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Eloquent spaces: meaning and community in early Indian architecture / [edited by] Shonaleeka Kaul

Rotch Library - NA1502.E46 2019




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[ASAP] Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

Organometallics
DOI: 10.1021/acs.organomet.9b00792




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[ASAP] Breaking Scaling Relationships in CO<sub>2</sub> Electroreduction with Isoelectronic Analogs [Fe<sub>4</sub>N(CO)<sub>12</sub>]<sup>-</sup> and [Fe<sub>3</sub>MnO(CO)<sub>12</sub&

Organometallics
DOI: 10.1021/acs.organomet.9b00848




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[ASAP] Quantifying the Electronic and Steric Properties of 1,3-Imidazole-Based Mesoionic Carbenes (iMICs)

Organometallics
DOI: 10.1021/acs.organomet.0c00045




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[ASAP] Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere

Organometallics
DOI: 10.1021/acs.organomet.9b00815




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[ASAP] Activation of C–C Bonds via s-Bond Metathesis: Hydroborenium-Catalyzed Hydrogenolysis of Cyclopropanes

Organometallics
DOI: 10.1021/acs.organomet.0c00099




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[ASAP] Metal-Free Room-Temperature Phosphorescence from Amorphous Triarylborane-Based Biphenyl

Organometallics
DOI: 10.1021/acs.organomet.0c00068




ed

[ASAP] Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation

Organometallics
DOI: 10.1021/acs.organomet.0c00148




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[ASAP] Electrochemical CO<sub>2</sub> Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00129




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[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




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[ASAP] Dibromine Promoted Transmetalation of an Organomercurial by Fe(CO)<sub>5</sub>: Synthesis, Properties, and Cytotoxicity of Bis(2-C<sub>6</sub>H<sub>4</sub>-2'-py-<italic toggle="yes">?C,N</

Organometallics
DOI: 10.1021/acs.organomet.0c00107




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[ASAP] Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization

Organometallics
DOI: 10.1021/acs.organomet.0c00112




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[ASAP] Potentiostatically Controlled Olefin Metathesis

Organometallics
DOI: 10.1021/acs.organomet.0c00052




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[ASAP] [2 + 2] Cycloaddition of <italic toggle="yes">o</italic>-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes

Organometallics
DOI: 10.1021/acs.organomet.0c00163




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[ASAP] Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00154




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[ASAP] Fe(0)-Mediated Reductive Disproportionation of CO<sub>2</sub>

Organometallics
DOI: 10.1021/acs.organomet.0c00175




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[ASAP] S<sub>N</sub>2 and E2 Branching of Main-Group-Metal Alkyl Intermediates in Alkane CH Oxidation: Mechanistic Investigation Using Isotopically Labeled Main-Group-Metal Alkyls

Organometallics
DOI: 10.1021/acs.organomet.0c00120




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[ASAP] Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based <italic toggle="yes">N</italic>^<italic toggle="yes">N</italic><sup><italic tog

Organometallics
DOI: 10.1021/acs.organomet.0c00161




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[ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency

Organometallics
DOI: 10.1021/acs.organomet.0c00117




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[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




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[ASAP] C–F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

Organometallics
DOI: 10.1021/acs.organomet.0c00176




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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




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[ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

Organometallics
DOI: 10.1021/acs.organomet.0c00196




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[ASAP] Improving Redox Reversibility and Intermetallic Coupling of Co(III) Alkynyls through Tuning of Frontier Orbitals

Organometallics
DOI: 10.1021/acs.organomet.0c00183




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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




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[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




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[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] C5 Metalation of Imidazole-Based Monothiolates en Route to Selenothiolates

Organometallics
DOI: 10.1021/acs.organomet.0c00201




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Mixed Bag

Episode #016 sees us discussing the recent Generate Conference in London, Shopify’s amazing Build a Business annual contest, faces for apps, Happy Cog giving us insights into their workflow and a couple of revisits including Editorially and Draft.




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So Entitled?

As we reach the ripe old age of 30 we sit back and chat about a topic we often come back to over an artisinal flat white – why do people think everything on the web “should” be free? We discuss some possible causes, the backlash against app developers charging for previously free tools and ponder if the rise of big VC has played it’s part too.

Oh and yes there’s yet more microphone drama. All will be explained next week. As always we do apologise for the disruption to the service.

If you like our show please feel free to leave us a review on iTunes.




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We Don&#8217;t Need no Education

I’ll say this — time off between episodes certainly gives us plenty to talk about. In our 45th, almost hour–long, outing behind the mics we welcome new members to “the club“, discuss Kieran’s move into the world of coffee capsule commerce, ponder on new forms of web education, and learn more what Kieran receives in the post!




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The Future of Medium?

Happy New Year to you all! Rather unsurprisingly we missed our end of year review but the outline was probably one of our best. Maybe we’ll do it next year!

This episode we catch up on Kieran’s move behind the camera, argue over what exactly constitutes a pair of Daps and delve into the future of Medium in light of Ev Williams recent announcement.

If you like the show don’t forget you can support our astronomical S3 costs by becoming an exclusive member of the Back to Front Show Club!




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Kieran&#8217;s Big Red Button

It’s hard to believe it’s only been one week, no really, since our last confession. Where does the time go?

In this episode we catch up on what’s happened in our lives in the last seven days, discuss the latest goings on at Medium, ponder why the Guardian doesn’t write listicles and end on probably the best API in the world!




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Gujarat HC allows an accused bail for Ramzan

The Gujarat high court has granted temporary bail to a murder accused to observe fasts during the holy month of Ramzan. He will have to surrender to jail on May 25, after Eid-ul-Fitr.​




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Saurashtra on edge over infection due to influx

The district administration in Saurashtra is jittery fearing import of coronavirus cases into the district with the permission for intrastate travel granted by the state government. Jamnagar, which had only one Covid case till now reported five new cases in the past one week.




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Ahmedabad lockdown: Today's news from the city




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'Pvt hosp staff at par with govt medical staff'




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Covid-19 medical staff to get addl compensation

The Amdavad Municipal Corporation (AMC) has decided to give additional financial compensation to health and paramedical staff of AMC and private designated Covid-19 hospitals who contact coronavirus infection on duty.




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Ahd Covid-19 waste peaked to 8,422kg in 1 day

On March 24, when the lockdown was imposed, the total biomedical Covid waste incinerated in Ahmedabad that day was 82kg. The waste was mainly from the initial admissions at SVP Hospital,




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Ahd: Patient’s death discovered 7 hours later

In an incident that raises serious questions about Covid-19 care centres run by the city civic body, a 27-year-old coronavirus positive man died in his bed after suffering seizure at room 808-Block G3, at Samras Covid-19 care centre in Navrangpura. Only asymptomatic patients are isolated here so that they can be monitored and sent to hospital if they develop symptoms, or discharged when they turn negative.




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Ahmedabad lockdown: Today's updates

Amid prevalent chaos and uncertainty over access to the essential services and commodities during the lockdown, we bring you the latest updates from your city.




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Ahmedabad: 3,175 beds arranged in 104 hotels

The Ahmedabad Municipal Corporation, which had marked four hotels as Covid care centres till now, will now have 100 more hotels with a bed capacity of 3,175 for the purpose. In another important development, the civic body has planned a massive sanitization campaign in AMC areas from Saturday.




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Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Humin based resin for wood modification and property improvement

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03620B, Paper
Open Access
Anna Sangregorio, Anitha Muralidhara, Nathanael Guigo, Lisbeth G. Thygesen, Guy Marlair, Carlo Angelici, Ed de Jong, Nicolas Sbirrazzuoli
Focus on humins, a co-product from sugar conversion, to highlight their capacity to impregnate wood cell walls for making durable wood products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00885K, Critical Review
Siavash Iravani, Rajender S. Varma
Recent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry