me Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC02213F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu Mao, Wenxuan Zhao, Shuo Lu, Lei Yu, Yi Wang, Yong Liang, Shengyang Ni, Yi PanRedox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for Cu-catalysed C–C bond formation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00512F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lívia S. Mészáros, Pierre Ceccaldi, Marco Lorenzi, Holly J. Redman, Emanuel Pfitzner, Joachim Heberle, Moritz Senger, Sven T. Stripp, Gustav BerggrenThe mechanism of hydrogen gas formation by [FeFe] hydrogenase is probed under whole cell conditions, revealing the formation of reactive metal hydride species under physiologically relevant conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00480D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi-Tsao Chen, Haw Yang, Jhih-Wei ChuThe mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me When Hollow Multi-Shelled Structures (HoMSs) Meet Metal-Organic Frameworks (MOFs) By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01284J, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zumin Wang, Nailiang Yang, Dan WangHollow multishelled structures (HoMSs) have distinguished advantages, such as large effective surface area, short mass transport route, and high loading capacity, but the fabrication of HoMS was a big challenge....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Spontaneous mirror symmetry breaking in benzil-based soft crystalline, cubic liquid crystalline and isotropic liquid phases By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01396J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tino Reppe, Silvio Poppe, Xiaoqian Cai, Yu Cao, Feng Liu, Carsten TschierskeBenzil (diphenylethane-1,2-dione), which is a long known example for an achiral molecule crystallizing in a chiral space group, can also show mirror symmetry breaking in the fluid state if it...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01911A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech PisulaThe solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Covalent Organic Frameworks as Microreactors: Confinement-enhanced Electrochemiluminescence By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01817A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wei-Jia Zeng, Kun Wang, Wenbin Liang, Yaqin Chai, Ruo Yuan, Ying ZhuoHerein, the electrochemiluminescence (ECL) microreactors with enhanced intensity and extreme stability were firstly established by the assembly of tris(2,2’-bipyridyl) ruthenium (II) (Ru(bpy)32+) onto the covalent organic frameworks (COFs) where a...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Thermal effects – an alternative mechanism for plasmon-assisted photocatalysis By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/C9SC06480J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yonatan Dubi, Ieng Wai Un, Yonatan SivanA simple Arrhenius-based theory of heating, rather than “hot electrons”, can reproduce some high-profile photocatalysis experimental results to remarkable accuracy. Flaws in temperature measurement may have led to wrong conclusions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Programmable synthesis of multiply arylated cubanes through C–H metalation and arylation By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01909G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ryo Okude, Genki Mori, Akiko Yagi, Kenichiro ItamiCubane has attracted attention due to its unique 3D structure. Herein, we report the programmable synthesis of multiply arylated cubanes. The developed reaction allows the late-stage and regioselective installation of aryl groups.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01890B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Santosh K. Pagire, Naoya Kumagai, Masakatsu ShibasakiAn efficient cooperative chiral Lewis acid and photoredox catalytic system towards the highly enantioselective radical conjugate addition of α-amino radicals to α,β-unsaturated amides is developed with the implementation of unique auxiliaries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Water-induced formation of an alkali-ion dimer in cryptomelane nanorods By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01517B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shaobo Cheng, Vidushi Sharma, Altug S. Poyraz, Lijun Wu, Xing Li, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, Marivi Fernández-Serra, Yimei ZhuWater displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Metal-metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00646G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shubham Deolka, Orestes Rivada, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin, Julia R KhusnutdinovaWe report selective formation of heterobimetallic PtII/CuI complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00997K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don TilleyA cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Expedient synthesis of conjugated triynes via alkyne metathesis By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01124J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Idriss Curbet, Sophie Colombel-Rouen, Romane Manguin, Anthony Clermont, Alexandre Quelhas, Daniel S. Müller, Thierry Roisnel, Olivier Baslé, Yann Trolez, Marc MauduitThe first synthesis of symmetrical and dissymmetrical conjugated triynes by self- and cross-metathesis was successfully achieved thanks to the use of hindered diynes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00463D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. WilliamsA new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Ring-Fused Cyclobutanes via Cycloisomerization of Alkylidenecyclopropane Acylsilanes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC02224A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Erick M Carreira, Sarah S Eichenberger, Moritz Hönig, Matthieu JR Richter, Renana Gershoni-PoranneA novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed. The readily available starting materials participate in tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes, which...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Pore engineering of ultrathin covalent organic framework membranes for organic solvent nanofiltration and molecular sieving By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01679A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Digambar B. Shinde, Li Cao, A. D. Dinga Wonanke, Xiang Li, Sushil Kumar, Xiaowei Liu, Mohamed N. Hedhili, Abdul-Hamid Emwas, Matthew Addicoat, Kuo-Wei Huang, Zhiping LaiPore surface engineering of ultrathin COF membranes by introducing different lengths of alkyl chains into the skeleton, which allows us to precisely control the pore size of COF membranes for OSN applications and molecular sieving.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC02253E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juan Mangas-Sanchez, Mahima Sharma, Sebastian C. Cosgrove, Jeremy I. Ramsden, James R. Marshall, Thomas W. Thorpe, Ryan B. Palmer, Gideon Grogan, Nicholas J. TurnerFungal reductive aminases as effective biocatalysts for the preparation of chiral primary amines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I) By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01512A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana SanchezThe first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4287-4296DOI: 10.1039/C9SC06006E, Minireview Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. EngleNickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me DP4-AI automated NMR data analysis: straight from spectrometer to structure By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4351-4359DOI: 10.1039/D0SC00442A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander Howarth, Kristaps Ermanis, Jonathan M. GoodmanA robust system for automatic processing and assignment of raw 13C and 1H NMR data DP4-AI has been developed and integrated into our computational organic molecule structure elucidation workflow.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Redox-responsive supramolecular polymeric networks having double-threaded inclusion complexes By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4322-4331DOI: 10.1039/C9SC05589D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hikaru Aramoto, Motofumi Osaki, Subaru Konishi, Chiharu Ueda, Yuichiro Kobayashi, Yoshinori Takashima, Akira Harada, Hiroyasu YamaguchiA hydrogel actuator with a 1:2 host–guest complex controlled by redox stimuli has been developed to realize faster and larger deformation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me SAXS studies of the thermally-induced fusion of diblock copolymer spheres: formation of hybrid nanoparticles of intermediate size and shape By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4312-4321DOI: 10.1039/D0SC00569J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.E. J. Cornel, P. S. O'Hora, T. Smith, D. J. Growney, O. O. Mykhaylyk, S. P. ArmesDilute dispersions of poly(lauryl methacrylate)-poly(benzyl methacrylate) diblock copolymer spheres of differing mean diameter are mixed and thermally annealed at 150 °C to produce either spherical or non-spherical nanoparticles of intermediate size.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4297-4304DOI: 10.1039/D0SC00735H, Minireview Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Eike Brunner, Marcus RaucheMetal–organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4397-4402DOI: 10.1039/D0SC00844C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong LiA novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4381-4390DOI: 10.1039/D0SC01026J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen NiemeyerSupramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me J-dimer emission in interwoven metal–organic frameworks By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4391-4396DOI: 10.1039/D0SC00876A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wesley J. Newsome, Arnab Chakraborty, Richard T. Ly, Gavin S. Pour, David C. Fairchild, Amanda J. Morris, Fernando J. Uribe-RomoJ-dimer emission is an emergent property that occurs when pairs of ground-state fluorophores associate within multivariate MOFs producing tunable red shifted emission.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4516-4524DOI: 10.1039/D0SC01319F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar WillnerBiocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4499-4507DOI: 10.1039/D0SC00135J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming HuMetal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Correction: Metal complexes as a promising source for new antibiotics By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4531-4531DOI: 10.1039/D0SC90075C, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Angelo Frei, Johannes Zuegg, Alysha G. Elliott, Murray Baker, Stefan Braese, Christopher Brown, Feng Chen, Christopher G. Dowson, Gilles Dujardin, Nicole Jung, A. Paden King, Ahmed M. Mansour, Massimiliano Massi, John Moat, Heba A. Mohamed, Anna K. Renfrew, Peter J. Rutledge, Peter J. Sadler, Matthew H. Todd, Charlotte E. Willans, Justin J. Wilson, Matthew A. Cooper, Mark A. T. BlaskovichThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4475-4481DOI: 10.1039/D0SC01194K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-EwingShort-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Designing naphthopyran mechanophores with tunable mechanochromic behavior By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4525-4530DOI: 10.1039/D0SC01359E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Brooke A. Versaw, Molly E. McFadden, Corey C. Husic, Maxwell J. RobbStructure–activity relationships for strategic substitution of the naphthopyran mechanophore scaffold enable polymeric materials with tunable mechanochromic behavior.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Multifunctional streptavidin–biotin conjugates with precise stoichiometries By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4422-4429DOI: 10.1039/D0SC01589J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dongdong Xu, Seraphine V. WegnerMultifunctional streptavidin-biotin conjugates with defined stoichiometry and number of open binding pockets provide molecularly precise alternatives to the statistical mixture of products that typically forms.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Functional group interaction profiles: a general treatment of solvent effects on non-covalent interactions By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4456-4466DOI: 10.1039/D0SC01288B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mark D. Driver, Mark J. Williamson, Joanne L. Cook, Christopher A. HunterFunctional group interaction profiles are a quantitative tool for predicting the effect of solvent on the free energy changes associated with non-covalent interactions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me A highly stable RNA aptamer probe for the retinoblastoma protein in live cells By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4467-4474DOI: 10.1039/D0SC01613F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Thao T. Le, Andreas Bruckbauer, Bogachan Tahirbegi, Alastair J. Magness, Liming Ying, Andrew D. Ellington, Anthony E. G. CassAn RNA G-quadruplex aptamer, specific for the human retinoblastoma protein (RB) and highly stable inside cells, is selected and its application to live cell probing of the protein illustrated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Geometric landscapes for material discovery within energy–structure–function maps By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00049C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seyed Mohamad Moosavi, Henglu Xu, Linjiang Chen, Andrew I. Cooper, Berend SmitWe introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00266F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yunyi Wang, Jihyun Kim, Christian HiltyElucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01544J, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rebecca A. Olson, Angie B. Korpusik, Brent S. SumerlinLight-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC02020F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey StephensonHydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01025A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor AlabuginHow far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01763A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal KhanThe first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00021C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Koichiro Masuda, Shū KobayashiA direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Near-infrared light-activated membrane fusion for cancer cell therapeutic applications By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00863J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar WillnerThe spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01796E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.David Zhi Hong Zee, T. David HarrisCatalytic heme active sites of enzymes are sequestered by the protein superstructure and are regulated by precisely defined outer coordination spheres. Here, we emulate both of these protective functions in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me A time-domain view of charge carriers in semiconductor nanocrystal solids By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/C9SC05925C, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wenbi Shcherbakov-Wu, William A. TisdaleTime-domain spectroscopy and transient photocurrent techniques have revealed new understanding of mesoscale carrier dynamics in nanocrystal solids, including the role of energetic disorder, interactions with trap states, and nonequilibrium dynamicsTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Weather Warnings for Queensland - land areas. Issued by the Australian Bureau of Meteorology By www.bom.gov.au Published On :: Full Article
me UP: 1200 AMU students from Bihar return home By timesofindia.indiatimes.com Published On :: Fri, 08 May 2020 19:46:48 IST Aligarh Muslim University (AMU) has made arrangement for transportation of students from Bihar by a special train on Friday. Over 1200 students were scheduled to return home after completing their medical screening. Full Article
me Show-cause notices issued to 87 medicos of JNMCH By timesofindia.indiatimes.com Published On :: Sat, 09 May 2020 12:30:15 IST Dr Sinha on Friday said that show-cause notices have been issued to 87 erring PG students. Full Article
me Who are intermediaries in an IPO? By economictimes.indiatimes.com Published On :: 2020-04-06T12:18:25+05:30 All the relevant information regarding the four intermediates such as addresses, telephone/fax numbers, registration number, and contact person and email addresses, are disclosed in the offer documents. Full Article
me Laxmi Goldorna IPO overall subscribed 1.15 times By economictimes.indiatimes.com Published On :: 2020-04-06T18:23:00+05:30 The company would be listed on NSE EMERGE after the lockdown is eased. Full Article