyamoorthy1,1,2-Triarylethanes embedded with an azaarene unit were prepared in a single step at ambient temperature via the sodium hexamethyldisilazide mediated 1,6-conjugate addition of unactivated alkylazaarenes on para-quinone methides (p-QMs).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Modular synthesis of oligoacetylacetones via site-selective silylation of acetylacetone derivatives By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3297-3302DOI: 10.1039/D0OB00501K, PaperParantap Sarkar, Yuya Inaba, Hayato Shirakura, Tomoki Yoneda, Yasuhide InokumaAliphatic oligoketones with tailored carbonyl and substituent sequences were modularly synthesized utilizing site-selective formation of enol silyl ethers. Their unique conformational preferences in solid-state were revealed by X-ray crystallography.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Copper-catalyzed direct amination of benzylic hydrocarbons and inactive aliphatic alkanes with arylamines By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3263-3268DOI: 10.1039/D0OB00491J, CommunicationHua Yao, Bo Xie, Xiaoyang Zhong, Shengzhou Jin, Sen Lin, Zhaohua YanA new synthetic method toward direct C–N bond formation through saturated C–H amination of benzylic hydrocarbons and inactive aliphatic alkanes with primary aromatic amines under an inexpensive catalyst/oxidant (Cu/DTBP) system has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la O-Cyclopropyl hydroxylamines: gram-scale synthesis and utility as precursors for N-heterocycles By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3281-3287DOI: 10.1039/D0OB00611D, PaperKaitlyn Lovato, Urmibhusan Bhakta, Yi Pin Ng, László KürtiA novel and scalable synthesis of O-cyclopropyl hydroxylamines is reported. These compounds are bench-stable and have been shown to be practical precursors for the synthesis of N-heterocycles via a di-heteroatom [3,3]-sigmatropic rearrangement.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Dipyrazolodioxadiazocines as shelf-stable “ready-to-use” precursors for an in situ generation of enolate-iminium 1,4-dipoles: a straightforward atom-economical approach to pyrazolo[5,1-d][1,3,5]dioxazines By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, 18,3382-3391DOI: 10.1039/D0OB00451K, PaperVladimir E. Zhulanov, Valeria A. Vigovskaya, Maksim V. Dmitriev, Pavel S. Silaichev, Andrey N. Maslivets, Michael RubinGeneration of cyclic enolate-iminium 1,4-dipoles via thermolysis of dipyrazolodioxadiazocines in the presence of ketones allowed for efficient preparation of pyrazolo[5,1-d][1,3,5]dioxazines.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Controlling the liberation rate of the in situ release of a chemical fuel for the operationally autonomous motions of molecular machines By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00669F, PaperChiara Biagini, Giorgio Capocasa, Daniele Del Giudice, Valerio Cataldi, Luigi Mandolini, Stefano Di StefanoAminolysis of the anhydride of 2-cyano-2-phenylpropanoic acid can be employed to conveniently regulate the liberation rate of the related acid which, in turn, can be used as a fuel for acid–base operated molecular machines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Late-stage synthesis and application of photoreactive probes derived from direct benzoylation of heteroaromatic C–H bonds By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB00336K, CommunicationKevin D. Hesp, Jun Xiao, Graham M. WestA synthetically-driven, late-stage C–H benzoylation strategy for the expedited preparation and evaluation of heterocyclic alternatives to more classical benzophenone photoreactive probes is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Arylation of Indoles Using Cyclohexanones Dually-Catalyzed by Niobic Acid and Palladium-on-Carbons By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00702A, PaperKazuho Ban, Yuta Yamamoto, Hironao Sajiki, Yoshinari Sawama3-Arylindoles were easily constructed from indoles and cyclohexanone derivatives using a combination of catalytic niobic acid-on-carbon (Nb2O5/C) and palladium-on-carbon (Pd/C) under heating conditions without any oxidants. The Lewis acidic Nb2O5/C...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la Hierarchical Self-Assembly of Azobenzene Dyad with Inverted Amide Connection into Toroidal and Tubular Nanostructures By feeds.rsc.org Published On :: Org. Biomol. Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0OB00833H, CommunicationShiki Yagai, Takuho SaitoInversion of the connectivity of amide groups in foldable azobenzene dyads with chiral side chains, which can self-assemble into toroids and nanotubes, significantly increases the thermal stability of these aggregates....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
la DMRC delays inauguration of Yamuna Bank-Noida line By archive.indianexpress.com Published On :: Mon, 10 Aug 2009 12:46:35 GMT Delhi Metro has delayed the inauguration of the Yamuna Bank-Noida line by a month. Full Article
la 'My goal is playing for Manchester United one day' By timesofindia.indiatimes.com Published On :: Wed, 11 Jun 2014 00:06:41 IST Rajib Boy from Kolkata is 16-year-old and a talented footballer, recently selected after a national scouting contest to attend a Manchester United Football Club training camp. Full Article
