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Gefitinib salts/cocrystals with phenolic acids as a promising solid-state approach to improve solubility

CrystEngComm, 2024, 26,2112-2122
DOI: 10.1039/D4CE00039K, Paper
Yao Zou, Xin Meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lu, Guanhua Du
In this study, we designed and synthesized a series of gefitinib (GEF) salts and cocrystals with phenolic acids, comprising two salts, one cocrystal, and two salt cocrystals. All these forms exhibited significant improvements in solubility compared to pure GEF.
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Coral-mimetic production of aragonite films from CO2 captured by biogenic polyamines

CrystEngComm, 2024, 26,2065-2071
DOI: 10.1039/D4CE00126E, Paper
Open Access
Kohei Takashina, Hiroto Watanabe, Yuya Oaki, Yoshikazu Ohno, Ko Yasumoto, Hiroaki Imai
We designed CaCO3 films comprised of aragonite nanorods by mimicking the microstructure and the formation process of the calcareous skeleton of a stony coral in the sea.
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A novel one-dimensional Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructure fabricated by a single-nozzle electrospinning technique and its low color drift property at high temperature

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00149D, Paper
Shanshan Cong, Zhuang Tian, Hongquan Yu, Sai Xu, Lihong Cheng, Baojiu Chen, Tianshuo Liu
1D Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructures were fabricated by a simple single-nozzle electrospinning method. These materials exhibit excellent luminescent stability and lower color drift performance at high temperatures.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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S-scheme heterojunction based on CuWO4/WO3 microspheres with improved photocatalytic property under visible light

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00301B, Paper
Yangang Sun, Jianhua Ge, jiaqi xu, Jinguo Wang
Dye wastewater green treatment has always been one of the research hotspots in the environmental protection and remediation field. The photocatalytic degradation and mineralization of organic dyes are considered to...
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3-(3,5-Dinitrophenyl)-5-amino-1,2,4-oxadiazole: synthesis, structure and properties of a novel insensitive energetic material

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00201F, Paper
Binshan Zhao, Baolong Kuang, Mou Sun, Tingwei Wang, Chao Zhang, Meiqi Xu, Cong Li, Zujia Lu, Jian-guo Zhang
A novel heat-resistant energetic compound 3-(3,5-dinitrophenyl)-5-amino-1,2,4-oxadiazole with low mechanical sensitivity on the basis of combining dinitrobenzene and aminooxadiazole was synthesized through a simple method in this work.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Highly efficient and durable P, Ru–CeO2 self-supporting electrodes toward industrial-level hydrogen production

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00143E, Paper
Wenguang Ma, Xiaodong Yang, Yanru Xu, Cuncheng Li, Yiqiang Sun, Qi Shen, Zhixin Sun
The electrolysis of seawater has become a preferred method for hydrogen production since the current shortage of freshwater resources, offering an effective strategy to address the energy crisis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Synthesis and photophysical properties of charge transfer cocrystals based on TCNB and fluorene and its derivatives

CrystEngComm, 2024, 26,2155-2165
DOI: 10.1039/D3CE01208E, Paper
Wenxiu Yao, Pengfei Wu, Yidan Xie, Xinyu Shen, Shuwei Xia, Liangmin Yu
A series of charge transfer cocrystals with fluorescence properties involving 1,2,4,5-tetracyanobenzene as acceptor, fluorene, 2-bromofluorene, carbazole and 2-bromocarbazole as donor were synthesized via cocrystal design strategies.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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The development of an approach for the precision determination of thermal strain tensor elements for single crystals using the example of t-Ag0.8Li0.2InSe2

CrystEngComm, 2024, 26,2207-2218
DOI: 10.1039/D3CE01186K, Paper
Polina S. Serebrennikova, Sergey I. Lobanov, Alexander S. Sukhikh, Lyudmila I. Isaenko, Sergey A. Gromilov
A new approach to the precision determination of single-crystal unit cell parameters is proposed and demonstrated using tetragonal Ag0.8Li0.2InSe2.
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Reddit protest: Why are thousands of subreddits going dark?

Starting next month, third-party app developers using Reddit's vast troves of data will have to pay a price and the changes could affect players across the spectrum




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Elon Musk weighs monthly user fees to fight X bot problem

Musk says that subscription for all users would make “the effective cost of bots” very high.




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Microblogging giant X and X Pro hit by global outage, users unable to access platforms

Reports from Downdetector.com revealed access issues, with X users unable to view posts and encountering a “Welcome to X!” message, while X Pro (previously TweetDeck) experienced loading problems displaying a “Waiting for posts” pop-up.




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India to register 14% growth in seafood exports products valued at close to $8.86 b in FY23

MPEDA looking to ramp up seafood exports into newer markets




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Industrial production grows at 12.3 per cent in June

IIP grew in double digit for the second month in a row due to strong performance by manufacturing, power and mining sectors




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India’s kharif rice, foodgrain production estimated lower than last year

First advance estimate pegs foodgrain output 6.12 mt lower; record maize, sugarcane crop likely




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Cabinet approves 50% incentive to manufacture semiconductors

‘The modifications will strengthen the semi-conductor scheme and raise capacities within the country’




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Windfall profit tax on crude oil hiked, levy on export of diesel cut

The export tax on jet fuel or ATF, which was set at ₹5 a litre in the last review on November 1, has not been altered




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Can climate-resilient farming become a profitable venture?  

The mantra of climate-resilient farming was simple but difficult to digest for traditional farming households




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Operating profit margin of 625 listed companies hits multi-year low

This, even as earnings jumped 27 per cent y-on-y, finds an ICRA study




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More than 5.57 lakh cos struck off due to non-compliance with companies law provisions

A special task force has recommended the use of certain red flag indicators as alerts to identify shell companies




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Steel ministry identifies infrastructure gaps in 38 projects

Of these, there are 11 new projects, while 27 are existing ones, according to an internal report by the Ministry




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Global headwinds, a challenge to India’s trade prospects in 2023

Successful implementation of FTAs, rupee trade, export schemes, PLI may provide relief




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Eyeing ethanol, sugar industry ramps up investments to improve cane yield

Move is part of ISMA’s efforts to divert sugar for ethanol production




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Eleven captive and commercial coal mines to begin production in FY23: IEA

IEA projects that India’s domestic supply will continue to grow in line with the steady increase in demand while also striving to reduce import dependency




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India-EU FTA: EU seeks ambitious commitments in government procurement, India resists

New Delhi unwilling to show flexibility in elements such as non-discrimination, dispute settlement




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Economic Survey: States taking new initiatives to improve their revenue sources

Some measures include increasing property tax and power tariffs and privatising state public sector enterprises




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Prolonged Persian Gulf crisis can affect India’s economic activity: FinMin

Depending on how the situation develops, crude oil prices may push higher, says Finance Ministry’s monthly economic review




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After weak December quarter, winter products begin seeing an uptick in demand

Demand for winterwear apparel segment has also witnessed an uptick in the past few days




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India to focus on climate finance, accountability, protection for vulnerable communities at COP29

India's national statement is scheduled for November 18-19




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Focus on One Health approach at veterinary science congress




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Waqf land issue: KCBC approaches Parliament committee directly

In a letter undersigned by KCBC president Cardinal Baselios Cleemis Catholicos, the council says enforcement of Waqf law has been causing hardships for over 600 families at Munambam




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Seaplane lands in Idukki with brighter tourism prospects

Trial run from Kochi to Mattupetty dam completed in 30 minutes. Tourism stakeholders say the service will be a game changer for a district that had no air connectivity hitherto




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Paddy procurement to be expedited soon: G.R. Anil




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Journalists protest against Union Minister Suresh Gopi’s ‘abhorrent behaviour’ towards media

Kerala Union of Working Journalists demands apology from Suresh Gopi, urges BJP to address Union Minister’s repeated confrontations with journalists




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Anxiety sweeps through upper Kuttanad as wait begins for payment of paddy procured

Over 1,061 tonnes of the 22,000 tonnes harvested this season has been procured so far. Yet, the farmers have received no payments




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Police, NMMC probe hand behind hoardings against Tukaram Mundhe




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No school for these kids (and their parents approve)

A small group of city parents are opting to home-school their children, rejecting the school system




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Marathas rev protest engines in city

Organisers claim 50,000 bikers participated in first mass agitation by the community in Mumbai, a ‘warm-up’ for a bigger one if the govt. fails to meet their demands, including for reservation




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HC directs Collector to probe encroachments on Mulund land




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Journos threaten to intensify protest if Tatas don’t remove Top Groups guards

MRA Marg police make two more arrests in connection with the assault on photojournalists




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State approves special bus service for women

Rs. 90-crore project to ply 300 buses in five civic bodies




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Man rapes 23-year-old in Nerul after promising job

Police working on call detail record to trace him




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No toll till Friday, police to protect banks, ATMs




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Maken cautions Goans against AAP’s promises ahead of Assembly election




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MHADA redevelopment: FSI to be proportionate to tenements, says govt.




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At APMCs, no takers for agricultural produce




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A perturbational approach for approximating heterogeneous agent models [electronic resource] / Anmol Bhandari, Thomas Bourany, David Evans, Mikhail Golosov

Cambridge, MA. : National Bureau of Economic Research, 2023