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Prediction of ternary fluorooxoborates with coplanar triangular units [BOxF3−x]x− from first-principles

Dalton Trans., 2020, 49,5424-5428
DOI: 10.1039/D0DT00160K, Communication
Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan
From first-principles prediction, we got all the basic structural units of fluorooxoborates, namely, tetrahedral elements [BOxF4−x] (x = 1,2,3) like [BO4] and triangular elements [BOxF3−x] (x = 1,2) like [BO3].
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Trinuclear Mn2+/Zn2+ based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids

Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper
Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
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Templated syntheses of heterometal tungsten–cobalt–sulfur clusters with different nuclearities

Dalton Trans., 2020, 49,5523-5530
DOI: 10.1039/D0DT00765J, Paper
Jia-Ting Guo, Xu-Dong Chen
A series of heterometal tungsten–cobalt–sulfur clusters with different nuclearities have been synthesized rationally using a chelating template.
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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

Dalton Trans., 2020, 49,5440-5444
DOI: 10.1039/D0DT00966K, Communication
Lijuan Huang, Lei Wang, Yan Zhao, Ling Huang, Jian Bi, Guohong Zou, Zhien Lin, Daojiang Gao
An amino acid-templated gallium phosphate with a zeolitic topology has been prepared under surfactant-thermal conditions and it shows exceptional water stability and interesting proton-conducting properties.
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Oxaliplatin and [Pt(R,R-DACH)(panobinostat-2H)] show nanomolar cytotoxicity towards diffuse intrinsic pontine glioma (DIPG)

Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
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Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
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NHC–Au(I) complexes bearing trispyrazolyl borate (Tp) ligands: efficient platforms for bimetallic species

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00908C, Paper
Carlos Ángel-Jijón, David Rendón-Nava, Jose M. Vazques-Pérez, Alejandro Álvarez-Hernández, Daniel Mendoza-Espinosa, Verónica Salazar-Pereda
Treatment of NHC–AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTpR2 (R = Me, H) salts in tetrahydrofuran produces in high yields the heteroleptic complexes 3–6 with the general formula NHC–Au–TpR2.
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Enhancing the energy barrier by replacing the counterions in two holmium(III)-pentagonal bipyramidal single-ion magnets

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00905A, Paper
Lei-Lei Li, Hong-Dan Su, Shuang Liu, Wen-Zhen Wang
Upon changing the employed halide ions as counterions, Ueff increases from 290 K to 320 K in two HoIII-SIMs with pentagonal-bipyramidal structures.
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Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper
Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
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Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper
Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH4 hydrogens are shown for clarity).
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Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper
Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
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Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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An ultra-effective pathway for fully removing the oxygen components of graphene oxide by a flame-assisted microwave process

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication
Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
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The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper
Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication
Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper
Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt)

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00923G, Paper
Stefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero Mastrorilli
Double addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)] (Pt–Pt) affords the η1-alkenyl-μ,η12-alkynyl complex [(η1-trans-(Ph)HCCH)(PHCy2)Pt(μ-PCy2)(μ,η12-PhCC)Pt{κP-P(O)Cy2}(PHCy2)].
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A molecular boron cluster-based chromophore with dual emission

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00826E, Paper
Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. Spokoyny
Bromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid.
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Two [Ln4] molecular rings folded as compact tetrahedra

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01259A, Paper
Guillem Aromi, Olivier Roubeau, Leoní Alejandra Barrios, Jorge Salinas-Uber
The design of photoactive ligands may provide an entry into multifunctional molecular nanomagnets. We report here the design and synthesis of a new multitopic chelating ligand, 1,2-bis-(5-(N’-(pyridine-2-yl-methylene)-carbohydrazide)-3-methyl-thien-3-yl)-cyclopentene (H2L), bearing a...
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Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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High Pressure and Elastic properties of a Guanidinium -formate Hybrid Perovskite

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04805G, Paper
Hong-Qiang Gao, Chao Li, Lin-Sui Li, Wen-Juan Wei, Yu-hui Tan, Yun Zhi Tang
The high pressure and elastic properties in a hybrid ABX3-type perovskite, [C(NH2)3][Cd(HCOO)3] (CdGF), based on the A-site guest molecular is revealed via combining the high-pressure synchrotron X-ray diffraction experiments with...
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Photophysical, photodynamical, redox properties and BSA-interactions of novel isomeric tetra-cationic peripheral palladium(II)-bipyridyl porphyrins

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper
Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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Platinum Complexes of a Boron-Rich Diphosphine Ligand

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00963F, Paper
Marcus W. Drover, Eric G Bowes, Maeve C Dufour, Lindsay Lesperance-Nantau
Herein, we describe the preparation, characterization, and reactivity of two PtIIbis-hydrocarbyl complexes containing the 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P2BCy4) ligand. These scaffolds are readily accessed from four-fold hydroboration of 1,2-bis(diallylphosphino)ethane PtII precursors....
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What is a “third place,” and do you have one?

The term “happy place” is not in the Oxford English Dictionary (though “happy slap” is), but I’ve been hearing the term a lot. There’s even a new shop in Great Barrington called HappyPlace Berkshires. I first dismissed it as therapeutic slang, but discovered that the concept actually goes back to the Greeks: a utopia is

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Big History Ebooks Now Available For WH & BHP Classes

Cynthia Stokes Brown wrote BIG HISTORY, SMALL WORLD to help Big History Project students and their teachers, many of whom she knew and befriended in the earliest days of big history education. David Christian's THIS FLEETING WORLD is widely used in AP World History as well as big history courses. BIG HISTORY: A BERKSHIRE ESSENTIAL is a collection of essays by

The post Big History Ebooks Now Available For WH & BHP Classes appeared first on Berkshire Publishing.




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Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti

Dewey Library - KF6289.I49 2018




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Real estate finance in a nutshell / Vada Waters Lindsey, Associate Professor of Law, Marquette University Law School

Rotch Library - KF695.Z9 L56 2018




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Many nations under many gods: public land management and American Indian sacred sites / Todd Allin Morman

Rotch Library - KF5605.M67 2018




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No property in man: slavery and antislavery at the nation's founding / Sean Wilentz

Hayden Library - KF4545.S5 W59 2018




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Separate: the story of Plessy v. Ferguson, and America's journey from slavery to segregation / Steve Luxenberg

Hayden Library - KF223.P56 L88 2019




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Gender quotas in South America's big three: national and subnational impacts / Adriana Piatti-Crocker, Gregory D. Schmidt, and Clara Araujo

Dewey Library - KH136.W64 P53 2017




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Winning together: the natural resource negotiation playbook / Bruno Verdini Trejo

Dewey Library - KZ6047.V47 2017




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Strategic indeterminacy in the law / David Lanius

Online Resource




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Authors, users, and pirates: copyright law and subjectivity / James Meese

Dewey Library - K1420.5.M44 2018




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Armed conflict and forcible displacement: individual rights under international law / edited by Elena Katselli Proukaki

Dewey Library - KZ6530.A75 2018




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Punishing atrocities through a fair trial: international criminal law from Nuremberg to the age of global terrorism / Jonathan Hafetz

Dewey Library - KZ7050.H34 2018




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From slaves to prisoners of war: the Ottoman Empire, Russia, and international law / Will Smiley

Dewey Library - KZ6495.S63 2018




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Regulatory counter-terrorism: a critical appraisal of proactive global governance / Nathanael Tilahun Ali

Dewey Library - KZ7220.A9565 2018




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Habeas data: privacy vs. the rise of surveillance tech / Cyrus Farivar

Dewey Library - KF1262.F37 2018




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Transactional intellectual property: from startups to public companies / Richard S. Gruner, professor of law, John Marshall Law School), Shubha Ghosh (Crandall Melvin Professor of Law, director, Technology Commercialization Law Program & Syracuse Inte

Dewey Library - KF2980.G78 2018




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International migration law / Vincent Chetail

Dewey Library - K3275.C44 2019




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Land use planning and development regulation law / Julian Conrad Juergensmeyer (professor and Ben F. Johnson Jr. Chair in Law, Georgia State University College of Law, adjunct professor in city and regional planning, Georgia Institute of Technology), Tho

Rotch Library - KF5698.J84 2018




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The U.S. Supreme Court and racial minorities: two centuries of judicial review on trial / Leslie F. Goldstein, Judge Hugh M. Moris Professor Emerita, University of Delaware, USA

Dewey Library - KF8742.G65 2017




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The grey zone: civilian protection between human rights and the laws of war / edited by Mark Lattimer and Philippe Sands

Dewey Library - KZ6515.G74 2018