Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01211G, Paper

Eun Gyung Lee, Lorenzo Cena, Jiwoon Kwon, Ali Afshari, HaeDong Park, Gary Casuccio, Kristin Bunker, Traci Lersch, Ashley Gall, Huy Pham, Alixandra Wagner, Sushant Agarwal, Cerasela Zoica Dinu, Rakesh Gupta, Sherri A. Friend, Todd A. Stueckle
Manufacturing, processing, use, and disposal of nanoclay-enabled composites potentially lead to the release of nanoclay particles from the polymer matrix in which they are embedded; however, exposures to airborne particles are poorly understood.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01321K, Critical Review

Botao Liu, Kumar Vikrant, Ki-Hyun Kim, Vanish Kumar, Suresh Kumar Kailasa
Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).
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Environ. Sci.: Nano, 2020, 7,1061-1067
DOI: 10.1039/C9EN01246J, Communication

Zhiyun Zhang, Ming Xia, Chuanxin Ma, Huiyuan Guo, Wenhao Wu, Jason C. White, Baoshan Xing, Lili He
An organic solvent-based extraction approach coupled with surface enhanced Raman spectroscopic mapping technique to quantify silver nanoparticles in spinach leaf.
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Environ. Sci.: Nano, 2020, 7,1041-1060
DOI: 10.1039/C9EN00938H, Critical Review

Open Access

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Andrew J. Chetwynd, Iseult Lynch
Metabolites present in the corona may play a key role in biological recognition of nanomaterials yet remain a much-overlooked aspect of the corona.
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Environ. Sci.: Nano, 2020, 7,1115-1125
DOI: 10.1039/C9EN01294J, Paper

Jiating Zhao, Xujun Liang, Nali Zhu, Liming Wang, Yunyun Li, Yu-Feng Li, Lirong Zheng, Zhiyong Zhang, Yuxi Gao, Zhifang Chai
Naturally and anthropogenic selenium nanoparticles highly work on mercury immobilization and inactivation in aquatic-plant systems.
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Environ. Sci.: Nano, 2020, 7,1126-1135
DOI: 10.1039/D0EN00016G, Paper

Qiuju Shi, Weina Zhang, Yuemeng Ji, Jiaxin Wang, Dandan Qin, Jiangyao Chen, Yanpeng Gao, Guiying Li, Taicheng An
Glyoxal (GL) exhibits a preferential tendency to the acidic nanoparticle interface, and sulfuric acid (SA) has a catalytic effect on hydration reaction of glyoxal in the aqueous phase.
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Environ. Sci.: Nano, 2020, 7,1163-1178
DOI: 10.1039/C9EN01448A, Paper

Open Access

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Kevin Hoffmann, Sylvain Bouchet, Iso Christl, Ralf Kaegi, Ruben Kretzschmar
Natural organic matter (NOM) impedes the growth of colloidally stable Cu_xS nanoparticles and slows down their morphological development, but also drives their oxidative dissolution.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00182A, Paper

Zimo Lou, Zheni Wang, Jiasheng Zhou, Chuchen Zhou, Jiang Xu, Xinhua Xu
Efficient dechlorination of a chlorinated aromatic compound was achieved with the application of a novel Pd/TiC/Ti electrode.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90021D, Retraction

Open Access

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Yubing Sun, Wencheng Song, Yang Liu, Tasawar Hayat, Ahmed Alsaedi, Yuejie Ai, Virender K. Sharma, Xiangke Wang
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90019B, Retraction

Open Access

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Yubing Sun, Xiangxue Wang, Wencheng Song, Songhua Lu, Changlun Chen, Xiangke Wang
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00131G, Paper

Jonghun Lim, Michael R. Hoffmann
The Co-TNT/PMS system enables the continuous degradation of organic pollutants under dark and solar light-irradiation conditions.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90016H, Editorial

Kristopher McNeill, Paige J. Novak, Peter J. Vikesland
The Editors-in-Chief of the Environmental Science journals introduce the Best Papers of 2019.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00023J, Paper

Joana Figueiredo, Susana Loureiro, Roberto Martins
Biocides encapsulation appears to be a promising solution to develop a new generation of efficient anti-fouling additives (e.g. SiNC–DCOIT; SiNC–DCOIT–Ag) for maritime coatings with lower environmental hazard than the current state-of-the-art biocides (e.g. DCOIT).
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00024H, Paper

Qiantao Shi, George E. Sterbinsky, Shujuan Zhang, Christos Christodoulatos, George P. Korfiatis, Xiaoguang Meng
Soluble Fe(III)–As(V) complexes were found at both acidic and neutral conditions, which significantly change the solubility of ferric oxides.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00197J, Paper

Yanlong Wang, Kun Yang, Daohui Lin
Although there is an increasing use of nanoparticulate zero-valent iron (nZVI) in the remediation of contaminated soil and water environments, there is still little understanding of the mechanisms of interaction...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00163E, Paper

Yueyang Zhang, Greg G. Goss
The presence of microplastics in the environment and their potential effects on the health of organisms are a subject of great concern.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00202J, Paper

Yuhang Wu, Meiting Song, Zhanli Chai, Jintian Huang, Xiaojing Wang
Formaldehyde (HCHO) is the primary pollutant in indoor, thus it is very essential to establish feasible proposal to decontaminate HCHO up to the accepted level in terms of human health....
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00091D, Paper

Yunyun Li, Nali Zhu, Xujun Liang, Xu Bai, Lirong Zheng, Jiating Zhao, Yu-Feng Li, Zhiyong Zhang, Yuxi Gao
Mercury (Hg) pollution is a worldwide concern. Silica nanoparticles (Nano-SiO2) can be released into ecosystems through natural and anthropogenic (engineered Nano-SiO2) processes. Here, the influence of two sizes (30 nm...
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00284D, Paper

Fanqing Meng, wei Ma, Yinglong Wang, Zhaoyou Zhu, zhen chen, gung Lu
The elimination of antibiotics by piezo-catalysis method has recently drawn great attention for its benefits in engineering application. However, the risk assessment of the target antibiotics and its degradation intermediates...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper

Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00214C, Paper

Li Lu, Min Huang, Yuxiong Huang, Philippe F.-X. Corvini, Rong Ji, Lijuan Zhao
Mn₃O₄ nanoenzymes boost endogenous antioxidants in, and enhance resistance of, the cucumber (Cucumis sativus) plant subjected to salinity stress.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01300H, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Adam Davis, Fatima Nasser, Jamie R Lead, Zongbo Shi
The pH within the gastrointestinal (GI) tract of zooplankton regulates the bioavailability of nutrients and inorganic toxins (metals, nanoparticles) and the breakdown of ingested food. However, measuring the spatial distribution...
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01427F, Paper

Vincent Noel, Naresh Kumar, Kristin Boye, Lilia barragan, Juan Lezama-Pacheco, Rosalie K. Chu, Nikola Tolic, Gordon Brown, John Bargar
We have used synchrotron-based X-ray absorption spectroscopy (structure of Fe-S clusters), transmission electron microscopy (solid-phase crystallinity), Fourier-transform ion-cyclotron-resonance mass spectrometry (identity and composition of natural organic carbon compounds), inductively coupled...
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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication

Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a Rh^III₄Zn^II₄ polycarboxylate is reported.
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CrystEngComm, 2020, 22,2849-2858
DOI: 10.1039/D0CE00024H, Paper

T. V. M. Sreekanth, P. C. Nagajyothi, K. C. Devarayapalli, J. Shim, K. Yoo
A ZnCo₂O₄ electrocatalyst for the efficient MOR and ORR.
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CrystEngComm, 2020, 22,2728-2742
DOI: 10.1039/C9CE01972C, Paper

Marc Robin, Stanislas Von Euw, Guillaume Renaudin, Sandrine Gomes, Jean-Marc Krafft, Nadine Nassif, Thierry Azaïs, Guylène Costentin
Monitoring apatite formation through in situ RAMAN and ex situ ssNMR spectroscopy.
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CrystEngComm, 2020, 22,2781-2787
DOI: 10.1039/C9CE02018G, Paper

Hyo Chang Jang, Katsuhiko Saito, Qixin Guo, Kin Man Yu, Wladek Walukiewicz, Tooru Tanaka
We have grown Zn_1−xCd_xO (ZnCdO) thin films by molecular beam epitaxy on α-Al₂O₃ (0001) substrates across the full composition range of 0 ≤ x ≤ 1. A large optical gap of 3.0 eV is obtained in rocksalt-ZnCdO with a low resistivity and high mobility.
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CrystEngComm, 2020, 22,2866-2872
DOI: 10.1039/D0CE00096E, Paper

Andrei V. Churakov, Dmitry A. Grishanov, Alexander G. Medvedev, Alexey A. Mikhaylov, Mikhail V. Vener, Mger A. Navasardyan, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V. Prikhodchenko
2-Aminobenzimidazole peroxosolvate – the third H₂O₂ crystalline adduct stabilized with the maximum possible number of hydrogen bonds formed by one hydrogen peroxide molecule.
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CrystEngComm, 2020, 22,2837-2844
DOI: 10.1039/D0CE00238K, Paper

Xinfang Liu, Liyong Du, Rongfang Li, Ningning Ma, Mengdi You, Xun Feng
Isostructural Ln-CPs (1-Eu and 2-Tb) show almost the same high detection ability for Fe³⁺ and different detection abilities for aniline. The detection difference was studied through PXRD, UV-vis, luminescence lifetimes and Hirshfeld surface analysis.
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CrystEngComm, 2020, 22,2743-2755
DOI: 10.1039/D0CE00064G, Paper

Bowen Sun, Hui Wang, Jiakun Wu, Yanling Geng, Jixiang Xu, Yaowei Wang, Yanyan Li, Haifeng Lin, Lei Wang
Unique ZnS@CdS@Cd_0.5Zn_0.5S-MoS₂ hollow nanospheres with abundant active sites and enhanced light-harvesting and charge separation demonstrate efficient H₂ evolution from visible-light-driven water-splitting.
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CrystEngComm, 2020, 22,2827-2836
DOI: 10.1039/D0CE00171F, Paper

Binghui Xu, Xin Dai, Qingke Tan, Yuan Wei, Gonggang Liu, Guanglei Wu
In this work, a nano-sized goethite and zinc oxide hetero-structure (FeOOH@ZnO) dispersed on reduced graphene oxide (RGO) sheets was synthesized for the first time to construct a ternary composite (FeOOH@ZnO/RGO) via a stepped graphene oxide (GO) deoxygenation process.
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CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper

Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between Fe^III/Cr^I ion and Cu^II ion.
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CrystEngComm, 2020, 22,2817-2826
DOI: 10.1039/D0CE00070A, Paper

Florbela Pereira
Machine learning algorithms were explored for the prediction of the crystallization propensity based on molecular descriptors and fingerprints generated from 2D chemical structures and 3D chemical structures optimized with empirical methods.
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CrystEngComm, 2020, 22,2766-2771
DOI: 10.1039/D0CE00014K, Paper

Ornella E. Y. Kilinkissa, Krishna K. Govender, Nikoletta B. Báthori
Comparison of chiral and racemic binary cocrystals showed that the chiral building block limits the formation of certain intermolecular interactions, decreases the packing efficiency, lowers the melting point and increases aqueous solubility.
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CrystEngComm, 2020, 22,2845-2848
DOI: 10.1039/D0CE00263A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Teng Li, Frank Krumeich, Jeroen A. van Bokhoven
Exploiting the protective role of extra-framework aluminum species on the crystal rim, all-silica hollow zeolites are efficiently produced by demetallation.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00317D, Paper

Zhen-Li Yang, Jian Qin, Jun- Qing Yang , Jianguo Zhang
Research on novel energetic coordination polymers (ECPs) is becoming increasingly important for energetic materials, numerous ECPs were reported and found to be potential energetic materials. In this study, 4,5-dicarboxylic-1,2,3-triazolean was...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00269K, Paper

Selma Piranej, Michael A. W. Shelhart Sayers, Gregory J. Deye, Sergey N. Maximoff, Jonathan P. Hopwood, Haejun Park, Jean G. Slavsky, Jacob Ciszek
Reactivity trends for molecular solids cannot be explained exclusively through topochemical phenomenon (i.e. diffusivity, reaction cavities) or electronic structure of the molecules. As an example of this class, Diels-Alder reactions...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00294A, Paper

Chih-Tung Yang, Xiang-Kai Yang, Ji-Hong Hu, Wei-Te Lee, Tsun-Ren Chen, Chih-Chieh Wang, Jhy-Der Chen
Two extended metal chains based on linear tetracopper units are reported, in which the bromide complex undergoes reversible structural transformation and luminescence change.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00430H, Paper

Hai-Huan Yu, Jia-Qi Chi, Zhong-Min Su, Xiao Li, Jing Sun, Chen Zhou, Xiao-Li Hu, Qun Liu
The existence of Cr2O72- anions, excessive Fe3+ cations in water and picric acid in seawater have irreversible harm to human health and aquatic organism. Herein, a water-stable terbium metal-organic framework...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00347F, Paper

Yu Feng, Erwei Du, Shijing Gong, Ke Yu, Xiaofan Chen, Ziqiang Zhu
The MoS2@VS2 micro-nano composite was synthesized via a two-step hydrothermal method. The field emission properties of MoS2@VS2 micro-nano composite were investigated for the first time. The finger-like VS2 has a...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00360C, Paper

Xiufang Li, Qunmei Fan, Qiang Zhang, Shuqin Yan, Renchuan You
Thermal annealing strongly impacts the crystallization of proteins. Despite the fundamental importance for the crystallization of silk fibroin, the underlying crystallization kinetics of silk fibroin in freezing state has not...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00168F, Paper

Shubhangi Kakkar, K. Renuka Devi, Michael Svärd, Åke Rasmuson
Nucleation behaviour of salicylamide in different solvents was determined and compared with salicylic acid, attempting to progress the rationalization of the influence of the solvent and solute on crystal nucleation of organic compounds in solution.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00526F, Paper

Shuang Zhao, Baiqi Shao, Yang Feng, Senwen Yuan, Langping Dong, Liang Zhang, Hongpeng You
A novel synthesis strategy of porous/hollow YVO₄ submicro-ellipsoids with multicolor emissions has been developed based on the high structural matching of LYH and YVO₄.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00026D, Paper

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Thai T. H. Nguyen, Robert B. Hammond, Ioanna D. Styliari, Darragh Murnane, Kevin J. Roberts
A detailed inter-molecular (synthonic) analysis of terbutaline sulfate, an ionic addition salt for inhalation drug formulation, is related to its crystal morphology, the surface chemistry of the habit faces and hence to its crystal surface energy.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/C9CE01884K, Communication

Shuangliang Cheng, Rachel E. Hunneke, Mengkun Tian, Eric Lukosi, Mariya Zhuravleva, Charles L. Melcher, Yuntao Wu
We developed novel LiCl–CeCl₃ eutectic scintillators that are capable of detecting thermal neutrons.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00084A, Paper

Yang Wang, Mengjia Luo, pei Zhao, Xiangli Che, Yunzhen Cao, Fu Qiang Huang
A new mid-infrared nonlinear optical oxyselenide, Sr₄Pb_1.5Sb₅O₅Se₈, was successfully synthesized by traditional solid-state reaction. It crystallizes in the noncentrosymmetric space group Cm (No. 8) of the monoclinic system. The crystal...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00214C, Paper

João P. P. Copetti, Paulo R. S. Salbego, Tainára Orlando, Jéssica M. L. Rosa, Gabriela F. Fiss, João P. G. de Oliveira, Mário L. A. A. Vasconcellos, Nilo Zanatta, Helio G. Bonacorso, Marcos A. P. Martins
The crystallization mechanisms of a series of fourteen 7-chloro-4-substituted-quinolines were proposed based on a retrocrystallization approach using the supramolecular cluster as demarcation.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00417K, Paper

Weidong Hou, Jia Yang, Haiming Xu, Dongya Li, Zhongwei Zou, Dongsheng Xia
Nymphaea-like BiOCl with oxygen vacancies (OVs) was successfully prepared by adjusting the pH of the precursor and using aspartic acid as surfactant. The as-fabricated samples were investigated by XRD, SEM,...
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CrystEngComm, 2020, 22,2904-2913
DOI: 10.1039/C9CE01157A, Paper

Edurne S. Larrea, Roberto Fernández de Luis, Arkaitz Fidalgo-Marijuan, Eva M. Maya, Marta Iglesias, Maria I. Arriortua
The versatility of CuBTC (HKUST-1) MOF materials to be functionalized to improve their catalytic activity performance was evaluated. CuBTC@IL catalysts are selective for the cycloaddition of CO₂ to epoxides, giving rise to value-added products.
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