el Apple now lets app developers apply to be featured on the App Store By techcrunch.com Published On :: Wed, 13 Nov 2024 16:09:17 +0000 App developers now have a new way to promote their app launches, updates, and other new features on Apple’s App Store. First announced at the company’s Worldwide Developers Conference in June, Apple this week introduced a “Featuring Nominations” option in App Store Connect, which is the service developers use to submit their apps, games, and […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Apps app store Apple developers Marketing
el Haribhau S/O Rajaram Telgote And 2 ... vs The State Of Maharashtra Thr. Pso, Ps, ... on 13 November, 2024 By indiankanoon.org Published On :: Extreme penalty provided under the Indian Penal Code (IPC) i.e. Death Penalty imposed by the Sessions Judge is placed before us for scrutiny due to mandate of Section 366 of the Code, as well as by virtue of appeal preferred by the accused in terms of Section 374[2] of the Code of Criminal Procedure (Cr.P.C.) 2. Appellant Nos.1 to 3 were tried and convicted by the Additional Sessions Judge, Akot vide judgment and order dated 17.05.2024 in Sessions Case No.57/2015 for the offence punishable under Sections 302 read with Section 34 of the IPC and Section 506 [Part-II] read with Section 34 of the IPC. Though they have also been charged for the offence punishable under Section 323 of the Indian Rgd. Full Article
el The State Of Mah. Thr. Psops Hivarkhed ... vs Haribhau Rajaram Telgote And 2 Others on 13 November, 2024 By indiankanoon.org Published On :: Extreme penalty provided under the Indian Penal Code (IPC) i.e. Death Penalty imposed by the Sessions Judge is placed before us for scrutiny due to mandate of Section 366 of the Code, as well as by virtue of appeal preferred by the accused in terms of Section 374[2] of the Code of Criminal Procedure (Cr.P.C.) 2. Appellant Nos.1 to 3 were tried and convicted by the Additional Sessions Judge, Akot vide judgment and order dated 17.05.2024 in Sessions Case No.57/2015 for the offence punishable under Sections 302 read with Section 34 of the IPC and Section 506 [Part-II] read with Section 34 of the IPC. Though they have also been charged for the offence punishable under Section 323 of the Indian Rgd. Full Article
el Bgsctpl- Mskel Consortium,,Ahmedabad vs The Income Tax Officer, Ward-10(1),, ... on 7 November, 2024 By indiankanoon.org Published On :: These four appeals filed by two separate assessees have arisen from separate appellate orders passed by learned Commissioners of Income-tax (Appeals), Ahmedabad for the assessment years, 2010-11 & 2011-12. 2. Since facts and issues involved in all these four appeals are similar which is agreed to by both the rival parties before us and that these four appeals were heard together, we deem it appropriate to dispose of all these appeals by this consolidated order for the sake of brevity and convenience. We will first take up the appeal of the assessee in ITA No. 2498/Ahd/2013 for A.Y. 2010-11, and our decision in this appeal shall apply mutatis mutandis to remaining three appeals. Full Article
el Bgsctpl- Mskel (Jv),Ahmedabad vs The Income Tax Officer, Ward-5(2)(1),, ... on 7 November, 2024 By indiankanoon.org Published On :: These four appeals filed by two separate assessees have arisen from separate appellate orders passed by learned Commissioners of Income-tax (Appeals), Ahmedabad for the assessment years, 2010-11 & 2011-12. 2. Since facts and issues involved in all these four appeals are similar which is agreed to by both the rival parties before us and that these four appeals were heard together, we deem it appropriate to dispose of all these appeals by this consolidated order for the sake of brevity and convenience. We will first take up the appeal of the assessee in ITA No. 2498/Ahd/2013 for A.Y. 2010-11, and our decision in this appeal shall apply mutatis mutandis to remaining three appeals. Full Article
el Hitesh Jogenderlal Rajpal vs Externel Affairs on 9 November, 2024 By indiankanoon.org Published On :: The applicant, an Indian Foreign Service (IFS) Officer of 2006 batch has approached this Tribunal by way of the captioned Original Application (OA), filed under Section 19 of the Administrative Tribunals Act, 1985 to challenge the Office Memorandum dated 17.06.2022 (Annexure-A/1(i)) vide which respondent no. 1 has proposed to hold an inquiry against him under Rule 14 of the Central Civil Services (Classification, Control and Appeal) Rules, 1965 and further to challenge the communication dated 16.05.2023 (Annexure-A/1(ii)) vide which the recommendations of the DPC in his respect for promotion to Grade-III of IFS for the panel year 2023 has been kept in "sealed cover". 2. In the OA, the applicant has prayed for the following reliefs and interim relief: Full Article
el Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "What kind of punishment is sanctioned by the law for any Pilot who gets the RTR permit or licence on the basis of false documents?" The CPIO, Sr. DWA (COP & regulations) vide letter dated 05.10.2023 replied as under:- "- Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convinced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
el Shiv Kumar vs Office Of The Chief Minister Delhi on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 31.05.2023 seeking the following information: Page 1 of 3 "1- द ल सरकार के SC/ST DEPARTMENT 2018,2019,2020,2021,2022 तक कतना फ ड पछले चार साल म कतनी योजनाओंपर खच कया है उसक" पण ू जानकार द जाये 2- द ल सरकार ने 2014 से 2022 तक अपने व'ापन पर कतना फ ड द ल व ् द ल से बाहार खच कया है उसक" जानकार द जाये 3- द ल के मु+यमं ,ी ने JANUARY 2014 से 2023 JANUARY तक द ल से बाहार के दोरो पर कतना फ ड खच कया है उसक" जानकार द जाये 4- द ल सरकार ने पछले 8 साल म वधायक. को गाडी खर दने के 0लए कतना फ ड दया है उसक" जानकार द जाये" Full Article
el Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "To, Shri Umang Srivastva Sr.DWA (COP) I had complained on 05/05/2023 against Rahul Sinha regarding his COP permit. What action or inquiry has been conducted in this regard?" The CPIO, Sr DWA (COP & Regulation) vide letter dated 05.10.2023 replied as under:- "Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA, JWA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convir.ced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
el Vishnu Kumar Kashram Patel vs Department Of Scientific & Industrial ... on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 10.07.2023 seeking information on following points:- "(1) Copy of filled up application form in which my name & designation is mentioned submitted by Avani seeds Ltd, Ahmedabad to Department of Scientific and Industrial Research to get In-house R &D Units certificate issued in FY 2019 (on March 2019 vide certificate F.No.TU/TV- RD/4444/2019). (2) Copy of filled up application form in which my name & designation is mentioned submitted by Avani seeds Ltd, Ahmadabad to Department of Scientific and Industrial Research to get In-house R&D Units certificate issued in FY 2021." Full Article
el Shakeel Akhtar vs North Western Railway on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 08.05.2023 seeking the following information: Page 1 of 5 "1 रे ल्वे वर्कशॉप लाल गठ इस्तिथ तटोर मे चिुथक श्रेणी र्मकचारी सुमेर पुत्र अमजद अली निवासी सवोदय बतिी बीर्ािेर र्े इस र्ायाकलय मे र्ब पदभार ग्रहण कर्या, प्रमाणणि प्रनि। 2 सुमेर द्वारा नियुस्ति र्े समय प्रतिुि समति दतिावेजो र्ी प्रमाणणि प्रनिललपप। 3 सुमेर र्ो नियुस्ति आदे श एव पदभार ग्रहण र्रिे र्े आदे श र्ी प्रमाणणि प्रनि।" The CPIO furnished a reply to the Appellant on 25.05.2023 stating as under: "उपरोति संदलभकि पत्र र्े माध्यम से आवेदि र्िाक द्वारा मांगी गई जािर्ारी िि ृ ीय पक्षर्ार से सम्बस्धिि होिे र्े र्ारण आरटीआई अधिनियम 2005 र्े नियम सख्या 11 र्े िहि प्रदाि िही र्ी जा सर्िी।" Full Article
el Lalit Kumar vs Delhi Metro Rail Corporation on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (online) RTI application dated 23.03.2023 seeking the following information: Page 1 of 5 "In continuation to RTI Application No- DMRCP/R/E/22/00489, received to you dated 15-11-2022 please provide some more details which were not given, related to the same points mentioned below: 1. My policy number of superannuation (GSPS) is 321581 and my LIC ID is 1779. Please provide my annuity number for the same. 2. In my last application number stated above I desired for DMRC pay scale comparison with the CDA pay scale which was denied to me. As an exemployee of your prestigious organization, I can help, it is available at D2 in the HR Manual- A Compendium of service rules in DMRC. Kindly provide. Full Article
el R S Bhati vs Office Of The Chief Minister Delhi on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 06.02.2023 seeking the following information: Page 1 of 7 " नवेदन यह है क नेह वहार वाड मु तफाबाद वधान सभा म कर ब चार वष पहले सीवर क" लाईन डाल गई थी और अब सीवर क" लाइन से घर-घर तक सीवर कने*शन का काम चल रहा है । सीवर लाइन के -.येक मैन होल म घर0 म कने*शन करने के 1लए चार चीनी के पाइप लगाए गए थे। इ3ह ं पाइप0 म घर0 के कने*शन जोड़ने थे। ले कन उन चीनी पाइप0 से कने*शन नह ं 8दए जा रहे ह9 और म9ने होलो म कने*शन दे ने के 1लए नये सरु ाख करके पाईप लगाये जा रहे ह9 और नये सरु ाख0 क" मर;मत भी नह ं क" जा रह है और जो पहले से ह -.येक मैन होलो म चार पाईप लगाये गये ह9। उन पाईप0 से 1स वर ओवर=लो होने पर पानी अ3दर ह अ3दर मकान0 क" नींव म जाएगा। और कने*शन के 1लये अब नये पाईप डाले जा रहे ह9 वह रोड से एक से डेढ़ फुट गहराई पर ह9 और जो मकान नीचे पड़ गए ह9 उनका 1सवरे ज का पानी म9न होल म नह जायेगा। और मैन होल म जो नए सरु ाख कये गये है उनसे मैनहोल बहुत कमजोर हो गये है अतः Aीमान जी से नवेदन है क R.T.I Act न;न1लBखत सच ू ना दे ने क" कृEया करे । Full Article
el Vânzările globale de automobile electrice și hibride, în creștere cu 35% în octombrie By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:11:40 +0000 Vânzările globale de automobile complet electrice şi vehicule hibride de tip plug-in au crescut cu 35% în luna octombrie a acestui an comparativ cu aceeaşi lună a anului trecut, graţie în primul rând unui salt de 54% al vânzărilor de pe piaţa chineză, arată cifrele publicate de firma de cercetare de piaţă Rho Motion. Potrivit ... The post Vânzările globale de automobile electrice și hibride, în creștere cu 35% în octombrie appeared first on Forbes Romania. Full Article Actualitate autovehicule electrice Rho Motion sondaj EV vehicule hibride
el Eurostat: România a fost al șaptelea producător agricol din UE în 2023 By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:14:46 +0000 Valoarea producţiei agricole a blocului comunitar a scăzut cu 1,5% în 2023, comparativ cu 2022, până la 537,1 miliarde de euro, însă România se numără printre ţările UE a căror valoare a producţiei agricole a crescut de la un an la altul, arată datele publicate miercuri de Eurostat. Scăderea uşoară din 2023 vine după o ... The post Eurostat: România a fost al șaptelea producător agricol din UE în 2023 appeared first on Forbes Romania. Full Article Actualitate Eurostat producator agricol Romania UE
el Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională By www.forbes.ro Published On :: Wed, 13 Nov 2024 15:06:09 +0000 Pehart Grup, una dintre cele mai mari companii producătoare de hârtie tissue din Sud-Estul Europei, celebrează tradițiile românești prin cea de-a doua ediție a campaniei naționale Pufina Tradiții Românești. După ce anul trecut, de 1 Decembrie, producătorul a dat startul campaniei naționale Pufina Tradiții Românești, anul acesta, la debutul lui noiembrie a lansat cea de-a ... The post Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională appeared first on Forbes Romania. Full Article Actualitate Pehart Grup producator de hartie Pufina traditii romanesti
el Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie By www.forbes.ro Published On :: Wed, 13 Nov 2024 16:55:16 +0000 Grupul Bitdefender, cea mai importantă companie din domeniul tehnologiei cu sediul central în România, a înregistrat venituri nete de 391,9 milioane de dolari, în creștere cu 16% comparativ cu anul anterior, și un profit operațional ajustat (EBITDA) de 85 de milioane de dolari, cu 21,7% mai mare decât în 2022. Florin Talpeș, CEO și cofondator ... The post Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii Tech
el Wayanad Chelakkara Byelection 2024: ചേലക്കരയിൽ പോളിംഗ് ശതമാനത്തിൽ റെക്കോഡ് വർധനവ്; വയനാട്ടിൽ പോളിങ് കുത്തനെ ഇടിഞ്ഞു By zeenews.india.com Published On :: Wed, 13 Nov 2024 20:20:08 +0530 തെരഞ്ഞെടുപ്പ് കമ്മീഷന്റെ അന്തിമ കണക്ക് പ്രകാരം വയനാട്ടിൽ 64.53 ആണ് പോളിങ് ശതമാനം. Full Article
el Lovely 3D: മാത്യുവിന്റെ നായികയായി 'ഈച്ച'; മലയാളത്തിൽ വീണ്ടുമൊരു ഹൈബ്രിഡ് ചിത്രം, വരുന്നു 'ലൗലി 3D' By zeenews.india.com Published On :: Wed, 13 Nov 2024 14:13:28 +0530 Lovely 3D: അടുത്ത വർഷം ജനുവരിയിലായാണ് സിനിമയുടെ റിലീസ്. Full Article
el Hello Mummy: കോമഡിയും ഹൊററും ഫാന്റസിയും ചേർന്ന കിടിലൻ ട്രെയിലർ; 'ഹലോ മമ്മി' തിയേറ്ററുകളിലേക്ക് By zeenews.india.com Published On :: Wed, 13 Nov 2024 20:18:16 +0530 നവംബർ 21നാണ് ചിത്രം തിയേറ്ററുകളിലെത്തുന്നത്. ജോമിൻ മാത്യു, ഐബിൻ തോമസ്, രാഹുൽ ഇ. എസ് ചേർന്നാണ് ചിത്രം നിർമ്മിക്കുന്നത്. Full Article
el Delhi becomes world's most polluted city, overtakes Pakistan's Lahore, AQI recorded at... By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:46:22 GMT At 9 am on Wednesday, the air quality was 'very poor' with a reading of 366 which later rose to 418. Full Article India
el Highly selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00364K, Research ArticleZhongwen Liu, Ming Li, Shuai Fang, Li Shao, Bin Hua, Feihe HuangHerein the selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals is investigated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00140K, Research ArticleQun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin ZhangHere, an unprecedented one-step modular construction of C2-symmetric N-PACs through reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be converted into a powerful organic photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00421C, Research ArticleCarina Mützel, Kazutaka Shoyama, Ana-Maria Krause, Frank WürthnerA doubly helical boron-doped polycyclic aromatic hydrocarbon was synthesized, which showed a low LUMO level, a high absorption coefficient and fluorescence (ΦF = 0.73), combined with a one-dimensional π–π stacking interaction in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Regio- and stereo-selective synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QO02078A, Research ArticleYunqing Zhuang, Jin Zhang, Kai Yang, Gehua Bi, Xin Huang, Weimin ZhangAn efficient and novel method for the direct synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00148F, Research ArticleDong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei XuThe challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00358F, Research ArticleShan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui ShaoChiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00312H, Research ArticleFang-Fang Xu, Zhong-Lei Ruan, Pei-Qiang HuangWe report a highly efficient, versatile, and chemoselective method for the catalytic reduction of sulfoxides to sulfides under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00171K, Research ArticleLi-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei WuA method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Iodine-catalyzed intermolecular 1,2-thio (seleno)amination of alkenes with 1,2,3-triazoles and disulfides (diselenides) in air By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00246F, Research ArticleJian Ji, Xuwen Chen, Zongjing Hu, Cong Guan, Jinhua Liu, Yaqi Deng, Shunying LiuIodine-catalyzed 1,2-thio (seleno)amination of alkenes via direct N- and C-centered radical cross-coupling was established to elicit highly regioselective β-triazolized thioalkyl compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Nickel metallaphotoredox-catalyzed C–O bond activation/Csp2–Csp3 coupling enabled by phosphine By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00310A, Research ArticleJiaxi Fang, Ziheng Jian, Huan Liu, Yuting Wang, Xianbo Yu, Zehuai Mou, Huifei WangA novel and general nickel/photoredox dual catalysis platform for benzyl alcohol C–O bond activation/Csp2–Csp3 cross coupling of benzothiazolyl bromide and free alcohol, enabled by the catalytic generation of an alkyl radical, is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Electrochemical switching in mechanically interlocked molecules (MIMs) By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00061G, Review ArticleAyush Bhadani, Murugavel KathiresanMechanically interlocked molecules (MIMs) which include rotaxanes and catenanes are formed by the mechanical linking of two or more components and has the ability to switch between different states in the presence of an external stimuli.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Three-component Friedel–Crafts-type difunctionalization of ynamides with (hetero)arenes and iodine(III) electrophile By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00489B, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jun Kikuchi, Toya Nagata, Shingo Ito, Naohiko YoshikaiA three-component Friedel–Crafts type difunctionalization of ynamides with an iodine(III) electrophile and electron-rich (hetero)arenes has been developed, enabling regio- and stereoselective synthesis of densely functionalized enamides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Correction: Stereodivergent and enantioselective total syntheses of isochaetominines A–C and four pairs of isochaetominine C enantiomers: a six-step approach By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO90034K, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhong-Yi Mao, Hui Geng, Tian-Tian Zhang, Yuan-Ping Ruan, Jian-Liang Ye, Pei-Qiang HuangTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Sulfamide instead of urea in Biginelli reaction: from black box to reality By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2155-2160DOI: 10.1039/D3QO01926H, Research ArticleAlexander Yu. Lyapunov, Andriy V. Tarnovskiy, Sergey Yu. Boron, Eduard B. Rusanov, Galyna P. Grabchuk, Dmytro M. Volochnyuk, Serhiy V. RyabukhinThe scope and limitations of the classical Biginelli reaction have been expanded to principally novel substrates: sulfamide and its monosubstituted analogues.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2344-2350DOI: 10.1039/D3QO01955A, Research ArticleLinge Huai, Li Zhang, Zhentao Wang, Yewen FangN → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2171-2177DOI: 10.1039/D3QO02029K, Research ArticleRong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo HanAn asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2277-2282DOI: 10.1039/D3QO01999C, Research ArticleYan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang MoWe describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Visible light/copper catalysis enabled Heck-like coupling between alkenes and cyclic sulfonium salts via selective C–S bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2195-2200DOI: 10.1039/D3QO02009F, Research ArticleXianqin Liu, Xufeng Li, Linyuan Wang, Yongjia Shi, Jian Lv, Daoshan YangA Heck-like coupling of cyclic sulfonium salts with alkenes via selective C–S bond cleavage using a copper complex as a photosensitizer through a visible-light-driven redox-neutral process has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Electrode-switchable: exploring this new strategy to achieve regiodivergent azidoiodination of alkenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2189-2194DOI: 10.1039/D3QO01935G, Research ArticleXin-Lei Sun, Chen-Xi Xia, Yue Ren, Yu-Jin Li, Zhi-Qian Cao, Ling-Guo MengAn “electrode-switchable” organic electrochemistry method for the azidoiodination of alkenes, where the choice of anode dictates the regiodivergent alkene azidoiodination, reveals a novel pathway for controlled regioisomers.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2313-2318DOI: 10.1039/D4QO00116H, Research ArticleZhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong XueThe selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2269-2276DOI: 10.1039/D4QO00073K, Research ArticleYujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang LuTwo major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2231-2240DOI: 10.1039/D4QO00177J, Research ArticleRomain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas PoissonHerein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Regioselective electrochemical cascade C–H sulfonylation–bromination of indolizines to access difunctionalized indolizines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2306-2312DOI: 10.1039/D4QO00035H, Research ArticleWenxuan Jiang, Xiang Liu, Chuanying Zhu, Meiyi Chen, Weidan Li, Hua CaoRegioselective electrochemical C–H sulfonylation–bromination between indolizines, sodium sulfinates, and KBr has been established in an undivided cell, in which KBr serves as both the brominating agent and electrolyte.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Electrochemical remote C(sp3)–H thiocyanation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2283-2288DOI: 10.1039/D4QO00032C, Research ArticleXinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li, Weisi GuoAn electrochemical thiocyanation of distal C(sp3)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Nickel/photoredox-catalyzed carbonylative transformations of α-phosphorus-, α-sulfur-, and α-boron-substituted alkyl halides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2297-2305DOI: 10.1039/D4QO00167B, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Le-Cheng Wang, Xiao-Feng WuA novel dual nickel/photoredox catalyzed direct amino- and alkoxycarbonylation of α-heteroatom substituted organohalides has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Assembly of ionic supramolecular polymers using a decacationic pillar[5]arene to noncovalently crosslink hyaluronic acid for short DNA delivery By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00447G, Research ArticleQian Li, Danying Ma, Yue-Yang Liu, Hui Wang, Wei Zhou, Dan-Wei Zhang, Zhan-Ting LiA multicationic pillar[5]arene noncovalently crosslinks hyaluronic acid to afford ionic supramolecular polymers for intramolecular delivery of short DNA.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Selective deletion of one carbon atom from C60 through benzylamine mediated reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00449C, Research ArticleYaqiong Wang, Yiran Wu, Yuming Yu, Jie Su, Yi Qiu, Liangbing GanBenzylamine selectively adds to one of the two carbonyl groups on the 9-membered orifice to form an N,O-aminal moiety. Subsequent oxidation and hydrogen atom transfer lead to a decarboxylation process and formation of a nor [59]fullerene derivative.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00351A, Research ArticleFei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng ZhuLovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
el Concise synthesis of succinimide-fused densely 1,3-cyclohexadienes via Co-catalyzed [2+2+2] cycloaddition of 1,6-diynes and maleimides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00435C, Research ArticleJinhui Cai, Kaili Cen, Ziyi Zhai, Yuan Liu, Jiahao Wei, Mixia Ouyang, Guojun He, Shuyu Huang, Feng ZhaoHerein, we report a new route towards succinimide-fused densely 1,3-cyclohexadienes through the reaction of 1,6-diynes with electron-deficient alkenes under cobalt catalysis. This method shown high efficiency, wide substrate scope, good...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article