In a process for producing polyethylene having a molecular weight of at least 3×105 g/mol as determined by ASTM 4020, ethylene is contacted under polymerization conditions with a slurry of a catalyst composition in at least one hydrocarbon. The catalyst composition comprises a Group 4 metal complex of a phenolate ether ligand and the slurry includes from about 5 to less than 40 ppm per liter of a compound effective to increase the conductivity of said at least one hydrocarbon.

Polyolefin production using an improved catalyst system and, in particular, a method for production of a polyolefin is disclosed. One or more monomers are contacted with a catalyst system. The catalyst system includes titanium tetrachloride as a catalyst precursor and magnesium ethylate as a support for the catalyst precursor. The catalyst system also includes a hydrocarbyl aluminum cocatalyst represented by the formula R3Al, where R is an alkyl radical having 1 to 14 carbon atoms, and where the molar ratio of the hydrocarbyl aluminum cocatalyst to the titanium tetrachloride catalyst precursor ranges from 50:1 to 400:1. The catalyst system also includes a halogenated hydrocarbon as a promoter, where the molar ratio of the halogenated hydrocarbon promoter to the titanium tetrachloride catalyst precursor ranges from 0.001:1 to 300:1.

The present invention provides a diene polymer in which a polar functional group is introduced into an end by radical polymerization, and its production method; a polymer emulsion and a rubber composition each containing the diene polymer; and a pneumatic tire containing the rubber composition. The present invention relates to a diene polymer, which is obtained by radical polymerization of at least one radical polymerizable monomer in the presence of at least one polar functional group-containing thiol compound, and has a polar functional group at at least one end: The polar functional group-containing thiol compound is preferably represented by formula (1): X—R1—SH (1) wherein X represents an ester group, a hydroxyl group, a carboxyl group, an amino group, or an alkoxysilyl group, and R1 represents an alkylene or arylene group which may have a substituent.

The invention relates to free-radical polymerization and free-radical cross-linking and more particularly provides a process of free-radical polymerization or cross-linking wherein at least one polymerizable monomer or at least one compound to be cross-linked is contacted in the presence of at least one selected organic peroxides, characterized in that the organic peroxide is prepared continuously by an ex situ process with the aid of a closed plate exchanger. In the process according to the invention, it's possible to introduce the above selected organic peroxide continuously during the polymerization or cross-linking reaction.

A magnetic particle-polymer hybrid material can include: a substance having a structure of Formula 1 or derivative or salt thereof:Z(Y-Triazole-CH2—X—CH2—(FP)n)m (Formula 1), wherein Z is a magnetic particle smaller than 1 mm; n and m are independently integers; Y includes a first linker having an alkyl and/or aryl linked to the magnetic particle; X is CH2 or a heteroatom; FP is a functionalized polymer having: a first structure derived from a first norbornene compound linked to the magnetic particle through the Y-Triazole-CH2—X—CH2 linker; and one or more monomeric units each including a second structure derived from a second norbornene compound, where one of the monomeric units is linked to the first structure through a saturated or unsaturated alkyl, each monomeric unit includes a functional group capable of binding with another substance.

The present invention is directed to a copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diolefin monomer and optionally at least one vinyl aromatic monomer; and a polymeric side-chain bonded exclusively to a terminal end of the backbone chain, the side-chain comprising a polymer derived from a monomer having a hydrogen bond donor moiety and a hydrogen bond acceptor moiety.

The present description relates to an olefin block copolymer preferably useful to form nonslip pads due to excellences in elasticity and heat resistance, and a sheet-shaped molded body comprising the olefin block copolymer The olefin block copolymer includes a plurality of blocks or segments, each of which includes an ethylene or propylene repeating unit and an α-olefin repeating unit at different weight fractions. The olefin block copolymer satisfies a defined relationship when a load of 5 to 10 kg is applied to a sheet-shaped molded body of the block copolymer for 12 hours or longer at a temperature of 60° C. or higher, and then removed.

A strap comprising a propylene and 1-hexene copolymer containing from 0.3 wt % to less than 5 wt % of 1-hexene derived units said copolymer having a melt flow rate (MFR) determined according to ISO method 1133 (230° C., 2.16 kg ranging from 0.3 to less than 11 g/10 min.

Process for the preparation of etherified melamine/formaldehyde condensates, in which first a methylolation of melamine with a formaldehyde component in the molar ratio of from 1:6 to 1:15, preferably at a pH of >7, is carried out. This is followed by an etherification of the resulting hydroxymethylation intermediate in the presence of a C1-C20-alkyl, preferably of a C1-C6-alcohol, particularly preferably of a C1-C4-alcohol, at a pH of 9.5 being established before, during and/or after the distillation. According to the invention, a plurality of hydroxymethylation, etherification and distillation steps follow in order to achieve an etherified melamine/formaldehyde condensate which is distinguished by a high degree of hydroxymethylation, a high solids content and a low viscosity.

An ion conducting membrane for fuel cells involves coupling a compound having a sulfonic acid group with a polymeric backbone. Each of the compounds having a sulfonic acid group and the polymeric backbone are first functionalized with a halogen.

The present invention relates to a polymer composition comprising polylactide and, based on the weight of this polymer, from 17 to 25 wt % of a chain modifier, from 30 to 55 wt % of an elastomeric polymer and from 20 to 45 wt % of a plasticizer. The invention also relates to the method of preparing said composition as well as to the method of manufacturing an article starting from said composition and the article per se.

To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20° C., monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.

The present invention provides polymerization processes utilizing an ansa-metallocene catalyst system for the production of olefin polymers. Polymers produced from the polymerization processes have properties that vary based upon the presence or the absence of hydrogen and/or comonomer in the polymerization process.

The present invention relates to a process for preparing a diene elastomer. The invention especially applies to the production of a polybutadiene with a high level of cis-1,4 linkages that has at the same time a Mooney viscosity ML (1+4) greater than or equal to 40, a polydispersity index less than 2.1 and a reduced cold flow and of a polyisoprene. The process according to the invention comprises a reaction of a catalyst system with at least one conjugated diene monomer, this catalyst system being based on at least: one conjugated diene;one organic phosphoric acid salt of one or more rare-earth metals, said salt being in suspension and in at least one saturated and aliphatic or alicyclic, and inert hydrocarbon-based solvent;one alkylating agent composed of an alkyl aluminum for formula AlR3 or HAlR2 anda halogen donor belonging to the family of alkylaluminium halides, with the exclusion of alkylaluminium sesquihalides. This process comprises a separate bringing together of the monomer(s) to be polymerized with at least one alkylaluminium compound of formula AlR3 or HAlR2 which is identical or not to the alkylating agent of said catalyst system, said amount being chosen as a function of the characteristics of the polymerization medium and/or the polymerization conditions and/or said elastomer to be obtained.

A method for preparing a catalyst system for heterogenous catalysis of an isobutylene polymerization reaction includes the steps of forming an alumina support in which the alumina support has pores formed therein, and reacting BF3/methanol catalyst complex with the alumina support. The ratio of methanol to BF3 in the catalyst complex ranges from 0.5 moles to 2 moles of methanol per mole of BF3. The alumina support is formed so as to have pores each having a diameter of greater than twenty nanometers. The alumina support can be in the form of beads or extrudates having a length significantly greater than a diameter. The extrudate can also have a tri-lobe configuration.

A true tetrafluoroethylene (TFE) copolymer of the fine powder type is provided, wherein the copolymer contains polymerized comonomer units of at least one comonomer other than TFE in concentrations of at least or exceeding 1.0 weight percent, and which can exceed 5.0 weight percent, wherein the copolymer is expandable, that is, the copolymer may be expanded to produce strong, useful, expanded TFE copolymeric articles having a microstructure of nodes interconnected by fibrils. Articles made from the expandable copolymer may include tapes, membranes, films, fibers, and are suitable in a variety of end applications, including medical devices.

The invention relates to a method for preparation of platinum siloxane compounds containing at least one CO ligand molecule (Pt carbonyl siloxanes). The method comprises reacting gaseous carbon monoxide (CO) with a platinum siloxane compound, preferably a platinum vinyl-cyclosiloxane compound, in solution with an organic solvent. The method is straightforward and applicable to industrial scale. With this method, specific isomers of platinum carbonyl vinylcyclosiloxanes are prepared, in which the two η-2-ethenyl groups coordinated to the Pt atom are bonded in trans-configuration relative to the cyclosiloxane backbone. The Pt compounds obtained by the method are used as catalysts for hydrosilylation and for crosslinking and curing of siloxanes and silanes.

A road safety barrier having a plurality of ropes supported by posts rigidly mounted on or in the ground is described. Each rope is held in tension against the posts and supported in a notch or groove in a side of the posts. The ropes are released from a post and the post is not pulled from the ground when a vertical force is exerted on the rope. The ropes when weaved are tensioned against the posts and this gives use to a combined frictional resistance to displacement of the ropes relative to each post along the length of the safety barrier. The structure of at least some of the posts and/or their mounting with respect to the ground defines a minimum bending yield strength in a direction along the length of the barrier. This minimum bending yield strength is greater than the bending moment resulting from the combined frictional resistance forces acting on the post.

A method of constructing a pump island protector to alleviate continuous maintenance required for a deteriorating existing steel pump island base, and a pump island protector constructed by the method. Using an adjustable form system and the combination of stainless steel members and new concrete, the existing pump island is re-wrapped with the stainless steel member and the new concrete.

A method of constructing a pump island protector to alleviate continuous maintenance required for a deteriorating existing steel pump island base, and a pump island protector constructed by the method. Using an adjustable form system and the combination of stainless steel members and new concrete, the existing pump island is re-wrapped with the stainless steel member and the new concrete.

An auxiliary member for pavement construction, including: a cylinder, a base plate and a leveling bolt; the cylinder includes a first cylinder part and a second cylinder part which are connected and communicated with each other, the first cylinder part is provided with a sling installing member and a slurry inlet, bottom of the second cylinder part is connected with the base plate, the base plate is provided with a bolt extending hole and multiple slurry discharging holes which are communicated with the inner cavity of the second cylinder part, the leveling bolt includes a bolt head and a screw, the screw extends through the bolt extending hole, the bolt head is arranged in the second cylinder part and the bolt head is smaller than the inner diameter of the second cylinder part. The present invention further provides a concrete slab and a method for pavement construction.

A storm grate locking device and method of use with a lock body. The lock body has at least one hook arm engaged with a latch assembly, a security flange nut engaged with the latch assembly, and a deep well socket. When the lock body is placed into the recessed area of a storm grate; and the hook arm engaged with the latch assembly may be extended to extend under the storm grate thereby preventing removal of the storm grate by rotating the security flange nut.

A surface drainage structure formed above a subgrade may include an elongate drain conduit disposed partially within the subgrade. The elongate drain conduit may define at least one drain slot extending through a wall thereof. The structure may include a pavement layer with an exposed top surface and a drainage channel extending therefrom. The drainage channel may be in fluid communication with the drain slot of the elongate drain conduit. A method of forming the surface drainage structure includes placing the elongate drain conduit in the subgrade, forming the pavement layer, cutting an upper channel along the elongate drain conduit, and cutting a lower channel and the drain slot in the elongate conduit.

A form-fitting connection between two components (5 and 14) has a break-away function in one direction. At least one connection element, designed as a shear bolt (6), is formfittingly connected to the first component (5) to be connected. The end of the shear bolt (6) is formfittingly and functionally connected to a second component (14) via an attached component (17) that is resilient in the direction of the formfitting connection.

A grader blade mounted to a support frame has an auger-grinder mounted ahead of the grader blade. The auger-grinder has a first helical vane fixed to a rotatable axle with a plurality of teeth attached to and protruding outwardly from the auger. A shroud above and partially surrounding the auger-grinder has an inner shroud end wall, an outer shroud end wall and bearings in which the axle is journaled transverse to the direction of travel. A beater is fixed to the axle between an inner end of the helical vane and the inner wall. The beater has a plurality of paddles extending outwardly from the axle. An inner barrier wall is attached to the inner shroud wall and extends forward of the auger-grinder. A drive link is connected to the axle for connection to a prime mover for driving the axle in rotation.

A mobile thermoplastic applicator comprises a kettle, a main gas burner, a heat exchanger plenum, and a screed die box. The kettle has walls which define an interior space for melting thermoplastic. The main gas burner is situated beneath the kettle, and is configured to heat the kettle. The heat exchanger plenum is situated inside the thermoplastic kettle and is configured to subdivide the interior space and circulate heated air from the main gas burner. The screed die box is configured to receive molten thermoplastic from the kettle and deposit that molten thermoplastic on a surface.

A track system may include a plurality of connected slat members that may form rollable tracks. The rollable tracks may be used in moving vehicles across sensitive ground. The rollable track may be deployed using various methods and/or apparatus such as, e.g., deployment apparatus including one or more spool portions for rolling and unrolling the rollable tracks.

A method for laying down a pavement in which a compaction unit such as a tamper pre-compacts the paving material with a selectable stroke and at a selectable frequency while the pavement having a selectable pavement thickness is in the process of being laid down at a selectable paving speed, the stroke of the compaction unit is automatically adjustable in response to paving parameters, such as the paving speed and/or the pavement thickness, along a characteristic curve or in a characteristic map. The compaction unit includes an adjusting mechanism which is operable during the paving operation for adjusting the stroke of the compaction unit.

A system for converting an existing traffic intersection into an intersection having a roundabout traffic control feature includes a center island framework, one or more splitter island frameworks, and one or more diverter frameworks. The frameworks are secured to the road surface, and fill material is added to free spaces defined in the frameworks to thereby form a center island, one or more splitter islands, and one or more diverters. The system allows a roundabout to be implemented into an existing intersection on a temporary or semi-permanent basis, in a minimal amount of time and without requiring significant construction at the site of the intersection.

A system for measuring the height of paving material distributed by an auger of a paving machine in front of a grading implement, such as a screed, is disclosed. The system includes a sonic sensor and a laser pointer. The sonic sensor generates a sonic signal which is directed at the paving material distributed by the auger. The laser pointer generates a laser beam which is similarly directed at the paving material that has been distributed by the auger. The laser beam and the sonic signal meet at a common position on the paving material.

Disclosed is an automotive road construction machine, particularly a recycler or a cold stripping machine, comprising an engine frame that is supported by a chassis, a working roller which is stationarily or pivotally mounted on the engine frame and is used for machining a ground surface or road surface. The chassis is provided with wheels or tracked running gears which are connected to the engine frame via lifting column and are vertically adjustable relative to the engine frame. Each individually vertically adjustable lifting column is equipped with a device for measuring the actual vertical state of the lifting column.

A system and method are provided for coupling a manhole cover to an underground utility box to support the manhole cover substantially flush with a ground surface such as a roadway. A holder couples to an underground utility box and includes upper and lower ends and a channel extending therebetween, and a support structure extending into the channel and defining an upwardly facing support surface. An adjustment member for coupling to a manhole cover is inserted within the channel, and includes upper and lower ends, and a passageway extending therebetween and communicating with the channel. The adjustment member is movably receivable within the channel to be seated on the support surface, and to define an adjustment space between the adjustment member and the holder. The adjustment member may thus be adjusted for accommodating a slope and elevation of a ground surface, and sealed with the holder after adjustment.

A method for installing a paver system includes positioning a first grid substrate adjacent to a second grid substrate, the first and second grid substrates form a paver support surface. At least the first grid substrate includes an integrated boundary ridge extending along the first paver support surface. The first grid substrate is interlocked with the second grid substrate with a first paver piece bridging the first and second grid substrates to form a paver linkage. Movement of at least the first paver piece is arrested beyond the integrated boundary ridge by directly or indirectly engaging at least the first paver piece against the integrated boundary ridge. In another example, movement of the first paver piece is arrested by anchoring at least the first paver piece on the first and second paver support surfaces through distribution of forces incident on at least the first paver piece through the paver linkage.

A method and a system for applying a road surface using a mixing plant for producing laying material, a road finishing machine processing the laying material to a road surface, and a supply chain transporting the laying material from the mixing plant to the road finishing machine. Request commands are transmitted from the road finishing machine to the mixing plant and/or to the supply chain, and, depending on these request commands, the production rate of the laying material in the mixing plant, the temperature of the laying material produced in the mixing plant, and/or the mass flow of laying material supplied to the road finishing machine per time unit by means of the supply chain are adjusted.

A combined stair screed and float device for quickly and efficiently spreading and smoothing wet concrete comprising a generally shoe shaped member with a vertically and horizontally adjustable top guide and base bar to rest on riser forms. In operation, a user rests the top guide and the base bar on two riser forms with a pointed corner finder floating over the concrete at the desired corner position. The user grasps a grip portion and a handle and guides the device across the tread in a simultaneous screed and float step preparing a smooth surface for finishing. The device is both vertically and horizontally adjustable to accommodate a full range of conceivable step heights, tread lengths, toe kick overhang lengths, and corners.

This invention provides a modular ducting section and a networked utilities ducting system and rain and road water management system formed from two or more modular ducting sections laying end-to-end. Each modular ducting section comprises open-topped utility channels for carrying utility service supply lines such as electricity, gas, water, or communications, an open-topped catchment channel for carrying rain water captured from a building structure or garden, and a supply channel for supplying an end user with utility services via a supply line, while also allowing the end user to feed an end-user generated utility supply back into the corresponding utility service supply line via a return line. Each modular ducting section further comprises a road water runoff flange and a main channel cover, which when combined, form a curb-side structure that functions to keep any contaminated road water from the reusable rain water collected in the catchment channel.

A method of repairing cracks in a paved surface includes identifying at least one crack in the surface that needs to be repaired. The crack is then filled with an asphalt sealer including approximately 40-55% by weight of slag sand.

A manhole cover assembly includes a manhole structure, a manhole frame carried by the manhole structure and a manhole frame grout cementing the manhole frame to the manhole structure. The manhole frame grout includes a grout mixture having an epoxy resin, a curing agent and an aggregate. The epoxy resin and the aggregate are present in the grout mixture in an epoxy resin:aggregate weight ratio of about 0.09. A removable manhole cover is carried by the manhole frame. A manhole cover assembly fabrication method is also disclosed.

The present invention provides a system and method for controlling an asphalt repair apparatus. An additional aspect of the present invention is to provide a system that may position a heater repair element adjacent a targeted asphalt surface, acquire and analyze surface and heater sensing data, and control heater output to prepare the targeted asphalt surface for repair. Further, the system may be configured to control an asphalt repair apparatus to satisfy user-defined asphalt repair requirements.

A concrete finishing machine includes a mobile frame supported above the slab on front and rear wheels with at least one screed roller and a plurality of vibrators are suspended from the frame between the front and rear wheels. The front and rear wheels are rotatable at least ninety degrees between a longitudinally directed traveling orientation and a laterally directed concrete finishing orientation. The front and rear wheels are driven and steerable so that the mobile frame may travel longitudinally down a lane of a road, and then upon pivoting of the wheels, move laterally over a hole in an adjacent lane having uncured concrete to be finished by the finishing machine.

The present invention relates to a stripping device for a drum of a soil compaction roller, in particular, a stripping device for a drum of a trench roller, wherein the stripping device comprises a first scraping element disposed on a drum surface. The drum surface is provided with protrusions disposed on the periphery of the drum surface, wherein a drum extender is adapted to be attached to the drum. Provision is also made for the stripping device to have a second scraping element which is mounted on the first scraping element in an axially displaceable manner, wherein the second scraping element is adapted for attachment to the first scraping element by means of at least one fixing means.

A vibratory compactor having a first compacting element having a variable vibratory mechanism that sets a modifiable compaction effort, a second compacting element, a first sensor configured to measure a first surface compactability associated with the first compacting element, a second sensor configured to measure a second surface compactability associated with the second compacting element and a control system. The control system is configured to receive the first surface compactability, receive the second surface compactability, determine a target compaction effort for the first compacting element based on the first surface compactability and the second surface compactability, and modify the variable vibratory mechanism to set the compaction effort at the target compaction effort.

In a method of milling asphalt, a relative elevation of an unmilled asphalt pavement surface adjacent to an area to be milled is sensed with respect to a milling machine body and rotatable milling drum of the milling machine. An elevation of a bottom surface of the rotatable milling drum is determined using a computer processor. Based on a map, stored in a computer memory, of a design surface specifying a design elevation of a milled surface over the area to be milled, the elevation of the milling machine body and the rotatable milling drum are automatically adjusted such that the rotatable milling drum mills the asphalt surface to the design elevation over the area to be milled.

An apparatus and method to install contraction joints in concrete slabs. The method uses a device, which inserts a strip of plastic or paper tape into freshly laced concrete, as the device is driven across a concrete slab. The tape is folded immediately prior to being inserted into freshly placed concrete, and functions to weaken the slab at the contraction joint location for the purpose of causing a crack to form in the slab. Plastic tape can be used, which functions as a moisture vapor retarder, and thereby, protects floor coverings from moisture damage, such as mold and mildew, at contraction joint locations.

A paver for laying down a strip of concrete and inserting therein dowel bars parallel to the strip. A dowel bar inserter orients the bars and places them into the concrete. A pair of transport chains transverse to the travel direction extends across a width of the inserter. Pairs of generally L-shaped opposing cups hold the bars so that they can drop downwardly from the cups towards the strip. The chains move in a single direction. A dowel bar holding magazine, above the chains, stores bars, and gravitationally moves the bars towards the chains for pick-up by cups as the chains move the cups past a bar loading station. Elastic bands extend about a bar engaging surface defined by a wheel and resiliently bias the bars moving along the chain turn-around section against the wheel.

A compaction device includes at least one traveling drum rotatable about a drum shaft and having vibration exciters including unbalanced masses rotating out of phase by 180 degrees in the same direction of rotation and generating an oscillation torque about the drum shaft, and having a drive shaft running coaxial to the drum shaft for driving the vibration exciters. The drum is divided at least once and each drum part includes at least two coupled vibration exciters mounted at a distance from the drum shaft in the drum.

Disclosed is a pencil-type case for allowing pressing a pressure button to discharge liquid content out to a content brush. The container for dispensing a preset quantity of liquid content accommodated in a main body by pressing a pressure button. The container includes: main body including content case to accommodate content in outer body and having pushing member; pumping member including: folding link driven by pressure button; check valve preventing content from flowing backward when content is introduced into cylinder tube via content-introducing hole formed in cylinder tube, and piston pumping content out to content brush of content brush body; and content brush body including: content-introducing tube in which check valve is installed; cam surface adjusting stroke of folding link; and content brush provided at leading end to discharge content of content-introducing tube.

A plastic pencil comprising a writing core, an interlayer coating material placed about the writing core, a porous casing enclosing the interlayer coating material on the writing core and a covering applied to the exterior surface of the porous casing.

A structure for mounting a clip for a writing implement which has a barrel extending along a longitudinal axis. The structure includes a fastening member made of plastic material integral with the barrel and having a proximal wall and a distal wall with respect to the barrel, the proximal and distal walls being arranged opposite each other and overall extending in substantially parallel respective planes in order to form between them a recess having an open insertion end. The clip includes a fastening portion having a substantially uniform thickness and is suitable for mounting in the recess by the open insertion end.

A package for two liquid personal care compositions, including an applicator, a first reservoir, and a second reservoir. The applicator is non-removably connected at and extends away from the first cavity. The first and second reservoirs each hold a quantity of a liquid composition therein. The first reservoir includes an open end sized for independent insertion and removal of the applicator therethrough. The first reservoir is removable and protectively encases the applicator. The second reservoir includes a closed end an opposing open end, through which a liquid composition can be dispensed.