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Transmission Lines

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Power Transmission Projects

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Essar Power Transmission

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Associated Transmission System

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Rise in bank credit to infrastructure sectors

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Multimodal Logistics Park

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Ministry of New and Renewable Energy

Ministry of New and Renewable Energy





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A polymerization-induced self-assembly process for all-styrenic nano-objects using the living anionic polymerization mechanism

Polym. Chem., 2020, 11,2635-2639
DOI: 10.1039/D0PY00296H, Communication
Chengcheng Zhou, Jian Wang, Peng Zhou, Guowei Wang
By combination of the living anionic polymerization (LAP) mechanism with the polymerization-induced self-assembly (PISA) technique, the all-styrenic diblock copolymer poly(p-tert-butylstyrene)-b-polystyrene (PtBS-b-PS) based LAP PISA was successfully developed.
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Tin(II) 2-ethylhexanoate catalysed methanolysis of end-of-life poly(lactide)

Polym. Chem., 2020, 11,2625-2629
DOI: 10.1039/D0PY00292E, Communication
Melanie Hofmann, Christoph Alberti, Felix Scheliga, Roderich R. R. Meißner, Stephan Enthaler
The depolymerisation of end-of-life poly(lactide) (PLA) goods was studied as part of the chemical recycling of PLA.
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A covalently crosslinked silk fibroin hydrogel using enzymatic oxidation and chemoenzymatically synthesized copolypeptide crosslinkers consisting of a GPG tripeptide motif and tyrosine: control of gelation and resilience

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00187B, Paper
Hiromitsu Sogawa, Takuya Katashima, Keiji Numata
A covalently crosslinked silk fibroin hydrogel was successfully formed via an enzymatic crosslinking reaction using copolypeptides, which consist of a glycine–proline–glycine tripeptide motif and tyrosine, as linker molecules.
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Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00369G, Paper
Xun Zhang, Siping Hu, Qiang Ma, Saihu Liao
A visible light-regulated ring-opening polymerization of lactones has been developed based on the excited state acidity of ESPT molecules.
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Synthesis and enantioseparation of proline-derived helical polyacetylenes as chiral stationary phases for HPLC

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00205D, Paper
Ge Shi, Xiao Dai, Yue Zhou, Jie Zhang, Jun Shen, Xinhua Wan
Proline-derived aliphatically substituted polyacetylenes with stable helical conformations exhibit an excellent enantioseparation ability as chiral stationary phases of HPLC.
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Synthesis of star-shaped polyzwitterions with adjustable UCST and fast responsiveness by a facile RAFT polymerization

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00318B, Paper
Zhi Li, Hao Li, Zhonghe Sun, Botao Hao, Tung-Chun Lee, Anchao Feng, Liqun Zhang, San H. Thang
We describe crosslinking of polyzwitterions for the formation of novel star-shaped polymers with low polydispersities and dual-responsiveness using RAFT polymerization.
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Poly(alanine-nylon-alanine) as a bioplastic: chemoenzymatic synthesis, thermal properties and biological degradation effects

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00137F, Paper
Open Access
Prashant G. Gudeangadi, Kei Uchida, Ayaka Tateishi, Kayo Terada, Hiroyasu Masunaga, Kousuke Tsuchiya, Hitoshi Miyakawa, Keiji Numata
Poly(amino acids) such as polypeptides and proteins are attractive biomass-based polymers that potentially contribute to circular economy for plastic.
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Surfactant-free synthesis of layered double hydroxide-armored latex particles

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00140F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
X. G. Qiao, P.-Y. Dugas, V. Prevot, E. Bourgeat-Lami
MgAl-layered double hydroxide (LDH)-armored latexes were produced by Pickering emulsion polymerization of styrene using 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) as auxiliary comonomers.
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Using the dynamic behavior of macrocyclic monomers with a bis(hindered amino)disulfide linker for the preparation of end-functionalized polymers

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00366B, Paper
Hirogi Yokochi, Rikito Takashima, Daisuke Aoki, Hideyuki Otsuka
End-functionalized polymers were synthesized by simply heating a mixture of a macrocyclic compound with one bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) moiety and bifunctional acyclic BiTEMPS compounds as sources of repeat units and terminal groups, respectively.
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Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00249F, Communication
Zhonghua Cheng, Lei Wang, Yan He, Xingjia Chen, Xiaojun Wu, Hangxun Xu, Yaozu Liao, Meifang Zhu
A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts.
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Synthesis of acrylamide-based block-copolymer brushes under flow: monitoring real-time growth and surface restructuring upon drying

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00219D, Paper
Open Access
Joydeb Mandal, Andrea Arcifa, Nicholas D. Spencer
Block-copolymer brushes of water-soluble acrylamides have been synthesised by SI-ATRP under continuous flow and their growth monitored in situ by means of a quartz-crystal microbalance with dissipation (QCM-D).
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Temporal control of RAFT polymerization via magnetic catalysis

Polym. Chem., 2020, 11,2838-2846
DOI: 10.1039/D0PY00220H, Paper
Amin Reyhani, Omid Mazaheri, Masood S. Alivand, Kathryn A. Mumford, Greg Qiao
Magnetic core–shell structured Fe3O4@Fe(II)–MOF nanoparticles have enabled the temporal control of RAFT polymerization via an “on–off” process.
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Simple improvements to Gilch synthesis and molecular weight modulation of MEH-PPV

Polym. Chem., 2020, 11,2831-2837
DOI: 10.1039/D0PY00072H, Paper
Riley O'shea, Wallace W. H. Wong
The solvent and temperature used in the Gilch synthesis of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) were varied to achieve an improved set of reaction conditions.
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Synthesis of a side-chain hole transporting polymer through Mitsunobu post-functionalization for efficient inverted perovskite solar cells

Polym. Chem., 2020, 11,2883-2888
DOI: 10.1039/D0PY00134A, Paper
Liuyuan Lan, Xiang Deng, Jie Zhang, Jingdong Luo, Alex K.-Y. Jen
Mitsunobu post-functionalization was utilized to construct a new efficient dopant-free side-chain hole transporting polymer for inverted perovskite solar cells, exhibiting a power conversion efficiency of 17.75% and a high fill factor over 81%.
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Synthesis of biscarboxylic acid functionalised EDTA mimicking polymers and their ability to form Zr(IV) chelation mediated nanostructures

Polym. Chem., 2020, 11,2799-2810
DOI: 10.1039/D0PY00304B, Paper
Meike N. Leiske, Julia A. Walker, Aadarash Zia, Nicholas L. Fletcher, Kristofer J. Thurecht, Thomas P. Davis, Kristian Kempe
We present a new biscarboxylic acid acrylate, which is used for the synthesis of double hydrophilic EDTA-mimicking block copolymers capable of self-assembly upon zirconium complexation.
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Outstanding Reviewers for Polymer Chemistry in 2019

Polym. Chem., 2020, 11,2774-2774
DOI: 10.1039/D0PY90061C, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Polymer Chemistry in 2019, as selected by the editorial team for their significant contribution to the journal.
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Amide transformation as an efficient postpolymerization modification approach for the synthesis of functional polyacetylenes

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00398K, Paper
Juntao Ren, Heng Liu, Xuequan Zhang, Yanming Hu, Guangyuan Zhou, Toshio Masuda
Modification of a precursor polyacetylene with various amines and alcohols through amide transformation gives access to a series of functional polymers showing nonlinear optical, luminescence, enhanced surface energy, and redox active properties.
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Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00453G, Paper
Yongjun Shin, Matthew L. Becker
A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)2(THF)2 catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.
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Sequential and alternating RAFT single unit monomer insertion: model trimers as the guide for discrete oligomer synthesis

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00390E, Paper
Ruizhe Liu, Lei Zhang, Zixuan Huang, Jiangtao Xu
A complete set of model trimers and their synthetic kinetics are established to guide the synthesis of diverse sequence-defined polymers.
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Self-assembly of strawberry-like organic–inorganic hybrid particle clusters with directionally distributed bimetal and facile transformation of the core and corona

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00237B, Paper
Shuxing Mei, Mingwang Pan, Juan Wang, Xiaopeng Zhang, Shaofeng Song, Chao Li, Gang Liu
Controllable structure of organic–inorganic hybrid particle clusters were successfully fabricated by self-assembly which derived from the strong interaction between carboxyl groups of the organic particles and amino groups of the inorganic particles.
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From isoselectivity to syndioselectivity: Lewis base regulates stereochemistry in 2-vinylpyridine polymerization

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00320D, Paper
Yu Wang, Jiang-Bing Duan, Zhao-Xuan Liu, Tie-Qi Xu
We have developed an effective synthesis of syndiotactic poly(2-vinylpyridine) by a novel catalytic system. Switching from isoselective to syndioselective polymerization was achieved by adding Lewis base.
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Rapid production of block copolymer nano-objects via continuous-flow ultrafast RAFT dispersion polymerisation

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00276C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sam Parkinson, Stephen T. Knox, Richard A. Bourne, Nicholas J. Warren
Continuous-flow reactors are exploited for conducting ultrafast RAFT dispersion polymerisation for the preparation of diblock copolymer nanoparticles.
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Correction: Flow-facilitated ring opening metathesis polymerization (ROMP) and post-polymerization modification reactions

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY90065F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Selesha I. Subnaik, Christopher E. Hobbs
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Room Temperature Synthesis of Block Copolymer Nano-Objects with Different Morphologies via Ultrasound Initiated RAFT Polymerization-Induced Self-Assembly (Sono-RAFT-PISA)

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00461H, Paper
Jing Wan, Bo Fan, Yiyi Liu, Tina Hsia, Kaiyuan Qin, Tanja Junkers, Boon M. Teo, San Thang
Polymerization-induced self-assembly (PISA), which allows scalable synthesis of nano-objects, has drawn significant research attention in the past decade. However, the initiation methods in most of the current reported PISA are...
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Dibenzothiophene-S,S-Dioxide-Bispyridinium-Fluorene-Based Polyelectrolytes for Cathode Buffer Layers of Polymer Solar Cells

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00416B, Paper
Guiting Chen, Dan Cheng, Wenyan Zou, Ziyan Cai, Yufeng Xie, Yaqi Chen, Baitian He, Hong-Qing Hao, Wei Yang, Yong Cao
Herein, a novel electron-deficient conjugated water/alcohol-soluble polyelectrolyte (WSPE) named as PFSOPyCl-E, consisting of dibenzothiophene-S,S-dioxide, bispyridinium salts and fluorene with ethylene oxide side chains, was presented. Previously we have synthesized another...
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Viscoelastic and thermoreversible networks crosslinked by non-covalent interactions between “clickable” nucleic acid oligomers and DNA

Polym. Chem., 2020, 11,2959-2968
DOI: 10.1039/D0PY00165A, Paper
Alex J. Anderson, Heidi R. Culver, Stephanie J. Bryant, Christopher N. Bowman
An approach to efficient and scalable production of oligonucleotide-based gel networks is presented.
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Effects of tacticity and chiral center-to-dipole distance on mesogen-free liquid crystalline self-assembly of sulfonyl-containing comb-like polymers

Polym. Chem., 2020, 11,3018-3031
DOI: 10.1039/D0PY00199F, Paper
Caleb A. Bohannon, Man-Hin Kwok, Ruipeng Li, Lei Zhu, Bin Zhao
Mesogen-free comb-like polyethers bearing strongly interacting mono- and di-sulfonylated side chains exhibit well-defined liquid crystalline self-assembly.
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Development and disassembly of single and multiple acid-cleavable block copolymer nanoassemblies for drug delivery

Polym. Chem., 2020, 11,2934-2954
DOI: 10.1039/D0PY00234H, Review Article
Arman Moini Jazani, Jung Kwon Oh
Acid-degradable block copolymer-based nanoassemblies are promising intracellular candidates for tumor-targeting drug delivery as they exhibit the enhanced release of encapsulated drugs through their dissociation.
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Synthesis of well-defined heteroglycopolymers via combining sequential click reactions and PPM: the effects of linker and heterogeneity on Con A binding

Polym. Chem., 2020, 11,3054-3065
DOI: 10.1039/D0PY00302F, Paper
Meina Liu, Xingyou Wang, Dengyun Miao, Caiyun Wang, Wei Deng
A versatile post- polymerization modification strategy to synthesize well-defined glycopolymers via the combination of RAFT polymerization and sequential CuAAC and thiol–ene click reactions was developed.
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Synthesis of conjugated polymers via cyclopentannulation reaction: promising materials for iodine adsorption

Polym. Chem., 2020, 11,3066-3074
DOI: 10.1039/D0PY00286K, Paper
Open Access
Noorullah Baig, Suchetha Shetty, Saleh Al-Mousawi, Bassam Alameddine
A new class of conjugated polymers is prepared by means of a versatile palladium-catalyzed cyclopentannulation reaction using a series of specially designed diethynyl aryl synthons with the commercially available 9,10-dibromoanthracene DBA monomer.
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Double-click synthesis of polysiloxane third-order nonlinear optical polymers with donor–acceptor chromophores

Polym. Chem., 2020, 11,3046-3053
DOI: 10.1039/C9PY01771B, Paper
Zhitao Li, Dong Wang, Daniele Ramella, Hong Gao, Hui Cao, Yuzhen Zhao, Zongcheng Miao, Zhou Yang, Wanli He
A series of third-order nonlinear polysiloxane polymer materials were prepared by thiol–ene click polymerization and [2 + 2] click chemistry. All the polymers exhibit good electron transfer capabilities and nonlinear optical properties.
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Synthesis, thermoresponsivity and multi-tunable hierarchical self-assembly of multi-responsive (AB)mC miktobrush-coil terpolymers

Polym. Chem., 2020, 11,3003-3017
DOI: 10.1039/D0PY00245C, Paper
Xiaomin Zhu, Jian Zhang, Cheng Miao, Siyu Li, Youliang Zhao
Stimuli-responsive miktobrush-coil terpolymers can exhibit unique physical properties and hierarchical self-assembly behaviors dependent on composition, concentration and external stimuli.
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Light and Latex: Advances in the photochemistry of polymer colloids

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00349B, Review Article
Philip Scott, Christopher Kasprzak, Keyton Feller, Viswanath Meenakshisundaram, Christopher Williams, Timothy Long
Unparalleled temporal and spatial control of colloidal chemical processes introduces immense potential for the manufacturing, modification, and manipulation of latex particles. This review highlights major advances in photochemistry, both as...
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Controlling the crystal structure of precisely spaced polyethylene-like polyphosphoesters

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00272K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tobias Haider, Oksana Suraeva, Miriam Leslie O'Duill, Julian Mars, Markus Mezger, Ingo Lieberwirth, Frederik R Wurm
Understanding polymer crystallization is important for polyethylene-like materials. A small fraction of monomers with functional groups within the polyethylene chain can act as crystallization “defects”. Such defects can be used...
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Organocatalyzed ring opening polymerization of regio-isomeric lactones: reactivity and thermodynamics considerations

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9PY01777A, Paper
Marie A. F. Delgove, Ola Wróblewska, Jules Stouten, Christian A. M. R. van Slagmaat, Jurrie Noordijk, Stefaan de Wildeman, Katrien V. Bernaerts
Organocatalysts are increasingly gaining attention for the ring opening polymerization (ROP) of lactones due to numerous advantages. In this work, the goal is to expand the scope of catalysts for...
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Design of new phenothiazine derivatives as visible light photoinitiators

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00497A, Paper
Mahmoud Rahal, Mira Abdallah, Thanh-Tuân Bui, Fabrice Goubard, Bernadette Graff, Frédéric Dumur, Joumana Toufaily, Tayssir Hamieh, Jacques Lalevée
In this article, four new phenothiazine derivatives (denoted as PT1, PT2, PT3 and PT4) are specifically in silico designed by molecular modelling for good light absorption properties @405 nm.
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A Copper(I)-Catalyzed Azide-Alkyne Click Chemistry Approach towards Multifunctional Two-Way Shape-Memory Actuators

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00217H, Paper
Zhong-Cheng Liu, Bo Zuo, Hai-Feng Lu, Meng Wang, Shuai Huang, Xu-Man Chen, Baoping Lin, Hong Yang
Nowadays, two-way shape memory polymeric materials with reversible shape-morphing capability, exhibit extraordinary application prospects in robotic, biomedical and intelligent material technologies, and have attracted extensive scientific attention. However, exploration of...
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Influence of the polymer matrix on the viscoelastic behaviour of vitrimers

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00114G, Paper
Yann Spiesschaert, Christian Taplan, Lucas Stricker, Marc Guerre, Johan M. Winne, Filip Du Prez
Vitrimer materials are a rapidly growing field of research, in which still many fundamental aspects of material design remain to be explored. In this study, we report a systematic study...
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Diphenyl Functional Porphyrins and Their Metal Complexes as Visible-Light Photoinitiators for Free-Radical, Cationic and Thiol-Ene Polymerizations

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00468E, Paper
Davy-Louis Versace, Yusuf Yagci, Agata Blacha-Grzechnik, Nicolas Bogliotti, V. Brezova, Jean-Pierre Malval, Marc Presset, Hugo Marcille
This investigation demonstrates the excellent photoinitiating properties of novel visible-light absorbing diphenylporphyrins (DPPs) for the free-radical (FRP), cationic (CP) and thiol-ene polymerizations under visible LEDs irradiation (405 and 530 nm)...
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Precise Tracking and Modulating Aggregation Structures of Conjugated Copolymers in Solutions

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00456A, Paper
Zi-Yuan Wang, Ze-Fan Yao, Yang Lu, Li Ding, Zi-Di Yu, Hao-Yang You, Xin-Yi Wang, Yang-Yang Zhou, Lin Zou, Jie-Yu Wang, Jian Pei
The effects of the backbone shape of the conjugated polymers on the aggregation features in solutions, and further on the morphology in solid states are rarely reported. Herein, four copolymers,...
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Alkene-Azide Chemistry: A Facile, One-Step, Solvent- and Catalyst-Free Approach for Developing New Functional Monomers and Polymers

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00346H, Paper
Santimukul Santra, Ren Bean, Blaze Heckert, Zachary Shaw, Vedant Jain, Lok Shrestha, Raghunath Narayanam, Quentin Austin
In this study, a one-step Hüisgen 1,3-dipolar cycloaddition reaction, alkene-azide chemistry, was explored using a solvent and catalyst free method forming 1,2,3-triazoline ring-containing molecules. This facile method was utilized by...
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Highly conductive mechanically robust high Mw polyfluorene anion exchange membrane for alkaline fuel cell and water electrolysis application

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00334D, Paper
Shoji Miyanishi, Takeo Yamaguchi
New, high molecular weight poly-(fluorene-alt-tetrafluorophenylene) anion exchange membranes were synthesized by a Pd-catalyzed C–H activation method. The synthesized membranes exhibited high OH− conductivity over 100 mS/cm, and membrane swelling could...
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