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Construction of hierarchical MoSe2@C hollow nanospheres for efficient lithium/sodium ion storage

By pubs.rsc.org
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Inorg. Chem. Front., 2020, 7,1691-1698
DOI: 10.1039/D0QI00017E, Research Article
Xueqian Zhang, Yali Xiong, Mengfei Dong, Zhiguo Hou, Yitai Qian
Hierarchical MoSe2@C hollow nanospheres are synthesized via an anion-exchange reaction and exhibit good electrochemical performance.
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Construction of well-designed 1D selenium–tellurium nanorods anchored on graphene sheets as a high storage capacity anode material for lithium-ion batteries

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Inorg. Chem. Front., 2020, 7,1750-1761
DOI: 10.1039/C9QI01701A, Research Article
Sadeeq Ullah, Ghulam Yasin, Aftab Ahmad, Lei Qin, Qipeng Yuan, Arif Ullah Khan, Usman Ali Khan, Aziz Ur Rahman, Yassine Slimani
The graphical illustration of the preparation of the SeTe@rGO composite material and its electrochemical application in Li-ion batteries.
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Arranging strategies for A-site cations: impact on the stability and carrier migration of hybrid perovskite materials

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Inorg. Chem. Front., 2020, 7,1741-1749
DOI: 10.1039/D0QI00102C, Research Article
Wei Jian, Ran Jia, Hong-Xing Zhang, Fu-Quan Bai
An essential understanding is obtained from the cation engineering process into the expected excited-state properties of hybrid perovskite materials.
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Rational design of the pea-pod structure of SiOx/C nanofibers as a high-performance anode for lithium ion batteries

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Inorg. Chem. Front., 2020, 7,1762-1769
DOI: 10.1039/D0QI00069H, Research Article
Yuchao Zheng, Xiangzhong Kong, Ibrahim Usman, Xuefang Xie, Shuquan Liang, Guozhong Cao, Anqiang Pan
Pea-pod structured SiOx/C nanofibers were synthesized by the electrospinning method, whose structure can be controlled by adjusting the addition amounts of organosilica-polymer nanospheres and they exhibit superior electrochemical performance.
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Anisotropic proton conduction realized by a layered vanadium selenite single crystal

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Inorg. Chem. Front., 2020, 7,1699-1703
DOI: 10.1039/D0QI00040J, Research Article
Hai-Yan Sun, Shi-Hao Sun, Bing Hu, Liao-Kuo Gong, Yan-Min Zou, Ji-Long Li, Mei-Ling Feng, Xiao-Ying Huang
A new layered vanadium selenite single crystal exhibits anisotropic proton conductivities along the [100] and [001] directions with the Grotthuss and Vehicle mechanisms, respectively.
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High-efficiency photocatalytic water splitting by a N-doped porous g-C3N4 nanosheet polymer photocatalyst derived from urea and N,N-dimethylformamide

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Inorg. Chem. Front., 2020, 7,1770-1779
DOI: 10.1039/D0QI00117A, Research Article
Feng Guo, Lijing Wang, Haoran Sun, Mingyang Li, Weilong Shi
N-Doped porous g-C3N4 nanosheets for high-efficiency photocatalytic water splitting were prepared by mixing the precursor of N,N-dimethylformamide and urea through a simple one-step thermal copolymerization method.
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Excellent lightweight carbon-based microwave absorbers derived from metal–organic frameworks with tunable electromagnetic properties

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Inorg. Chem. Front., 2020, 7,1667-1675
DOI: 10.1039/D0QI00099J, Research Article
Weihua Gu, Jing Zheng, Xiaohui Liang, Xiaoqing Cui, Jiabin Chen, Zhu Zhang, Guangbin Ji
Upon introducing Gibbs free energy to effectively control the final products, the as-prepared carbon-based composites show excellent absorbing ability at 1.4 mm.
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Unraveling the complexation mechanism of actinide(III) and lanthanide(III) with a new tetradentate phenanthroline-derived phosphonate ligand

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Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article
Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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Highly efficient and stable CsPbBr3 perovskite quantum dots by encapsulation in dual-shell hollow silica spheres for WLEDs

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00208A, Research Article
Lei Qiu, Hang Yang, Zhigao Dai, Fengxu Sun, Jiarui Hao, Mengyu Guan, Peipei Dang, Chunjie Yan, Jun Lin, Guogang Li
A highly stable and efficient CsPbBr3@SiO2 composite phosphor is achieved by protecting the CsPbBr3 QDs from direct exposure to the atmosphere by encapsulating CsPbBr3 into dual-shell hollow silica nanospheres.
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Hydrophobic tail length in spin crossover active iron(II) complexes predictably tunes T½ in solution and enables surface immobilisation

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01478K, Research Article
Sriram Sundaresan, Jonathan A. Kitchen, Sally Brooker
Linear correlation of the hydrophobic alkyl tail length R employed in [FeII(LH-OR)(NCBH3)2] with the spin crossover switching temperature is a very convenient method of predictably tuning the iron(II) spin state.
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A sponge-like small pore zeolite with great accessibility to its micropores

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00261E, Research Article
Kok-Giap Haw, Simona Moldovan, Lingxue Tang, Zhengxing Qin, Qianrong Fang, Shilun Qiu, Valentin Valtchev
The accessibility of SSZ-13 is enhanced by having a sponge-like structure after etching under neutral pH conditions.
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A single-ligand-protected Eu60−nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00226G, Research Article
Xi-Ming Luo, Ning-Fang Li, Qing-Fang Lin, Jia-Peng Cao, Peng Yuan, Yan Xu
Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln60. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.
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Intermetallic borides: structures, synthesis and applications in electrocatalysis

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00146E, Review Article
Hui Chen, Xiaoxin Zou
This review summarizes structural features and recent synthesis methods of structurally ordered intermetallic borides, and the theoretical–experimental advances in the emerging boride-catalyzed reactions.
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Binder-free preparation of ZSM-5@silica beads and their use for organic pollutant removal

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00259C, Research Article
Ping He, Jiehua Ding, Zhengxing Qin, Lingxue Tang, Kok-Giap Haw, Yiying Zhang, Qianrong Fang, Shilun Qiu, Valentin Valtchev
Organic structure directing agent (OSDA)- and binder-free preparation of ZSM-5@silica beads and their use for aniline removal.
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Disentangling Site Occupancy, Cation Regulation, and Oxidation State Regulation of the Broadband Near Infrared Emission in Chromium Doped SrGa4O7 Phosphor

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00332H, Research Article
Jun'an Lai, Jianbei Qiu, Qi Wang, Dacheng Zhou, Zhangwen Long, yong yang, SongHan Hu, Xizheng Li, Jiacheng Pi, Jing Wang
Cr3+-doped phosphors are attracting attention for broadband near-infrared (NIR) applications. However, some mechanisms are still unclear due to the entangled crystallographic site occupancy and changeable valence of chromium in the...
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A slowly magnetic relaxing SmIII monomer with a D5h equatorial compressed ligand field

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00326C, Research Article
Ji-Dong Leng, Qiu-Yan Hua, Li-Shan Lin, Wei-Quan Lin, Jun-Liang Liu, Yong-Ze Pan, Yi-Bo Qiu, Ai-Ju Zhou
By using a bi-dentate phosphine oxide ligand L (L = bis(diphenylphosphino)methane dioxide), two mono-nuclear lanthanide complexes [LnL2(DMF)Cl2]Cl (Ln = Sm, 1; Dy, 2) with a D5h equatorial ligand field (LF)...
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SrTaO2N co-doped with La/Zr as promising photocatalysts for water reduction under visible light illumination

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article
Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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A one-pot synthesis of hetero-Co9S8–NiS sheets on graphene to boost lithium–sulfur battery performance

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01691K, Research Article
Liang Chen, Xuefang Xie, Zhian Zhang, Xiangzhong Kong, Shuquan Liang, Anqiang Pan
Graphene decorated with hetero-Co9S8–NiS sheets have abundant active sites, which can efficiently catalyze the electrochemical conversion of lithium polysulfides in Li–S battery.
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Ni-Doped magnesium manganese oxide as a cathode and its application in aqueous magnesium-ion batteries with high rate performance

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article
Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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Highly efficient water splitting over a RuO2/F-doped graphene electrocatalyst with ultra-low ruthenium content

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article
Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO2/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm−2 for electrocatalytic water splitting.
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Enabling high performance n-type metal oxide semiconductors at low temperatures for thin film transistors

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Inorg. Chem. Front., 2020, 7,1822-1844
DOI: 10.1039/D0QI00038H, Review Article
Nidhi Tiwari, Amoolya Nirmal, Mohit Rameshchandra Kulkarni, Rohit Abraham John, Nripan Mathews
The review highlights low temperature activation processes for high performance n-type metal oxide semiconductors for TFTs.
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Constructing heterostructured FeS2/CuS nanospheres as high rate performance lithium ion battery anodes

By pubs.rsc.org
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Inorg. Chem. Front., 2020, 7,1900-1908
DOI: 10.1039/C9QI01674K, Research Article
Xiaoxia Xu, Lingjie Li, Huiqing Chen, XiaoSong Guo, Zhonghua Zhang, Jing Liu, Changming Mao, Guicun Li
Heterostructured porous FeS2/CuS nanospheres exhibit enhanced reaction kinetics, excellent rate capability and desirable long-term cycling stability performance.
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Temperature-regulated construction of hierarchical titanosilicate zeolites

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Inorg. Chem. Front., 2020, 7,1872-1879
DOI: 10.1039/D0QI00120A, Research Article
Yue Song, Risheng Bai, Yongcun Zou, Zhaochi Feng, Jihong Yu
A temperature-regulated method was developed to construct anatase-free hierarchical TS-1 zeolite catalysts by utilizing a two-step hydrothermal crystallization strategy with tetrabutylammonium hydroxide as the sole organic template.
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Ligand substitution induced single-crystal-to-single-crystal transformations in two Ni(II) coordination compounds displaying consequential changes in proton conductivity

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Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article
Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Coral-like ZnFe2O4–ZnO mesoporous heterojunction architectures: synthesis and enhanced sensing properties for triethylamine

By pubs.rsc.org
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Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article
Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe2O4–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
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Electrochemical behavior of NiCl2/Ni in acidic AlCl3-based ionic liquid electrolyte

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Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article
Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl2 cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl2 during discharging in acidic AlCl3-based electrolyte.
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Highly efficient CO2 capture and conversion of a microporous acylamide functionalized rht-type metal–organic framework

By pubs.rsc.org
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Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article
Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO2-philic acylamide groups exhibits high performance for CO2 capture, separation and chemical conversion.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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π-Type halogen bonding enhanced the long-lasting room temperature phosphorescence of Zn(II) coordination polymers for photoelectron response applications

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article
Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Evolution of D6R units in the interzeolite transformation from FAU, MFI or *BEA into AEI: transfer or reassembly?

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00359J, Research Article
Juan Zhang, Yueying Chu, Feng Deng, Zhaochi Feng, Xiangju Meng, Feng-Shou Xiao
The formation and evolution of building units for zeolites play an important role during crystallization.
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An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Mechanism of oxygen vacancy assisted water-splitting of LaMnO3: Inorganic perovskite prediction for fast solar thermochemical H2 production

By pubs.rsc.org
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article
Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Cyclometalated Ir(III) Complexes Towards Blue-Emissive Dopant for Organic Light-Emitting Diodes: Fundamentals of Photophysics and Designing Strategies

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article
Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

By darius.uleth.ca
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1 videodisc (101 min.) : sound, color ; 4 3/4 in


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It's no more just about Real or Barca breaking records: La Liga India head

By www.business-standard.com
Published On :: Fri, 20 Mar 2020 15:10:00 +0530

Jose Antonio Cachaza, MD, LaLiga India, dwells on his team's digital strategy to reach fans in remote villages that even courier companies don't reach


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Will consider raising duties on fuel and liquor: Manpreet Badal, Punjab FM

By www.business-standard.com
Published On :: Thu, 09 Apr 2020 23:07:00 +0530

Punjab would like to help the Centre in any way possible to deal with the coronavirus disease (Covid-19) pandemic, said state Finance Minister Manpreet Singh Badal


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India could use 3-5% of GDP stabilising economy: World Bank economists

By www.business-standard.com
Published On :: Sun, 19 Apr 2020 14:42:00 +0530

The lockdown of economies around the world causes a much sharper decline in economic activity than in normal recessions, says World Bank chief economist south Asia region, Hans Timmer


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The Quiet Liturgy of Fred Rogers

By feeds.christianitytoday.com
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‘Mister Rogers’ Neighborhood’ taught us to love—not fear—our neighbor.


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‘Little Women’ and the Feminist Search for Righteousness

By feeds.christianitytoday.com
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The real story is not whether the four young women will marry, but whether they will become better people.


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Netflix’s ‘Messiah’ Says the World Needs a Savior

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The problem is, which one?


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Bryan Stevenson Wants to Liberate People from the Lie That Their Life Doesn’t Matter

By feeds.christianitytoday.com
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The author of the book behind the new film ‘Just Mercy’ shows the church a way forward.


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Article :: Geometry for Modeling and Design

By www.peachpit.com
Published On :: Thu, 09 Mar 2017 00:00:00 GMT

This excerpt from Technical Drawing with Engineering Graphics shows how to identify and specify basic geometric elements and shapes.


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Article :: Visualization and Sketching

By www.peachpit.com
Published On :: Fri, 06 Apr 2018 00:00:00 GMT

In this sample chapter from Modern Graphics Communicaiton, 5th Edition, learn how to visualize and sketch objects in three dimensions to communicate your ideas quickly and accurately.


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Article :: Use the Command-Line Interface

By www.peachpit.com
Published On :: Fri, 06 Apr 2018 00:00:00 GMT

In this sample chapter from macOS Support Essentials 10.13 (Apple Pro Training Series): Supporting and Troubleshooting macOS High Sierra, learn how to use the command-line interface (CLI) to access additional administrative functionality.


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Article :: Sketchnoters' Stories: 8th-grader Allison Huang revolutionizes her school notes with sketchnotes

By www.peachpit.com
Published On :: Wed, 08 Aug 2018 00:00:00 GMT

We are excited to share this story about Allison Huang, an eighth grader passionate about sketchnoting. This is her story about discovering and integrating sketchnoting as a powerful tool for the way she thinks in school and in her life.


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Article :: macOS Mojave Command-Line Interface

By www.peachpit.com
Published On :: Thu, 17 Jan 2019 00:00:00 GMT

Learn how to use the command-line interface (CLI) to access additional administrative functionality in macOS Mojave.


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Article :: Simplicity: Why It Matters

By www.peachpit.com
Published On :: Sat, 14 Dec 2019 00:00:00 GMT

In this sample chapter from Presentation Zen, Third Edition, author Garr Reynolds talks about simplicity - in daily life, then in professional life. He discusses how designers can bring clarity, directness, subtlety, essentialness, and minimalism into their work.


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