Environ. Sci.: Nano, 2020, 7,1041-1060
DOI: 10.1039/C9EN00938H, Critical Review

Open Access

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Andrew J. Chetwynd, Iseult Lynch
Metabolites present in the corona may play a key role in biological recognition of nanomaterials yet remain a much-overlooked aspect of the corona.
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Environ. Sci.: Nano, 2020, 7,1214-1224
DOI: 10.1039/C9EN01279F, Paper

Xue Han, Peng Lv, Lu-Guang Wang, Fei Long, Xiao-Lin Ma, Chang Liu, Yu-Jie Feng, Ming-Feng Yang, Xiang Xiao
The spread of antibiotic resistance genes (ARGs) in the environment has aroused growing concern for human health and ecological safety.
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Environ. Sci.: Nano, 2020, 7,1115-1125
DOI: 10.1039/C9EN01294J, Paper

Jiating Zhao, Xujun Liang, Nali Zhu, Liming Wang, Yunyun Li, Yu-Feng Li, Lirong Zheng, Zhiyong Zhang, Yuxi Gao, Zhifang Chai
Naturally and anthropogenic selenium nanoparticles highly work on mercury immobilization and inactivation in aquatic-plant systems.
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Environ. Sci.: Nano, 2020, 7,1266-1274
DOI: 10.1039/C9EN01466G, Paper

Peng Wang, Du Sun, Mingxia Deng, Shaoning Zhang, Qingyuan Bi, Wei Zhao, Fuqiang Huang
FAPTO exhibits a low pH_zpc value along with abundant amino and hydroxyl bifunctional groups for efficient heavy metal removal from sewage.
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Environ. Sci.: Nano, 2020, 7,1252-1265
DOI: 10.1039/C9EN01270B, Paper

Chi-Wei Huang, Chun-Han Chang, Shang-Wei Li, Pei-Ling Yen, Vivian Hsiu-Chuan Liao
Co-exposure to foodborne and waterborne ZnO nanoparticles in aquatic sediment environments increases mortality, Zn bioaccumulation, stress genes expression, and DNA damage in freshwater Asian clam Corbicula fluminea.
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Environ. Sci.: Nano, 2020, 7,1136-1149
DOI: 10.1039/D0EN00049C, Paper

Open Access

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Laura-Jayne A. Ellis, Eugenia Valsami-Jones, Iseult Lynch
Pristine engineered nanomaterials (NMs) entering the aquatic environment become ‘aged’ during their lifetime via chemical, physical and/or biological process.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00137F, Paper

Stuart S. Lichtenberg, Kanthi Nuti, Jason DeRouchey, Olga V. Tsyusko, Jason M. Unrine
Chitosan/dsRNA polyplex nanoparticles have shown great potential as insect biocontrol agents. Here, we show that polyplex nanoparticles have their gene silencing capacity altered by environmental variables.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90019B, Retraction

Open Access

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Yubing Sun, Xiangxue Wang, Wencheng Song, Songhua Lu, Changlun Chen, Xiangke Wang
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90017F, Retraction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Fengbo Li, Xiaoyu Li, Pu Cui, Yubing Sun
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN90016H, Editorial

Kristopher McNeill, Paige J. Novak, Peter J. Vikesland
The Editors-in-Chief of the Environmental Science journals introduce the Best Papers of 2019.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00202J, Paper

Yuhang Wu, Meiting Song, Zhanli Chai, Jintian Huang, Xiaojing Wang
Formaldehyde (HCHO) is the primary pollutant in indoor, thus it is very essential to establish feasible proposal to decontaminate HCHO up to the accepted level in terms of human health....
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/C9EN01439J, Paper

Mohammad Nassar, Mélanie Auffan, Catherine Santaella, Armand Masion, Jérôme Rose
Associating mesocosm experimentations with multivariate analyses to identify the parameters governing the behavior and impact of nanomaterials on aquatic ecosystems.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00091D, Paper

Yunyun Li, Nali Zhu, Xujun Liang, Xu Bai, Lirong Zheng, Jiating Zhao, Yu-Feng Li, Zhiyong Zhang, Yuxi Gao
Mercury (Hg) pollution is a worldwide concern. Silica nanoparticles (Nano-SiO2) can be released into ecosystems through natural and anthropogenic (engineered Nano-SiO2) processes. Here, the influence of two sizes (30 nm...
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00284D, Paper

Fanqing Meng, wei Ma, Yinglong Wang, Zhaoyou Zhu, zhen chen, gung Lu
The elimination of antibiotics by piezo-catalysis method has recently drawn great attention for its benefits in engineering application. However, the risk assessment of the target antibiotics and its degradation intermediates...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper

Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00214C, Paper

Li Lu, Min Huang, Yuxiong Huang, Philippe F.-X. Corvini, Rong Ji, Lijuan Zhao
Mn₃O₄ nanoenzymes boost endogenous antioxidants in, and enhance resistance of, the cucumber (Cucumis sativus) plant subjected to salinity stress.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01366K, Paper

Peirui Liu, Jianfeng Zhou, Ting Wang, Cecilia Yu, Yu Hong, Xing Xie
Locally enhanced electric field treatment (LEEFT) has been considered as a novel and promising technology for efficient microorganism inactivation in recent years. Previous studies were primarily conducted on bacteria and...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00008F, Paper

Jeffrey M. Farner, Jacopo De Tommaso, Heather Mantel, Rachel S. Cheong, Nathalie Tufenkji
Research has focused on nanoparticle (NP) aggregation and transport behavior in saturated granular porous media, but few studies have looked at the effect that temperature variability associated with winter conditions will have on engineered NPs.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01300H, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Adam Davis, Fatima Nasser, Jamie R Lead, Zongbo Shi
The pH within the gastrointestinal (GI) tract of zooplankton regulates the bioavailability of nutrients and inorganic toxins (metals, nanoparticles) and the breakdown of ingested food. However, measuring the spatial distribution...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00075B, Paper

Jaroslav Semerád, Jan Filip, Alena Ševců, Miroslav Brumovský, Nhung H. A. Nguyen, Jiří Mikšíček, Tomáš Lederer, Alena Filipová, Jana Boháčková, Tomáš Cajthaml
This work describes an important, environmentally relevant phenomenon of metal nanoparticle aging in relation to the toxicity of nanomaterials; in this case, sulfidated nanoscale zero-valent materials intended for remediation purposes.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00404A, Communication

Xinrui He, Jian Zhao, Zeqing Tan, Jiaxin Zhao, Xiao Cheng, Chuanjian Zhou
Chalcone single crystals with distinctively different emission color and photoinduced mechanical response are designed and fabricated via fine-tuning the donor substituents.
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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication

Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a Rh^III₄Zn^II₄ polycarboxylate is reported.
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CrystEngComm, 2020, 22,2849-2858
DOI: 10.1039/D0CE00024H, Paper

T. V. M. Sreekanth, P. C. Nagajyothi, K. C. Devarayapalli, J. Shim, K. Yoo
A ZnCo₂O₄ electrocatalyst for the efficient MOR and ORR.
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CrystEngComm, 2020, 22,2788-2794
DOI: 10.1039/C9CE01228A, Paper

Zsolt Dallos, Viktória Kovács Kis, Ferenc Kristály, István Dódony
Bioapatite, the main inorganic component of bone, is similar to hydroxyapatite (HAp, Ca₅[PO₄]₃(OH)) having some [CO₃]²⁻ content which plays an important role in leaching/precipitation processes in many biological lesions.
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CrystEngComm, 2020, 22,2709-2717
DOI: 10.1039/C9CE01966A, Paper

Xiaojuan Bai, Boxuan Sun, Xuyu Wang, Tianshuo Zhang, Qiang Hao, Bing-Jie Ni, Ruilong Zong, Ziyang Zhang, Xiaoran Zhang, Haiyan Li
The mechanism of the photocatalytic reaction of defective ZnO systems was determined.
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CrystEngComm, 2020, 22,2837-2844
DOI: 10.1039/D0CE00238K, Paper

Xinfang Liu, Liyong Du, Rongfang Li, Ningning Ma, Mengdi You, Xun Feng
Isostructural Ln-CPs (1-Eu and 2-Tb) show almost the same high detection ability for Fe³⁺ and different detection abilities for aniline. The detection difference was studied through PXRD, UV-vis, luminescence lifetimes and Hirshfeld surface analysis.
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CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper

Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between Fe^III/Cr^I ion and Cu^II ion.
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CrystEngComm, 2020, 22,2859-2865
DOI: 10.1039/D0CE00119H, Paper

Ines E. Collings, Paul J. Saines, Mirko Mikolasek, Tiziana Boffa Ballaran, Michael Hanfland
Effects of A-site and M-site substitutions on the structural properties of perovskite dimethylammonium iron formate.
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CrystEngComm, 2020, 22,2772-2780
DOI: 10.1039/D0CE00287A, Paper

S. Zänker, G. Scholz, M. Heise, F. Emmerling, E. Kemnitz
New coordination polymers with 2D network structures with fluorine directly coordinated to the metal ion were prepared both via mechanochemical synthesis and fluorolytic sol–gel synthesis.
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CrystEngComm, 2020, 22,2817-2826
DOI: 10.1039/D0CE00070A, Paper

Florbela Pereira
Machine learning algorithms were explored for the prediction of the crystallization propensity based on molecular descriptors and fingerprints generated from 2D chemical structures and 3D chemical structures optimized with empirical methods.
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CrystEngComm, 2020, 22,2766-2771
DOI: 10.1039/D0CE00014K, Paper

Ornella E. Y. Kilinkissa, Krishna K. Govender, Nikoletta B. Báthori
Comparison of chiral and racemic binary cocrystals showed that the chiral building block limits the formation of certain intermolecular interactions, decreases the packing efficiency, lowers the melting point and increases aqueous solubility.
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CrystEngComm, 2020, 22,2845-2848
DOI: 10.1039/D0CE00263A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Teng Li, Frank Krumeich, Jeroen A. van Bokhoven
Exploiting the protective role of extra-framework aluminum species on the crystal rim, all-silica hollow zeolites are efficiently produced by demetallation.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00113A, Paper

Mohd Nazri Abd Rahman, Yusnizam Yusuf, Afiq Anuar, Mohamad Raqif Mahat, Narong Chanlek, Noor Azrina Talik, Muhammad I. M. Abdul Khudus, Norzaini Zainal, Wan Haliza Abd Majid, Ahmad Shuhaimi
An atomically flat covering with a dense and crack-free surface of aluminium nitride films was successfully deposited on a sapphire-(0 0 0 1) substrate through a pulsed atomic-layer epitaxy technique via horizontal metalorganic chemical vapour deposition.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00370K, Paper

Corrado Di Nicola, Alessia Tombesi, Marco Moroni, Rebecca Vismara, Fabio Marchetti, Riccardo Pettinari, Luca Nardo, Guglielmo Vesco, Simona Galli, Silvia Casassa, Luciano Pandolfo, Claudio Pettinari
Enlarging the family of CPs with the {Cu(μ-pz)₂} building unit: synthesis, thermal behaviour, crystal structure and spectroscopic properties of [Cu(μ-4-Xpz)₂(μ-DMF)]_n (4-Xpz = 4-Xpyrazolate, X = H, Cl, Br, I) and the non-solvated counterparts.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication

Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L²)₂] (M = Cu²⁺, Pd²⁺, Pt²⁺; L² = dinaphthoylmethanido⁻), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00317D, Paper

Zhen-Li Yang, Jian Qin, Jun- Qing Yang , Jianguo Zhang
Research on novel energetic coordination polymers (ECPs) is becoming increasingly important for energetic materials, numerous ECPs were reported and found to be potential energetic materials. In this study, 4,5-dicarboxylic-1,2,3-triazolean was...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00255K, Paper

Yunhao Zang, Jinying Wang, Jianfeng Gu, Jiangying Qu, Feng Gao
Herein, a mesoporogen-free, and steam-assisted route is proposed to synthesize highly crystalline hierarchical HZSM-5 using Stöber silica spheres as the precursor. The effect of crystallization time on the morphology and...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00269K, Paper

Selma Piranej, Michael A. W. Shelhart Sayers, Gregory J. Deye, Sergey N. Maximoff, Jonathan P. Hopwood, Haejun Park, Jean G. Slavsky, Jacob Ciszek
Reactivity trends for molecular solids cannot be explained exclusively through topochemical phenomenon (i.e. diffusivity, reaction cavities) or electronic structure of the molecules. As an example of this class, Diels-Alder reactions...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00294A, Paper

Chih-Tung Yang, Xiang-Kai Yang, Ji-Hong Hu, Wei-Te Lee, Tsun-Ren Chen, Chih-Chieh Wang, Jhy-Der Chen
Two extended metal chains based on linear tetracopper units are reported, in which the bromide complex undergoes reversible structural transformation and luminescence change.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00430H, Paper

Hai-Huan Yu, Jia-Qi Chi, Zhong-Min Su, Xiao Li, Jing Sun, Chen Zhou, Xiao-Li Hu, Qun Liu
The existence of Cr2O72- anions, excessive Fe3+ cations in water and picric acid in seawater have irreversible harm to human health and aquatic organism. Herein, a water-stable terbium metal-organic framework...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90057E, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00297F, Paper

Zhihui Hu, Zhi Chen, Juntong Huang, Mingge Yan, Meng Zhang, Lei Zhang, Xibao Li, Zhijun Feng
3C-SiC nanowires with nanosheets were synthesized via a direct reaction of Si vapor (from solid silicon) and SiO vapor (from silicon and silicon dioxide) with graphene nanosheets at 1500 °C without any additional metal catalyst.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00311E, Paper

Lei Gao, Yunhui Hao, Xiunan Zhang, Xin Huang, Ting Wang, Hongxun Hao
Photomechanical motions of the polymorphs of trans-4,4'-azopyridine are distinct under the influence of different molecular packing and intermolecular interactions.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00214C, Paper

João P. P. Copetti, Paulo R. S. Salbego, Tainára Orlando, Jéssica M. L. Rosa, Gabriela F. Fiss, João P. G. de Oliveira, Mário L. A. A. Vasconcellos, Nilo Zanatta, Helio G. Bonacorso, Marcos A. P. Martins
The crystallization mechanisms of a series of fourteen 7-chloro-4-substituted-quinolines were proposed based on a retrocrystallization approach using the supramolecular cluster as demarcation.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00644K, Communication

Kazuyuki Maeda, Kentaro Wakui, Kyosuke Arakawa, Atsushi Kondo
Topotactic pillaring of lamellar aluminophosphate (ALPO) layers with zinc cations is used to prepare microporous zincoaluminophosphate (ZnAPO) with AFY-type framework for the first time. This approach should be promising for...
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CrystEngComm, 2020, 22,2970-2977
DOI: 10.1039/D0CE00251H, Paper

Prasanata Kumar Bhaumik, Abhisek Banerjee, Tamal Dutta, Sudipta Chatterjee, Antonio Frontera, Shouvik Chattopadhyay
The ethoxy groups have a dual effect in hindering the attack of the pseudo-halides on the nickel(II) centre and also in stabilizing the complex by intra-molecular interactions.
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CrystEngComm, 2020, 22,2914-2918
DOI: 10.1039/D0CE00244E, Paper

Shengliang Zhong, Honghong Zou, Yanhua Ji, Chenghui Zeng, Lei Wang, Yanhong Chen, Hualan Xu
Coordination polymer superstructures connected by a flange union with a good geometry were fabricated. Assembly, disassembly and reassembly process happened during the formation.
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CrystEngComm, 2020, 22,2945-2952
DOI: 10.1039/D0CE00185F, Paper

Jiacheng Yao, Min Zhang, Hongfei Yin, Muhammad Arif, Xiaoheng Liu
Fabrication of rose-like WO₃ by chemical bath method.
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CrystEngComm, 2020, 22,2990-2997
DOI: 10.1039/D0CE00112K, Paper

Yan-Kai Li, Yu-Ge Wang, Cui-Liu Fu, You-Liang Zhu, Zhan-Wei Li, Zhao-Yan Sun
The crystallization transformation from form II to form I in PB-1/CNT materials is mainly influenced by the lamellar thickness.
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