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A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system

Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article
Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)4]2− complexes within π-acidic cavities.
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An In situ Raman study of intermediate adsorption engineering by high-index facet control during the hydrogen evolution reaction

Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article
Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO2 nanosheets.
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Temperature-regulated construction of hierarchical titanosilicate zeolites

Inorg. Chem. Front., 2020, 7,1872-1879
DOI: 10.1039/D0QI00120A, Research Article
Yue Song, Risheng Bai, Yongcun Zou, Zhaochi Feng, Jihong Yu
A temperature-regulated method was developed to construct anatase-free hierarchical TS-1 zeolite catalysts by utilizing a two-step hydrothermal crystallization strategy with tetrabutylammonium hydroxide as the sole organic template.
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Ligand substitution induced single-crystal-to-single-crystal transformations in two Ni(II) coordination compounds displaying consequential changes in proton conductivity

Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article
Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Coral-like ZnFe2O4–ZnO mesoporous heterojunction architectures: synthesis and enhanced sensing properties for triethylamine

Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article
Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe2O4–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
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Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Electrochemical behavior of NiCl2/Ni in acidic AlCl3-based ionic liquid electrolyte

Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article
Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl2 cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl2 during discharging in acidic AlCl3-based electrolyte.
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Restricted active space simulations of the metal L-edge X-ray absorption spectra and resonant inelastic X-ray scattering: revisiting [CoII/III(bpy)3]2+/3+ complexes

Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article
Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Luminescent metal–organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants

Inorg. Chem. Front., 2020, 7,1801-1821
DOI: 10.1039/D0QI00167H, Review Article
Partha Samanta, Sumanta Let, Writakshi Mandal, Subhajit Dutta, Sujit K. Ghosh
This review aims to provide an overview regarding the development of luminescent metal–organic frameworks (LMOFs) based sensory materials for the detection of cationic inorganic and organic water pollutants.
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Highly efficient CO2 capture and conversion of a microporous acylamide functionalized rht-type metal–organic framework

Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article
Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO2-philic acylamide groups exhibits high performance for CO2 capture, separation and chemical conversion.
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A new honeycomb metal–carboxylate-tetrazolate framework with multiple functions for CO2 conversion and selective capture of C2H2, CO2 and benzene

Inorg. Chem. Front., 2020, 7,1957-1964
DOI: 10.1039/D0QI00181C, Research Article
Gang-Ding Wang, Yong-Zhi Li, Wen-Juan Shi, Lei Hou, Zhonghua Zhu, Yao-Yu Wang
A stable Cd-MOF was built by a carboxylate-tetrazolate ligand, which contains hexagonal channels and reveals multiple functions including separation of CO2/CH4, C2H2/CO2, C2H2/CH4 and benzene/cyclohexane, and catalytic conversion of CO2 with epoxides.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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π-Type halogen bonding enhanced the long-lasting room temperature phosphorescence of Zn(II) coordination polymers for photoelectron response applications

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article
Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Evolution of D6R units in the interzeolite transformation from FAU, MFI or *BEA into AEI: transfer or reassembly?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00359J, Research Article
Juan Zhang, Yueying Chu, Feng Deng, Zhaochi Feng, Xiangju Meng, Feng-Shou Xiao
The formation and evolution of building units for zeolites play an important role during crystallization.
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An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Interconnected porous nanoflakes of CoMo2S4 as an efficient bifunctional electrocatalyst for overall water electrolysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article
Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo2S4 are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Mechanism of oxygen vacancy assisted water-splitting of LaMnO3: Inorganic perovskite prediction for fast solar thermochemical H2 production

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article
Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Cyclometalated Ir(III) Complexes Towards Blue-Emissive Dopant for Organic Light-Emitting Diodes: Fundamentals of Photophysics and Designing Strategies

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article
Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Aerobic Oxidation Catalyzed by Polyoxometalates Associated to an Artificial Reductase at Room Temperature and in Water

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article
Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

1 videodisc (101 min.) : sound, color ; 4 3/4 in




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Roxanne [videorecording] / Columbia Pictures presents a Daniel Melnick Indieprod & LA Films production ; screenplay by Steve Martin ; produced by Michael Rachmil & Daniel Melnick ; directed by Fred Schepisi

1 videodisc (approximately 107 min.) : sound, color ; 4 3/4 in




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Crimson tide [videorecording] / Hollywood Pictures presents a Don Simpson/Jerry Bruckheimer production ; produced by Don Simpson, Jerry Bruckheimer ; story by Michael Schiffer and Richard P. Henrick ; screenplay by Michael Schiffer ; directed by Tony Scot

1 videodisc (116 min.) sound, color; 4 3/4 in




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Professor Marston and the Wonder Women [videorecording]/ Annapurna Pictures presents in association with Stage 6 Films ; a Topple Pictures & Boxspring Entertainment production ; produced by Terry Leonard, Amy Redford ; written and directed by Angela R

1 videodisc (approximately 108 minutes) : sound, color ; 4 3/4 in




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We cannot run away to moon, need to develop herd immunity: Epidemiologist

Muliyil tells Somesh Jha that the days of eradicating the disease is over and the country should move towards developing 'herd immunity'




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‘The Two Popes’ Pits Tradition Against Progress

What the new Netflix drama can teach us about the interdependency of orthodoxy and reform.




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Netflix’s ‘Messiah’ Says the World Needs a Savior

The problem is, which one?




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Article :: An Introduction to MySQL

See how to define a simple table using MySQL’s allowed data types and other properties and learn how to interact with the MySQL server using two different client applications.




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Article :: Visualization and Sketching

In this sample chapter from Modern Graphics Communicaiton, 5th Edition, learn how to visualize and sketch objects in three dimensions to communicate your ideas quickly and accurately.




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Article :: Sketchnoters' Stories: 8th-grader Allison Huang revolutionizes her school notes with sketchnotes

We are excited to share this story about Allison Huang, an eighth grader passionate about sketchnoting. This is her story about discovering and integrating sketchnoting as a powerful tool for the way she thinks in school and in her life.




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Article :: Using Animation Presets

When you apply an effects preset, it can contain multiple effects that already use specific settings and may be a combination of effects that produce a specific result. In this sample chapter from Learn Adobe After Effects CC for Visual Effects and Motion Graphics, learn how to save time with animation presets.




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Single-parent house tied to hypertension in offspring




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How nutrition and diet can influence autoimmune diseases




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Compounds in plastic, cosmetic lotion affects fertility in men






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Statins may lead to consumption of more fats, cholesterol




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British experiment shows food companies can help to reduce hypertension




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A test for early detection of Alzheimer’s




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A new kind of mammography test to improve detection rate




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In manuka honey, find solution to digestive disorders




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Drumsticks: One solutions to several health problems





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Sugar addiction is key contributor to heart disease, cancer risk




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Regulate iron content to ‘switch on’ cellular functions




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Exercise may protect against depression




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Treat food addiction to combat obesity epidemic




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Great vacation? Don’t brag to your friends




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Transfer addiction: Off drugs, onto cupcakes