li

Ring-Fused Cyclobutanes via Cycloisomerization of Alkylidenecyclopropane Acylsilanes

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02224A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Erick M Carreira, Sarah S Eichenberger, Moritz Hönig, Matthieu JR Richter, Renana Gershoni-Poranne
A novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed. The readily available starting materials participate in tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes, which...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01833C, Edge Article
Open Access
Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D Bloch
We describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01445A, Edge Article
Open Access
Lei Zhang, Xile Hu
A direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01112F, Edge Article
Open Access
Matthias Müller, Antti J Karttunen, Magnus Richard Buchner
The hexa-μ2-amido-tetraammine-tetraberyllium compounds [Be4(NH2)6(NH3)4]X2 (X = Cl, Br, I, CN, SCN, N3) have been prepared from beryllium metal and NH4X or [Be(NH3)4]X2 in liquid ammonia at ambient temperature. The obtained...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Evolution of pure hydrocarbon hosts: simpler structure, higher performance and universal application in RGB phosphorescent organic light-emitting diodes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01238F, Edge Article
Open Access
Qiang Wang, Fabien Lucas, Cassandre Quinton, Yang-Kun Qu, Joëlle Rault-Berthelot, Olivier Jeannin, Sheng-Yi Yang, Fan-Cheng Kong, Sarvendra Kumar, Liang-Sheng Liao, Cyril Poriel, Zuo-Quan Jiang
In this work, we propose pure hydrocarbon materials as universal hosts for high-efficiency red, green and blue phosphorescent organic light-emitting diodes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes

Chem. Sci., 2020, 11,4287-4296
DOI: 10.1039/C9SC06006E, Minireview
Open Access
Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. Engle
Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Peculiar bond characters of fivefold coordinated octet compound crystals

Chem. Sci., 2020, 11,4340-4350
DOI: 10.1039/D0SC00292E, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
An-An Sun, Shang-Peng Gao, Gong Gu
A refreshed view of chemical bonds in solids unveils unusual bonding in fivefold coordinated bulk crystals of octet compounds: out-of-plane cation–anion chain bonding via overlapping pz orbitals replaces in-plane π bonding of the isolated monolayer.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

Chem. Sci., 2020, 11,4297-4304
DOI: 10.1039/D0SC00735H, Minireview
Open Access
Eike Brunner, Marcus Rauche
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery

Chem. Sci., 2020, 11,4397-4402
DOI: 10.1039/D0SC00844C, Edge Article
Open Access
Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong Li
A novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation

Chem. Sci., 2020, 11,4439-4443
DOI: 10.1039/D0SC01289K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Arunachalam Sagadevan, Anastasios Charitou, Fen Wang, Maria Ivanova, Martin Vuagnat, Michael F. Greaney
A ruthenium-catalyzed ortho C–H arylation process is described using visible light.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Intramolecular Csp3–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines

Chem. Sci., 2020, 11,4482-4487
DOI: 10.1039/C9SC05522C, Edge Article
Open Access
Xiaojin Wen, Xinyao Li, Xiao Luo, Weijin Wang, Song Song, Ning Jiao
A novel intramolecular cyclization of alkyl azides for the synthesis of cyclic imines and tertiary amines has been developed. The aliphatic C–H or C–C bond was selectively cleaved with the efficient formation of two C–N single bonds or a CN double bond.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin

Chem. Sci., 2020, 11,4516-4524
DOI: 10.1039/D0SC01319F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar Willner
Biocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

Chem. Sci., 2020, 11,4499-4507
DOI: 10.1039/D0SC00135J, Edge Article
Open Access
Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming Hu
Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Machine-enabled inverse design of inorganic solid materials: promises and challenges

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00594K, Minireview
Open Access
Juhwan Noh, Geun Ho Gu, Sungwon Kim, Yousung Jung
The grand challenge of materials science, discovery of novel materials with target properties, can be greatly accelerated by machine-learned inverse design strategies.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Small-molecule fluorescent probes for imaging gaseous signaling molecules: current progress and future implications

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01482F, Perspective
Open Access
Mingwang Yang, Jiangli Fan, Jianjun Du, Xiaojun Peng
This perspective article aims to introduce the design principles and recognition strategies of small-molecule fluorescent probes which are applied for the detection of gas signaling molecules including NO, CO and H2S in biological systems.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

A highly stable RNA aptamer probe for the retinoblastoma protein in live cells

Chem. Sci., 2020, 11,4467-4474
DOI: 10.1039/D0SC01613F, Edge Article
Open Access
Thao T. Le, Andreas Bruckbauer, Bogachan Tahirbegi, Alastair J. Magness, Liming Ying, Andrew D. Ellington, Anthony E. G. Cass
An RNA G-quadruplex aptamer, specific for the human retinoblastoma protein (RB) and highly stable inside cells, is selected and its application to live cell probing of the protein illustrated.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Ultraviolet photochemistry of ethane: implications for the atmospheric chemistry of the gas giants

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01746A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yao Chang, Jiayue Yang, Zhichao Chen, Zhiguo Zhang, Yong Yu, Qingming Li, Zhigang He, Weiqing Zhang, Guorong Wu, Rebecca A. Ingle, Matthew Bain, Michael N. R. Ashfold, Kaijun Yuan, Xueming Yang, Christopher S. Hansen
The vacuum ultraviolet photodissociation dynamics of ethane provide clues for modelling the atmospheric chemistry of the gas giants.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00266F, Edge Article
Open Access
Yunyi Wang, Jihyun Kim, Christian Hilty
Elucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01544J, Perspective
Open Access
Rebecca A. Olson, Angie B. Korpusik, Brent S. Sumerlin
Light-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC90081H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Leslie A. Nickerson, Benjamin D. Bergstrom, Mingchun Gao, Yuan-Shin Shiue, Croix J. Laconsay, Matthew R. Culberson, Walker A. Knauss, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01025A, Edge Article
Open Access
Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor Alabugin
How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01763A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal Khan
The first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

Near-infrared light-activated membrane fusion for cancer cell therapeutic applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00863J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar Willner
The spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...
The content of this RSS Feed (c) The Royal Society of Chemistry




li

N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00968G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. Lipshutz
A new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

A time-domain view of charge carriers in semiconductor nanocrystal solids

Chem. Sci., 2020, Advance Article
DOI: 10.1039/C9SC05925C, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wenbi Shcherbakov-Wu, William A. Tisdale
Time-domain spectroscopy and transient photocurrent techniques have revealed new understanding of mesoscale carrier dynamics in nanocrystal solids, including the role of energetic disorder, interactions with trap states, and nonequilibrium dynamics
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




li

BS Insurance Round Table: Sandbox opens up avenues for bundling services

A power-packed panel said that AI is the game changer in the non-life insurance business and underlined the need to generate underwriting profits and rely less on investment gains




li

09/22:00 CST Marine Wind Warning Summary for South Australia




li

Weather Warnings for Queensland - land areas. Issued by the Australian Bureau of Meteorology




li

We are buying in this market on a daily basis, says LIC MD Vipin Anand

The IPO is a time-consuming thing, which is going to be there, says Vipin Anand.




li

Sebi extends regulatory approval validity for IPO, rights issue by 6 months

Sebi's observation is necessary for any company to launch public issues.




li

Applied learning design in an online teacher-education course / Jillian J. Downing

Downing, Jillian J., author




li

National Strategy for International Education 2025 / Australian Government

Australia, author, issuing body




li

Educating for sustainability / Energy Action Australia

Energy Action Australia




li

Creating environments for learning : birth to age eight / Julie Bullard, University of Montana Western

Bullard, Julie, author




li

Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman




li

The Humboldtian tradition : origins and legacies / edited by Peter Josephson, Thomas Karlsohn, Johan Östling




li

The value of international education to Australia / prepared by Deloitte Access Economics

Deloitte Access Economics




li

Understanding the University : institution, idea, possibilities / Ronald Barnett

Barnett, Ronald, 1947- author




li

Teaching and learning for the twenty-first century : educational goals, policies, and curricula from six nations / Fernando M. Reimers, Connie K. Chung, editors




li

The silent university : towards a transversal pedagogy / edited by Florian Malzacher, Ahmet Ögüt, Pelin Tan




li

Professional development, instructional intelligence and teacher emotions : a mixed methods study of a four-year systemic change initiative / by Rebecca Ann Saunders

Saunders, Rebecca Ann, author




li

Corporate humanities in higher education : moving beyond the neoliberal academy / Jeffrey R. Di Leo

Di Leo, Jeffrey R., author




li

The falling rate of learning and the neoliberal endgame / David J. Blacker

Blacker, David J., author




li

Alternatives to privatizing public education and curriculum : Festschrift in honor of Dale D. Johnson / by Daniel Ness & Stephen J. Farenga




li

Secondary schooling in a changing world / Susan Groundwater-Smith ... [et al.]




li

Education and the crisis of public values : challenging the assault on teachers, students, and public education / Henry A. Giroux

Giroux, Henry A, author




li

Neoliberalism, education, and terrorism : contemporary dialogues / by Jeffrey R. Di Leo, Henry A. Giroux, Sophia McClennen, and Kenneth J. Saltman

Di Leo, Jeffrey R., author




li

Pedagogy and the politics of hope : theory, culture, and schooling : a critical reader / Henry A. Giroux

Giroux, Henry A