the

[ASAP] Crystallization-Induced Diastereoisomer Transformation of Dihydroartemisinic Aldehyde with the Betti Base

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00481




the

[ASAP] Comparing Gas–Liquid Segmented and Tube-in-Tube Setups for the Aerobic Dimerization of Desmethoxycarpacine with an Automated Flow Platform

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00525




the

[ASAP] A Perspective on Continuous Flow Chemistry in the Pharmaceutical Industry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00524




the

[ASAP] Evaluation of Sponge Metal Catalysts in a Trickle Bed Reactor for the Continuous Hydrogenation of an Aliphatic Nitro Intermediate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00447




the

[ASAP] Development of a Robust Protocol for the Synthesis of 6-Hydroxybenzofuran-3-carboxylic Acid

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00546




the

[ASAP] Development of a General Automated Flow Photoredox <sup>18</sup>F-Difluoromethylation of N-Heteroaromatics in an AllinOne Synthesizer

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00442




the

[ASAP] From Industrial Method to the Use of Silylated P(III) Reagents for the Synthesis of Relevant Phosphonylated Molecules

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00490




the

[ASAP] Total Synthesis of (+)-Oxo-tomaymycin

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00009




the

[ASAP] Synthesis of 5-Substituted 1<italic toggle="yes">H</italic>-Tetrazoles from Nitriles by Continuous Flow: Application to the Synthesis of Valsartan

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00526




the

[ASAP] Nontraditional Application of the Photo-Fenton Process: A Novel Strategy for Molecular Construction Using Formamide and Flow Chemistry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00057




the

[ASAP] Development of an Efficient Synthetic Process for Broflanilide

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00028




the

[ASAP] Green Chemistry Articles of Interest to the Pharmaceutical Industry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00154




the

[ASAP] Scalable Synthesis of Esp and Rhodium(II) Carboxylates from Acetylacetone and RhCl<sub>3</sub>·<italic toggle="yes">x</italic>H<sub>2</sub>O

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00164




the

[ASAP] Photo-oxidation of Cyclopentadiene Using Continuous Processing: Application to the Synthesis of (1<italic toggle="yes">R</italic>,4<italic toggle="yes">S</italic>)-4-Hydroxycyclopent-2-en-1-yl Acetate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00066




the

[ASAP] Process Development and Large-Scale Synthesis of BTK Inhibitor BIIB068

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00087




the

[ASAP] A Versatile Electrochemical Batch Reactor for Synthetic Organic and Inorganic Transformations and Analytical Electrochemistry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00091




the

[ASAP] Improved Synthesis of 6-Chloro-5-methylpyridin-2-amine: A Key Intermediate for Making Lumacaftor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00556




the

[ASAP] <italic toggle="yes">N</italic>-Acyl-5,5-Dimethylhydantoins: Mild Acyl-Transfer Reagents for the Synthesis of Ketones Using Pd–PEPPSI or Pd/Phosphine Catalysts

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00054




the

[ASAP] A Scalable Membrane Pervaporation Approach for Continuous Flow Olefin Metathesis

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00061




the

[ASAP] Scalable Synthesis of <italic toggle="yes">S</italic>-Fluoromethyl Benzenesulfonothioate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00101




the

[ASAP] Optimized Synthesis of 7-Azaindazole by a Diels–Alder Cascade and Associated Process Safety

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00184




the

[ASAP] Enzymatic Preparation of the Chiral (<italic toggle="yes">S</italic>)-Sulfoxide Drug Esomeprazole at Pilot-Scale Levels

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00115




the

[ASAP] Continuous Process for Preparing the Difluoromethylating Reagent [(DMPU)<sub>2</sub>Zn(CF<sub>2</sub>H)<sub>2</sub>] and Improved Synthesis of the ICHF<sub>2</sub> Precursor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00089




the

[ASAP] Development and Production of an Enantioselective Tetrahydroisoquinoline Synthesis Enabled by Continuous Cryogenic Lithium–Halogen Exchange

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00141




the

[ASAP] <sc>d</sc>-Serine as a Key Building Block: Enzymatic Process Development and Smart Applications within the Cascade Enzymatic Concept

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00024




the

[ASAP] Correction to “Application of Crabtree/Pfaltz-type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block”

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00206




the

[ASAP] Catalyst-Free Cyclization- and Curtius Rearrangement-Induced Functional Group Transformation: An Improved Synthetic Strategy of First-in-Class ATX Inhibitor Ziritaxestat (GLPG-1690)

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00511




the

The effect of crystallite size on low-temperature hydrothermal stability of Cu-SAPO-34

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00414F, Paper
Jinpeng Du, Xiaoyan Shi, Yulong Shan, Yingjie Wang, Wenshuo Zhang, Yunbo Yu, Wenpo Shan, Hong He
Two Cu-SAPO-34 catalysts with different crystallite sizes were obtained, and catalyst with smaller crystallite size had better low-temperature hydrothermal stability because of less Cu2+ species on the surface.
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the

Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00322K, Paper
Open Access
Elba Ochoa, Wilson Henao, Sara Fuertes, Daniel Torres, Tomas van Haasterecht, Elinor Scott, Harry Bitter, Isabel Suelves, Jose Luis Pinilla
Evaluation of the dispersion of Pd active sites on the catalyst performance during fatty acids decarbonylation to α-olefins was explored in this work. Pd subnanometric particles, clusters and aggregates were found to modulate the catalyst activity.
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the

Computational investigation of the ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02562F, Paper
Pan Li, Chaoren Shen, Jie Min, Jing-Yuan Mei, Huan Zheng, Lin He, Xinxin Tian
The ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation has been discussed.
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the

Synergetic effect of Lewis acid and base in modified Sn-β on the direct conversion of levoglucosan to lactic acid

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00089B, Paper
Wenda Hu, Zixin Chi, Yan Wan, Shuai Wang, Jingdong Lin, Shaolong Wan, Yong Wang
The synergetic effect of Lewis acid and base in modified Sn-β boosts the yield of lactic acid produced from levoglucosan.
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the

Superior adsorption capability and excellent photocatalytic activity derived from the ferroelectric external screening effect in Bi3TiNbO9 single-crystal nanosheets

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02513H, Paper
Xiaofeng Yin, Yingjie Sun, Xiaojun Wu, Xiaoning Li, Huan Liu, Wen Gu, Wei Zou, Liuyang Zhu, Zhengping Fu, Yalin Lu
A new strategy based on the ferroelectric external screening effect was used to enhance dye adsorption and degradation activity.
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the

Enhancing the methane low-temperature conversion on the Zn/ZSM-5 in the presence of methanol by regulating methanol-to-aromatics reaction pathway

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00449A, Paper
Zhixiang Xi, Bingjie Zhou, Yue Yu, Binbo Jiang, Zhengliang Huang, Zuwei Liao, Jingdai Wang, Yao Yang, Jingyuan Sun, Yongrong Yang
Co-reaction method provides efficient strategy for methane conversion in mild condition, which is of urgent importance of direct valorization of natural gas to liquid hydrocarbons. However, vague mechanism and neglect...
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the

Development of an engineered thermostable amine dehydrogenase for the synthesis of structurally diverse chiral amines

Catal. Sci. Technol., 2020, 10,2353-2358
DOI: 10.1039/D0CY00071J, Paper
Lei Liu, Dong-Hao Wang, Fei-Fei Chen, Zhi-Jun Zhang, Qi Chen, Jian-He Xu, Zhi-Long Wang, Gao-Wei Zheng
Structurally diverse chiral amines and amino alcohols were synthesized using an engineered thermostable amine dehydrogenase, demonstrating its extensive synthesis potential.
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the

Fine-tuning of the substrate binding mode to enhance the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase

Catal. Sci. Technol., 2020, 10,2462-2472
DOI: 10.1039/C9CY02335F, Paper
Aipeng Li, Xue Li, Wei Pang, Qing Tian, Ting Wang, Lianbing Zhang
Fine-tuning of the substrate binding mode was successfully applied for enhancing the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase.
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the

Effect of ceria morphology on the performance of MnOx/CeO2 catalysts in catalytic combustion of N,N-dimethylformamide

Catal. Sci. Technol., 2020, 10,2473-2483
DOI: 10.1039/C9CY02384D, Paper
Fengying Huang, Dongsheng Ye, Xiaohan Guo, Wangcheng Zhan, Yun Guo, Li Wang, Yunsong Wang, Yanglong Guo
MnOx/CeO2 catalysts were prepared by a deposition–precipitation method, through loading MnOx into ceria supports with different morphologies (nanorods (NRs), nanocubes (NCs) and nano-octahedrons (NOs)).
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the

Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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the

Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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the

Hydroxyl groups attached to Co2+ on the surface of Co3O4: a promising structure for propane catalytic oxidation

Catal. Sci. Technol., 2020, 10,2573-2582
DOI: 10.1039/D0CY00265H, Paper
Kun Chen, Wenzhi Li, Zean Zhou, Qifu Huang, Yang Liu, Qiuyan Duan
Co3O4 catalysts with three specific morphologies (nanocubes, nanosheets, and nanooctahedra) were prepared using simple preparation methods and tested for catalytic combustion of propane under the same reaction conditions.
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the

The direct decomposition of NO into N2 and O2 over copper doped Ba3Y4O9

Catal. Sci. Technol., 2020, 10,2513-2522
DOI: 10.1039/D0CY00194E, Paper
Siman Fang, Atsushi Takagaki, Motonori Watanabe, Tatsumi Ishihara
Both NO decomposition activity and long-term stability increase significantly after the introduction of Cu into Ba3Y4O9.
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the

Trace amounts of Cu(OAc)2 boost the efficiency of cumene oxidation catalyzed by carbon nanotubes washed with HCl

Catal. Sci. Technol., 2020, 10,2523-2530
DOI: 10.1039/C9CY02536G, Paper
Jie Deng, Yuhang Li, Yonghai Cao, Hongjuan Wang, Hao Yu, Qiao Zhang, Jiangliang Zuo, Feng Peng
Trace amounts of Cu(OAc)2 significantly improve the activity and selectivity of cumene oxidation catalyzed by HCl-washed carbon nanotubes.
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the

New findings and current controversies in the reaction of ruthenium red and ammonium cerium(IV) nitrate: focus on the precipitated compound

Catal. Sci. Technol., 2020, 10,2491-2502
DOI: 10.1039/C9CY02499A, Paper
Bahram Sarvi, Seyedeh Maedeh Hosseini, Bahareh Deljoo, Abdelhamid El-Sawy, Alireza Shirazi Amin, Mark Aindow, Steven L. Suib, Mohammad Mahdi Najafpour
During water-oxidation reaction in the presence of RuR and CAN, a heterogeneous nano-sized Ru-Ce compound is detected, which is formed by the interaction of [(NH3)5RuORu(NH3)4ORu(NH3)5],6+/7+ nitrate ions, and the products of the reduction of CAN.
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the

Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution

Catal. Sci. Technol., 2020, 10,2333-2336
DOI: 10.1039/D0CY00416B, Communication
Open Access
G. Blanco-Brieva, F. Desmedt, P. Miquel, J. M. Campos-Martin, J. L. G. Fierro
We show the first catalyst family able to produce hydrogen peroxide at concentrations higher than 5 wt% in the absence of any promoter or stabilizing agent in dissolution.
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the

Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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the

Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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the

Highly-efficient Ru/Al–SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of p-phthalic acid

Catal. Sci. Technol., 2020, 10,2443-2451
DOI: 10.1039/D0CY00047G, Paper
Cong Mao, Jingwei Zheng, Babasaheb M. Matsagar, Ranjith Kumar Kankala, Tansir Ahamad, Yucheng Yang, Kevin C.-W. Wu, Xueqin Zhang
A Ru/Al–SBA-15 catalyst with excess Lewis acid sites displayed excellent efficiency (100%), high cis-isomer selectivity (84%), and exceptional stability towards hydrogenation of p-phthalic acid in water.
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the

Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
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the

Aerobic oxidation of 1,6-hexanediol to adipic acid over Au-based catalysts: the role of basic supports

Catal. Sci. Technol., 2020, 10,2644-2651
DOI: 10.1039/D0CY00183J, Paper
Open Access
Noemi Capece, Achraf Sadier, Camila Palombo Ferraz, Joëlle Thuriot-Roukos, Mariusz Pietrowski, Michał Zieliński, Sébastien Paul, Fabrizio Cavani, Robert Wojcieszak
1,6-Hexanediol is a relevant building blocks that could be obtained from biomass and transformed under base free conditions into adipic acid used for polymer synthesis.
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the

Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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the

Mechanistic insights into the oxidation of copper(I) species during NH3–SCR over Cu-CHA zeolites: A DFT study

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00379D, Paper
Chong Liu, Hiroe Kubota, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu
Selective catalytic reduction of nitrogen oxides using ammonia (NH3–SCR) over Cu-exchanged zeolites proceeds via reduction of Cu(II) to Cu(I) and subsequent reoxidation of Cu(I) to Cu(II). Although the mechanism of...
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