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Facile fabrication of a hybrid polymer electrolyte via initiator-free thiol–ene photopolymerization for high-performance all-solid-state lithium metal batteries

Polym. Chem., 2020, 11,2732-2739
DOI: 10.1039/D0PY00203H, Paper
Cai Zuo, Binghua Zhou, Ye Hyang Jo, Sibo Li, Gong Chen, Shaoqiao Li, Wen Luo, Dan He, Xingping Zhou, Zhigang Xue
The article reports the facile fabrication of a solid polymer electrolyte via initiator-free thiol–ene photopolymerization for all-solid-state lithium metal batteries.
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A polymerization-induced self-assembly process for all-styrenic nano-objects using the living anionic polymerization mechanism

Polym. Chem., 2020, 11,2635-2639
DOI: 10.1039/D0PY00296H, Communication
Chengcheng Zhou, Jian Wang, Peng Zhou, Guowei Wang
By combination of the living anionic polymerization (LAP) mechanism with the polymerization-induced self-assembly (PISA) technique, the all-styrenic diblock copolymer poly(p-tert-butylstyrene)-b-polystyrene (PtBS-b-PS) based LAP PISA was successfully developed.
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Correction: Dynamic covalent polymer networks via combined nitroxide exchange reaction and nitroxide mediated polymerization

Polym. Chem., 2020, 11,2761-2761
DOI: 10.1039/D0PY90053B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yixuan Jia, Yannick Matt, Qi An, Isabelle Wessely, Hatice Mutlu, Patrick Theato, Stefan Bräse, Audrey Llevot, Manuel Tsotsalas
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Correction: Block copolymer hierarchical structures from the interplay of multiple assembly pathways

Polym. Chem., 2020, 11,2762-2762
DOI: 10.1039/D0PY90057E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessandro Ianiro, Meng Chi, Marco M. R. M. Hendrix, Ali Vala Koç, E. Deniz Eren, Michael Sztucki, Andrei V. Petukhov, Gijsbertus de With, A. Catarina C. Esteves, Remco Tuinier
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A covalently crosslinked silk fibroin hydrogel using enzymatic oxidation and chemoenzymatically synthesized copolypeptide crosslinkers consisting of a GPG tripeptide motif and tyrosine: control of gelation and resilience

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00187B, Paper
Hiromitsu Sogawa, Takuya Katashima, Keiji Numata
A covalently crosslinked silk fibroin hydrogel was successfully formed via an enzymatic crosslinking reaction using copolypeptides, which consist of a glycine–proline–glycine tripeptide motif and tyrosine, as linker molecules.
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Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00369G, Paper
Xun Zhang, Siping Hu, Qiang Ma, Saihu Liao
A visible light-regulated ring-opening polymerization of lactones has been developed based on the excited state acidity of ESPT molecules.
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Synthesis and enantioseparation of proline-derived helical polyacetylenes as chiral stationary phases for HPLC

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00205D, Paper
Ge Shi, Xiao Dai, Yue Zhou, Jie Zhang, Jun Shen, Xinhua Wan
Proline-derived aliphatically substituted polyacetylenes with stable helical conformations exhibit an excellent enantioseparation ability as chiral stationary phases of HPLC.
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Synthesis of star-shaped polyzwitterions with adjustable UCST and fast responsiveness by a facile RAFT polymerization

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00318B, Paper
Zhi Li, Hao Li, Zhonghe Sun, Botao Hao, Tung-Chun Lee, Anchao Feng, Liqun Zhang, San H. Thang
We describe crosslinking of polyzwitterions for the formation of novel star-shaped polymers with low polydispersities and dual-responsiveness using RAFT polymerization.
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Injectable dual cross-linked adhesive hyaluronic acid multifunctional hydrogel scaffolds for potential applications in cartilage repair

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00371A, Paper
Chenxi Yu, Huichang Gao, Qingtao Li, Xiaodong Cao
A double crosslinked hydrogels was designed and prepared by combining the Diels–Alder click reaction and possessed good mechanical strength, injectability and adhesion.
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Poly(alanine-nylon-alanine) as a bioplastic: chemoenzymatic synthesis, thermal properties and biological degradation effects

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00137F, Paper
Open Access
Prashant G. Gudeangadi, Kei Uchida, Ayaka Tateishi, Kayo Terada, Hiroyasu Masunaga, Kousuke Tsuchiya, Hitoshi Miyakawa, Keiji Numata
Poly(amino acids) such as polypeptides and proteins are attractive biomass-based polymers that potentially contribute to circular economy for plastic.
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Self-crosslinking smart hydrogels through direct complexation between benzoxaborole derivatives and diols from hyaluronic acid

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00308E, Paper
Tamiris Figueiredo, Yu Ogawa, Jing Jing, Vanina Cosenza, Isabelle Jeacomine, Johan D. M. Olsson, Thibaud Gerfaud, Jean-Guy Boiteau, Craig Harris, Rachel Auzély-Velty
By tailoring the structure of benzoxaborole (BOR), self-crosslinking hydrogels based on hyaluronic acid (HA) modified with BOR derivatives are obtained for the first time through the direct BOR-HA diol complexation at physiological pH.
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Photo-controlled RAFT polymerization mediated by organic/inorganic hybrid photoredox catalysts: enhanced catalytic efficiency

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00171F, Paper
Wulong Wang, Sheng Zhong, Guicheng Wang, Hongliang Cao, Yun Gao, Weian Zhang
Photo-controlled RAFT polymerization mediated by an organic/inorganic hybrid photoredox catalyst (ZnTPP–POSS) was performed and showed enhanced catalytic efficiency compared with the ZnTPP photocatalyst.
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Poly(hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00088D, Review Article
Elena Gabirondo, Ainara Sangroniz, Agustin Etxeberria, Sergio Torres-Giner, Haritz Sardon
Poly(hydroxy acids) derived from the self-condensation of hydroxy acid are biodegradable and can be fully recycled in a Circular Economy approach.
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Miniemulsion polymerization of styrene using carboxylated graphene quantum dots as surfactant

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00404A, Paper
Le N. M. Dinh, Lakshmi N. Ramana, Vipul Agarwal, Per B. Zetterlund
Carboxylated graphene quantum dots (cGQDs) were synthesized from dextrose and sulfuric acid via a hydrothermal process, and subsequently used as sole surfactant in miniemulsion polymerization of styrene.
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Using the dynamic behavior of macrocyclic monomers with a bis(hindered amino)disulfide linker for the preparation of end-functionalized polymers

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00366B, Paper
Hirogi Yokochi, Rikito Takashima, Daisuke Aoki, Hideyuki Otsuka
End-functionalized polymers were synthesized by simply heating a mixture of a macrocyclic compound with one bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) moiety and bifunctional acyclic BiTEMPS compounds as sources of repeat units and terminal groups, respectively.
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Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00249F, Communication
Zhonghua Cheng, Lei Wang, Yan He, Xingjia Chen, Xiaojun Wu, Hangxun Xu, Yaozu Liao, Meifang Zhu
A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts.
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Preparation of aryl polysulfonates via a highly efficient SuFEx click reaction, their controllable degradation and functionalized behavior

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00435A, Communication
Zhenlei Cao, Feng Zhou, Pei-Yang Gu, Dongyun Chen, Jinghui He, John R. Cappiello, Peng Wu, Qingfeng Xu, Jianmei Lu
Polysulfonates obtained from SuFEx click reaction can be degraded using DBU. The degradation process was further utilized to prepare functional polymers.
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Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00174K, Paper
Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai, Bao-Tsan Ko
Catalyst 1 was reported for the first time to be effective for nickel-catalyzed CO2/CHO copolymerization at 1 atm CO2 pressure.
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Smart functionalized phosphonic acid based copolymers: new structures for old purposes

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00337A, Paper
Xavier Solimando, Yohann Catel, Norbert Moszner, Jean-Jacques Robin, Sophie Monge
Innovative well-defined acidic photopolymerizable phosphorus-based copolymers were prepared and tested in well-known dental applications to improve the adhesion of dental self-etch adhesives (SEAs).
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Pillar[5]arene-based self-assembled linear supramolecular polymer driven by guest halogen–halogen interactions in solid and solution states

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00327A, Paper
Talal F. Al-Azemi, Mickey Vinodh
A pillar[5]arene-based linear supramolecular polymer mediated by guest halogen–halogen interactions (C–Br⋯Br–C) was studied in both the solution and solid states.
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