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Oxidation of lignocellulosic platform molecules to value-added chemicals using heterogeneous catalytic technologies

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00240B, Minireview
Pedro L. Arias, Juan A. Cecilia, Iñaki Gandarias, José Iglesias, Manuel López Granados, Rafael Mariscal, Gabriel Morales, Ramón Moreno-Tost, Pedro Maireles-Torres
This minireview gives an overview about heterogeneous catalytic technologies for the oxidation of key platform molecules (glucose, 5-hydroxymethylfurfural, furfural and levulinic acid) into valuable chemicals.
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Water-soluble NHC-stabilized platinum nanoparticles as recoverable catalysts for hydrogenation in water

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00481B, Paper
Andrea M. Ruiz-Varilla, Edwin A. Baquero, Bruno Chaudret, Ernesto de Jesús, Camino Gonzalez-Arellano, Juan C. Flores
Aromatic compounds have been hydrogenated in water using recoverable catalysts based on water-soluble platinum nanoparticles capped with NHC ligands.
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Enhancing the methane low-temperature conversion on the Zn/ZSM-5 in the presence of methanol by regulating methanol-to-aromatics reaction pathway

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00449A, Paper
Zhixiang Xi, Bingjie Zhou, Yue Yu, Binbo Jiang, Zhengliang Huang, Zuwei Liao, Jingdai Wang, Yao Yang, Jingyuan Sun, Yongrong Yang
Co-reaction method provides efficient strategy for methane conversion in mild condition, which is of urgent importance of direct valorization of natural gas to liquid hydrocarbons. However, vague mechanism and neglect...
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Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
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Single-step benzene hydroxylation by cobalt(II) catalysts via a cobalt(III)-hydroperoxo intermediate

Catal. Sci. Technol., 2020, 10,2540-2548
DOI: 10.1039/C9CY02601K, Paper
Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan
Cobalt(II) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H2O2. The catalysis proceeds likely via cobalt(III)-hydroperoxo species.
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Facile sulfolane-modified resins for enhanced dimethoxymethane carbonylation

Catal. Sci. Technol., 2020, 10,2561-2572
DOI: 10.1039/D0CY00201A, Paper
Jie Yao, Lei Shi, Wenjie Deng, Jiaqi Fan, Yan Wang, Weizhe Gao, Dongxi Zhang, Wenliang Zhu, Zhongmin Liu
A simple resin modification method for 50 h DMM carbonylation with a high STY of 3.15 mmolMMAc (gcat h)−1 and 100% MMAc selectivity.
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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

Catal. Sci. Technol., 2020, 10,2615-2626
DOI: 10.1039/C9CY02407G, Paper
Dan Zhao, Guoqiang Zhang, Lifei Yan, Lingqi Kong, Huayan Zheng, Jie Mi, Zhong Li
The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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Carbon nanotube/PTFE as a hybrid platform for lipase B from Candida antarctica in transformation of α-angelica lactone into alkyl levulinates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00545B, Paper
Anna Szelwicka, Anna Kolanowska, Piotr Latos, Sebastian Jurczyk, Slawomir Boncel, Anna Chrobok
A highly active biocatalyst based on a hybrid platform was designed for the conversion of α-angelica lactone to alkyl levulinates.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
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Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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Semi-rational hinge engineering: modulating the conformational transformation of glutamate dehydrogenase for enhanced reductive amination activity towards non-natural substrates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02576F, Paper
Xinjian Yin, Yayun Liu, Lijun Meng, Haisheng Zhou, Jianping Wu, Lirong Yang
The hinge region was identified to be a promising hotspot for activity engineering of GluDHs, providing a potent alternative for developing high-performance biocatalysts toward valuable optically pure L-amino acid production.
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Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00707B, Paper
Miguel González-Lainez, M. Victoria Jiménez, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Compound [IrBr(CO)2(κC-tBuImCH2PyCH2OMe)] featuring a flexible pyridine/OMe functionalized NHC ligand κ1C coordinated efficiently catalyzes the selective N-monomethylation of nitroarenes using methanol as both the reducing agent and the C1 source. A...
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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
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Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
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Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
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Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00092B, Paper
Xiao-Yun Wu, Hou-Ze Gui, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse
A convenient and efficient strategy for the synthesis of 3-pyrrolines containing an amino quaternary stereogenic center via phosphine-catalyzed formal [3 + 2] annulation of allenoates with 2-aminoacrylates is disclosed. A...
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Influence of gold on the reactivity behaviour of ceria nanorods in CO oxidation: Combining operando spectroscopies and DFT calculations

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00392A, Paper
Marc Ziemba, Christian Hess
Au/CeO2 catalysts are commonly used for low-temperature CO oxidation. While many studies focus on the properties of gold and their relevance for the activity, the influence of the support properties...
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Interfacial Effect of Co4S3-Co9S8 Nanoparticles Hosted onto rGO Sheets Derived from Molecular Precursor Pyrolysis on Enhancing Electrochemical Behaviour†

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00564A, Paper
Mengmeng He, Linchao Zhu, Yanyan Liu, Hao Wen, Yunxia Hu, Baojun Li
The reasonable design and synthesis of Co-based compound with superior electrochemical activity and durability have aroused tremendous research interests. Herein, a simple molecular precursor pyrolysis strategy is proposed to fabricate...
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Reply To: .last-child or???

Hello there. Interesting thread, thanks for the information.




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centered heading over multible lines, underline just the last words

Hey everyone!

I have invested much time, but I cannot find a solution to make the CSS underline like the following picture:

Here how it should look: https://i.stack.imgur.com/CPqMl.jpg

It is a heading with centered text. At bigger screens, the text is displayed in just one line.

It would be nice if the red underline isn´t directly connected with the words (so that it is responsively).

Have you a CSS snippet or a link?

Thanks in advance!




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Reliance General Insurance scraps IPO plan; withdraws draft offer documents

Markets regulator Sebi had received draft red herring prospectus for the proposed IPO on February 8




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Shapoorji Pallonji group subsidiary announces plan to list Eureka Forbes

Forbes & Company, a Shapoorji Pallonji group firm on Tuesday announced plans to list its subsidiary Eureka Forbes to unlock value for shareholders. The company's board has authorised the management to evaluate any such scheme in this regard, Forbes & Company said in a regulatory filing. "The Board of Directors of the company has authorised the management...to evaluate a scheme of arrangement and/or other appropriate mechanisms to enable an eventual listing of Eureka Forbes with an intention to unlock value in the hands of all the shareholders of the company," it said. These may also include listing, dilution/sale or combination thereof of Eureka Forbes, it added. Eureka Forbes is a wholly-owned subsidiary of Forbes & Company. "The Board will consider the above (schemes) when the relevant proposals are placed before it in the near future, but in principle has approved supporting the endeavours of the management in this regard," it said. It operates in water purifier, air ...




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Puranik Builders re-files IPO papers, plans to raise Rs 1k-cr to pare debt

Edelweiss Financial Services Ltd and Axis Capital will manage the company's initial share-sale. Shares of the company will be listed on the BSE and NSE.




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NSE approaches Sebi for IPO, hopes to launch public issue by September

The entire IPO would be offer-for-sale (OFS), wherein existing shareholders will sell NSE's shares




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Planning to apply for SBI Cards IPO? Check out the eligibility criteria

Normally, IPOs are open for subscription for three days but SBI Cards IPO will run for four days. The first three days, i.e. from March 2 to March 4, the issue will be open for all bidders




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Antony Waste extends IPO closing to March 16, cites exceptional volatility

Antony Waste IPO comprises of Rs 35 crore of fresh fund raising and Rs 171 crore of secondary share sale




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'Death Cap' mushrooms kill six in Meghalaya

The poisonous mushrooms that killed six people at a remote village in Meghalaya's West Jaintia Hills district have been identified as Amanita phalloides, commonly known as the 'Death Cap', a senior official said on Saturday.




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Kol schools reduce bus, lab and library fees

Several schools in the city have suspended or offered concessions in school bus, laboratory charges, library fees, optional computer training and other student-based activities that are payable.




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Somnambulance / Fiona Smyth

Hayden Library - PN6733.S638 A6 2018




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The American way: those above and those below / written by John Ridley ; pencils by Georges Jeanty ; inks by John Livesay [and 3 others] ; colors by Nick Filardi ; letters by Travis Lanham

Hayden Library - PN6728.A496 R54 2018




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Shuri / Nnedi Okorafor, writer ; Leonardo Romero, artist ; Jordie Bellaire, color artist ; VC's Joe Sabino, letterer ; Wil Moss, editor

Hayden Library - PN6728.S4774 O56 2019




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Batman/The Shadow: the murder geniuses / story by Scott Snyder and Steve Orlando ; script by Steve Orlando ; art by Riley Rossmo ; colors by Ivan Plascencia ; letters by Clem Robins ; cover art and original series covers by Riley Rossmo

Barker Library - PN6728.B36 S674 2017




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Tales from la vida: a Latinx comics anthology / edited by Frederick Luis Aldama

Barker Library - PN6725.T35 2018




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Woman world / Aminder Dhaliwal ; color by Nikolas Ilic

Barker Library - PN6733.D35 W66 2018




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Freedom Hospital / Hamid Sulaiman ; translated by Francesca Barrie

Barker Library - PN6790.S953 S85 2018




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Infidel / writer, Pornsak Pichetshote ; artist, Aaron Campbell ; colorist & editor, José Villarrubia ; letterer & designer, Jeff Powell ; introduction by Tananarive Due ; afterword by Jeff Lemire

Barker Library - PN6727.P534 I53 2018




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Black Panther. writer[s], Nnedi Okorafor, Aaron Covington ; artists, André Lima Araújo, Mario del Pennino ; color artist[s], Chris O'Halloran, Ian Herring, Irma Knivila ; penciler, Tana Ford ; inkers, Tana Ford, Terry Pallot, Scott Hanna ;

Barker Library - PN6728.B53 L66 2018




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Ricanstruction: reminiscing & rebuilding Puerto Rico / publisher, executive producer, editor, title design, book design, writer, Edgardo Miranda-Rodriguez ; cover artists Tony Daniel, Danny Miki, Tomeu Morey ; inside cover artist Nicole Virella ; back

Barker Library - PN6726.R53 2018




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Frankenstein: Junji Ito story collection / story & art by Junji Ito ; translation, Jocelyn Allen ; English adaptation, Nick Mamatas ; other stories translation & adaptation, Jocelyn Allen ; touch-up art & lettering, James Dashiell ; cover &

Barker Library - PN6790.J33 I73413 2018




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Self/made / writer, Mat Groom ; artist, Eduardo Ferigato ; colorist, Marcelo Costa ; color flats, Mariana Calil ; letterer, A Larger World Studios' Troy Peteri ; editor, Kyle Higgins

Barker Library - PN6728.S437 G76 2019