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The origin of regioselectivity in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides

Org. Chem. Front., 2020, 7,1137-1148
DOI: 10.1039/D0QO00214C, Research Article
Shengnan Liu, Jianbiao Liu, Qiong Wang, Jin Wang, Fang Huang, Wenjuan Wang, Chuanzhi Sun, Dezhan Chen
Steric interactions mediate a switch between a ketone and allylic alcohol in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rh(III)-Catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes

Org. Chem. Front., 2020, 7,1158-1163
DOI: 10.1039/D0QO00248H, Research Article
Shaonan Wu, Zhuo Wang, Dianxue Ma, Chen Chen, Bolin Zhu
We reported a Rh(III)-catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes, which provided diversiform functionalized N,N-bidentate chelating compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An Aspidosperma-type alkaloid dimer from Tabernaemontana bovina as a candidate for the inhibition of microglial activation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00296H, Research Article
Yang Yu, Si-Meng Zhao, Mei-Fen Bao, Xiang-Hai Cai
As a representative of twelve undescribed Aspidosperma-type alkaloid dimers, tabernaemontine F (6) inhibited microglial activation by blocking P38 MAPK activation, revealing a potential candidate for chronic neurodegenerative diseases.
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Tricarabrols A–C, three anti-inflammatory sesquiterpene lactone trimers featuring a methylene-tethered linkage from Carpesium faberi

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00093K, Research Article
Jie Yuan, Xuelan Wen, Chang-Qiang Ke, Tian Zhang, Ligen Lin, Sheng Yao, Jason D. Goodpaster, Chunping Tang, Yang Ye
Three anti-inflammatory trimeric compounds constructed from carabrol-type sesquiterpenoids through a methylene-tethered linkage were characterized from Carpesium faberi.
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An exocyclic π-system extension of the phenanthriporphyrin framework: towards azaaceneporphyrinoids

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00436G, Research Article
Bartosz Szyszko, Damian Dróżdż, Aleksandra Sarwa, Sebastian G. Mucha, Agata Białońska, Michał J. Białek, Katarzyna Matczyszyn, Lechosław Latos-Grażyński
An exocyclic π-extension of phenanthriporphyrin reduces the macrocyclic antiaromaticity of the formed expanded carbaporphyrinoids.
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Catalyst-Controlled Formal [4+1] Annulation of N-Vinyl Fluorenone Nitrones and Allenoates to Prepare Spirofluorenylpyrrolines

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00224K, Research Article
Cui Wei, Jin-Qi Zhang, Jia-Jie Zhang, Cui Liang, Dong-Liang Mo
We report a readily commercial Gimeracil-catalyzed formal [4+1] annulation approach for the synthesis of spirofluorenylpyrrolines in good yields with high diastereoselectivity from easily available N-vinyl fluorenone nitrones and allenoates. The...
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A Vinylogous Michael Reaction of 2-Furanones Dimers to α, β-Unsaturated Nitroolefins for Constructing Chiral γ, γ-Disubstituted Butenolides

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00376J, Research Article
Zhushuang Bai, Cairong Zhang, Yongyi Chen, Aiqin Liu, Xinyu Wang, Chuna Yan, Xuechao Liu, Xiaoru Zhang, Ying Li, Ye Yuan, Zemei Ge, Jingxiang Pang, Yongshuai Chai, Xin Wang, Runtao Li
An efficient bifunctional thiourea catalyzed asymmetric vinylogous Michael addition of 2-furanones dimers to α, β-unsaturated nitroolefins has been developed to give the functional chiral γ,γ-disubstituted butenolides in good yields (up...
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Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00330A, Research Article
Satyasheel Sharma, Bharatkumar Chaudhary, Neeraj Kulkarni
The Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...
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Targeted Isolation of Two Disesquiterpenoids Macrocephadiolides A and B from Ainsliaea macrocephala using Molecular Networking-based Dereplication Strategy

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00030B, Research Article
Yong-Mei Ren, Shuaizhen Zhou, Tian Zhang, Meijia Qian, Rui Zhang, Sheng Yao, Hong Zhu, Chunping Tang, Ligen Lin, Yang Ye
A molecular networking-based dereplication strategy was applied to the phytochemical investigation of Ainsliaea macrocephala, leading to the isolation of two novel disesquiterpenoids macrocephadiolides A (1) and B (2). Their structures,...
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How to write and publish a scientific paper / Robert A. Day

Day, Robert A., 1924-




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Writing scientific papers in English : an ELSE-Ciba Foundation guide for authors / Maeve O'Connor and F.Peter Woodford

O'Connor, Maeve




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The art of scientific writing : from student reports to professional publications in chemistry and related fields / Hans F. Ebel, Claus Bliefert, William E. Russey

Ebel, Hans Friedrich




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How to write and publish a scientific paper / Robert A. Day

Day, Robert A., 1924-




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The chemist's English / Robert Schoenfeld

Schoenfeld, Robert




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A guide to scientific writing : manual for students and research workers / David Lindsay

Lindsay, David




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How to write & publish a scientific paper / by Robert A. Day

Day, Robert A., 1924-




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Writing scientific English : a textbook of English as a foreign language for students of physical and engineering sciences / John Swales

Swales, John




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A primer of mathematical writing : being a disquisition on having your ideas recorded, typeset, published, read and appreciated / Steven G. Krantz

Krantz, Steven G. (Steven George), 1951-




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A guide to scientific writing / David Lindsay

Lindsay, D. R




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Handbook of microscopy for nanotechnology / edited by Nan Yao, Zhong Lin Wang




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Nanotechnology and the environment : applications and implications / Barbara Karn ... [et al.], [editors]




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Introduction to nanoscale science and technology / edited by Massimiliano Di Ventra, Stephane Evoy. James R. Heflin




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Applied physics of carbon nanotubes : fundamentals of theory, optics and transport devices / S.V. Rotkin, S. Subramoney (eds.)




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Nanoscale calibration standards and methods : dimensional and related measurements in the micro- and nanometer range / edited by Günter Wilkening, Ludger Koenders




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Principles of nanotechnology : molecular-based study of condensed matter in small systems / G. Ali Mansoori

Mansoori, G. A. (G. Ali)




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Nanotechnology : environmental implications and solutions / Louis Theodore, Robert G. Kunz ; foreword - Rita D'Aquino

Theodore, Louis




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Nanotechnology : global strategies, industry trends and applications / edited by Jurgen Schulte




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Ordered porous nanostructures and applications / edited by Ralf B. Wehrspohn




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Nanostructured and advanced materials for applications in sensor, optoelectronic and photovaltaic technology / edited by A. Vaseashta, D. Dimova-Malinovska and J. M. Marshall

NATO Advanced Study Institute on Nanostructured and Advanced Materials for Applications in Sensors, Optoelectronic and Photovoltaic Technology (2004 : Sozopol, Bulgaria)




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Clusters and nano-assemblies : physical and biological systems / editors, P. Jena, S.N. Khanna, B.K. Rao




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How to write and publish a scientific paper / Robert A. Day and Barbara Gastel

Day, Robert A., 1924-




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Nanostructures & nanomaterials : synthesis, properties & applications / Guozhang Cao

Cao, Guozhong




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Micromanufacturing and nanotechnology / N.P. Mahalik (ed.)




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Nanodevices for the life sciences / edited by Challa S.S.R. Kumar




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Nanoscale devices : fundamentals and applications / edited by Rudolf Gross, Anatolie Sidorenko and Lenar Tagirov

NATO Advanced Research Workshop on Nanoscale Devices - Fundamentals and Applications (2004 : Kishinev, Moldova)




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Biomolecular computation for bionanotechnology / Jian-Qin Liu, Katsunori Shimohara

Liu, Jian-Qin




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Environmental applications of nanomaterials : synthesis, sorbents and sensors / editors, Glen E. Fryxell, Guozhong Cao




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Environmental nanotechnology : applications and impacts of nanomaterials / editors, Mark R. Wiesner, Jean-Yves Bottero




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Nanoethics : the ethical and social implications of nanotechnology / edited by Fritz Allhoff ... [et al.]




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Nanofabrication : fundamentals and applications / editor Ampere A. Tseng




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Carbon nanotube devices : properties, modeling, integration and applications / edited by Christofer Hierold




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The Oxford handbook of nanoscience and technology / edited A.V. Narlikar, Y.Y. Fu




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Inorganic nanowires : applications, properties, and characterization / M. Meyyappan, Mahendra Sunkara

Meyyappan, M




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Progress in nanotechnology. Applications




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What is nanotechnology and why does it matter? : from science to ethics / Fritz Allhoff, Patrick Lin, and Daniel Moore

Allhoff, Fritz




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Introduction to nanoscience / S.M.Lindsay

Lindsay, S. M. (Stuart Martin)




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Nanostructured titanium dioxide materials : properties, preparation and applications / Alireza Khataee, G. Ali Mansoori

Khataee, A. R. (Ali Reza), 1977-




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Nanotechnology intellectual property rights : research, design, and commercialization / Prabuddha Ganguli, Siddarth Jabade

Ganguli, Prabuddha




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Complex-shaped metal nanoparticles : bottom-up syntheses and applications / edited by Tapan K. Sau and Andrey L. Rogach ; with a foreword by Catherine J. Murphy




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Microfabrication for industrial applications / Regina Luttge

Luttge, Regina