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Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals grown by travelling Te solution method

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00081A, Paper
Yuchen Song, Tingting Zhang, Jiahui Lv, Guorong Zhang, Changyou Liu, Tao Wang, Gangqiang Zha, Wanqi Jie
Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals were successfully grown by travelling Te solution method. The segregation of Mg with the growth of crystal is weaken and the as-grown crystal has high homogeneity.
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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The structural evolution of CL-20-based energetic host–guest solvates at decomposition temperature according to the perceptions of THz spectroscopy

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01310C, Paper
Lu Shi, XiaoHui Duan, Hongzhen Li
This work employed variable-temperature THz spectroscopy to analyze the structural evolution of host–guest energetic CL-20/H2O2 and CL-20/H2O solvates, as well as the mechanism of intermolecular interactions using DFT calculation and MD simulation.
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A novel one-dimensional Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructure fabricated by a single-nozzle electrospinning technique and its low color drift property at high temperature

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00149D, Paper
Shanshan Cong, Zhuang Tian, Hongquan Yu, Sai Xu, Lihong Cheng, Baojiu Chen, Tianshuo Liu
1D Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructures were fabricated by a simple single-nozzle electrospinning method. These materials exhibit excellent luminescent stability and lower color drift performance at high temperatures.
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First-principles prediction of a direct Z-scheme WSe2/HfS2 van der Waals heterostructure for overall photocatalytic water decomposition

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00267A, Paper
Yan Zhang, Zhi-Bo Qiang, Jian-Xin Ding, Kang-Xin Xie, Li Duan, Lei Ni
The direct Z-scheme heterostructures photocatalyst has been validated as an efficacious approach for addressing the energy source issues and environmental challenges. This manuscript employs the first-principles to scrutinize singular-layer WSe2...
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Evolution of fractal patterns in lead-free, zero-dimensional perovskite Cs2InBr5(H2O)

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00204K, Paper
Wanyin Ge, Yang Maohao, Masaki Saruyama, Kenshi Matsumoto, Ryota Sato, Haruka Takekuma , Ryo Takahata, Toshiharu Teranishi
The crystallization behavior of halide perovskites is of great significance. Fractal structures, featured by self-similarity between local morphology and global structures, have consistently captivated scientists’ interest across diverse disciplines. In...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced Zn ion storage performance of polypyrrole coated Mn3O4 composites electrode

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00252K, Paper
Shilong Li, Ming Zhao, Weichao Zhang, Xiang Wu
Aqueous zinc ion batteries (AZIBs) possess significant application potential in energy storage field due to their large capacity, low redox potential and high safety. Among various materials, Mn3O4 electrode has...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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Coordinatively unsaturated 5-nitroisophthalate based cobalt(II) coordination polymers: efficient catalytic CO2 fixation and Hantzsch condensation

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00102H, Paper
Subham Sahoo, Rajesh Patra, Debajit Sarma
Labile-coordinated water-based CPs have been synthesized. SSICG-6 serves as an excellent heterogeneous catalyst in CO2 cycloaddition and one-pot Hantzsch condensation reactions compared to other 1D-reported CPs due to the presence of OMSs.
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Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00221K, Communication
Open Access
Sumea Klokic, Benedetta Marmiroli, Denys Naumenko, Giovanni Birarda, Simone Dal Zilio, Miriam de J. Velásquez-Hernández, Paolo Falcaro, Lisa Vaccari, Heinz Amenitsch
Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage.
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3-(3,5-Dinitrophenyl)-5-amino-1,2,4-oxadiazole: synthesis, structure and properties of a novel insensitive energetic material

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00201F, Paper
Binshan Zhao, Baolong Kuang, Mou Sun, Tingwei Wang, Chao Zhang, Meiqi Xu, Cong Li, Zujia Lu, Jian-guo Zhang
A novel heat-resistant energetic compound 3-(3,5-dinitrophenyl)-5-amino-1,2,4-oxadiazole with low mechanical sensitivity on the basis of combining dinitrobenzene and aminooxadiazole was synthesized through a simple method in this work.
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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Flux growth and characterization of gallium-rare earth borates

CrystEngComm, 2024, 26,2180-2189
DOI: 10.1039/D3CE01269G, Paper
Victor V. Maltsev, Elizaveta V. Koporulina, Elena A. Volkova, Diana D. Mitina, Anna I. Jiliaeva, Vladimir L. Kosorukov, Alexey E. Afanasev, Daniil A. Naprasnikov
YGa3(BO3)4 single crystals were grown from a K2Mo3O10-based flux, and also RGa3(BO3)4 (R = Y, Pr–Yb) spontaneous crystals (RGB) were obtained by a high-temperature flux growth technique from a complex R2O3–Bi2O3–B2O3–Ga2O3 solvent.
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Effects of B2S3 additive on diamond crystallization at HPHT conditions

CrystEngComm, 2024, 26,2190-2196
DOI: 10.1039/D4CE00147H, Paper
Yong Li, Shuai Wang, Hongyu Xiao, Qiang Wang, Zhengguo Xiao, Yanchao She, Ying Wang
The color of the diamond obtained with the B2S3 additive changes from yellow to light blue and the resistivity of the synthesized diamond drops from 3.89 × 10 Ω cm to 2.51 × 10−1 Ω cm with the introduction of Ti/Cu into the synthetic cavity.
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Zuckerberg’s Threads could disrupt Musk’s Twitter

New platform garnered over 30 million users after its debut




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WhatsApp desktop users can now adjust text size

WhatsApp unveils the new feature for beta users




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Elon Musk says fight with Mark Zuckerberg will be live-streamed on X

Musk had tested a live video feature on X.




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Centre weighs new WFH rules for SEZs to balance needs of units, developers

IT firms units want WHF for more employees for a longer period, developers are concerned about losing customers for office space




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Live life king-size

Planning a trip to Europe? Skip the hotels and find a fairytale castle to stay in, writes SMITA TRIPATHI




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Can the Dark Sky Reserve at Hanle be a gamechanger for stargazing in India?

As Hanle in Ladakh is poised to have India’s first Dark Sky Reserve, prospects for stargazing and astro tourism shine bright




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Olympic gold medallist Neeraj Chopra sky dives, paraglides and hikes around Switzerland, between servings of fondue

The javelin thrower has been roped in as the Friendship Ambassador of Switzerland. He also donated his gold-winning javelin to the The Olympic Museum in Lausanne



  • Life & Style

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Data | Kerala tops the country in terms of citizens with passports

India ranks low in terms of visa-free/visa-on-arrival regimes for travellers in 2022




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This eatery in a Himalayan village serves pizza, but only by reservation

In Kasauli, Dochi Pizzeria & Coffee House is garnering popularity, with its owner claiming an average footfall of nearly 150 people every day



  • Life & Style

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ICAI launches new chapters in Florida and Zurich, expands global presence

ICAI’s network now spans 81 cities across 47 countries, comprising 52 chapters, 29 representative offices globally.




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Pinarayi thwarted chances of Dalit person becoming CM in future, alleges Kuzhalnadan




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₹19.70 lakh seized at Cheruthuruthy ahead of Chelakkara bypoll in Kerala

Seizure has raised suspicions and officials are investigating whether the money was intended for use in election-related expenses




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Senior citizen in bank queue collapses, dies




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Do surgical strike on Swiss banks, not on citizens: Uddhav




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With no leads, cops seek further forensic tests on seized RDX




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Financial aid and social mobility [electronic resource] : evidence from Colombia's Ser Pilo Paga / Juliana Londono-Velez, Catherine Rodriguez, Fabio Sanchez, Luis E. Alvarez-Arango

Cambridge, MA. : National Bureau of Economic Research, 2023




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The refugee advantage [electronic resource] : English-language attainment in the early twentieth century / Ran Abramitzky, Leah Platt Boustan, Peter Catron, Dylan Connor, Rob Voigt

Cambridge, MA. : National Bureau of Economic Research, 2023




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Financial Macroeconomics [electronic resource]/ edited by Jan A. Kregel, Felipe Rezende

La Vergne : Anthem Press, 2024.




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How costs limit contraceptive use among low-income women in the U.S [electronic resource] .: a randomized control trial / Martha J. Bailey, Vanessa Wanner Lang, Alexa Prettyman, Iris Vrioni, Lea J. Bart, Daniel Eisenberg, Paula Fomby, Jennifer Barber, Van

Cambridge, MA. : National Bureau of Economic Research, 2023




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Treatment for mental health and substance use [electronic resource] : spillovers to police safety / Monica Deza, Thanh Lu, Johanna Catherine Maclean, Alberto Ortega

Cambridge, MA.: National Bureau of Economic Research, 2024




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The shadow price of capital [electronic resource] : accounting for capital displacement in cost benefit analysis / Richard G. Newell, William A. Pizer, Brian C. Prest

Cambridge, MA. : National Bureau of Economic Research, 2023




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Elgar companion to Herbert Simon [electronic resource]/ edited by Gerd Gigerenzer (Herbert Simon Society; Max Planck Institute for Human Development, Berlin, Germany), Shabnam Mousavi (Center for Artificial Intelligence (CENTAI), Turin, Italy) and Riccar

Cheltenham, UK ; Northampton, Massachusetts : Edward Elgar Publishing, [2024]




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Bitcoin and carbon dioxide emissions [electronic resource] : evidence from daily production decisions / Anna Papp, Douglas Almond, Shuang Zhang

Cambridge, MA. : National Bureau of Economic Research, 2023




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Managing to learn [electronic resource] / Sabrin A. Beg, Anne E. Fitzpatrick, Adrienne Lucas

Cambridge, Mass. : National Bureau of Economic Research, 2023




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Bombay HC restricts Customs Dept. from destroying artworks by famous artists F. N. Souza and Akbar Padamsee

The artworks were seized in 2023 over allegations of obscenity




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Bombay High Court orders Customs Dept. to release artworks of Francis Newton Souza and Akbar Padamsee in next two weeks  

The High Court pulled up the Customs Department of Mumbai and said that every nude painting or every painting depicting some sexual intercourse poses cannot be styled as obscene




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Special court in Mumbai rejects Sachin Waze’s plea to turn approver in PMLA case  

The special court under the Prevention of Money Laundering Act rejected the application and said that prima facie, the Enforcement Directorate has sufficient evidence against Sachin Waze that is sufficient to show his involvement and other accused in the case. 




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Maharashtra polls: ₹17 lakh unaccounted cash seized from vehicle in Ulhasnagar

The seizure was made by flying squad number 6, operating in Ulhasnagar Assembly constituency, between Kalyan and Murbad at 2 a.m.




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Maharashtra Assembly polls: Diamonds, other jewellery worth ₹24 crore seized from car in Ahilyanagar toll booth

Election Commission’s SST seizes ₹24 crore worth of diamonds, gold, and silver near toll booth in Maharashtra




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Case against 5 members of flying squad for extorting ₹85,000 from bizman in Thane

Police in Thane, Maharashtra register case against poll squad members for extorting money from flower merchant




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Amazon’s new Bengaluru facility aims to empower underserved students with advanced technological skills

In its first such initiative in the country, Amazon Future Engineer Program has announced a free-of-cost facility in Bengaluru in partnership with The Innovation Story aimed to train underserved students in robotics, AI, and 3D printing